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Copper(II) oxide

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Copper(II) oxide

Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite, or sometimes black copper. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds.

It is produced on a large scale by pyrometallurgy, as one stage in extracting copper from its ores. The ores are treated with an aqueous mixture of ammonium carbonate, ammonia, and oxygen to ultimately give copper(II) ammine complex carbonates, such as [Cu(NH3)4]CO3. After extraction from the residues and after separation from iron, lead, etc. impurities, the carbonate salt is decomposed with steam to give CuO.

It can be formed by heating copper in air at around 300–800 °C:

For laboratory uses, copper(II) oxide is conveniently prepared by pyrolysis of copper(II) nitrate or basic copper(II) carbonate:

Dehydration of cupric hydroxide has also been demonstrated:

Copper(II) oxide reacts with mineral acids such as hydrochloric acid, sulfuric acid, and nitric acid to give the corresponding hydrated copper(II) salts:

In presence of water it reacts with concentrated alkali to form the corresponding cuprate salts:

It can also be reduced to copper metal using hydrogen, carbon monoxide, and carbon:

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