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Superconductor classification
Superconductor classification
from Wikipedia

Superconductors can be classified in accordance with several criteria that depend on physical properties, current understanding, and the expense of cooling them or their material.

By their magnetic properties

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By their agreement with conventional models

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This criterion is useful as BCS theory has successfully explained the properties of conventional superconductors since 1957, yet there have been no satisfactory theories to fully explain unconventional superconductors. In most cases conventional superconductors are type I, but there are exceptions such as niobium, which is both conventional and type II.

By their critical temperature

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77 K is used as the demarcation point to emphasize whether or not superconductivity in the materials can be achieved with liquid nitrogen (whose boiling point is 77K), which is much more feasible than liquid helium (an alternative to achieve the temperatures needed to get low-temperature superconductors).

By material constituents and structure

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Most superconductors made of pure elements are type I (except niobium, technetium, vanadium, silicon, and the above-mentioned carbon allotropes).
  • Alloys, such as
    • Niobium-titanium (NbTi), whose superconducting properties were discovered in 1962.
  • Ceramics (often insulators in the normal state), which include
  • Palladates – palladium compounds.[4][5]
  • others, such as the "metallic" compounds Hg
    3
    NbF
    6
    and Hg
    3
    TaF
    6
    which are both superconductors below 7 K (−266.15 °C; −447.07 °F).[6]

See also

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References

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Revisions and contributorsEdit on WikipediaRead on Wikipedia
from Grokipedia
Superconductors are materials that exhibit zero electrical resistance and expel magnetic fields below a critical temperature, and their classification organizes these materials into categories based on magnetic behavior, pairing mechanisms, and transition temperatures to facilitate understanding and application in fields like energy transmission and quantum computing. The primary magnetic classification distinguishes between Type I and Type II superconductors. Type I superconductors, such as mercury (T_c ≈ 4.2 K) and lead (T_c ≈ 7.2 K), exhibit a complete Meissner effect, fully expelling magnetic fields up to a single critical field H_c beyond which superconductivity abruptly ceases, making them suitable for low-field applications but limited by their low critical fields (typically < 0.1 T). In contrast, Type II superconductors, including niobium-titanium alloys (T_c ≈ 9.5 K) and high-temperature cuprates like YBa₂Cu₃O₇ (T_c ≈ 92 K), allow partial magnetic field penetration through quantized flux vortices between a lower critical field H_{c1} and an upper critical field H_{c2} (often > 10 T), enabling operation in stronger magnetic environments such as MRI machines and particle accelerators. A complementary classification divides superconductors by their electron-pairing mechanisms into conventional and unconventional types. Conventional superconductors adhere to Bardeen-Cooper-Schrieffer (BCS) theory, where phonon-mediated electron-phonon interactions form isotropic s-wave Cooper pairs, as seen in elements like aluminum (T_c ≈ 1.2 K) and compounds like MgB₂ (T_c ≈ 39 K), with critical temperatures typically up to around 40 K. Unconventional superconductors, however, involve non-phonon mechanisms such as magnetic spin fluctuations or electronic correlations, leading to anisotropic or nodal pairing symmetries and often higher transition temperatures; prominent examples include cuprate high-T_c materials (T_c up to 135 K in HgBa₂Ca₂Cu₃O_{8+δ}) and iron-based pnictides like LaFeAsO (T_c ≈ 26 K). This distinction highlights ongoing research into achieving room-temperature superconductivity, with recent advances in hydride materials under high pressure, such as in lanthanum decahydride (LaH_{10}) reaching T_c ≈ 250 K. Additional classifications, such as those based on critical temperature maps using electron-phonon coupling strength (λ) and phonon frequencies (Ω_p), further refine groupings into regions corresponding to material types—from in low-Ω_p regions to potential hydrogen-rich compounds in high-Ω_p areas—guiding the search for superconductors. Overall, these schemes underscore the diversity of superconducting states, from simple metals to complex layered structures, and inform technological developments while revealing fundamental quantum phenomena.

Fundamental Properties

Critical Parameters

Superconductivity is characterized by three primary critical parameters that define the conditions under which the superconducting state persists: the critical temperature TcT_c, the critical HcH_c, and the critical JcJ_c. These parameters delineate the boundaries of the superconducting phase in the of a , below which electrical resistance vanishes and perfect emerges. The critical temperature TcT_c is the temperature below which a material exhibits zero electrical resistance and the , marking the onset of the superconducting state. This phenomenon was first observed by in 1911, who discovered that the resistance of mercury dropped to zero at approximately 4.2 K when cooled using . Historically, TcT_c serves as the foundational metric for identifying superconductors, as it represents the thermal energy scale where quantum pairing of electrons stabilizes the superconducting order parameter. The critical magnetic field HcH_c (or Hc1H_{c1} and Hc2H_{c2} in more complex cases) is the applied strength at which is suppressed, restoring the normal resistive state. For type I superconductors, the thermodynamic critical field is given by Hc=8π(energy density difference between normal and superconducting states)H_c = \sqrt{8\pi \cdot (\text{energy density difference between normal and superconducting states})}
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