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Bushveld Igneous Complex
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The Bushveld Igneous Complex (BIC) is the largest layered igneous intrusion[1][2] within the Earth's crust.[3] It has been tilted and eroded forming the outcrops around what appears to be the edge of a great geological basin: the Transvaal Basin. It is approximately two billion years old[4] and is divided into four limbs or lobes: northern, eastern, southern and western. It comprises the Rustenburg Layered suite, the Lebowa Granites and the Rooiberg Felsics, that are overlain by the Karoo sediments.[5] The site was first publicised around 1897 by Gustaaf Molengraaff who found the native South African tribes residing in and around the area.[6]
Located in South Africa, the BIC contains some of the richest ore deposits on Earth.[7][8][9] It contains the world's largest reserves of platinum-group metals (PGMs) and platinum group elements (PGEs) — platinum, palladium, osmium, iridium, rhodium and ruthenium — along with vast quantities of iron, tin, chromium, titanium and vanadium. These are used in, but not limited to, jewellery, automobiles and electronics. Gabbro or norite is also quarried from parts of the complex and rendered into dimension stone. There have been more than 20 mine operations.[10] There have been studies of potential uranium deposits.[11] The complex is well known for its chromitite reef deposits, particularly the Merensky reef and the UG2 reef. It represents about 75 percent of the world's platinum and about 50 percent of the world's palladium resources. In this respect, the Bushveld complex is unique and one of the most economically significant mineral deposit complexes in the world.[12]
Geology
[edit]


Origin and formation
[edit]The Bushveld Igneous Complex covers a pear-shaped area in the central Transvaal. It is divided into an eastern and western lobe, with a further northern extension.
All three sections of the system were formed around the same time—about 2 billion years ago—and are remarkably similar. Vast quantities of molten rock from Earth's mantle were brought to the surface through long vertical cracks in Earth's crust—huge arcuate differentiated lopolithic intrusions—creating the geological intrusion known as the Bushveld Igneous Complex.
These intrusions are thought to predate the nearby Vredefort impact to the south, by some 30 million years.[13] The effects of these injections of molten rock over time, combined with the crystallisation of different minerals at different temperatures, resulted in the formation of a structure rather like a layered cake consisting of distinct rock strata, including three PGM-bearing layers, referred to as reefs. Large portions of the central area are covered by younger rocks.
The extrusions were emplaced over an early diabasic sill, outcrops of which are visible on the southeastern side of the Complex. These are typically greenish in colour and composed of clinopyroxene, altered to hornblende and plagioclase, and are regarded as the earliest phase of the Complex.
The Complex includes layered mafic intrusions (the Rustenburg Layered Suite) and a felsic phase. The complex has its geographic centre located north of Pretoria in South Africa at about 25° S and 29° E. It covers over 66,000 km2 (25,000 sq mi), an area the size of Ireland.
The complex varies in thickness, in places reaching 9 kilometres (5.6 mi) thick. Lithologies vary from largely ultramafic peridotite, chromitite, harzburgite, and bronzitite in the lower sections to mafic norite, anorthosite, and gabbro toward the top, and the mafic Rustenburg Layered Suite is followed by a felsic phase (the Lebowa Granite Suite).
The orebodies within the complex include the UG2 (Upper Group 2) reef containing up to 43.5% chromite, and the platinum-bearing horizons Merensky Reef and Platreef. The Merensky Reef varies from 30 to 90 cm in thickness. It is a norite with extensive chromitite and sulfide layers or zones containing the ore.
The Reef contains an average of 10 ppm platinum group metals in pyrrhotite, pentlandite, and pyrite as well as in rare platinum group minerals and alloys. The Merensky and UG2 reefs contain approximately 90% of the world's known PGM reserves. About 80% of the platinum and 20% of the palladium mined each year are produced from these horizons.
Proposed mechanisms of formation
[edit]The formation mechanisms of the chromitite seams in the Bushveld Igneous Complex are highly debated: numerous mechanisms have been proposed. The following is a non-exhaustive list of chromitite formations process.
- Changes in chemical and physical properties causes the magma to become concentrated in chromite. When this happens the liquidus becomes free from any other phases. Therefore, chromite is the only mineral to crystallize in the melt thus, accumulating in monomineralic layers on the floor of the magma chamber.[14]
- Increase in total pressure of the system, oxygen fugacity and alpha-silica.[14]
- One of the most accepted mechanisms were proposed by Irvine: it is suggested the chromitites may have formed when a chemically primitive magma intruded into an existing chamber to mix with a differentiated magma.[14][15]
- Gravity and size controlled settling and separation of chromite (concurring with olivine and OPX) grains within crystal-rich slurries[14]
- The mixing of resident magma and granitic melts derived from fusible country rocks[15]
- Mixing of ultramafic magma of layered intrusions, with magma parental to anorthosites[15]
- Deformation of the magma chamber, nucleation, ascent and expansion of gas bubbles or the emplacement of a new pulse of magma increasing total pressure conditions.[15]
- An increase in oxygen fugacity of the magma within the chamber possibly through the release of gas pressure, differential diffusion of hydrogen, or loss of gasses by diffusion.[15]
- Absorption of water by the magma[15]
There has been a proposal of the origins of at least three different processes used to model the PGE mineralization in the area:
Structures
[edit]Layers
[edit]
The Bushveld Igneous Complex is a layered mafic intrusion (LMI) with well-defined ore bodies of stratiform chromitite layers concentrated with the so-called Critical Zone; these are referred to as reefs. The three main reef deposits are the Merensky reef, UG2 Reef, and the Platreef. These reefs are mostly continuous to discontinuous chromite layers with amounts of PGE mineralization. The surface rocks are exposed as separate lobes or limbs (the main ones being eastern, western and northern limbs) spans an area of approximately 66,000 km2. This large igneous province comprises the three main igneous suites the Lebowa Granite Suite (large A-type granitic intrusions), Rustenburg Layered Suite (c. 8 km-thick layered mafic-ultramafic cumulate sequence), and the Rashoop Granophyre Suite (granophyric rocks).[20] These are exposed as layered sequences of sheet like intrusions that are commonly subdivided as five main zones (from bottom to surface): Marginal, Lower, Critical, Main, and Upper Zones. These can be seen in sequence within the mentioned lobes. As for the center area, it is dominated by granites and other related rocks.
A large metamorphic contact aureole is observed within the northern limb, the Potgietersrus area.[21]
The Vredefort impact structure is predated by the BIC intrusion and has been shown to be likely unrelated to the BIC's mineralization.[22]
The Merensky Reef can be subdivided into five layers (from bottom to top):[16]
- Mottled Anorthosite (Mer-Ano): light coloured footwall (base of the overlying chromite layers) anorthosite with dark-coloured bands of pyroxene oikocrysts. This layer has a much higher ratio in Pd/Pt minerals (~20:2) and contains Fe-poor sulphides such as chalcopyrite, pentlandite, pyrrhotite with minor amounts of galena and sphalerite.
- Lower Chromitite (Mer-ChL): dark coloured layer of subhedral to anhedral chromite with varying grain sizes from 0.5 to 2 mm in diameter, enclosed by plagioclase (some observed relicts within poikilitic feldspar with comparable sizes to the anorthosite base layer) and orthopyroxene oikocrysts. This layer is terminated by a sharp footwall contact. In terms of mineralization, in contains minor amounts (c. 0.7%) of granular pentlandite, chalcopyrite, pyrrhotite and pyrite. The PGE mineralization is dominated by Pt-sulphides and other Pt-minerals with minor amounts of Pd-minerals resulting in a high Pt/Pd ratio (c. 106:4).
- Upper Chromitite (Mer-ChU): somewhat similar to the Lower Chromitite layer, but the chromite grains are finer (0.2 to·4 mm) and more densely packed. It is again Pt-mineral dominant with respect to Pd with minor amounts of Cu-Ni-rich sulphides (chalcopyrite, pentlandite and minor pyrrhotite).
