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Sorbothane is the brand name of a synthetic viscoelastic urethane polymer used as a shock absorber and vibration damper. It is manufactured by Sorbothane, Inc., based in Kent, Ohio.

History

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Sorbothane was invented and patented in 1982 by Dr. Maurice Hiles,[1] a British inventor. It was prepared by mixing polyol and isocyanate.[2] His research into the energy dissipation properties of human soft tissue disclosed a structure very similar to an interpenetrating polymer network. This led to his synthesis of the first commercial simultaneous interpenetrating network, now called Sorbothane.[3] Dr. Hiles wrote in his patent "The resulting solid polymer behaves like a quasi-liquid, being readily deformed by an applied force and slow to recover, although in the absence of such a force it takes up a defined shape and volume". In 1976, he contacted the National Research Development Corporation (NRDC) about his invention; the NRDC spent almost £10,000 in helping him to improve and patent the polymer. BTR Industries obtained the license from NRDC for selling them.[2]

Properties

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The material combines some of the properties of rubber, silicone, and other elastic polymers. It is considered to be a good vibration damping material, an acoustic insulator, and highly durable. An unusually high amount of the energy from an object dropped onto Sorbothane is absorbed. The feel and damping qualities of Sorbothane have been likened to those of meat.

Sorbothane is a visco-elastic material, meaning that it exhibits properties of both liquids (viscous solutions) and solids (elastic materials), with a relaxation time of two seconds.[4] Because visco-elastic behavior is desirable in shock and vibration applications, many materials claim to be viscoelastic; however, many of these materials have only trace viscoelastic properties.[citation needed]

Similar materials include polynorbornene, Noene, and Astro-sorb.

Uses

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Sorbothane has many industrial applications, from acoustic shielding to machine mounts. It has been used to quiet personal computers by being packed around the hard drive and other noisy spinning components. Sorbothane damps vibration transmission from vibrating hardware. In addition, Sorbothane has been used by NASA to isolate vibration,[5][6] in the Air Force Memorial,[7] and to transport the Liberty Bell.[8] It is currently used with insoles and heel pads to absorb impacts during sports activities such as football, cricket, and rugby.[citation needed] It is also used in recoil pads of guns.[9]

See also

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References

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Revisions and contributorsEdit on WikipediaRead on Wikipedia
from Grokipedia
Sorbothane is a proprietary, thermoset, polyether-based polyurethane viscoelastic polymer renowned for its ability to absorb shock, isolate vibrations, and dampen noise by converting mechanical energy into heat.[1][2] Developed in 1975 by materials scientist Dr. Maurice Hiles (who later served as a professor at the University of Akron), Sorbothane was inspired by the shock-absorbing properties of human flesh and initially tested through self-experiments measuring impact forces during running.[3] Dr. Hiles' formulation earned a 17-year patent, with its first commercial application in the early 1980s as shock-absorbing insoles for athletic and orthopedic uses.[3] Key properties of Sorbothane include a high damping coefficient, excellent memory for returning to its original shape after deformation, low creep rate compared to materials like rubber or neoprene, and operational stability across a temperature range of -20°F to 160°F (-29°C to 72°C).[1] As a viscoelastic material, it exhibits both viscous (liquid-like flow under load) and elastic (solid-like recovery) behaviors, making it highly effective for energy dissipation under cyclic loading without the need for metal components.[2][1] Sorbothane's applications span multiple industries, including athletics (e.g., insoles and heel pads), medicine (e.g., therapeutic cushions), electronics (e.g., protecting delicate components), and industrial machinery (e.g., vibration isolators and noise control).[1][2] Its durability allows it to withstand millions of cycles, providing long-term performance in demanding environments.[1]

