Hubbry Logo
Ostwald processOstwald processMain
Open search
Ostwald process
Community hub
Ostwald process
logo
8 pages, 0 posts
0 subscribers
Be the first to start a discussion here.
Be the first to start a discussion here.
Ostwald process
Ostwald process
Ostwald process
View on Wikipedia
from Wikipedia
A laboratory structure of the Ostwald method.
A laboratory structure of the Ostwald method.

The Ostwald process is a chemical process used for making nitric acid (HNO3).[1] The Ostwald process is a mainstay of the modern chemical industry, and it provides the main raw material for the most common type of fertilizer production.[2] Historically and practically, the Ostwald process is closely associated with the Haber process, which provides the requisite raw material, ammonia (NH3). This method is preferred over other methods of nitric acid production, in that it is less expensive and more efficient.[3]

Reactions

[edit]

Ammonia is converted to nitric acid in 2 stages.

Initial oxidation of ammonia

[edit]

The Ostwald process begins with burning ammonia. Ammonia burns in oxygen at temperature about 900 °C (1,650 °F) and pressure up to 8 standard atmospheres (810 kPa)[4] in the presence of a catalyst such as platinum gauze, alloyed with 10% rhodium to increase its strength and nitric oxide yield, platinum metal on fused silica wool, copper or nickel to form nitric oxide (nitrogen(II) oxide) and water (as steam). This reaction is strongly exothermic, making it a useful heat source once initiated:[5]

4NH3 + 5O2 → 4NO + 6H2O (ΔH = −905.2 kJ/mol)

Side reactions

[edit]

A number of side reactions compete with the formation of nitric oxide. Some reactions convert the ammonia to N2, such as:

4NH3 + 6NO → 5N2 + 6H2O

This is a secondary reaction that is minimised by reducing the time the gas mixtures are in contact with the catalyst.[6] Another side reaction produces nitrous oxide:

4NH3 + 4O2 → 2N2O + 6H2O (ΔH = −1105 kJ/mol)

Platinum-rhodium catalyst

[edit]

The platinum and rhodium catalyst is frequently replaced due to decomposition as a result of the extreme conditions which it operates under, leading to a form of degradation called cauliflowering.[7] The exact mechanism of this process is unknown, the main theories being physical degradation by hydrogen atoms penetrating the platinum-rhodium lattice, or by metal atom transport from the centre of the metal to the surface.[7]

Secondary oxidation

[edit]

The nitric oxide (NO) formed in the prior catalysed reaction is then cooled down from around 900˚C to roughly 250˚C to be further oxidised to nitrogen dioxide (NO2)[8] by the reaction:

2NO + O2 → 2NO2 (ΔH = -114.2 kJ/mol)[9]

The reaction:

2NO2 → N2O4 (ΔH = -57.2 kJ/mol)[10]

also occurs once the nitrogen dioxide has formed.[11]

Conversion of nitric oxide

[edit]

Stage two encompasses the absorption of nitrous oxides in water and is carried out in an absorption apparatus, a plate column containing water.[citation needed] This gas is then readily absorbed by the water, yielding the desired product (nitric acid in a dilute form), while reducing a portion of it back to nitric oxide:[5]

3NO2 + H2O → 2HNO3 + NO (ΔH = −117 kJ/mol)

The NO is recycled, and the acid is concentrated to the required strength by distillation.

This is only one of over 40 absorption reactions of nitrous oxides recorded,[11] with other common reactions including:

3N2O4 + 2H2O → 4HNO3 + 2NO

And, if the last step is carried out in air:

4NO2 + O2 + 2H2O → 4HNO3 (ΔH = −348 kJ/mol).

Overall reaction

[edit]

The overall reaction is twice that of the first equation, 3 times the second equation, and 2 times the last equation; all divided by 2:

2NH3 + 4O2 + H2O → 3H2O + 2HNO3 (ΔH = −740.6 kJ/mol)

Alternatively, if the last step is carried out in the air, the overall reaction is the sum of equation 1, 2 times equation 2, and equation 4; all divided by 2.

Without considering the state of the water,

NH3 + 2O2 → H2O + HNO3 (ΔH = −370.3 kJ/mol)

History

[edit]

Wilhelm Ostwald developed the process, and he patented it in 1902.[12][13] This is so because some of the products are recycled for the next step and after use some are taken out.