- Merensky Pegmatite (Mer-Peg): a green-brown layer of coarse-grained to pegmatitic melanorite that is about 2.4 to 2.8 cm thick. It contains blebby patches of intercumulus plagioclase with meso- to adcumulate pyroxenite with some orthopyroxene grains reaching sizes of up to 5 cm. Chromite grains are next to absent with minor amounts near the upper chromitite contact. Sulphide mineralization is again less than c. 0.7% of the minerals and is dominated by Fe-rich sulphides (more pyrrhotite with respect to pentlandite and chalcopyrite). There are lesser amounts of PGMs compared to the chromitites.
- Merensky Melanorite (Mer-Nor): Somewhat similar to the previous layer, but is a finer (medium-grained) orthocumulate melanorite with an account 1.6% of disseminated and intergranular to granular Fe-dominant sulphide mineralization (pyrrhotite with some pentlandite and chalcopyrite). It is more chalcopyrite-rich, but occurs as smaller (< 1.5 mm) grains than those found within the pegmatite. There is intercumulus quartz, rare earth element-bearing minerals and albite–anorthite–orthoclase symplectites.
The UG2 Pyroxenite (Reef): The host rock of the UG2 chomitites is dominated by granular orthopyroxene, interstitial plagioclase and clinopyroxene with minor variable amounts accessory minerals such as phlogopite. The UG2 chromitites are underlain by pyroxenite footwall that is distinct from hanging wall pyroxenite. Chromite subhedral to subrounded (less than 0.5 mm in size) grains are a minor (c. 4%) but constant phase that is embedded with orthopyroxene (and other interstitial phases such as mentioned) throughout this footwall pyroxenite. Large oikocrysts are visible within the outcrops and on mine walls.[14]
The Platreef: this reef structure is divided into three sections:[16]
- The Lower Reef is composed of norites and feldspathic pyroxenites that have been recrystallized and overprinted. This layer has abundant country-rock xenoliths particularly near the base of the layer.
- The Central or Middle Reef is composed of igneous peridotite and recrystallized "vari-textured" mafic rocks with metasedimentary xenoliths.
- The Upper Reef is composed primarily of plagioclase-pyroxenite and norite that gradually changed to norite and gabbronorite toward the Main Zone (see units) contact. There are xenoliths but these are relatively scarce brecciated chromitite within the feldspathic pyroxenite near the top of the reef.
Faults and Shear Structures
[edit]The BIC contains several shear zones, some are within known faults, the most important of which are the Jagersfontein Shear Zone (JSZ), the Klerksdorp Shear Zone (KSZ), the Potgietersrus Shear Zone (PSZ), the Thabazimbi-Murchison Lineament (TML), the Brits Shear Zone (BSZ), the Olifants River Shear Zone (ORSZ) and the Steelpoort Shear Zone (SSZ).
These shear structures control several factors and have major geological implications within the Bushveld Igneous Complex, including structural, mineralogical, tectonic, metamorphic and economic. Some structural controls include the direction and flow of magma and intrusions, structural traps for mineralization and the structural evolution of the complex. Mineralization controls the Platinum Group Elements (PGEs) and Platinum Group Metals (PGMs), chromium, copper, nickel, gold and vanadium concentrates, reef formation and orientation, and affect the type of mineralization, for example magmatic and hydrothermal deposits.[23][24] Tectonic controls and effects can be seen or indicated by stratigraphic and crustal thickening and thinning, record of tectonic activity by type of structure such as collision and rifting, and influence on the evolution of the BIC. Metamorphic controls are localised metamorphism and alteration in shear zones, they affect mineral formation and stability, and they may show evidence of pressure-temperature-time (P-T-T) paths.[25] Economic controls include, mineral deposits, they help to guide mining and exploration and with resource and reserve estimation and extraction.
Eastern Lobe
[edit]The eastern lobe of the Bushveld Complex comprises three distinct zones, each of which is separated from the others by structural boundaries. The southern and central zones are separated by the Steelpoort Fault. The eastern lobe is further subdivided by the presence of the Stofpoort and Wonderkop Faults, which serve to differentiate the northeast from the central zone. The Stofpoort Fault is situated in close proximity to the Olifants River. The western zone is separated from the remainder of the region by two anticlines, namely the Katloof and Phosiri.[26]
The Merensky Reef has been displaced by 2 km to the south in the vicinity of Zebediela, as a consequence of the Madika Fault. The Madika Fault is sub-parallel to the Wonderkop Fault, which is located in the Bojanala Platinum District Municipality in the vicinity of the town of Wonderkop. The critical zone of the Rustenburg Layered Suite is displaced 500 m to the south by the Makweng Fault.[26]
The Sekhukhune Fault trends in a north-south direction and has a throw of up to 2 km to the west. The Sekhukhune Fault is situated to the east of the Fortdraai Anticline. The Laersdrift Fault is located to the NW of the eastern Bushveld Complex.[27]
Western Lobe
[edit]The Pilanesberg Complex is situated in the western lobe of the Bushveld Complex. The southern part of the Pilanesberg Complex exhibits NW–SE isopach lines that trend parallel to the Rustenburg Fault, which dips in the same direction towards the center of the Western Bushveld Complex.[27]
Southern Lobe
[edit]The Brits Graben is situated in the eastern region, in close proximity to Hartebeespoort. This Graben is delimited by a series of parallel faults, among which the most prominent is the Brits Fault, which trends NW–SE and intersects the Rustenburg Layered Suite, the Transvaal Supergroup and the Pretoria Group.[27] The BSZ is NW–SE trending and is located within the Brits Fault.
Northern Lobe
[edit]The NE–SW trending Ysterberg–Planknek Fault (YPF) is situated within the northern lobe of the Bushveld Complex. An additional ENE–WSW trending fault is situated within the northern lobe and is designated the Grasvally Fault.[27]
The boundary between the northern and southern lobes is defined by the Melinda Fault, which dips to the west and is situated within the Pietersburg terrane. The Melinda Fault extends in an eastern direction along the Palala Shear Zone (PSZ). This Fault and the PSZ are collectively designated as the Palala-Zoetfontein Lineament.[28]
The TML represents the boundary between the southern portion of the Northern Limb and the remainder of the Bushveld. It demarcates the boundary between the Pietersburg terrane and the central portion of the Kaapvaal craton.[28] In general, the TML is a large EW trending shear zone that forms a boundary between the Bushveld Complex and the Limpopo Belt and is 20 and 30 km wide. The JSZ is located within the TML, it trends NE–SW and is between 10 and 15 km wide. The KSZ runs parallel to the JSZ, trends NS and can be up to 10 km thick in places, while the PSZ is located in the northern part of the BIC, trends EW and can be 5–10 km wide.
Two distinct fault orientations have been identified within the Pietersburg terrane: a NE–SW orientation and an ENE–WSW orientation. The most conspicuous faults with these orientations are the YPF and the Zebediela Faults.[28]
Mineralization within Shear Zones
[edit]Different mineral occurrences are more strongly associated in the BIC[25] in specific shear zones. PGEs are generally associated with the Jagersfontein, Klerksdorp and Potgietersrus shear zones and the Thabazimbi-Murchison lineament, chromium with the Rustenburg Layered Suites (RLS) critical zone and the TML, and gold with the Jagersfontein and Klerksdorp shear zones. Vanadium deposits are associated with the vanadium-rich magnetite deposits of the Bushveld, such as the TML, some of which may be associated with shear zones, and copper and nickel deposits, which often occur together in the same deposit, are associated with mafic and ultramafic intrusions and shear zones, such as the JSZ.