History and Development

Invention

Sorbothane was invented in 1975 by Dr. Maurice Hiles, a British materials scientist working under the British Technology Group (BTG), a government-owned organization promoting technology commercialization.[3][4] The material, later licensed non-exclusively to BTR in 1978, is a proprietary urethane with superior energy dissipation properties.[4] The primary motivation was to engineer a viscoelastic substance that could effectively absorb impacts—such as those equivalent to heel-strike forces up to 17 Gs—while rapidly returning to its original shape, mimicking the protective qualities of human soft tissue like flesh or fat pads.[3] Hiles drew inspiration from biomechanical studies, seeking to address the shortcomings of existing materials like natural rubber, which often degraded or failed to recover fully under repeated stress in high-impact scenarios.[3] Early research involved rigorous self-testing by Hiles, who implanted electrical probes in his own leg to quantify shock transmission during activities like running and walking, providing critical data on energy absorption and material performance.[3] The initial formulation emerged as a thermoset polyether-based polyurethane, a proprietary blend that combined high damping capacity with shape memory, distinguishing it from conventional elastomers.[3] Following extensive laboratory validation, the material received a 17-year patent, securing its unique composition and securing the foundation for future applications.[3]

Commercialization

Sorbothane, Inc. was founded in 1982 by BTR, Inc., a U.S. subsidiary of the British company BTR plc, to manufacture and commercialize the viscoelastic polymer invented by Dr. Maurice Hiles under the British Technology Group.[4][5] BTR, which had obtained a non-exclusive license from the British Technology Group in 1978, established operations initially under its subsidiary Hamilton-Kent Manufacturing in 1980 before forming Sorbothane, Inc. specifically for this purpose, with Kenneth M. Leighton Sr. leading production efforts.[4] Dr. Hiles, the material's creator, served as a consultant during this transition, contributing to early product development.[4] The company relocated its headquarters and manufacturing to Kent, Ohio, in 1984 to increase production capacity.[5] Commercialization began in the early 1980s with launches of consumer-oriented products, such as shock-absorbing heels and full-sole insoles targeted at athletic and orthopedic markets, marking the shift from government-funded research to market availability.[5][3] By 1985, the focus expanded into industrial applications for vibration control, securing the first major contract with Digital Equipment Corporation for use in electronics equipment.[5] This period also saw the award of a dual-casting patent, enabling broader product configurations.[5] In the late 1980s, consumer adoption grew significantly, exemplified by Brown Shoe Company's sale of over 2 million Naturalizer shoe pairs incorporating Sorbothane, alongside accreditation from the American Podiatric Medical Association.[5] The 1990s brought further diversification into consumer goods, including integration into Wilson premium baseball gloves in 1993, while an in-house engineering staff was established in 1990 to support custom solutions.[5] In 2000, Trelleborg acquired Sorbothane, Inc. from BTR, enhancing its resources for global expansion and adaptation to evolving market demands.[5] By 2003, the company transitioned to private ownership, allowing focused growth from its origins in government-backed innovation to widespread commercial sales across industries.[6] As of 2025, Sorbothane, Inc. has operated for over 40 years, continuing to deliver shock and vibration solutions from its Kent, Ohio base.[6]

Composition and Properties

Chemical Makeup

Sorbothane is a proprietary thermoset polyether-based polyurethane formulation designed to exhibit viscoelastic behavior through the integration of polyether chains and urethane linkages. This material is synthesized by reacting a slightly branched polyol with a limited amount of isocyanate in a 10:1 polyol-to-isocyanate ratio, which minimizes chain branching and contributes to its unique quasi-liquid properties.[1][7] The key components include polyol precursors as the primary building blocks, isocyanates for forming the urethane bonds, and specialized additives that enhance damping capabilities, all within a fully synthetic structure that excludes natural rubber and differentiates it from conventional elastomers. This composition results in a cross-linked polymer network, characteristic of thermoset polyurethanes, where energy dissipation occurs via hysteresis in the molecular structure.[1][7] Sorbothane demonstrates a chemical resistance profile typical of polyether-based polyurethanes, offering good tolerance to oils, mild solvents, and water, with a water-resistant variant available for enhanced hydrolytic stability in wet environments.[8][1][9] However, it is susceptible to degradation from gasoline, alcohols, and certain plastic solvents, limiting its use in environments with such exposures.[1][9]