See also

[edit]

References

[edit]
[edit]
Revisions and contributorsEdit on WikipediaRead on Wikipedia

Ostwald process

View on Grokipedia
from Grokipedia
The Ostwald process is an industrial chemical process for the large-scale production of (HNO₃) from (NH₃) and atmospheric oxygen, serving as the primary method worldwide for this purpose. It involves three principal steps: the of to (NO) at high temperature, the non-catalytic oxidation of NO to (NO₂), and the absorption of NO₂ in water to yield dilute , which is then concentrated. The key reactions are 4NH₃ + 5O₂ → 4NO + 6H₂O (first step), 2NO + O₂ → 2NO₂ (second step), and 3NO₂ + H₂O → 2HNO₃ + NO (third step), with the NO from the absorption step recycled to improve efficiency. Developed between 1900 and 1901 by German Wilhelm and Eberhard Brauer, the process was first implemented commercially in 1908 at a plant in Gerthe, , , marking a breakthrough in catalytic technology that earned Ostwald the 1909 for his contributions to . In the initial oxidation step, a platinum-rhodium gauze (typically 90% Pt and 10% Rh) serves as the catalyst, operating at 800–900°C and pressures of 4–10 bar to achieve over 95% conversion of . The subsequent steps occur at lower temperatures (50–100°C for cooling and oxidation) and involve countercurrent absorption in water-filled towers to produce nitric acid concentrations of 50–70%, which can be further distilled to 98% purity using dehydration. The process is exothermic and highly efficient, with modern plants recovering for energy use and minimizing emissions through tail gas treatment. Nitric acid produced via the Ostwald process is essential for manufacturing fertilizers, which support global agriculture, as well as explosives like TNT, precursors, and various dyes, pharmaceuticals, and metal processing agents. Accounting for over 90% of global output (approximately 58 million tonnes annually as of 2024), the process underscores the interplay between the Haber-Bosch ammonia synthesis and in industrial chemistry. Ongoing focuses on alternatives like ruthenium-based materials to reduce costs and environmental impact while maintaining high yields.

Overview

Definition and Purpose

The Ostwald process is an industrial chemical method that produces through the of , proceeding via intermediate nitrogen oxides to enable efficient large-scale manufacturing primarily for fertilizers and explosives. Developed by and Eberhard Brauer in 1900–1901 and patented in 1902, it represents a cornerstone of modern by converting abundant ammonia feedstock into a versatile acid essential for agricultural and industrial applications. The primary purpose of the Ostwald process is to serve as the dominant route for (HNO₃) synthesis, accounting for over 90% of global production and supporting key downstream products such as fertilizers, which constitute the majority of nitric acid use (primarily ~80% overall for fertilizers), along with nitro-based explosives and organic compounds. This process addresses the high demand for nitric acid in to enhance crop yields through fertilization and in defense for explosive materials. At its core, the mechanism encompasses a three-stage oxidation and absorption sequence: is oxidized to using air, is then oxidized to , and the resulting is absorbed in to yield . This streamlined approach utilizes atmospheric oxygen and , minimizing needs while achieving typical conversion efficiencies of 95-98%, which culminate in concentrations ranging from 50-70%.

Industrial Significance

The Ostwald process accounts for nearly all global production, with annual output approximately 60-70 million metric tons as of 2024. This scale underscores its pivotal role in , where the acid serves as a key precursor for nitrogen-based fertilizers like , supporting crop yields essential for feeding the global population. In the chemical sector, it enables the synthesis of for production and nitro compounds for explosives, highlighting its broad industrial utility. The process integrates seamlessly with the Haber-Bosch process for , closing the anthropogenic nitrogen cycle. Economically, the process's low production costs and high scalability have made it dominant in the market, far surpassing alternative methods and facilitating seamless integration with the Haber-Bosch ammonia synthesis to close the anthropogenic —from atmospheric fixation to application. This has revolutionized utilization, reducing dependency on natural sources and enabling cost-effective scaling to meet surging demand from and industry. In terms of applications, roughly 80% of goes toward fertilizers (primarily ), 10-15% toward nylon precursors such as , and about 5% toward explosives, collectively bolstering for billions by enhancing and supporting infrastructure development. These uses demonstrate the process's indispensable contribution to global economic stability and resource management. Compared to the earlier Birkeland-Eyde arc process, the Ostwald method offers superior efficiency and lower costs, which led to its widespread adoption in the early and the obsolescence of arc-based production; however, it remains energy-intensive, consuming significant for oxidation.