Units
[edit]
The general mineral assemblage of the chromitite seams in the Bushveld Complex consists of olivine + chromite, chromite +/- bronzite + plagioclase, chromite + plagioclase, and chromite + clinopyroxene.[29]
The BIC's layered sequence is commonly divided into five different zones:
- Upper Zone : This is the uppermost component of the Rustenburg Layered Suite (RLS). This zone is a thick gabbroic succession and is laterally dominant in iron-rich cumulates that host one of the world's largest titanium-magnetite resources.[30] The general rock assemblage is Gabbro + Olivine diorite + Anorthorsite. The upper zone is approximately 1,000-2,700 m thick and is composed of gabbro and anorthosite which overlays more differentiated rocks such as diorite progressively. The Upper Zone composes of 24 major layers of massive magnetite up to roughly 6 m thick. The contact between the Main and Upper Zones is commonly defined via the first occurrence of cumulus magnetite. On the other hand, some workers place the boundary on a notable pyroxenite layer characterized by reversals in stratigraphic trends of Sr isotopic ratios and iron enrichment that is located hundreds of meters under the first occurrence of cumulus magnetite.[20]
- Main Zone : This is composed of a succession of gabbronorites with bands of pyroxenite and anorthosite.[30] The Main Zone is roughly 1,600–3,500 m thick. There is a uniform sequence of cumulates consisting of norite and gabbronorite. The anorthosite layers make up roughly 5 percent of the lithology. Moreover, pyroxenite is scarce, and magnesian olivine and chromium spinel are not present in this zone.[20]
- Critical Zone : Approximately 930-1500m thick, delimited as its section because it contains several chromitite seams/layers, this is where the chromitite layers are concentrated: composed of Lower Group chromites (LG) LG1-LG7, LG6 (subdivided as LG6A, LG6B), Middle Group chromites (found between lcz and ucz, t boundary) (MG) MG1 to MG4, and Uper Group chromites (UG) UG1 and UG2 for a total of 13 chromite[20] seams recognized in the Critical zone. Zone subdivided as Upper and Lower critical subzones. As many as 25 individual chromite layers have been identified in the critical zone alone[29] with 14 being identified as major chromitite seams subdivided into four different type: Type I-LCZ base cycles, Type II-UCZ base cycles, Type III-thin intermediate layer within cyclens, Type IV-stringers associated to OPX pegmatoids.[29]
- Upper Critical Zone: Approximately 450-1000m thick, defined as Anorthosite layer found between two chromite layers, MG2 and MG3 chromitites, with repetitive or cyclic layers of (the cyclic origin is disputed whether it is multiple injections of new magma[31][32] or if it is by basal settling of a crystal mush transported by slurry flow[33]), chromites overlain by harzburgite (not always present), then pyroxenite, norite and finally anorthosite.
- Lower Critical Zone: It is an olivine-rich ultramafic cumulates that is approximately 500 m thick, composed entirely of ultramafic cumulates,[20] dominated by pyroxenite with some presence of cumulus plagioclase in some rock layers. The LGs (LG1-LG7) hosted by this feldspathic pyroxenite contains LG6 is the thickest and most economic chromitite seam in Bushveld with a general rock assemblage of Pyroxenite, Harzburgite, Dunite[29]
- Lower Zone: The general rock assemblage is Pyroxenite + Harzburgite + Dunite. The Lower Zone is roughly 900–1,600 m in thickness and is composed of layered olivine-saturated and orthopyroxene-saturated cumulates. The chromitite layers in this zone are only known from the northern and western parts of the complex.[20]
- Marginal Zone: (not always present) is a section that is up to 250 m thick, composed of massive, fine to medium-grained norite and gabbronorite[20] with varying amounts of accessory minerals such as quartz, hornblende, clinopyroxene, and biotite. This is a clear indication of metasediments contaminating the magma.[34]
Industry
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Mining
[edit]
The area has many different ore deposits, but mostly with a focus on PGEs (primarily platinum and palladium), vanadium, iron (generally from magnetite), chromium, uranium, tin, ...[7] There are multiple major mining companies that are heavily involved within this area, particularly AngloAmerican, African Rainbow Minerals, Impala Platinum, Northam Platinum Ltd., Lonmin plc, and more recently Bushveld Minerals. It has been reported that more than 20 billion metric tons of PGE ore rock has been indicated in South Africa by the different exploration and mining companies of which contains about 38.1 kilotons of platinum metal in mineral reserves and resources in the Bushveld. The sum of PGEs and Gold resources and reserves equates to a total of about 72 kilotons from the Bushveld Complex alone.[20] Most are underground mines (such as Longhole Stoping, Drift-and-Fill mining, etc.[34]), fewer are open pit like the large Mogalakwena mine.[35]
Environmental and health issues
[edit]Mining feasibility studies have identified impacts on surface water, groundwater, wetlands, flora, fauna and related social issues. Additionally, these impacts include increased drainage of salts, sediments thought channels and streams near the mine sites. There has been an increased fleeting dust generation contaminating air and water, surface water runoff is leading to a decrease in water recharge for downstream users, possibly the loss of certain vulnerable flora and fauna species, soil compaction and land erosion; the contamination and quality deterioration of the surface and ground water is driven by seepage from waste rock dumps, stockpiles, gas spills, etc. The mining activities that make large use of water could potentially lead to dewatering of local aquifers. Moreover, construction activity impacts such as removal of natural land and noise from machinery and vehicles may disrupt the surrounding ecosystems.[34]
Depending on the beneficiation and concentration methods, there are different impacts plausible such acid runoff from leaching and metal slimes.[36] Hexavalent chromium from mine wastes has been shown to be highly toxic.[29]
A study has shown that up to 5% of the world total production of PGEs is lost and emitted as dust entering the global biogeochemical cycle.[9] Nearby towns have shown elevated levels of platinum within the soil, atmosphere and vegetation. Since some of the food production activities are located near these areas, the primary concern is that the local population (several towns and cities, including Rustenburg with more than 500,000 inhabitants[37]) will ultimately be exposed to the contaminants either by skin contact, dietary intake or inhalation.[38] PGEs such as platinum, palladium, and rhodium have been shown to bioaccumulate under the form of PGE-Chloride in the liver, kidneys, bones and lungs. The intake is generally through metallic or oxide dust that is inhaled or is absorbed through the skin causing contact dermatitis, on the long term causing sensitization and can eventually to lead to cancers.[39] A study from January 2013, has shown an increasing trend of the development of silicosis caused by silica dust and asbestos fibers related to workers mining in the Bushveld igneous complex.[40] Similarly, another study has found high concentrations of microscopic (<63 μm) PGE airborne dust particles near the mining areas. These have been found to be transported surface runoff and atmospherically, then further concentrated into soils and rivers such as the Hex River which flows directly into Rustenburg, the most populated municipality of North West Province of South Africa.[8]
A study from Maboeta et al. in 2006, has revealed through chemical analysis that the soil from a tailings disposal facility had higher levels of C, N, NH4 and K in comparison to the other general sampling sites. The difference was attributed to rehabilitation regimes being implemented reducing the abundance of these microbial and bacterial nutrients.[41]
