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Slurry ice
Slurry ice
from Wikipedia
Shenzhen Lier Flake ice machine manufacturer-www.liermachine.com
Slurry ice with propylene glycol as depressant viewed through a microscope.

Slurry ice is a phase changing refrigerant made up of millions of ice "micro-crystals" (typically 0.1 to 1 mm in diameter) formed and suspended within a solution of water and a freezing point depressant. Some compounds used in the field are salt, ethylene glycol, propylene glycol, alcohols like isobutyl and ethanol, and sugars like sucrose and glucose. Slurry ice has greater heat absorption compared to single phase refrigerants like brine, because the melting enthalpy (latent heat) of the ice is also used.

Characteristics

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The small ice particle size results in greater heat transfer area than other types of ice for a given weight. It can be packed inside a container as dense as 700 kg/m3, the highest ice-packing factor among all usable industrial ice.

The spherical crystals have good flow properties, making them easy to distribute through conventional pumps and piping and over product in direct contact chilling applications, allowing them to flow into crevices and provide greater surface contact and faster cooling than other traditional forms of ice (flake, block, shell, etc.).

Its flow properties, high cooling capacity, and flexibility in application make a slurry ice system a substitute for conventional ice generators and refrigeration systems, and offers improvements in energy efficiency: 70%, compared to around 45% in standard systems, lower freon consumption per ton of ice, and lower operating costs.

Application fields

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Slurry ice is commonly used in a wide range of air conditioning, packaging, and industrial cooling processes, supermarkets, and cooling and storage of fish, produce, poultry and other perishable products.

Fish chilling with slurry ice.

Slurry ice can boost by up to 200% the cooling efficiency of existing cooling or freezing brine systems without any major changes to the system (i.e. heat exchanger, pipes, valves), and reduce the amount of energy consumption used for pumping.

Advantages

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Slurry ice is also used in direct contact cooling of products in food processing applications in water resistant shipping containers. It provides the following advantages:

  • Product is cooled faster – the smooth round shape of the small crystals ensures maximum surface area contact with the product and as a result, faster heat transfer.
  • Better product protection – the smooth, round crystals do not damage product, unlike other forms of sharp, jagged ice (flake, block, shell, etc.).
  • Even cooling – unlike other irregular shaped ice which mostly conducts heat through the air, the round shape of the slurry crystals enables them to flow freely around the entire product, filling all air pockets to uniformly maintain direct contact and the desired low temperature.

Slurry ice generators

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Slurry ice is generated using a unique type of ice-making technology. Conventional ice generators produce sharp edged, dry ice fragments, not the small, spherical crystals found in slurry ice. In traditional brine chiller systems, crystals forming inside the solution would block or damage the system.

Scraped surface generators

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The world’s first patent for a slurry ice generator was filed by Sunwell Technologies Inc. of Canada in 1976. Sunwell Technologies Inc. introduced slurry ice under the trade name deepchill ice, in the late 1970s. Slurry ice is created through a process of forming spherical ice crystals within a liquid. The slurry ice generator is a scraped-surface vertical shell and tube heat exchanger. It consists of concentric tubes with refrigerant flowing between them and the water/freezing point depressant solution in the inner tube. The inner surface of the inner tube is wiped using a mechanism which in the original Sunwell design consists of a central shaft, spring-loaded plastic blades, bearings, and seals. The small ice crystals formed in the solution near the tube surface are wiped away from the surface and mixed with unfrozen water, forming the slurry. Other slurry ice generators adapted the first idea of wiping the surface using an auger originally designed to create flake ice. Wipers also can be brushes or fluidized bed heat exchangers for ice crystallization. In these heat exchangers, steel particles circulate with the fluid, mechanically removing the crystals from the surface. At the outlet, steel particles and slurry ice are separated.

Direct contact generators

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An immiscible primary refrigerant evaporates to supersaturate the water and form small, smooth crystals. With direct contact chilling, there is no physical boundary between the brine and the refrigerant, increasing the rate of heat transfer. However, the major disadvantage of this system is that a small amount of refrigerant stays in the brine, trapped in the crystals. This refrigerant is pumped with the slurry out of the generator and into the environment.

Supercooling generators

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Pure water is supercooled in a chiller to −2°C and released through a nozzle into a storage tank. Upon release, it undergoes a phase transition, forming small ice particles with 2.5% ice fraction. In the storage tank, it is separated by the difference in density between ice and water. The cold water is supercooled and released again, increasing the ice fraction in the storage tank. However, a small crystal in the supercooled water or a nucleation cell on the surface will act as a seed for ice crystals and block the generator.