Chemical Reactions

Ammonia Oxidation to Nitric Oxide

The first stage of the Ostwald process involves the catalytic oxidation of ammonia (NH₃) to nitric oxide (NO), which is a highly exothermic reaction represented by the equation: 4NH3+5O2→4NO+6H2O(ΔH=−902 kJ)4\mathrm{NH_3} + 5\mathrm{O_2} \rightarrow 4\mathrm{NO} + 6\mathrm{H_2O} \quad (\Delta H = -902 \, \mathrm{kJ}) This reaction releases approximately 902 kJ of heat per mole of the reaction as written, necessitating careful temperature control to prevent overheating of the catalyst and equipment. The oxidation occurs under specific conditions to maximize efficiency: temperatures of 750–900°C, pressures ranging from slightly negative to about 4 , and a feed mixture containing 9–11% NH₃ in air to ensure excess oxygen. These parameters promote rapid reaction kinetics while minimizing unwanted byproducts, with the preheated ammonia-air mixture passing over at high velocity. Competing side reactions reduce the overall yield by forming nitrogen (N₂) and nitrous oxide (N₂O), such as: 4NH3+3O2→2N2+6H2O4\mathrm{NH_3} + 3\mathrm{O_2} \rightarrow 2\mathrm{N_2} + 6\mathrm{H_2O} and 2NH3+2O2→N2O+3H2O.2\mathrm{NH_3} + 2\mathrm{O_2} \rightarrow \mathrm{N_2O} + 3\mathrm{H_2O}. These reactions account for yield losses of 2–7%, primarily at lower temperatures where selectivity to NO decreases. Mitigation strategies include maintaining precise NH₃ concentrations around 10% and operating at the higher end of the temperature range to favor the primary pathway and suppress N₂O formation, a potent greenhouse gas. Under optimal conditions, the selectivity to NO reaches 93–98%, enabling near-complete NH₃ conversion and contributing significantly to the process's overall nitric acid yield of up to 95%. This high selectivity underscores the stage's critical role, as inefficiencies here directly impact downstream production economics.

Nitric Oxide Oxidation to Nitrogen Dioxide

The second stage of the Ostwald process involves the homogeneous gas-phase oxidation of (NO) to (NO₂), a critical step that converts the primary product of ammonia oxidation into a form suitable for subsequent absorption. The reaction proceeds according to the equation: 2NO+O2→2NO22 \mathrm{NO} + \mathrm{O_2} \to 2 \mathrm{NO_2} This process is exothermic, with a standard change of ΔH = -114 kJ/mol, reflecting the strong thermodynamic favorability of NO₂ formation under appropriate conditions. Unlike the catalytic ammonia oxidation stage, this reaction occurs without a catalyst and is inherently slower, necessitating careful control to maximize efficiency. The kinetics of this oxidation follow a third-order rate law, expressed as rate = k [NO]² [O₂], where the rate constant k exhibits a negative temperature dependence—unusual for most reactions—as lower temperatures accelerate the process due to the involvement of a pre-equilibrium step forming a transient (NO)₂ dimer. To promote high conversion, the hot gases (initially around 900°C from the first stage) are rapidly cooled via heat exchangers to 200–300°C, which not only enhances the but also shifts the exothermic equilibrium toward NO₂ according to . Excess oxygen, provided by the air used throughout the process, further drives the reaction forward, typically achieving 95% conversion of NO to NO₂ within the available . The resulting NO₂ imparts a characteristic brown coloration to the gas stream, forming visible fumes that indicate successful oxidation. Prompt cooling is essential to minimize partial reversal of the equilibrium, which could otherwise regenerate NO at higher temperatures and reduce overall yield. This stage's output, primarily NO₂ with residual NO and oxygen, proceeds directly to the absorption tower for formation.