Mining operations in general consume much energy and water, producing much waste rock, trailings and greenhouse gases. A study has shown that PGM mining has a significant impact on the global environment. The environmental costs for platinum mines are only slightly higher in energy, somewhat lower in water and moderately higher in greenhouse gas emissions when compared to gold mining.[42]
Social issues
[edit]South Africa's economy is heavily tied to its mining industry and has been greatly affected by low metal prices. Mining companies have had to cut costs by lowering production, closing mines, selling off projects, and reducing the work force. Miners are quite often on strike asking to get the minimum salary, and mines continue to fail safety standards and face labour unrest.[citation needed] A research study in 2016 by eunomix showed that Rustenburg, one of the fastest-growing cities in South Africa, has an "abnormally high concentration of young men who are separated from their families due to the migrant labour system". The population is facing a lack of education, high crime levels, and health problems within the workforce. Additionally, they are facing high poverty levels, government deficits, and are still heavily dependent on the platinum mining industry which is "responsible for more than 65% of local GDP and 50% of all direct jobs" (over 70,000 jobs). The accommodations and housing are lacking and have seen little to no effort from the mining companies to improve them. Between 2013 and 2016, the platinum companies contributed more than ZAR 370 million into the city; funding local infrastructure, water supply and treatment centres, sporting programmes, tourism, public road expansions, sewage treatment plants, cultural activities. The primary concern is the combination of high poverty rates and social injustice.[43]
Operations
[edit]There have been much more than 30 individual mine operations mostly mining for PGEs, some chrome, tin, and others (of which most are underground, few are open cut). These are shown below as a non-exhaustive list:
- Western Lobe: Rustenburg, Impala, Bafokeng Rasimone,[44] Union,[45][46] Amandelbult[47] (composed of Tumela and Dishaba[48]), Northam, Hartebeestpoort, Styldrift, Elandsfontein,[49] Crocodile River,[50] Thaba, Vametco Mine, Pandora,[51] Lonmin, Marikana.[52] Kroondal,[53][54] Rooiberg Tin mine, Leeuwpoort,[55] Pilanesberg,[56] 2008 Prospects: Frishgewaagd Ledig, Leeuwkop[57]
- Eastern Lobe: Lebowa/Bokoni, Twickenham, Marula,[56] Modikwa, Smokey Hills,[56] Two Rivers,[56] Mototolo, Everest,[56] Limpopo and Mogalakwena (Potgietersrus),[58] Maandagshoek, Middelpunt Hill, Blue Ridge,[56] 2008 Prospects: Ga-Phasha,[59] Kennedy's Vale, Sheba's Ridge and Booysendal[60]
Reserves
[edit]The three largest ore bodies are the Merensky Reef, the UG2 Chromitite Reef and the Platreef:[20]
- The Merensky Reef is a predominantly sulfide-rich pyroxenite layer mined on both the eastern and western limbs of the Bushveld Complex not only supplies most of the world's PGEs but also notable amounts of copper, nickel, cobalt and gold as byproducts.[56]
- The UG2 Chromitite Reef, known as the UG2 Reef Upper Group 2, is a chromite-rich layer that lacks sulfide minerals. As a whole, it is possibly one of the largest resources in terms of platinum group elements, larger than the overlying Merensky Reef. and is also mined on both the eastern and western limbs.[56]
- The Platreef is the world's third largest PGE deposit (after UG2 and Merensky reefs). The ore body is composed of three "broadly mineralised horizons rather than a distinct reef".[56]
| Ore body | Ore (Mt) | Platinum (t) | Palladium (t) | Rhodium (t) | Ruthenium (t) | Iridium (t) | Gold (t) |
|---|---|---|---|---|---|---|---|
| Merensky Reef | 4200 | 13000 | 6100 | 800 | 250 | 51 | 1200 |
| UG2 Chromitite | 7300 | 20000 | 13000 | 3700 | 940 | 230 | 420 |
| Platreef | 5200 | 4500 | 5400 | 300 | N/A | N/A | 590 |
| Miscellaneous | 850 | 590 | 610 | 58 | N/A | N/A | 58 |
| Total | 17550 | 38090 | 25110 | 4858 | 1190 | 281 | 2268 |
* Table modified from USGS, 2010.[20]
Most of the identified mineral inventory is from the three described reefs, most of it is located within the eastern limb but most of the reserves are found within the western limb.[20]
Economy
[edit]The chrome deposits of the Bushveld forms the majority in terms of the proportion of all the known chrome reserves of the world. This area is very strategic as it is easy and cheap for mining; this is because their continuity in thick seams over scores of miles of strike and their persistence in depth, which has all been proved via deep drilling. Just like the chrome seams, Bushveld's titano-magnetite seams of the Main Zone illustrates similar continuity and persistence though, have not been extracted to date. Contained within the titano-magnetite ore is a persistent fractional percentage of vanadium. Reserves of the titanium and vanadium in these iron ores could potentially be very large. With that being said, it is evident that the ores existing in Bushveld occupy an important place in the world of mineral resources.[61]
Although other major platinum deposits have been found in places like the Sudbury Basin or Norilsk (Russia), the Bushveld Complex still remains as one of the prime sources of PGE ore. There have been many strikes for unfair pay and working conditions, illegal miners (so-called "zama-zamas"), gun-fire conflicts, political swindles and legal fights.[62] The prime use of platinum is for auto-catalytic converters (in cars) and jewellery.[63]
The total net demand of PGE in 2012 was 197.4 metric tons according to a Johnson Matthey 2013 estimate. The demand of platinum has somewhat steadily been increasing, driven by the more intensive use per capita with developing area and urbanization,[20] the demand reached an all-time high in 2005 of 208.3 metric tons.[63] From 1975 to 2013, the autocatalytic and jewellery industry dominated the market with more than 70% of the gross demand. Jewellery was barely ahead of autocatalysts prior to 2002 with brute gross demand values being somewhat similar or higher. From 2002 to 2003, the gross demand significantly decreased in jewellery (87.7 to 78.1 tons), but has largely increased in autocatalysts (80.6 to 101.7 tons) and has since then almost consistently dominated the market (with 2009[64] being the one exception linked to weak car sales).[65] In 2016, the platinum market continued to be in deficit for the 5th consecutive year, just barely reaching a demand 200,000 oz. In 2017, the two still dominate the market gross demand by far.[66] That being said, the global platinum demand is still expected to increase in subsequent years to 2017.[20]
The price of platinum is quite volatile in comparison to gold, but both have greatly increased over the last century.[64] Despite platinum being far much rarer than gold,[67] 2014 was the last year platinum was valued at a higher price than gold (2018).[64] This coincides with the 2014 South African platinum strike.
Platinum is more likely to be affected by social, environmental, political and economic issues where as gold not as much. This is because platinum has large mineral resources already identified and is not expected to be depleted for many decades (potentially up to year 2040). Furthermore, platinum is geographically restricted to the three by far the most significant resources, namely the BIC, the great dyke (Zimbabwe) and Noril'sk-Talnakh in Russia. An important detail to note is that palladium has been and is considered as the alternative to platinum.[20] Recently (2017), the supply-demand gap has greatly decreased.[66] Looking at political and social issues, there have been quite a few platinum mining-related strikes since before the 21st century: Impala strike,[68] 1986 Gencor strike,[69] 2004 Impala[70] and Anglo Plats strikes,[71] 2007 South Africa miners' strike, 2012 Marikana killings, Lonmin 2013 strike,[72] and 2014 South African platinum strike.
See also
[edit]References
[edit]- ^ Pirajno, Franco (2012-12-06). Hydrothermal Mineral Deposits: Principles and Fundamental Concepts for the Exploration Geologist. Springer Science & Business Media. ISBN 978-3-642-75671-9.