See also

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References

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Revisions and contributorsEdit on WikipediaRead on Wikipedia
from Grokipedia
Slurry ice, also known as or , is a two-phase consisting of a homogeneous suspension of fine crystals (typically 0.1–1 mm in diameter) within a carrier liquid, such as , , or a binary solution containing freezing point depressants like or glycols. This mixture operates at temperatures below the freezing point of the carrier liquid, leveraging the of fusion for high density—approximately 334 kJ/kg from formation—making it a pumpable, flowable alternative to traditional solid forms. The fraction typically ranges from 5% to 30% by mass, allowing the to behave as a at lower concentrations and a non-Newtonian one at higher levels, with enhanced coefficients 50–100% greater than those of chilled . Produced through methods such as scraped-surface heat exchangers (the most common commercial approach), , vacuum aggregation, fluidized beds, or direct contact cooling, slurry ice systems enable rapid generation and distribution without the need for mechanical compression in some cases. Its thermophysical properties, including high (up to 8 times that of conventional refrigerants) and efficient convective , provide 4–6 times the of chilled under similar conditions, while maintaining a constant low temperature during phase change. These attributes minimize product damage from uneven cooling or pressure, as the conforms to surfaces and flows easily through pipes or containers. In applications, slurry ice excels in , particularly for and perishable produce, where, as of 2022, over 700 systems were deployed globally to extend by achieving rapid, uniform chilling—reducing and maintaining texture in significantly longer than flake ice. Industrially, it supports in buildings and (e.g., as of 2010, more than 400 installations in ), breweries, and large-scale kitchens, cutting demands by up to 50% in some cases. Medically, it facilitates targeted for organ protection during surgeries, such as cardiac procedures or transplantation, enabling brain cooling by 4°C in as little as 10 minutes via minimally invasive delivery. Overall, slurry ice's versatility and efficiency have driven its adoption since the 1990s, with ongoing research focusing on optimized production and non-invasive monitoring techniques; as of 2024, the global market continues to grow at a projected CAGR of around 5-6% through 2033.

Fundamentals

Definition and Composition

Slurry ice is defined as a homogeneous suspension of fine micro-crystals, typically ranging from 0.1 to 1 in diameter, within a carrier . This two-phase combines the cooling capacity of with the flowability of a , distinguishing it as a suitable for various cooling applications. The micro-crystals form through controlled freezing processes that prevent larger formation, ensuring the mixture remains pumpable and uniform. The carrier liquid in slurry ice can be pure freshwater or a binary solution of mixed with a freezing point to lower the freezing point and maintain liquidity. Common depressants include salt () for brine-based slurries, propylene glycol for food-grade applications, and for industrial uses, allowing operation at temperatures below 0°C without full solidification. Binary solutions, such as or , enable the production of slurry ice directly from saline sources, while pure freshwater variants require additives to achieve similar stability. The (by ), typically ranging from 5% to 30%, ensures pumpability without excessive buildup. Unlike traditional forms such as flake ice or block ice, slurry ice offers superior homogeneity and flowability due to its uniform dispersion of micro-crystals, which eliminates air gaps and enables seamless pumping through pipes. Flake ice consists of larger, irregular shards that may settle or require manual handling, while block ice forms rigid masses unsuitable for transport, limiting their in dynamic cooling scenarios. This structural uniformity in slurry ice enhances contact with surfaces, promoting even absorption. The terminology for this material has evolved over time, originating from terms like "binary ice" in early industrial contexts referring to its two-phase composition, and "flow ice" emphasizing its pumpable nature. By the late , "slurry ice" became the standard , reflecting its slurry-like consistency and broad adoption in technologies. Alternative names such as fluid ice or slush ice persist in some regional or application-specific uses but are less common today.