Nitrogen Dioxide Absorption to Nitric Acid

The final stage of the Ostwald process involves the absorption of (NO₂) gas, derived from the prior oxidation of , into to form (HNO₃). The primary absorption reaction is a :
3NO2+H2O→2HNO3+NO3\text{NO}_2 + \text{H}_2\text{O} \rightarrow 2\text{HNO}_3 + \text{NO}
This produces (NO) as a , which is subsequently reoxidized to NO₂ using excess oxygen in the gas stream:
2NO+O2→2NO22\text{NO} + \text{O}_2 \rightarrow 2\text{NO}_2
Combining these yields the overall :
4NO2+O2+2H2O→4HNO34\text{NO}_2 + \text{O}_2 + 2\text{H}_2\text{O} \rightarrow 4\text{HNO}_3
The mechanism proceeds via intermediates such as (N₂O₄) and (HNO₂), where NO₂ dimerizes before reacting with , and any HNO₂ formed decomposes to regenerate NO for reoxidation. Absorption occurs in countercurrent towers, where the NOₓ gas mixture (primarily NO₂ with residual oxygen and NO) enters from the bottom and flows upward, while deionized water or dilute (typically starting at lower concentrations) is introduced from the top and cascades downward over trays or packing material. This setup maximizes contact and solubility, with liquid sometimes added at an intermediate point to enhance conversion. The resulting product is a dilute solution at 50-65 wt% concentration, containing traces of dissolved NOₓ. To achieve higher purity, this acid undergoes further : simple boiling concentrates it to the azeotropic limit of about 68 wt%, while using concentrated or other methods yields up to 98 wt% HNO₃ for industrial use. Incomplete absorption leads to NOₓ emissions in the tail gas, primarily as NO and NO₂, but modern plants scrub these to below 200 ppm through extended absorption columns or secondary treatments like catalytic reduction. Overall, the stage recovers over 95% of input NOₓ as HNO₃, minimizing byproducts beyond the recyclable NO, though residual intermediates must be managed to prevent decomposition and gas release. Tail gas treatment, such as non-selective catalytic reduction with , further mitigates emissions to comply with environmental regulations.

Catalysts and Conditions

Platinum-Rhodium Catalyst Properties

The platinum-rhodium employed in the Ostwald process primarily for the oxidation stage is composed of s made from an typically containing 90-95% and 5-10% by weight. These s consist of fine wires, approximately 60-80 μm in diameter, woven into a dense structure with a typical count of per cm² to maximize surface area exposure. Catalyst packs typically consist of 20–50 such layers to achieve the desired conversion. The component significantly improves the alloy's mechanical durability and selectivity by inhibiting rhodium oxide formation and reducing susceptibility to volatile losses under operating conditions. This catalyst functions by adsorbing and oxygen molecules on its surface, thereby lowering the barrier for the oxidation reaction to and enabling high efficiency. Contributing to near-complete conversion (>95%) while minimizing side reactions to nitrogen. However, the catalyst is highly sensitive to poisons such as or compounds, which adsorb irreversibly onto active sites, leading to rapid deactivation and reduced selectivity. Catalyst maintenance involves periodic replacement due to gradual platinum loss, estimated at 0.05-0.3 g per metric ton of produced, mainly through volatilization as platinum dioxide. Recovery of the precious metals from spent gauzes is achieved through solvent extraction techniques, which dissolve and separate and for reuse, recovering up to 95% of the lost material. Although platinum-rhodium remains the standard, research into palladium-based alloys as alternatives shows promise for lower cost and similar activity in ammonia oxidation, but these have not yet reached commercial scale in the Ostwald process.

Optimal Reaction Conditions

In the ammonia oxidation stage of the Ostwald process, the inlet gas temperature is typically maintained at around 850°C to initiate the catalytic reaction, with the exothermic process causing a rapid temperature rise to a peak of 900–1000°C for optimal selectivity toward nitric oxide. Pressures range from 1 to 9 atm, allowing efficient conversion while minimizing side reactions such as nitrogen formation. The feed composition consists of approximately 10% ammonia in air, a ratio carefully controlled to stay below the upper flammability limit and avoid explosion risks during the highly exothermic oxidation. Following ammonia oxidation, the product gases are cooled to 200–400°C to facilitate the non-catalytic oxidation of to , where the reaction equilibrium favors higher conversion at lower temperatures. A short of 0.5–2 seconds is employed to achieve near-equilibrium conversion without excessive , typically at 1–2 to balance kinetics and energy costs. In the absorption stage, the nitrogen dioxide-rich gases are contacted with at 20–50°C and 1–2 to promote dissolution and formation of , with temperatures kept low to enhance and minimize NO evolution. The water flow is regulated to achieve maximal dissolution efficiency and produce concentrated acid (around 60–65 wt%) in a single pass. Energy management across the process relies on heat recovery from the exothermic reactions, primarily through generation in boilers, which enables a net energy output of approximately 2–3 GJ per of (as steam) in modern , with over 90% of the reaction heat recovered. This recovery is critical for economic viability.

