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Jeremejevite
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| Jeremejevite | |
|---|---|
 | |
| General | |
| Category | Borate mineral |
| Formula | Al6B5O15(F,OH)3 |
| IMA symbol | Jer[1] |
| Strunz classification | 6.AB.15 |
| Crystal system | Hexagonal |
| Crystal class |
|
| Space group | P63/m |
| Identification | |
| Color | Colorless, white, yellowish, blue, light yellow brown, aquamarine blue, rarely violet; colourless in transmitted light |
| Crystal habit | Prismatic |
| Cleavage | None observed |
| Fracture | Conchoidal |
| Mohs scale hardness | 6.5 – 7.5 |
| Luster | Vitreous |
| Streak | White |
| Diaphaneity | Transparent |
| Specific gravity | 3.28 – 3.31 |
| Optical properties | Uniaxial (-) |
| Refractive index | nω = 1.653 nε = 1.640 |
| Birefringence | 0.0130 |
| Pleochroism | Colorless – light blue-violet |
| Other characteristics | Piezoelectric |
| References | [2][3][4] |
Jeremejevite is an aluminium borate mineral with variable fluoride and hydroxide ions. Its chemical formula is Al6B5O15(F,OH)3. It is considered as one of the rarest, thus one of the most expensive stones. For nearly a century, it was considered as one of the rarest gemstones in the world.[5][better source needed]
It was first described in 1883[6] as small, single crystals in loose granitic debris in Mt. Soktui, Nerschinsk district, Adun-Chilon Mountains, Siberia.[7] It was named after Pavel Vladimirovich Eremeev, Russian mineralogist, engineer and professor, who collected the first specimens (Jeremejev, German; 1830–1899).[4]
Properties
[edit]Jeremejevite is a mineral that shows pleochroic properties, which is an optical phenomenon in which the mineral's color appears to change depending on the angle at which it is viewed. Blue specimens from Namibia show a light cornflower blue to colorless to light yellow pleochroism, while yellow materials show light yellow to colorless pleochroism. This mineral is also piezoelectric, meaning that it would generate electricity when under mechanical stress.[7]
Mining and localities
[edit]Jeremejevite occurs as a late hydrothermal phase in granitic pegmatites in association with albite, tourmaline, quartz and rarely gypsum. It has also been reported in the Pamir Mountains of Tajikistan, Namibia and in micro-crystalline form at the Eifel district, Germany.[4] It was first found in facetable form in Namibia, which were blue-green pyramidal crystals up to 2 cm (0.79 in). Later, there was a new source revealed in Namibia, near Usakos in 2001.[7] Nowadays, most of the stones on the market are from that deposit.[5]
Jewelry industry
[edit]
As an OH-end member, scientists have been able to synthesize jeremejevite, but only in micro-crystalline form, without fluorine. This synthesized variant of the mineral has no use in the jewelry industry.
Typically, faceted gems can reach up to 5 carats, but usually they range between less than 1 carat and 2 carats. However, new sources produced much larger faceted stones, the biggest faceted gem weighing 254 carats. This gem was found in Sri Lanka in 1990.
Even though jeremejevite is a relatively durable stone, it should not be cleaned using ultrasound cleaning or steaming; the stone usually contains liquid inclusions, which could shatter the stone if cleaned using these methods. It is recommended to clean them with warm water, a mild detergent, and a soft brush instead.[7]
Due to its high value and rarity, it is considered a collectors' stone, who purchase it in mineral form, hence only a few specimens had been faceted so far.[5]
References
[edit]- ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- ^ Jeremjevite on Mindat.org
- ^ Jeremejevite on Webmineral.com
- ^ a b c Handbook of Mineralogy
- ^ a b c "Rare Jeremejevite Gems at AJS Gems". www.ajsgem.com. Archived from the original on 2022-03-08. Retrieved 2022-03-08.
- ^ Damour A. Note sur un borate d'alumine cristallisé de la Siberie. Nouvelle espèce minerale // Bulletin de la Société minéralogique de France. 1883. 6. N 1. P. 20-23.