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External links
[edit]- USGS: Platinum-Group Elements in Southern Africa—Mineral Inventory and an Assessment of Undiscovered Mineral Resources
- USGS: Stratiform Chromite Deposit Model
- Concentration of Particulate Platinum-Group Minerals during Magma Emplacement; a Case Study from the Merensky Reef, Bushveld Complex
- Origin of the UG2 chromitite layer, Bushveld Complex
- A Novel Hypothesis for Origin of Massive Chromitites in the Bushveld Igneous Complex
- Bushveld Igneous Complex by Judith A. Kinnaird (PDF 39 pages) – retrieved 2009-05-22
- Photos of Bushveld Igneous Complex (Rustenburg Layered Suite) – field exposures (University of Cape Town) retrieved 2018-03-23
- Bushveld Igneous Complex (Rustenburg Layered Suite) photomicrographs of thin sections (University of Cape Town) retrieved 2018-03-23
Bushveld Igneous Complex
View on GrokipediaThe Bushveld Igneous Complex is the largest layered mafic-ultramafic intrusion on Earth, emplaced approximately 2.06 billion years ago in the Paleoproterozoic Era within the Kaapvaal Craton of northeastern South Africa.[1][2] It covers an area exceeding 50,000 square kilometers across five major lobes, with rock sequences reaching thicknesses of up to 9 kilometers due to magmatic differentiation and sedimentation processes.[3][4]
The complex comprises the Rustenburg Layered Suite of ultramafic to gabbroic rocks, overlain by felsic phases including the Rooiberg Group volcanics and Lebowa Granite Suite, formed through repeated injections of mantle-derived magma into a subvolcanic chamber.[5][6] Its stratified layers, resulting from gravitational settling and in situ crystallization, host exceptional concentrations of platinum-group elements (PGEs) in horizons such as the Merensky Reef and UG2 chromitite, alongside vast chromite and vanadium resources.[1][7] These deposits supply over 70% of global platinum and significant portions of other critical minerals, underpinning South Africa's mining economy despite challenges from deep-level extraction and geological complexity.[6][8] Debates persist on the precise mechanisms of ore formation, with evidence supporting hybrid models involving magma mixing, assimilation, and density-driven segregation rather than simple cumulate settling.[9][10]
Location and Extent
Geographical Setting
The Bushveld Igneous Complex occupies a pear-shaped expanse exceeding 66,000 km² in northern South Africa, comparable in area to the Republic of Ireland, with maximum thicknesses reaching 9 km.[11] It is exposed along the margins of the ancient Transvaal Basin, primarily spanning the North West, Gauteng, Mpumalanga, and Limpopo provinces.[12] The complex's geographic center lies approximately north of Pretoria at coordinates around 25° S latitude and 29° E longitude, extending roughly from 21.5° S to 26.5° S and 26° E to 31° E.[13] Structurally, the Bushveld Complex comprises a southern basin that bifurcates into prominent eastern and western lobes, connected via a narrower southern region, alongside a detached northern limb.[2] This configuration reflects its emplacement as a large layered intrusion within the Kaapvaal Craton, intruding into volcanic and sedimentary rocks of the Rooiberg and Transvaal Supergroups.[14] The surface expression features undulating terrain typical of the bushveld savanna, with outcrops varying due to post-emplacement erosion and tectonic tilting.[15]Structural Features and Lobes
The Bushveld Igneous Complex displays a lopolithic geometry, forming a large, saucer-shaped intrusion with gently outward-dipping layered mafic and ultramafic rocks that thicken toward the margins.[16] This structure, first described as a lopolith, features a central synclinal axis where the layers sag, with dips typically ranging from 10° to 30° in the exposed sections. The complex covers an inferred area of approximately 66,000 km², though erosion has exposed only parts of the Rustenburg Layered Suite in arcuate outcrop patterns.[10] The intrusion outcrops primarily in three main lobes: the western, eastern, and northern lobes, which together span over 400 km in extent.[17] The western lobe, located in the western Transvaal, dips eastward at angles of about 20°-30°, forming a broad arc against the Pretoria Group sediments.[6] In contrast, the eastern lobe dips westward, exhibiting similar gentle inclinations and hosting significant exposures of the Upper and Main Zones, with its arcuate form reflecting the original emplacement against Archean basement. The northern lobe represents an extension northward from the eastern lobe, dipping southward and featuring thinner sequences compared to the southern parts, likely due to proximity to the feeder zones.[18] Additional minor lobes or extensions, sometimes counted to make five arcuate segments, connect these main outcrops and highlight the complex's composite nature, emplaced as multiple pulses into the Kaapvaal Craton.[10] Structural disruptions, such as faulting and post-emplacement tilting, have influenced the current configuration, but the primary lopolithic form persists without evidence of impact-related shock features.[19] These lobes enclose roof granites of the Lebowa Granite Suite, underscoring the intrusion's interaction with overlying continental crust during emplacement around 2.06 Ga.[20]Geological Formation
Age Determination
The age of the Bushveld Igneous Complex has been established primarily through U-Pb radiometric dating of igneous accessory minerals, including zircon, baddeleyite, and titanite, which provide robust constraints on crystallization timing due to their resistance to post-emplacement alteration and high closure temperatures. High-precision techniques such as secondary ion mass spectrometry (SHRIMP) and isotope dilution thermal ionization mass spectrometry (ID-TIMS) have been applied to samples from the Rustenburg Layered Suite, the dominant mafic-ultramafic component. These methods yield concordant ages typically ranging from 2060 Ma to 2055 Ma, indicating protracted but punctuated magma emplacement over approximately 5 million years rather than a single pulse.[21][22] Early U-Pb zircon dates from the 1970s to 1990s scattered between 2070 Ma and 2040 Ma, reflecting analytical limitations and potential lead loss or inheritance, but subsequent refinements using baddeleyite from ultramafic Lower Zone rocks and titanite from the Marginal, Lower, and Critical Zones have narrowed the timeframe. For instance, ID-TIMS on baddeleyite and zircon populations establishes an initiation age near 2059.5 ± 0.6 Ma for the earliest pulses, with terminal crystallization of the Upper Zone at around 2054.3 ± 0.3 Ma.[23][21] Titanite U-Pb data further corroborate a minimum emplacement age of 2054 ± 2 Ma for the layered mafic-ultramafic rocks, as these minerals record late-stage magmatic temperatures above 650°C.[23] Discrepancies in some datasets, such as slightly older inherited cores in zircon suggesting minor crustal assimilation, are resolved by focusing on rim analyses representing primary igneous growth.[22] Associated felsic phases, including the Rooiberg Group volcanics and Lebowa Granite Suite, overlap temporally with the layered suite, with SHRIMP U-Pb zircon ages of 2055 ± 3 Ma to 2052 ± 14 Ma, supporting coeval bimodal magmatism during a brief Proterozoic pulse.[24] Complementary ⁴⁰Ar/³⁹Ar dating on biotite and hornblende from chromitite layers like the UG-2 provides cooling ages of 1970–1950 Ma, indicating post-crystallization residence in the mid-crust before exhumation, but these do not alter the primary U-Pb emplacement chronology.[25] Recent apatite Lu-Hf and U-Pb analyses affirm the zircon-based framework, with no evidence for significant revision despite ongoing debates on exact duration versus rapidity of cooling.[26]Emplacement Processes