Industrial Implementation

Process Flow and Equipment

The Ostwald process operates as a continuous flow system in industrial nitric acid plants, beginning with the vaporization of anhydrous ammonia, which is mixed with filtered air in a preheater or vaporizer to form a gaseous mixture typically containing 10-12% ammonia by volume. This mixture is then compressed to the required pressure, often using multi-stage centrifugal compressors, before entering the catalytic reactor. Following the reactor, the hot process gas is cooled in heat recovery systems and directed to an oxidizer unit where further oxidation occurs, after which it proceeds to absorption towers for contact with water. The resulting dilute nitric acid solution undergoes bleaching to remove dissolved nitrogen oxides and may be further concentrated via distillation if higher strengths are needed, while tail gases are routed to scrubbers for residual NOx removal before venting or energy recovery. Key equipment in the process includes the platinum-rhodium (Pt-Rh) gauze reactor, which features a multi-layer catalyst basket typically comprising 20-30 fine- gauzes (1024 mesh/cm², wire ~0.06 mm) arranged in a cylindrical vessel with a of 2-6 meters to handle high gas throughputs. The absorption system consists of 2-3 columns, often with 4-6 sieve-plate or bubble-cap stages per tower, equipped with cooling coils and demisters to facilitate countercurrent gas-liquid contact and prevent entrainment. Tail gas , typically wet or entrainment separators made of corrosion-resistant materials, capture remaining and particulates downstream of the absorption towers. Additional apparatus includes ammonia vaporizers with heating, coolers using loops for , and employing air sparging or chemical treatment. Safety features are integral to the plant design to mitigate risks from combustible mixtures and corrosive gases. vents are installed on the and housings to relieve during potential detonations, while (NH3) detectors, often electrochemical sensors integrated into monitoring systems, continuously sample for leaks in storage and feed areas to maintain concentrations below the lower limit of 15-28% NH3 in air, with process feeds typically kept around 10% for safety margin. Modern plants incorporate distributed control systems (DCS) for , enabling real-time monitoring of flow rates, temperatures, and gas compositions to prevent unsafe operating conditions. Multistage air and mixed-gas filters ( >99% for particles >1 µm) upstream of the further reduce ignition sources by removing contaminants. The overall plant layout supports capacities of 300-2,000 tons of nitric acid per day through a linear, continuous arrangement of unit operations, with parallel cooling loops using water or air to manage heat from exothermic steps and waste-heat boilers for energy recovery. Compressors and expanders are often placed between the reactor and absorption sections to optimize pressure differentials, while storage tanks for ammonia and acid are segregated with secondary containment to enhance operational safety and efficiency.

Scale and Efficiency

Modern industrial implementations of the Ostwald process operate at significant scales, with single-train typically producing 300 to 500 tons of 100% (HNO₃) per day, while many global facilities employ dual-train configurations to achieve capacities exceeding 1,000 tons per day. This scaling is facilitated by advanced and absorption tower designs that handle high throughputs efficiently. The process demonstrates high efficiency in large-scale operations, achieving ammonia (NH₃) conversion rates of 93% to 96% in the oxidation step, with overall yields reaching 98% or higher through optimizations. Energy consumption is approximately 2.1-2.4 GJ per ton of HNO₃ (as of early 2020s), bolstered by heat recovery where up to 30% of requirements are met from exothermic process heat. Water usage varies by plant design but typically ranges from 5 to 10 m³ per ton of HNO₃ (as of early 2020s), primarily for absorption and cooling, with process water needs around 0.2 m³ per ton for weak acid production. Key optimizations enhance performance at scale, including the recycling of unreacted (NO) from the absorption stage back to the oxidation reactor, which minimizes losses and boosts overall . Modern plants achieve yields exceeding 98% by employing extended absorption columns that capture additional nitrogen oxides. Cost structures in Ostwald process operations are dominated by feedstock, with accounting for about 60% of total production costs at prices around $400-500 per ton (as of 2025). Maintenance contributes to operational expenses through periodic downtime of 5% to 10%, often linked to catalyst regeneration and equipment inspections.