- ^ a b c d "Jeremejevite Value, Price, and Jewelry Information". gemsociety.org. International Gem Society. Retrieved 2022-03-07.
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Jeremejevite
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Etymology and history
Discovery
Jeremejevite was initially discovered in 1883 during geological surveys conducted in the Adun-Cholon Range of Eastern Siberia, Russia, at the locality known as Mt. Soktui (or Soktuj Gora) in the Nerchinsk district.[1] The mineral occurred as small, colorless crystals in loose granitic debris, marking the type locality for the species.[4] The specimens were collected by Russian mineralogist and crystallographer Pavel Vladimirovich Eremeev (1830–1899), a professor at the St. Petersburg Academy of Sciences, who recognized their potential novelty based on preliminary observations during his fieldwork.[1] Suspecting a previously undocumented mineral, Eremeev arranged for the samples to be analyzed further to confirm their distinct composition.[5] In the same year, French mineralogist Augustin Alexis Damour conducted a detailed chemical analysis of the submitted material and published the first scientific description, validating jeremejevite as a new aluminum borate species.[3] This confirmation relied on quantitative assessment of its boron and aluminum content, distinguishing it from known borates. Early efforts to identify the mineral faced difficulties owing to its extreme scarcity, with only limited material available for study, necessitating precise analytical techniques to establish its uniqueness.Naming
Jeremejevite was named in 1883 by French mineralogist Augustin Alexis Damour in honor of Pavel Vladimirovich Eremeev (also spelled Jeremejev or Eremeew), a prominent Russian mineralogist and crystallographer who collected the initial specimens from Mount Soktui in Siberia.[5][4] This naming recognized Eremeev's significant contributions to Russian mineralogy, particularly his work on Siberian deposits. The suffix "-ite," derived from the Greek word for "stone," follows the conventional ending for newly identified minerals in the 19th century, reflecting the era's systematic nomenclature practices in mineral science.[7] Due to variations in transliterating the Russian name "Еремеев" (Eremeev) into Western languages, the mineral has appeared under several spellings, including Jeremejewite, Yeremeyevite, and Eremeevite. In English-language mineralogical literature, "jeremejevite" has become the standardized form, as adopted in major reference works.[1][8] The International Mineralogical Association (IMA) officially recognizes jeremejevite as a valid mineral species, classifying it as a grandfathered entry from pre-IMA establishment descriptions. Its approved IMA symbol is "Jer," facilitating its use in scientific databases and classifications. No formal synonyms or historical name changes have been documented beyond these transliteration variants.[1][9]Properties
Chemical composition and crystal structure
Jeremejevite is an aluminum borate mineral with the chemical formula Al₆B₅O₁₅(F,OH)₃, consisting primarily of aluminum, boron, oxygen, and variable proportions of fluorine and hydroxyl groups.[10] This composition highlights its role as a complex borate, where five isolated BO₃ trigonal planar units are integrated into the structure.[11] It is classified as a nesoborate mineral, featuring discrete borate anions rather than extended chains or sheets.[1] Jeremejevite crystallizes in the hexagonal system with space group P6₃/m (No. 176).[11] The unit cell parameters are a = 8.5591(3) Å, c = 8.1814(6) Å, and Z = 2, resulting in a calculated density of approximately 3.28 g/cm³.[10] The crystal structure comprises two types of independent BO₃ triangles linked by six aluminum-centered octahedra (AlO₆), forming a three-dimensional framework with open channels aligned parallel to the c-axis.[11] These channels accommodate the (F,OH) anions and contribute to the mineral's overall stability.[12] Minor compositional variations occur, particularly in the F/OH ratio, with natural specimens ranging from F-dominant (e.g., Al₆B₅O₁₅F₃) to more hydroxyl-rich end-members, influencing subtle differences in unit cell dimensions.[12]Physical and optical properties