Physical and Mechanical Characteristics

Sorbothane exhibits viscoelastic properties, characterized by both elastic and viscous behaviors, enabling it to store and dissipate energy effectively. Its high damping coefficient, measured as the tangent delta (tan δ), reaches values up to 0.65 at frequencies such as 50 Hz for the 50 Shore OO variant, indicating superior energy absorption compared to many polymers.[10] The loss modulus contributes to this by converting mechanical energy into heat through internal friction, particularly evident in the material's hysteresis loop during cyclic loading, where the area between loading and unloading curves represents dissipated energy.[1] Mechanically, Sorbothane is available in durometers ranging from 30 to 70 Shore OO, providing flexibility in stiffness for various applications. Tensile strength typically falls between 190 and 390 psi, depending on the formulation and durometer, while elongation at break can exceed 300% in certain variants, allowing significant deformation without permanent damage.[10] Shock absorption capabilities are notable, with the material dissipating up to 94.7% of impact energy in tested configurations, far surpassing many elastomers.[11] Physically, Sorbothane has a density of approximately 1.27 to 1.36 g/cm³ depending on the variant (e.g., 1.36 g/cm³ or specific gravity 1.36 for standard 50 Shore OO; 1.27-1.32 g/cm³ per safety data sheet; ~1.28 g/cm³ for water-resistant), contributing to its lightweight yet robust profile.[10][12][8] It performs optimally within a temperature range of -20°F to 160°F, where damping and strength remain consistent; performance diminishes above 200°F due to reduced viscoelastic response, and the glass transition temperature is around -20°F, below which rigidity increases.[13] These properties are evaluated using standards such as ASTM D2632 for resilience and damping assessment, and ASTM E1640 for tan delta measurement, ensuring reliable quantification of its energy dissipation mechanisms.[10]

Manufacturing and Forms

Production Methods

Sorbothane is produced through a casting process that involves mixing polyether-based polyols with isocyanates and catalysts under controlled conditions to form a thermoset polyurethane polymer via reaction molding.[14] The formulation typically employs a high ratio of polyol to isocyanate, often around 10:1 by weight, with the polyol being slightly branched to create a quasi-liquid precursor that reacts to yield a viscoelastic solid with minimal chain branching.[7] Catalysts such as dibutyltin dilaurate or triethylene diamine are added in small amounts (0.1-2% by weight) to facilitate the reaction, and mixing occurs at low speeds, such as 250 RPM for up to 30 seconds, to minimize air entrapment.[15] This batch process is conducted in closed book molds, allowing the mixture to be poured and shaped precisely while preventing defects.[7] Following mixing, the material undergoes curing stages where cross-linking occurs primarily at room temperature, though heat acceleration can be applied to speed up the process. The reaction generates exothermic heat, often reaching up to 80°C, leading to gelation in about 4 minutes and solidification within 8 minutes, resulting in a stable thermoset structure with urethane linkages.[14] Quality control measures ensure uniformity in damping properties, including testing for consistency in hardness (measured on the Shore 00 scale, typically 30-70 durometer) and viscoelastic behavior across batches, with adjustments made to factors like weight, frequency response, and temperature stability.[7] The proprietary formulation emphasizes precise stoichiometric control, leaving approximately 80–95% unsatisfied hydroxyl groups to maintain the material's energy absorption characteristics.[14] Production variations include standard and water-resistant grades, achieved by incorporating additives such as silicone (10-22% by weight) for enhanced hydrolytic stability in the latter.[15] Water-resistant versions maintain similar damping performance in wet environments without relying on coatings, differing from standard grades through modified polyol-isocyanate ratios or additional stabilizers to reduce water absorption.[16] Hardness and other properties are fine-tuned by varying isocyanate levels or including fillers like lightweight fly ash (0.2-2 parts by weight).[17] The process operates on a batch scale, producing sheets or custom-molded forms in specialized facilities, with the proprietary nature of the formulation ensuring consistent performance across production runs.[7] This time-consuming method prioritizes quality over high-volume output, supporting applications requiring reliable viscoelastic properties.[7]