History and Development

Invention and Early Patents

The Ostwald process was developed by German chemist in collaboration with Eberhard Brauer, his future son-in-law, between 1900 and 1901 at the University of Leipzig. This work focused on the of to using as a catalyst, addressing the need for an efficient method to produce from . Ostwald's approach built upon contemporary interest in catalytic reactions, including prior industrial explorations of ammonia oxidation by companies like , though his innovation emphasized precise control of reaction conditions to favor formation over side products. Key to the invention was the 1902 German patent (DRP), which detailed the use of catalysts for the selective oxidation of with air at elevated temperatures, marking a pivotal advancement in industrial catalysis. Early experiments conducted by Ostwald and Brauer demonstrated the feasibility of the process on a small scale, achieving moderate conversion rates that highlighted the potential for synthesis. A corresponding US patent, No. 858,904, was granted in 1907, covering aspects of the complete process for broader application. These patents laid the groundwork for transforming observations into a viable chemical technology. Ostwald's contributions to , including this process, earned him the in , recognizing his foundational studies on reaction rates and catalytic mechanisms. However, early iterations faced significant challenges, particularly low selectivity in the ammonia oxidation step, where competing reactions often produced inert gas, reducing efficiency. The outbreak of in 1914 intensified research efforts, as the demand for in explosives production drove rapid improvements in catalyst stability and process optimization.

Commercial Adoption

The commercial adoption of the Ostwald process commenced with a pilot-scale operation in in 1902, coinciding with Wilhelm Ostwald's patent for the ammonia oxidation method. The first full-scale industrial plant followed in 1906 at , operated by Ostwald's firm in collaboration with Eberhard Brauer, achieving an initial capacity of approximately 100 tons of per year through platinum-catalyzed oxidation of sourced from coke ovens. Expansion accelerated in the 1910s amid 's strategic needs for domestic , with the Gewerkschaft des Steinkohlenbergwerks Lothringen establishing a major facility at Gerthe near in 1908; by 1911, this plant produced 1,495 tons of annually, marking one of the earliest large-scale implementations tied to the coal industry. During , the process proved vital for munitions production, prompting further German scaling, though precise capacities remained limited by supply constraints until the Haber-Bosch synthesis matured around 1913. In the 1920s, adoption spread internationally as synthetic became available; in the , Brunner Mond & Co. integrated the Ostwald process at their site starting in 1923, supporting production from synthetic for and explosives precursors. In the United States, began constructing Ostwald-based plants in the mid-1920s, aligning with their expansion into synthetic to reduce reliance on Chilean imports. IG Farbenindustrie AG, formed in , rapidly scaled operations in , reaching substantial output by the 1930s through integrated ammonia oxidation at sites like Oppau and Leuna. World War II drove unprecedented growth, particularly in the , where production capacity surged to about 880,000 tons per year by the early 1940s, primarily for explosives and propellants via government-backed plants using the Ostwald method. Post-war, the process fueled a global boom, with licensing by firms like Chemical Construction Corporation (Chemico) facilitating widespread implementation; by 1950, the Ostwald process accounted for roughly 70% of worldwide production, underpinning agricultural expansion.

Modern Variants and Impacts

Efficiency Enhancements

Since the mid-20th century, advances in catalyst composition have improved the durability and selectivity of the platinum-rhodium gauzes used in ammonia oxidation. Increasing the rhodium content to 10% in Pt-Rh alloys enhances resistance to volatilization and maintains high conversion rates over extended periods. Pre-activation techniques, such as injecting sulfur-containing compounds like dimethyl disulfide during initial operation, further extend gauze service life by reducing ammonia decomposition and stabilizing the catalyst structure, allowing campaigns of up to several months without significant yield loss. Process modifications have optimized pressure profiles and absorption stages to boost overall . Dual-pressure configurations operate the oxidation stage at lower pressures (typically 4-6 bar) to minimize input while elevating absorption pressures (8-12 bar) to enhance NOx solubility in , achieving up to 99% recovery in extended absorption towers. systems capture exothermic heat from ammonia oxidation and NO-to-NO₂ conversion, converting a significant portion of the released thermal into high-pressure for on-site power generation or process use, often rendering modern plants energy self-sufficient. Since the 1980s, modeling has enabled precise optimization of gas flow and , reducing pressure drops and improving performance. These enhancements have elevated nitric acid yields from around 90% in early commercial implementations to over 99% in contemporary facilities, with ammonia losses minimized to less than 1% through refined selectivity and absorption . In 2025, advanced gauze geometries have been developed to increase further, while data-driven approaches using deduce key process parameter influences for optimized operation.

