Ice

Ice is water that is frozen into a solid state, typically forming at or below temperatures of 0 °C, 32 °F, or 273.15 K. It occurs naturally on Earth, on other planets, in Oort cloud objects, and as interstellar ice. As a naturally occurring crystalline inorganic solid with an ordered structure, ice is considered to be a mineral. Depending on the presence of impurities such as particles of soil or bubbles of air, it can appear transparent or a more or less opaque bluish-white color.

Virtually all of the ice on Earth is of a hexagonal crystalline structure denoted as ice I_h (spoken as "ice one h"). Depending on temperature and pressure, at least nineteen phases (packing geometries) can exist. The most common phase transition to ice I_h occurs when liquid water is cooled below 0 °C (273.15 K, 32 °F) at standard atmospheric pressure. When water is cooled rapidly (quenching), up to three types of amorphous ice can form. Interstellar ice is overwhelmingly low-density amorphous ice (LDA), which likely makes LDA ice the most abundant type in the universe. When cooled slowly, correlated proton tunneling occurs below −253.15 °C (20 K, −423.67 °F) giving rise to macroscopic quantum phenomena.

Ice is abundant on the Earth's surface, particularly in the polar regions and above the snow line, where it can aggregate from snow to form glaciers and ice sheets. As snowflakes and hail, ice is a common form of precipitation, and it may also be deposited directly by water vapor as frost. The transition from ice to water is melting and from ice directly to water vapor is sublimation. These processes play a key role in Earth's water cycle and climate. In the recent decades, ice volume on Earth has been decreasing due to climate change. The largest declines have occurred in the Arctic and in the mountains located outside of the polar regions. The loss of grounded ice (as opposed to floating sea ice) is the primary contributor to sea level rise.

Humans have been using ice for various purposes for thousands of years. Some historic structures designed to hold ice to provide cooling are over 2,000 years old. Before the invention of refrigeration technology, the only way to safely store food without modifying it through preservatives was to use ice. Sufficiently solid surface ice makes waterways accessible to land transport during winter, and dedicated ice roads may be maintained. Ice also plays a major role in winter sports.

Ice possesses a regular crystalline structure based on the molecule of water, which consists of a single oxygen atom covalently bonded to two hydrogen atoms, or H–O–H. However, many of the physical properties of water and ice are controlled by the formation of hydrogen bonds between adjacent oxygen and hydrogen atoms; while it is a weak bond, it is nonetheless critical in controlling the structure of both water and ice.

An unusual property of water is that its solid form—ice frozen at atmospheric pressure—is approximately 8.3% less dense than its liquid form; this is equivalent to a volumetric expansion of 9%. The density of ice is 0.9167–0.9168 g/cm³ at 0 °C and standard atmospheric pressure (101,325 Pa), whereas water has a density of 0.9998–0.999863 g/cm³ at the same temperature and pressure. Liquid water is densest, essentially 1.00 g/cm³, at 4 °C and begins to lose its density as the water molecules begin to form the hexagonal crystals of ice as the freezing point is reached. This is due to hydrogen bonding dominating the intermolecular forces, which results in a packing of molecules less compact in the solid. The density of ice increases slightly with decreasing temperature and has a value of 0.9340 g/cm³ at −180 °C (93 K).

When water freezes, it increases in volume (about 9% for fresh water). The effect of expansion during freezing can be dramatic, and ice expansion is a basic cause of freeze-thaw weathering of rock in nature and damage to building foundations and roadways from frost heaving. It is also a common cause of the flooding of houses when water pipes burst due to the pressure of expanding water when it freezes.

Because ice is less dense than liquid water, it floats, and this prevents bottom-up freezing of the bodies of water. Instead, a sheltered environment for animal and plant life is formed beneath the floating ice, which protects the underside from short-term weather extremes such as wind chill. Sufficiently thin floating ice allows light to pass through, supporting the photosynthesis of bacterial and algal colonies. When sea water freezes, the ice is riddled with brine-filled channels which sustain sympagic organisms such as bacteria, algae, copepods and annelids. In turn, they provide food for animals such as krill and specialized fish like the bald notothen, fed upon in turn by larger animals such as emperor penguins and minke whales.