Product Configurations

Sorbothane is available in several standard forms designed to accommodate diverse vibration and shock absorption requirements. These include sheet stock, which comes in sizes ranging from 4 by 4 inches to 25 by 25 inches and thicknesses from 0.04 inches to 2 inches, allowing for flexible application in gaskets, pads, and liners.[13] Other common configurations encompass isolation hemispheres with diameters from 0.25 inches to 2.5 inches, isolation pads in square shapes from 0.5 by 0.5 inches to 2.5 by 2.5 inches and thicknesses of 0.1 to 0.5 inches, bushings with diameters of 0.5 to 1.5 inches and heights up to 0.79 inches, and washers for mounting purposes.[13][18] Durometer options for these products are tailored to provide varying levels of stiffness and damping, typically available in 30, 40, 50, and 70 Shore OO scales, where softer durometers like 30 OO offer greater energy absorption at the expense of load-bearing capacity.[13] These variations influence the material's viscoelastic response, with higher durometers providing increased firmness for heavier loads.[1] Specialized variants expand Sorbothane's utility in challenging environments. Water-resistant grades, formulated for humid or wet conditions, maintain shock absorption and vibration isolation properties without degradation, available in sheet form and customizable durometers from 30 to 70 Shore OO.[16] Acoustic sheets and thin films, often in 40 or 50 durometer, are optimized for noise reduction applications, such as damping vibrations in audio equipment.[19] Customization enables integration into original equipment manufacturer (OEM) designs, with options including die-cutting for sheets up to 0.375 inches thick to achieve precise shapes and edges, and compression molding for complex custom-molded parts like specialized bushings or mounts.[20] Sizing flexibility spans from millimeters for small components to feet for larger sheets, ensuring adaptability across scales.[21][22]

Applications

Vibration Isolation

Sorbothane achieves vibration isolation through its viscoelastic properties, which enable high internal friction to dissipate vibrational energy as heat via hysteretic damping. This mechanism converts mechanical vibrations into thermal energy, preventing transmission to surrounding structures, and can reduce vibration by up to 94.7% in specialized mounts and isolators such as reinforced pads.[23][24] In industrial machinery, Sorbothane isolators are commonly applied to motors and pumps to minimize operational vibrations that could lead to wear or failure, as seen in NASA implementations for space station pumps. For electronics, it protects sensitive components like hard drives in computers by mounting them on damping pads that absorb transmitted vibrations from the chassis or environment. In audio equipment, Sorbothane serves as speaker stands or isolation feet to decouple speakers from floors, reducing structural vibrations that distort sound reproduction. Additionally, it isolates counterbalances in phonograph arms to maintain precise tracking and minimize feedback in turntable systems.[25][26][27][28][29] Design selection for Sorbothane in vibration isolation depends on the targeted frequency range, typically effective from 10 to 1000 Hz for most mechanical systems, with durometer ratings (30-70 Shore 00) chosen to match load and deflection needs for optimal energy absorption. Performance is evaluated using isolation efficiency curves, which demonstrate effective resonance control by showing low transmissibility peaks at natural frequencies and rapid attenuation above resonance, ensuring minimal vibration transfer in tuned applications.[30][31][32]

Shock Absorption

Sorbothane functions as a highly effective shock absorber by converting kinetic energy from sudden impacts into heat through viscoelastic deformation and hysteresis, allowing the material to compress and then slowly return to its original shape with minimal rebound due to its high damping coefficient.[33] This process dissipates up to 94.7% of impact energy, significantly reducing transmitted forces compared to traditional materials like rubber or foam.[33] Additionally, Sorbothane exhibits negligible compression set under load, maintaining its structural integrity over repeated impacts without permanent deformation.[34] In protective gear applications, Sorbothane is widely used in sports equipment such as padding for baseball gloves, tennis rackets, bicycle helmets, and gymnast socks to cushion abrupt jolts and minimize injury risk during high-impact activities.[35] For transportation, it serves in vehicle components like car seat cushions and bumpers to absorb shocks from road irregularities or collisions, as demonstrated in historical uses such as transporting the Liberty Bell.[33] In aerospace, Sorbothane forms equipment cradles that protect sensitive instruments during launch and landing vibrations, including solutions for NASA Space Shuttle payloads.[33] Practical examples include its integration as packing material around fragile electronics and components in shipping containers, where it safeguards against drops and handling impacts during air, truck, or sea transit.[35] Similarly, in footwear, Sorbothane heel inserts provide impact cushioning for runners and everyday users, reducing stress on feet, ankles, knees, and the lower back by absorbing ground reaction forces.[35] These applications leverage Sorbothane's ability to handle discrete shock events effectively, drawing on its core mechanical properties of high energy absorption and resilient recovery.[1]