Environmental and Economic Considerations

The Ostwald process generates nitrogen oxides () emissions in the tail gas from the absorption column, typically ranging from 100 to 3,500 ppm without abatement, primarily consisting of NO and NO2. These emissions contribute to atmospheric and, if uncontrolled, form in the atmosphere, exacerbating through deposition that acidifies soils and water bodies. To mitigate this, (SCR) systems using ammonia over vanadium-based catalysts have been widely adopted since the , in response to regulatory pressures like the U.S. Clean Air Act Amendments, reducing to below 100 mg/Nm³ (approximately 50-75 ppm). The process also involves significant water usage for cooling, steam generation, and absorption towers, with modern plants requiring cooling circulation of 50–93 m³ per of (Δt ≤10°C), though much is recycled internally with net consumption around 1–5 m³ per . from the absorption and neutralization steps contains acidic effluents and trace nitrates, requiring neutralization with lime or ammonia recovery via stripping to prevent environmental discharge and comply with effluent standards. Unneutralized can contribute to body eutrophication and pH imbalances if released. Economically, (CapEx) for a plant typically ranges from $150 to $500 per annual ton of capacity (2010–2020 estimates, inflation-adjusted to 2025), depending on scale and technology, with costs driven by , absorption, and emission control equipment. Operating expenses (OpEx) are dominated by feedstock, accounting for 70-90% of variable costs due to its stoichiometric role in the oxidation step. The process's , excluding upstream , is approximately 0.5-1 ton CO2 equivalent per ton of HNO3, mainly from energy use in compression and heating, though total lifecycle emissions can reach 1.5-3 tons when including ammonia sourcing. Sustainability efforts focus on integrating the Ostwald process with green ammonia produced via renewable , enabling low-carbon variants that reduce overall GHG emissions by up to 90% compared to conventional routes. Additionally, 's role in production supports practices through in , minimizing waste and enhancing in cycles.