Jeremejevite exhibits a Mohs hardness of 6.5 to 7.5, providing moderate resistance to scratching suitable for gem use but requiring care in handling.[10] Its specific gravity ranges from 3.27 to 3.31, reflecting the dense packing of its borate structure.[3] The mineral displays no observable cleavage, with a conchoidal to uneven fracture that contributes to its brittle tenacity.[1] Luster is vitreous, occasionally subadamantine in cut stones, and transparency varies from transparent to translucent depending on crystal quality and inclusions.[10] The mineral occurs in colorless, white, pale yellow, or blue varieties, with the blue hues ranging from cornflower to greenish-blue tones caused by trace iron impurities.[3] Jeremejevite is uniaxial negative, with refractive indices of nω = 1.649–1.653 and nε = 1.640–1.642, yielding a birefringence of 0.009–0.013.[1][3] Colored specimens show strong pleochroism, particularly in blue material where it appears blue to colorless along different axes, aiding in identification under polarized light.[3] Additional traits include reported piezoelectricity based on experimental tests, despite its centrosymmetric space group.[1][12] It exhibits no fluorescence under ultraviolet light, distinguishing it from some similarly colored gemstones.[13]Occurrence and mining
Geological formation
Jeremejevite primarily forms in late-stage granitic pegmatites, where it crystallizes from boron-rich hydrothermal fluids emanating from cooling magma bodies. These fluids, enriched in volatile components, facilitate the precipitation of rare borate minerals during the final phases of pegmatite consolidation. The process involves the concentration of incompatible elements like boron in residual melts, leading to the development of miarolitic cavities and fractures that host jeremejevite crystals.[14][2] In its paragenesis, jeremejevite typically appears as prismatic or acicular crystals lining vugs or filling fractures within the pegmatite matrix, often as a late-stage hydrothermal product following the deposition of earlier minerals. It is commonly associated with albite, quartz, tourmaline (such as elbaite or schorl), lepidolite, and other borates including hambergite, reflecting the lithium- and boron-enriched nature of these pegmatites. Fluorite may also occur nearby, highlighting the role of volatile elements in the system.[1][14] Although predominantly pegmatitic, jeremejevite has rare occurrences in metamorphic environments, such as metamorphosed limestones altered by boron-rich vapors during contact metamorphism. Formation is influenced by high concentrations of boron and aluminum in the fluids, coupled with fluorine activity that stabilizes the mineral's structure, and relatively low temperatures around 300–500 °C typical of late hydrothermal stages in pegmatite systems. These conditions promote the selective crystallization of aluminum borates over other phases.[15][16]Major localities
Jeremejevite was first discovered in 1883 at its type locality on Mt. Soktui in the Adun-Cholon Range, Eastern Siberia, Russia, where only microscopic crystals were found in granitic debris.[1][17] No significant production has occurred there since the initial find, limiting specimens to small, colorless examples preserved in collections.[4] Namibia represents the primary global source of gem-quality jeremejevite, with major occurrences in the Erongo Region since the 1970s. Key sites include the Mile 72 deposit near Cape Cross, where facetable crystals up to several centimeters were mined from pegmatites starting in 1973, yielding water-clear to blue material.[18][19] Additional finds at Ameib Farm near Usakos and in the Erongo Mountains have produced high-quality prismatic crystals, with occasional gem rough up to 5 cm long.[20][21] New discoveries near Arandis in the early 2000s further bolstered supplies, though extraction remains small-scale and sporadic.[22] Namibia is the dominant source of facetable material.[3] In Tajikistan, jeremejevite occurs in the Pamir Mountains, notably at the Sarydzhal deposit, where pale blue crystals have been reported in pegmatite veins.[1] These finds are limited, with no large-scale mining operations, and specimens are typically small and collector-oriented rather than gem-grade.[4] Germany hosts numerous minor occurrences of jeremejevite in the Eifel region, particularly around the Laacher See volcanic area, including sites at Burgbrohl, Ochtendung, and Mendig.[1] Discoveries date back to the late 20th century, but yields consist mostly of microcrystals in volcanic and pegmatitic settings, with no commercial production.[23] Other localities include Myanmar's Mogok region, where small crystals have been found in gem gravels, and Madagascar's Antsongombato area, yielding occasional facetable pieces.[24][25] Limited reports exist from Sri Lanka's gem gravels and sparse finds in Afghanistan, Zimbabwe (e.g., Sandawana area), and Austria (e.g., Styria region), but none have led to significant production.[24][2] Overall, total known jeremejevite specimens worldwide remain extremely limited, with no active large-scale mining due to the mineral's rarity and dispersed, small-pocket occurrences.[5]Uses