The Bushveld Igneous Complex was emplaced through episodic injections of primitive mafic to ultramafic magmas into the upper to mid-crust beneath the Kaapvaal Craton, intruding Archean granite-greenstone terrane and overlying Transvaal Supergroup sediments around 2055–2060 Ma.[1] These injections formed a composite sill-like body up to 9 km thick and covering approximately 66,000 km², with magma volumes estimated at 0.5–1 million km³ derived from mantle sources.[2] Emplacement occurred via feeder dykes exploiting pre-existing structures, such as the Thabazimbi-Murchison Lineament, enabling lateral spreading and development of the complex's lobate geometry in eastern, western, and northern sectors.[27] Multiple discrete pulses of magma, numbering at least several dozen based on compositional reversals in minerals like plagioclase and orthopyroxene, replenished transient magma chambers or lenses, promoting differentiation through fractional crystallization and assimilation of footwall rocks.[28] In the Lower and Critical Zones, ultramafic magmas (komatiitic in composition) intruded as sills into partially crystallized mafic hosts, evidenced by sharp contacts and xenoliths of norite in pyroxenites.[1] U-Pb geochronology of baddeleyite in chromitite and pyroxenite layers documents non-stratigraphic sequence, with the UG1 chromitite dated at 2056.28 ± 0.15 Ma underlying younger MG2A (2055.68 ± 0.20 Ma) and Merensky Reef (2055.54 ± 0.27 Ma) units, indicating intrusive emplacement rather than in situ gravitational settling over ~0.6 Myr.[1] The Rustenburg Layered Suite accumulated incrementally as a vertical stack of crystal mushes from these pulses, with magmas ponding at crustal pressures of 0.2–1 GPa and undergoing assimilation-batch crystallization (up to 43% crustal assimilation in lower-crustal sources) to generate ultramafic to gabbroic cumulates.[20] Directional recharge, primarily from north to south in the Upper Main Zone, is inferred from lateral geochemical variations and Sr isotopic disequilibria in plagioclase, reflecting flow-induced differentiation during sill propagation.[29] Thermal modeling constrained by mineral oxygen isotopes and diffusion profiles indicates total magma addition and initial cooling occurred within ~75,000 years, followed by protracted solidification over <1 Ma to below 450°C.[28][30] Local complexities, such as in the eastern lobe's peridotite bodies, involved stepwise sill emplacement as kilometer-scale magma fingers advancing southeastward, with structural evolution accommodating volume expansion through roof uplift and floor subsidence.[31] This multi-pulse mechanism contrasts with single-chamber models, as supported by the absence of widespread convective overturn signatures and the presence of intrusive relations across zone boundaries.[10]Debates on Origin Mechanisms
The origin of the Bushveld Igneous Complex (BIC) is primarily attributed to large-scale melting in the mantle, driven by thermal anomalies that generated voluminous mafic to ultramafic magmas subsequently emplaced into the upper crust of the Kaapvaal Craton around 2.06 Ga.[32] The dominant hypothesis posits derivation from a deep mantle plume impinging on the lithosphere base, causing partial melting and upward migration through radial dike swarms, as evidenced by Lu-Hf isotopic ratios in zircon and baddeleyite indicating a primitive, high-lu/Hf mantle source with minimal early differentiation.[32] This model aligns with the BIC's classification as part of a large igneous province (LIP), featuring over 400,000 km³ of intrusive and extrusive rocks, including the associated Rooiberg felsic volcanics.[33] Supporting geochemical data show mantle-derived parental magmas with tholeiitic compositions, variably contaminated by assimilation of Transvaal Supergroup sediments, yielding diverse isotopics (e.g., εNd from -4 to +3).[22] Alternatives to a primary plume trigger include models invoking lithospheric processes, such as upwelling of eclogite-rich subcontinental lithospheric mantle (SCLM) triggered by far-field tectonic stresses during early supercontinent assembly, leading to rapid decompression melting without requiring deep thermal anomalies.[34] This is inferred from the BIC's magmas exhibiting interactions with metasomatized SCLM, as traced by Re-Os isotopes, and the complex's location at the craton margin rather than a classic intraplate hotspot track.[34] An unpopular impact-related origin has also been proposed, citing initial catastrophic disruption evidenced by high siderophile element enrichments and shocked minerals in marginal facies, though this lacks broad acceptance due to insufficient meteoritic signatures and conflicts with precise U-Pb timelines showing no precursor crater.[35] These non-plume models challenge the plume paradigm by emphasizing edge-driven convection or delamination as sufficient for the observed volumes, but they are constrained by the BIC's radiogenic isotope homogeneity suggesting minimal recycled crust involvement compared to plume-influenced LIPs.[2] Debates persist on the tempo and style of magma generation and initial emplacement, with U-Pb geochronology indicating the entire Rustenburg Layered Suite crystallized in under 1 million years, implying pulsed, high-flux injections rather than prolonged accumulation.[34] Proponents of a single, massive plume-head event argue for dynamic crustal opening via plume-driven doming and rifting, but structural evidence favors a "stack-of-sills" mechanism, where repeated recharge built a mush-dominated chamber through slush zone remobilization, reconciling the rapid timescale with rhythmic layering.[36] This contrasts with early models of a vast, equilibrium crystal slurry settling in one chamber, now critiqued for underestimating convective overturn and sidewall accretion observed in seismic and xenolith data.[36] Resolution favors hybrid models integrating plume initiation with lithospheric response, as pure alternatives fail to account for the BIC's scale and association with synchronous felsic magmatism exceeding 2 million km³.[33]Stratigraphy and Petrology
Principal Zones
The Rustenburg Layered Suite, the mafic-ultramafic component of the Bushveld Igneous Complex, comprises four principal zones from base to top: the Lower Zone, Critical Zone, Main Zone, and Upper Zone. These zones exhibit progressive differentiation from ultramafic to more felsic compositions, reflecting fractional crystallization in a large magma chamber.[14][2] The Lower Zone consists primarily of ultramafic cumulates such as harzburgite, dunite, and orthopyroxenite, with rare plagioclase-bearing rocks. It reaches thicknesses exceeding 1 km in structural troughs but thins or is absent over swells, displaying significant lateral variations in thickness and lithology. Chromite content is low, typically less than 1 modal percent, and no major chromitite layers occur. This zone is best developed in the northern portions of the eastern and western limbs.[14][2] The Critical Zone, up to 1500 m thick, is subdivided into Lower and Upper parts and hosts the complex's most economically significant layers. The Lower Critical Zone, 700-800 m thick, is dominated by orthopyroxenite with nine major chromitite seams (LG1-7, MG1-2). The Upper Critical Zone, approximately 500 m thick, features cyclic units of orthopyroxenite (70%), norite (25%), and anorthosite, interrupted by 4-5 chromitite layers (MG3-4, UG1-3), including the PGE-rich Merensky Reef and UG2 chromitite. This zone exhibits spectacular rhythmic layering and is the primary source of platinum-group elements and chromite.[14][12] The Main Zone, over 3000 m thick and forming nearly half the suite's thickness, is composed mainly of gabbronorite with subordinate norite, featuring 10-30% orthopyroxene, 10-20% clinopyroxene, and about 50% plagioclase. Layering is subtle, with occasional anorthosite and pyroxenite bands; the base is marked by the Merensky cyclic unit. It is economically notable for dimension stone, such as the Pyramid Gabbronorite.[14][2] The Upper Zone, 1-2 km thick, includes cyclic sequences of magnetitite, gabbronorite, anorthosite, and ferrodiorite, with up to 26 magnetite-rich layers ranging from centimeters to over 10 m thick. These layers, including the Main Magnetite Layer (about 2 m thick), are sources of vanadium and iron. The zone displays intense banding and represents the most differentiated portion of the suite.[14][2]Key Layered Sequences
The key layered sequences of the Bushveld Igneous Complex primarily comprise the chromitite seams and associated cyclic cumulates within the Critical Zone of the Rustenburg Layered Suite, alongside magnetitite layers in the Upper Zone. These sequences exhibit rhythmic stratification resulting from fractional crystallization and density-driven settling of crystals in mafic magma chambers, with chromitite layers forming as thin, laterally extensive horizons of nearly monomineralic chromite cumulates. The Critical Zone sequences are subdivided into Lower Group (LG1–LG7), Middle Group (MG1–MG4), and Upper Group (UG1–UG2) chromitites, each interbedded with pyroxenites, norites, and anorthosites, spanning thicknesses from centimeters to over 2 meters per layer and persisting over 300 km laterally.[37][38] In the Lower Critical Zone, the LG chromitites consist of seven principal seams, with LG6 and LG7 being the thickest at up to 1–2 m, hosted within bronzitite and harzburgite cycles that reflect repeated influxes of primitive magma. The Middle Group layers in the central eastern lobe reach similar thicknesses but thin westward, associated with increasing anorthosite content and marking a transition to more evolved compositions. The Upper Critical Zone features the UG1 (typically <0.5 m thick, bifurcating in places) and UG2 chromitites (0.6–0.9 m average thickness, up to 2 m), the latter forming a major PGE reef due to associated sulfides and platinum-group minerals at its hangingwall contact. Immediately overlying UG2 lies the Merensky Reef, a 0.3–1 m thick layered orthopyroxenite with pegmatoidal textures, enriched in PGE sulfides (up to 10–20 ppm total PGE) and base metals, interpreted as a product of magma mixing and immiscible sulfide droplets.[39][40][41] The Upper Zone sequences include four to five magnetitite layers, dominated by vanadiferous magnetite cumulates with ilmenite and hemoilmenite, the thickest being the Main Magnetite Layer at 50–100 m, reflecting iron enrichment from prolonged differentiation of tholeiitic magmas. These layers, interstratified with ferrogabbros, host vanadium resources exceeding 500 million tonnes of ore at grades of 1–2% V2O5. Less prominent layering occurs in the Main Zone, comprising gabbronorite cycles without discrete economic horizons, while the Lower Zone features ultramafic sequences of dunite, harzburgite, and bronzitite with minor chromitite stringers, up to 1 km thick but lacking the persistence of Critical Zone markers.[42][28]Rock Types and Compositions