References

  1. https://pmc.ncbi.nlm.nih.gov/articles/PMC11755144/
  2. https://www.academia.edu/19401784/Nitric_Acid_Production
  3. https://chemicalnote.com/nitric-acid-hno3-manufacture-by-ostwalds-processreactions-test-structure-and-uses/
  4. https://pubs.acs.org/doi/10.1021/acs.iecr.8b01483
  5. https://www.chemanalyst.com/industry-report/nitric-acid-market-615
  6. https://www.epa.gov/sites/production/files/2020-09/documents/8.8_nitric_acid.pdf
  7. https://rschg.qmul.ac.uk/OccPapers/OccPap7.pdf
  8. https://pubs.rsc.org/en/content/articlehtml/2021/ee/d0ee03763j
  9. https://www.spglobal.com/content/dam/spglobal/ci/en/documents/products/pdf/CI_0325_Global_CEH_Nitric_Acid_Abstract.pdf
  10. https://www.mordorintelligence.com/industry-reports/nitric-acid-market
  11. https://www.grandviewresearch.com/industry-analysis/nitric-acid-market
  12. https://www.industryresearch.biz/market-reports/nitric-acid-market-107787
  13. https://www.nitricacidaction.org/transforming-the-sector/nitrous-oxide-emissions-from-nitric-acid-production/
  14. https://essentialchemicalindustry.org/chemicals/nitric-acid.html
  15. https://ureaknowhow.com/wp-content/uploads/2017/12/2018-01-Brouwer-An-Old-or-A-New-Technology-to-produce-Nitrogen-Fertilizer.pdf
  16. https://homework.study.com/explanation/the-ostwald-process-is-a-chemical-process-for-making-nitric-acid-the-first-step-in-the-production-of-nitric-acid-is-the-oxidation-of-ammonia-represented-by-the-following-equation-4nh3-g-plus-5o2-g-rightarrow-4no-g-plus-6h2o-g-delta-hf-degrees-902-kj-the.html
  17. https://www.mdpi.com/2624-781X/6/1/13
  18. https://research.tue.nl/files/1911936/200210267.pdf
  19. https://www.sciencedirect.com/science/article/pii/S138589472405397X
  20. https://www.nature.com/articles/s41467-022-28370-0
  21. https://webbook.nist.gov/cgi/cbook.cgi?ID=C10102439&Mask=1
  22. https://webbook.nist.gov/cgi/cbook.cgi?ID=C10102440&Mask=1
  23. https://ammoniaknowhow.com/wp-content/uploads/2019/05/Production-Of-Nitric-Acid-2018.pdf
  24. https://udspace.udel.edu/bitstream/19716/17559/1/2015_LoilandJason_PhD.pdf
  25. https://www.ammoniaknowhow.com/wp-content/uploads/2019/05/ABSROPTION-UNIT-IN-DILUTE-NITRIC-ACID-PRODUCTION-2012.pdf
  26. https://pubchem.ncbi.nlm.nih.gov/compound/Nitric-Acid
  27. https://pubs.acs.org/doi/10.1021/acs.jpcc.4c00041
  28. https://pmc.ncbi.nlm.nih.gov/articles/PMC8821626/
  29. https://www.sciencedirect.com/science/article/abs/pii/S0926860X05000669
  30. https://www.researchgate.net/publication/223463219_Reconstruction_of_platinum-rhodium_catalysts_during_oxidation_of_ammonia
  31. https://www.sciencedirect.com/science/article/abs/pii/S0021951708004405
  32. https://www.sciencedirect.com/science/article/abs/pii/S0926860X10002310
  33. http://www.ingentaconnect.com/content/matthey/pmr/1969/00000013/00000001/art00001
  34. https://pmc.ncbi.nlm.nih.gov/articles/PMC8569812/
  35. https://www.sciencedirect.com/science/article/pii/S0021951724001969
  36. https://www.ammoniaknowhow.com/wp-content/uploads/2019/05/Production-Of-Nitric-Acid-2018.pdf
  37. https://www.umweltbundesamt.at/fileadmin/site/publikationen/M150.pdf
  38. https://bibliotekanauki.pl/articles/779139.pdf
  39. https://www.researchgate.net/profile/Vlastimil-Fila/publication/31910858_A_Mathematical_Model_of_a_Gauze_Reactor_for_the_Ammonia_Oxidation/links/55c2298a08aeb975673e3bd4/A-Mathematical-Model-of-a-Gauze-Reactor-for-the-Ammonia-Oxidation.pdf
  40. https://www.azom.com/article.aspx?ArticleID=15689
  41. https://www.sciencedirect.com/science/article/pii/S0959652624001872
  42. https://scispace.com/pdf/nitric-acid-nitrous-acid-and-nitrogen-oxides-2464wsrfft.pdf
  43. https://www.phxequip.com/resource-detail/1/understanding-the-3-different-nitric-acid-production-processes
  44. https://pure.tue.nl/ws/portalfiles/portal/105883898/20180919_CO_Anastasopoulou.pdf
  45. https://par.nsf.gov/servlets/purl/10311649
  46. https://thundersaidenergy.com/downloads/ammonia-synthesis-the-economics/
  47. https://www.alleima.com/en/news-media/technical_articles_blogs/2023/06/material-solutions-for-nitric-acid-producing-plants/
  48. https://www.ias.ac.in/article/fulltext/reso/008/01/0077-0083
  49. https://patents.google.com/patent/US858904A/en
  50. https://www.nobelprize.org/prizes/chemistry/1909/ostwald/facts/
  51. https://www.chemistryworld.com/features/chemists-at-war/7568.article
  52. https://link.springer.com/chapter/10.1007/978-3-319-68963-0_11
  53. https://patents.google.com/patent/US8263036B2/en
  54. https://aiche.onlinelibrary.wiley.com/doi/10.1002/amp2.70039
  55. https://patents.google.com/patent/WO2023025868A1
  56. https://ammoniaknowhow.com/wp-content/uploads/2019/05/Concept-Selection-Nitric-Acid-Plant-2010.pdf
  57. https://www.bcinsight.crugroup.com/2025/09/12/increased-efficiency-through-advanced-gauze-geometries/
  58. https://www.emerson.com/documents/automation/article-emission-monitoring-in-nitric-acid-plants-rosemount-en-72470.pdf
  59. https://www.epa.gov/clean-air-act-overview/1990-clean-air-act-amendment-summary-title-iv
  60. https://www.epa.gov/sites/default/files/2016-06/documents/mac_report_2013-iv_industrial.pdf
  61. https://thundersaidenergy.com/downloads/nitric-acid-production-costs/
Add your contribution
Related Hubs
User Avatar
No comments yet.