Gemstone applications
Jeremejevite's faceting potential is excellent, owing to its hardness of 6.5–7.5 on the Mohs scale and high clarity in transparent specimens, allowing for precise cutting that maximizes its brilliance from a refractive index of 1.637–1.653.[4][5] Preferred cuts include emerald, oval, round brilliant, cushion, pear, and rectangular step cuts, which enhance its vitreous luster and optical properties.[4][3][5] Typical faceted sizes range from under 1 to 2 carats, though stones exceeding 5 carats are occasionally produced from larger rough material.[4][3] The gem is generally untreated, with no common enhancements applied to improve color or clarity, preserving its natural authenticity.[4][5] In jewelry, jeremejevite is suitable for rings, pendants, and earrings, where its blue varieties are particularly prized for their cornflower-blue to aquamarine-like hues that evoke a serene appeal.[4][5] Its durability, bolstered by the absence of cleavage and its conchoidal to uneven fracture, supports everyday wear, though its moderate hardness limits suitability for pieces subjected to heavy impact or abrasion.[4][5] Identification of jeremejevite can be challenging, as its blue shades resemble aquamarine or benitoite, but it is distinguished by its higher refractive index (1.637–1.653 versus aquamarine's 1.57–1.59 and benitoite's 1.757–1.804) and subtle pleochroism, which shifts from light blue to colorless or yellowish tones.[4][5][3] For care, jeremejevite should be cleaned gently with warm soapy water and a soft brush to avoid damaging liquid inclusions or inducing fractures along potential weak planes.[4] Ultrasonic or steam cleaners must be avoided due to the risk of harm from inclusions and the mineral's structure, and it should be stored separately from harder gems to prevent scratches.[4][5]Value and notable specimens
Jeremejevite ranks among the world's rarest gemstones due to its extreme scarcity as facetable material, with most known crystals yielding gems under 2 carats and only exceptional finds producing larger sizes.[4] Its supply is constrained by sporadic discoveries in limited geological settings, making high-quality specimens highly elusive in the global market.[5] Pricing for jeremejevite in the 2025 market reflects its rarity and quality attributes, including size, color saturation, and clarity, with blue varieties commanding the highest values. Fine blue faceted gems range from $2,000 to $20,000 per carat, where stones of 0.5–1 carat typically sell for $2,000–$5,000, those of 1–2 carats for $5,000–$10,000, and pieces over 2 carats up to $20,000.[5] Colorless examples are priced lower at $800–$7,000 per carat, while yellow specimens fall between $500 and $5,000 per carat, with wholesale and auction values often 20–50% below retail for comparable quality.[5] Among notable specimens, the largest faceted jeremejevite is a 106.50-carat gem cut from a 254-carat rough found in Sri Lanka during the 1990s.[4] An outstanding blue crystal from the 2001 discovery in Namibia's Erongo Mountains produced an 11.3-carat faceted oval, now housed in the Smithsonian National Museum of Natural History.[26] The original type material from its 1883 discovery in Siberia, Russia, is preserved in collections such as the Fersman Mineralogical Museum.[27] Jeremejevite's allure for collectors stems from its vivid colors, high clarity, and historical significance, fostering strong demand in niche mineral markets. Post-2000 auctions have highlighted its prestige, with exceptional pieces achieving record prices at venues like Christie's due to limited availability.[28] Market stability persists from ongoing scarcity, as no viable synthetic production exists for jewelry use—only microcrystalline forms for research—and no significant new finds have emerged since 2023.[5][29]References
- https://www.[mindat.org](/page/Mindat.org)/min-2090.html