The Rustenburg Layered Suite forms the core of the Bushveld Igneous Complex, comprising layered mafic and ultramafic cumulates such as dunites, harzburgites, peridotites, pyroxenites, troctolites, anorthosites, norites, gabbro-norites, and gabbros.[43] These rocks display cumulate textures, including adcumulates and mesocumulates, with euhedral cumulus grains of olivine, orthopyroxene, clinopyroxene, plagioclase feldspar, chromite, and magnetite embedded in poikilitic intercumulus matrices.[43] Accessory sulfides like pyrrhotite, pentlandite, and chalcopyrite occur, alongside platinum-group element (PGE) minerals such as laurite, cooperite, and braggite.[43] The Lower Zone consists of ultramafic rocks, primarily harzburgites, dunites, and pyroxenites, with dominant cumulus orthopyroxene (En84-87) and olivine (Fo85-87), the latter forming layers up to 98% orthopyroxene in pyroxenites; minor plagioclase and clinopyroxene appear upward.[2] The Critical Zone exhibits cyclic layering with chromitites (chromite 43–47 wt% Cr2O3; Cr/Fe ratios 1.26–1.6 in seams like UG2 and LG6), feldspathic pyroxenites, norites, and anorthosites, reflecting repetitive influxes of primitive magma.[2][43] The Main Zone features gabbronorites and norites with cumulus assemblages of orthopyroxene, clinopyroxene, and plagioclase, including plagioclase-rich layers reaching 70% modal plagioclase.[2]
The Upper Zone includes differentiated gabbros and magnetitites, with 25 layers of the latter up to 6 m thick, dominated by magnetite-ilmenite cumulates enriched in Fe-Ti-V, as exemplified by the 2 m Main Magnetite Layer.[2][43] The Marginal Zone comprises chilled norites bearing clinopyroxene, quartz, biotite, and hornblende, varying in thickness from 0 to 400 m.[2] Overall, the suite derives from high-Mg, Si-rich parent magmas in the lower zones evolving to aluminous tholeiites upward, with lateral facies variations from primitive (northwest) to evolved (southeast).[44] Chromitite and magnetitite layers require derivation from thin overlying liquids or magma mixing, without evidence for bulk compositional shifts across many cycles.[44]
Mineral Resources
Primary Mineralization Types
The Bushveld Igneous Complex (BIC) hosts primary magmatic mineralization dominated by stratiform chromitite layers, platinum-group element (PGE)-enriched reefs, and vanadiferous magnetitite seams, formed through fractional crystallization and accumulation processes in mafic-ultramafic magmas.[45] These deposits occur within the Rustenburg Layered Suite, with chromitite concentrated in the Lower and Critical Zones, PGE reefs in the Critical Zone, and magnetite layers in the Main and Upper Zones.[1] Chromitite layers, primarily in the Lower Zone (e.g., LG1–LG7 seams) and Critical Zone (e.g., UG1–UG2), consist of >70% chromite (FeCr₂O₄) crystals accumulated in ultramafic host rocks like pyroxenite and harzburgite. These seams, typically 10 cm to 2 m thick and laterally persistent over hundreds of kilometers, represent the world's largest chromium resources, with Cr₂O₃ contents exceeding 40 wt%.[46] The UG2 chromitite, in the Upper Critical Zone, uniquely combines high-grade chromite with PGE enrichment, averaging 8–15 ppm total PGE.[47] PGE mineralization occurs in thin, stratabound reefs such as the Merensky Reef and UG2, where platinum-group minerals (PGMs) like laurite (RuS₂), cooperite (PtS), braggite ((Pt,Pd)NiS), and sperrylite (PtAs₂) are disseminated or associated with sulfides in chromitite, pyroxenite, or pegmatoidal anorthosite.[48] The Merensky Reef, ~1–2 m thick at the Critical Zone's top, yields 5–10 ppm PGE with Ni-Cu sulfides, while the Platreef in the northern lobe features irregular PGE-Cu-Ni sulfide zones in gabbronorite.[49] These reefs formed via magma mixing, volatile influx, or in situ segregation, concentrating PGE up to 80% of global reserves.[50] Vanadiferous magnetitite layers, prevalent in the Main Zone (e.g., ~40 seams) and Upper Zone, comprise dense accumulations of magnetite (Fe₃O₄) with ilmenite, hosting 1–2.5 wt% V₂O₅ and minor TiO₂ (up to 10 wt%).[51] These layers, 1–10 m thick, result from late-stage iron enrichment during crystallization, providing substantial vanadium for ferroalloy production.[52] Minor associated sulfides contribute nickel and copper, though uneconomic relative to primary commodities.[6]Economic Deposits and Grades
The Bushveld Igneous Complex hosts some of the world's largest reserves of platinum-group elements (PGE), primarily in the Merensky Reef, UG2 chromitite layer, and Platreef of the Upper Critical Zone. The Merensky Reef, a thin pyroxenite-chromitite package typically 30-60 cm thick, yields ore grades of 4-6 g/t for combined Pt, Pd, Rh, and Au (4E), with resources estimated at 4,200 Mt ore containing 13,000 t Pt and 6,100-6,200 t Pd.[6] The UG2 chromitite, a 30-120 cm thick layer richer in chromite, supports higher PGE grades of 5-7 g/t 4E, with resources of 7,300 Mt ore including 20,000-21,000 t Pt and 13,000 t Pd, making it a primary source for PGE extraction despite its initial focus as a chromite byproduct.[6] The Platreef, a thicker basal deposit in the northern limb up to 300 m thick, has lower grades of 2-4 g/t 4E but substantial tonnage, with resources of 5,200 Mt ore holding 4,500-11,000 t Pt and 5,400-7,600 t Pd.[6] Chromium deposits occur in stratiform chromitite seams across the Critical Zone, with economic extraction from Lower Group (LG) layers like LG6 and Middle Group 1 (MG1), where chromite modal abundances reach 70-90% and Cr₂O₃ contents in chromite crystals range from 42-46 wt%, yielding concentrates of 40-48% Cr₂O₃.[53] The UG2 layer also produces chromium as a byproduct during PGE mining, with similar Cr₂O₃ levels but thinner seams limiting standalone viability.[53] These layers, up to 2 m thick in places, account for over 80% of global chromium resources, though grades decline upward in the sequence.[53] ![Chromitite from Bushveld Complex][float-right] Vanadium is concentrated in magnetitite layers of the Upper Zone, such as the Main Magnetite Layer, with whole-rock grades averaging 1.0-1.6% V₂O₅ and magnetite concentrates reaching 1.5-1.75% V₂O₅, enabling high recovery rates in titanomagnetite ores containing 50-60% Fe.[54][55] These deposits support vanadium production primarily as ferrovanadium for steel alloys, with resources exceeding 1,000 Mt ore at viable grades.[56]| Deposit/Reef | Key Commodity | Typical Grade | Resource Tonnage (Mt ore) | Source |
|---|---|---|---|---|
| Merensky Reef | PGE (4E: Pt+Pd+Rh+Au) | 4-6 g/t | 4,200 | [6] |
| UG2 Chromitite | PGE (4E) | 5-7 g/t | 7,300 | [6] |
| Platreef | PGE (4E) | 2-4 g/t | 5,200 | [6] |
| LG6/MG1 Chromitites | Cr (in chromite) | 42-46% Cr₂O₃ | >10,000 (inferred) | [53] |
| Magnetitite Layers | V (V₂O₅ in magnetite) | 1.5-1.75% | >1,000 | [54][55] |
Genetic Interpretations
Chromitite layers in the Bushveld Igneous Complex, including the Upper Group (UG1, UG2) and Lower Group (LG1–7) seams, formed through magmatic segregation processes where chromite crystals nucleated en masse and accumulated by gravitational settling within the differentiating magma chamber. Supersaturation of chromite in the melt is explained by periodic influxes of primitive, mantle-derived magma into the chamber, which mixed with more evolved, fractionated resident magma, altering melt composition to favor chromite precipitation; additional triggers include increased silica content from assimilation of footwall sediments or shifts in oxygen fugacity.[57][58][59] This model is supported by petrological evidence of rhythmic layering and sharp contacts between chromitite and host pyroxenites, indicating rapid deposition without significant post-cumulate alteration.[57] Platinum-group element (PGE) mineralization, concentrated in reefs like the Merensky and the UG2 chromitite, is interpreted as primarily syngenetic, arising from incompatible behavior of PGE in mafic magmas followed by efficient partitioning into minor immiscible sulfide liquids during sulfide saturation. Magma mixing events are central to these models, as fresh primitive magma injections destabilize sulfide solubility in the evolved melt, promoting segregation of dense sulfide droplets that scavenge PGE (and other chalcophile elements) from thousands of cubic kilometers of magma before settling or accumulating at cumulate interfaces.[60][61][62] The association of PGE with chromitite layers suggests chromite crystals provided nucleation sites for sulfide droplets or directly hosted PGE via inclusions, explaining enrichments despite low bulk sulfide contents (typically <2 vol%).[57][63] Alternative interpretations emphasize mechanical sorting of pre-formed PGE-bearing phases during crystal-laden slurry emplacement or late-stage redistribution, but empirical data from mineral zoning and isotopic homogeneity favor dominantly magmatic origins without substantial hydrothermal overprint.[60][61] For the Platreef, a contact-type deposit at the base of the complex, genetic models invoke hybridization between mafic magmas and footwall carbonates, leading to sulfur from country rocks triggering sulfide saturation and PGE enrichment.[64] Vanadium-bearing magnetitites in the Main Zone result from fractional crystallization concentrating Fe-Ti-V oxides in residual melts, with deposition in layers up to several meters thick.[65] These interpretations are constrained by geochemical correlations, such as PGE tenor varying with chromite composition, underscoring causal links between melt evolution and ore formation.[63]Mining and Industry