Noise Reduction

Sorbothane reduces noise by absorbing vibrational energy from sound waves and converting it into low-level heat through molecular friction within its viscoelastic structure, making it particularly effective for controlling structure-borne sound that transmits through solids.[36] This damping mechanism dissipates acoustic vibrations before they propagate as audible noise, outperforming rigid materials that merely reflect sound.[37] In practical applications, Sorbothane is widely used in HVAC systems, where sheets placed under units or in ductwork minimize rumbles and hums from fans and compressors, enhancing overall system quietness.[38] In consumer electronics, such as PC cases, it serves as lining material to dampen fan vibrations and reduce resonant noise transmission to surrounding surfaces.[39] For musical instruments, Sorbothane inserts in products like snare drum dampers control overtones and sustain, allowing musicians to modulate tone while lowering unwanted acoustic output.[40] Sorbothane also provides acoustic isolation in building structures, such as bumpers on cabinet doors that soften closing impacts and prevent noise transmission through walls.[38] In machinery, it lowers resonant frequencies to curb operational noise, as seen in applications under washing machines where pads like Silent Feet significantly attenuate vibrations that cause audible disturbances.[41] Targeted setups can achieve noise attenuation of up to 18 dB, as demonstrated in commercial blenders where Sorbothane components reduced sound levels compared to competitors.[42]

Advantages and Limitations

Key Benefits

Sorbothane demonstrates superior energy dissipation capabilities compared to traditional materials like rubber and open-cell foams. It absorbs up to 94.7% of shock energy, converting it primarily to low-level heat with minimal rebound, which contrasts with rubber's high rebound rates that return much of the energy undissipated. This property enables effective combined shock and vibration damping, where Sorbothane outperforms foams by providing better shape memory and sustained performance over repeated impacts.[43][1] The material's versatility stems from its operational effectiveness across a broad temperature range of -20°F to 160°F and frequency spectrum of 10 to 30,000 Hz. Unlike neoprene or silicone, which exhibit higher creep rates, Sorbothane maintains dimensional stability and reusability, allowing it to return to its original shape without permanent deformation after loading.[1][43] Sorbothane ensures longevity by retaining its viscoelastic properties over millions of cycles, far exceeding the fatigue life of many foam-based alternatives. This durability supports cost-effectiveness in custom applications, where ultra-low tooling costs and short lead times facilitate efficient prototyping and production.[1][44] Environmentally, Sorbothane is non-toxic and considered friendly due to its avoidance of endangered ingredients and minimal earth-damaging components. It outperforms natural materials like rubber in consistency, delivering reliable damping without the variability inherent in biological sources.[45][46][43]

Drawbacks and Considerations

Sorbothane exhibits temperature sensitivity that limits its performance in extreme environments. Its optimal operating range is -20°F to 160°F (-29°C to 71°C), with reduced damping efficiency and material strength above 160°F and increased stiffness below -20°F, making it unsuitable for applications without specialized variants designed for broader thermal tolerance.[1][10] As a proprietary viscoelastic polyurethane, Sorbothane is generally more expensive than conventional rubber materials, reflecting its specialized formulation and manufacturing process. In high-load static applications, excessive compression can lead to compression set, where the material fails to return to its original shape, potentially shortening service life if deflection exceeds recommended limits such as 20% of free height for low shape factors.[1][47][48] Standard Sorbothane demonstrates good general chemical stability, with minimal weight change in exposure to hydraulic fluids and motor oils, though it absorbs water significantly (up to ~42% weight gain); water-resistant formulations exhibit minimal swell. It shows potential swelling or degradation in certain solvents like gasoline (up to 58% weight gain) and complete breakdown in strong acids, with limited effect (~3% weight change) in hexane. Standard formulations offer limited inherent UV resistance for prolonged outdoor exposure, though it can be compounded for enhanced protection against ultraviolet and ozone degradation in such conditions.[10][1][16] Effective selection of Sorbothane requires matching durometer (typically 30-70 Shore OO) and shape factor to the anticipated load and vibration frequency, ensuring deflection stays within 3-20% of thickness to optimize isolation and prevent fatigue; tools like load rating calculators aid in determining these parameters for specific natural frequencies. Durability varies with environmental factors and loading, often lasting for millions of cycles under standard conditions.[48][49][1]

References

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