Frost

Frost is a layer of ice on a solid surface, which forms from water vapor that deposits onto a freezing surface. Frost forms when the air contains more water vapor than it can normally hold at a specific temperature. The process is similar to the formation of dew, except it occurs below the freezing point of water typically without crossing through a liquid state.

Air always contains a certain amount of water vapor, depending on temperature. Warmer air can hold more than colder air. When the atmosphere contains more water than it can hold at a specific temperature, its relative humidity rises above 100% becoming supersaturated, and the excess water vapor is forced to deposit onto any nearby surface, forming seed crystals. The temperature at which it will form is called the dew point, and depends on the humidity of air. When the temperature of the air drops below its dew point, excess water vapor is forced out of solution, resulting in a phase change directly from water vapor (a gas) to ice (a solid). As more water molecules are added to the seeds, crystal growth occurs, forming ice crystals. Crystals may vary in size and shape, from an even layer of numerous microscopic-seeds to fewer but much larger crystals, ranging from long dendritic crystals (tree-like) growing across a surface, acicular crystals (needle-like) growing outward from the surface, snowflake-shaped crystals, or even large, knifelike blades of ice covering an object, which depends on many factors such as temperature, air pressure, air motion and turbulence, surface roughness and wettability, and the level of supersaturation. For example, water vapor adsorbs to glass very well, so automobile windows will often frost before the paint, and large hoar-frost crystals can grow very rapidly when the air is very cold, calm, and heavily saturated, such as during an ice fog.

Frost may occur when warm, moist air comes into contact with a cold surface, cooling it below its dew point, such as warm breath on a freezing window. In the atmosphere, it more often occurs when both the air and the surface are below freezing, when the air experiences a drop in temperature bringing it below its dew point, for example, when the temperature falls after the sun sets. In temperate climates, it most commonly appears on surfaces near the ground as fragile white crystals; in cold climates, it occurs in a greater variety of forms. The propagation of crystal formation occurs by the process of nucleation, in specific, water nucleation, which is the same phenomenon responsible for the formation of clouds, fog, snow, rain and other meteorological phenomena.

The ice crystals of frost form as the result of fractal process development. The depth of frost crystals varies depending on the amount of time they have been accumulating, and the concentration of the water vapor (humidity). Frost crystals may be invisible (black), clear (translucent), or, if a mass of frost crystals scatters light in all directions, the coating of frost appears white.

Types of frost include crystalline (hoar frost or radiation frost) from deposition of water vapor from air of low humidity, white frost in humid conditions, window frost on glass surfaces, advection frost from cold wind over cold surfaces, black frost without visible ice at low temperatures and very low humidity, and rime under supercooled wet conditions.

Plants that have evolved in warmer climates suffer damage when the temperature falls low enough to freeze the water in the cells that make up the plant tissue. The tissue damage resulting from this process is known as "frost damage". Farmers in those regions where frost damage has been known to affect their crops often invest in substantial means to protect their crops from such damage.

If a solid surface is chilled below the dew point of the surrounding humid air, and the surface itself is colder than freezing, ice will form on it. If the water deposits as a liquid that then freezes, it forms a coating that may look glassy, opaque, or crystalline, depending on its type. Depending on context, that process may also be called atmospheric icing. The ice it produces differs in some ways from crystalline frost, which consists of spicules of ice that typically project from the solid surface on which they grow.

The main difference between the ice coatings and frost spicules arises because the crystalline spicules grow directly from desublimation of water vapour from air, and desublimation is not a factor in icing of freezing surfaces. For desublimation to proceed, the surface must be below the frost point of the air, meaning that it is sufficiently cold for ice to form without passing through the liquid phase. The air must be humid, but not sufficiently humid to permit the condensation of liquid water, or icing will result instead of desublimation. The size of the crystals depends largely on the temperature, the amount of water vapor available, and how long they have been growing undisturbed.