Historical Exploitation
The exploitation of the Bushveld Igneous Complex began with chromite mining in the early 1920s, driven by demand during World War I and subsequent industrial needs for ferrochrome production. Chromite deposits in the Lower Group chromitite layers were first systematically prospected around 1916, with initial mining on farms like Goudmyn in the eastern lobe yielding approximately 337 kilotons of ore.[66] Commercial-scale operations commenced in 1921, marking the start of South Africa's chromite industry, with early output focused on exporting ore for stainless steel and alloy applications.[67] By the mid-1920s, several small-scale mines operated in the eastern and western lobes, though production remained modest due to rudimentary extraction methods and transportation challenges in the rugged terrain. Platinum-group metals (PGMs) were reported in the complex as early as November 10, 1906, based on assays from chromite concentrates, but viable deposits eluded early prospectors until the 1920s.[68] The pivotal discovery occurred in 1924 when geologist Hans Merensky identified the platiniferous Merensky Reef on the farm Maandagshoek in the eastern lobe, revealing a laterally extensive layer with grades averaging 5-10 grams per tonne of platinum, palladium, and associated metals.[69] This led to the establishment of the first dedicated PGM mines, such as the Rustenburg Platinum Mines, with underground operations commencing in 1929-1931 using hand-held drills and trackless haulage.[70] Initial annual production hovered around 10,000-20,000 ounces of platinum equivalent, constrained by geological uncertainties and labor-intensive stoping techniques. Vanadium-bearing magnetite layers in the Upper Zone saw limited early exploitation, primarily through open-pit mining of titaniferous magnetitite from the 1920s onward for iron and vanadium recovery, though significant scaling occurred later. Mines like Kennedy's Vale supplied ore intermittently until the 1950s, with vanadium extracted via roasting processes yielding concentrates grading 1-1.5% V₂O₅.[71] Overall, pre-1940s efforts emphasized surface and shallow underground methods, yielding cumulative chromite output exceeding 1 million tons by 1930 and establishing the complex as a key global supplier, albeit with high costs due to the ore's disseminated nature and remote locations.[67]Modern Operations and Techniques
Mining operations in the Bushveld Igneous Complex focus predominantly on underground extraction for platinum group metals (PGMs) from the Merensky Reef and UG2 chromitite layer, employing a mix of conventional, hybrid, and mechanized methods to navigate deep, narrow tabular orebodies.[72] Conventional breast stoping, involving manual support installation and drilling, persists in many Western Limb operations like Rustenburg, which operate at shallow to intermediate depths of up to 1,000 meters with surface concentrators.[73] Hybrid approaches combine conventional stoping with mechanized off-reef development using trackless equipment to improve advance rates and reduce labor exposure in hazardous areas.[72] Mechanization has advanced significantly for UG2 mining since the 1980s, driven by the reef's competent rock and higher chromite content, which complicates conventional methods; bord-and-pillar techniques with raisebore pre-splitting and low-profile loaders enable wider spans and higher productivity, though challenges like chromitite stringers necessitate reinforced support such as 1.8-meter resin bolts for 6-meter spans.[72][74] In the Northern Limb, deposits like Flatreef employ highly mechanized bulk mining, including long-hole stoping and drift-and-fill, leveraging the orebody's 24-meter average thickness for economies of scale; Ivanhoe Mines' crews accessed the Flatreef orebody in May 2025 via a 1,000-meter-deep shaft, marking a shift toward scalable, low-cost production.[75][76] Open-pit methods are applied to massive chromitites in the Critical Zone, with recent excavations revealing large-scale features and supporting beneficiation advances through multi-technique mineralogical analysis of low-grade ores.[46][48] Geophysical techniques, including seismic and ground-penetrating radar, mitigate dyke intrusions that disrupt PGM mining continuity, informing real-time adjustments in excavation planning.[77] These innovations address escalating depths exceeding 2 kilometers in established mines, where geothermal gradients demand cooling systems, while prioritizing ore recovery in complex layered sequences.[78]Major Producers and Outputs
The Bushveld Igneous Complex hosts operations by several major mining companies specializing in platinum group metals (PGMs), chromium, and vanadium, with production concentrated in the Eastern, Western, and Northern Limbs. Primary PGM producers include Valterra Platinum (formerly Anglo American Platinum), Impala Platinum Holdings Limited (Implats), and Sibanye-Stillwater, which collectively account for a significant portion of South Africa's output from the complex's Merensky Reef, UG2 chromitite, and Platreef horizons. These companies employ underground shaft mining, hybrid shaft-and-open-pit methods, and advanced concentrator-refinery circuits to extract and process 4E PGMs (platinum, palladium, rhodium, iridium plus ruthenium). In 2024, Valterra Platinum reported platinum production of 1.85 million ounces from its Bushveld assets, including the Mogalakwena open-pit mine on the Northern Limb and underground operations like Mototolo and Tumela on the Eastern and Western Limbs. Sibanye-Stillwater achieved 1,738,946 ounces of 4E PGMs from its Bushveld operations, encompassing Rustenburg, Marikana, and Kroondal complexes on the Western Limb, amid challenges from labor disruptions and energy constraints. Implats, via its Impala Rustenburg and Bafokeng operations on the Western Limb, maintained multi-shaft underground extraction targeting Merensky and UG2 reefs, contributing to group PGM output though specific 2024 Bushveld volumes reflected declines due to lower-margin ore processing.[79][80][81] Chromium production from the Bushveld's Lower Group chromitite layers (e.g., LG6 and LG7) is dominated by ferrochrome smelters and ore exporters, with Glencore-Merafe Chrome Venture and Samancor Chrome as key players operating mines like Lion, Ruukki, and Eastern Chrome near Steelpoort and Brits. These entities produced chromite ore integral to South Africa's estimated 2023 output exceeding 11 million metric tons, primarily for stainless steel alloying via submerged arc furnaces, though export levies and energy costs pressured ferrochrome yields. Hernic Ferrochrome also extracts from Western Limb deposits, focusing on high-grade concentrates.[82][83] Vanadium extraction targets magnetite layers in the Upper Zone, led by Bushveld Minerals at the Vametco mine and Vanchem processing plant on the Western Limb, yielding ferrovanadium and vanadium pentoxide for steel strengthening and emerging battery applications. In 2023, Bushveld Minerals operated as one of three global primary vanadium producers from Bushveld sources, with output tied to integrated roasting-leaching circuits; Glencore supplements via by-product recovery from titaniferous magnetite. South Africa's vanadium contributions remain modest relative to PGMs but critical, with Vametco's 2023-2024 operations emphasizing sustainable recovery amid market deficits.[84][85]| Commodity | Major Producers | Key 2023-2024 Outputs (Bushveld-Specific) |
|---|---|---|
| PGMs (4E oz) | Valterra Platinum | 1.85M oz platinum (2024) [][79] |
| PGMs (4E oz) | Sibanye-Stillwater | 1.74M oz (2024) [][80] |
| PGMs (group) | Implats (Impala) | Multi-shaft output from Western Limb reefs [][86] |
| Chromite (Mt ore) | Glencore-Merafe, Samancor | >11 Mt national, Bushveld-dominant (2023) [][83] |
| Vanadium (V2O5 equiv.) | Bushveld Minerals (Vametco) | Primary production via magnetite processing [][85] |