Physical and Thermal Properties

Slurry ice possesses distinctive thermal properties that stem from the combination of its liquid carrier and suspended crystals. The primary contributor to its thermal performance is the high of fusion of the phase, which is approximately 334 kJ/kg for water-based compositions. This enables substantial energy absorption or release during or freezing without significant change, enhancing overall cooling efficiency. The effective of slurry ice, accounting for both and the contribution over a narrow range, can reach 30–40 kJ/kg·K depending on the ice fraction, as the phase change amplifies heat storage relative to single-phase fluids. Physically, slurry ice is characterized by a density of approximately 970 kg/m³ at a 30% ice mass fraction, derived from the volume-weighted contributions of the denser liquid phase (around 1000 kg/m³) and the lighter ice phase (917 kg/m³). Its viscosity is comparable to that of milk (typically 2–5 mPa·s at low shear rates), ensuring good pumpability through conventional piping without excessive pressure losses. The ice crystals are generally spherical or near-spherical in shape, with diameters ranging from 0.1 to 1 mm, which minimizes flow resistance and friction along surfaces. Rheologically, slurry ice behaves as a , exhibiting shear-thinning characteristics that reduce under increasing shear rates, facilitating easier transport in pipelines. This behavior becomes prominent above an of about 15%, where the suspension transitions from Newtonian-like flow to more complex models such as Herschel-Bulkley or Casson, influenced by particle interactions. The ϕ\phi, often defined as the mass ratio ϕ=micemice+mliquid\phi = \frac{m_{\text{ice}}}{m_{\text{ice}} + m_{\text{liquid}}}, directly correlates with , as the available is ϕ×334\phi \times 334 kJ/kg. Stability of the slurry is maintained through a narrow size distribution that inhibits agglomeration and , ensuring uniform suspension over time. For water-based slurry , typical operating temperatures range from -1°C to -2°C to balance ice formation and flowability. Brine-based variants, which incorporate salts to depress the freezing point, operate at lower temperatures for specialized applications.

History and Development

Origins and Early Adoption

The development of slurry ice technology traces its origins to the mid-1970s, when Sunwell Technologies Inc., a Canadian company, filed the world's first patent for a slurry ice generator utilizing a scraped-surface method designed specifically for cooling in the . This innovation addressed the need for a more efficient, pumpable alternative to traditional block or flake , enabling rapid chilling without the logistical challenges of solid handling. The patent was granted in , marking the formal inception of modern slurry ice production systems. Initial adoption occurred primarily in the preservation sector during the and 1990s, driven by the industry's demand for effective onboard chilling to extend the of catches at . Sunwell's was introduced to the global market in 1978, quickly gaining traction among vessels for its ability to provide uniform cooling and reduce physical damage to delicate products like fillets. By the late , early installations on trawlers and processing ships demonstrated slurry ice's superiority in maintaining low temperatures close to 0°C, which slowed and enzymatic degradation more effectively than conventional icing methods. This period also saw a transition from niche experiments with "binary ice"—a precursor slurry variant incorporating additives like glycols or alcohols to lower freezing points—to more standardized, water-based systems suitable for direct contact applications. Such binary ice research began in the and , where prototypes were tested for efficiency in food transport and storage, laying the groundwork for broader slurry adoption. A key milestone came in the with the commercialization of slurry ice generators for perishable goods transport, including land-based for , which significantly reduced spoilage rates by enabling faster and more consistent chilling throughout the .

Key Technological Advancements

In the , slurry ice technology saw significant expansion through its integration into (HVAC) systems and applications, enabling off-peak cooling storage and distribution for buildings and district systems. This period marked widespread adoption, with over 400 systems installed in by 2009 for enhanced building cooling efficiency, and approximately 150 in , leveraging the high of fusion (334 kJ/kg) to reduce pumping by about 40% compared to single-phase chilled systems. Such integrations allowed for smaller piping diameters—roughly one-third those of traditional chilled water setups—and storage tanks one-tenth the size, contributing to overall operational cost reductions in HVAC operations. The brought a rise in the method for slurry ice production, which achieves energy-efficient by cooling aqueous solutions below their freezing point without mechanical scraping, enabling higher ice fractions—up to an increase of approximately 1.25% per of —and simpler system designs with no moving parts. This approach, often enhanced by ultrasonic or techniques, operates at higher temperatures than traditional scraped-surface methods, yielding up to 20% greater overall in ice generation while minimizing energy consumption for . By the mid-, advancements in icephobic coatings for further stabilized the process, boosting degrees by 30-40% and supporting continuous production for industrial-scale applications. Recent developments through 2025 have expanded slurry ice into specialized domains, including medical cooling for therapeutic during and organ surgeries, where its rapid protects tissues by reducing oxygen demand. In , slurry ice supports cooling systems in hot underground environments, improving worker and equipment longevity. For heat prevention, products like ICE SLURRY were adopted in 2025 for staff, providing internal body cooling amid extreme heat. Patent trends reflect a shift toward eco-friendly freezing point depressants, favoring over salts due to its lower corrosivity and environmental impact, as seen in formulations for non-toxic, high-efficiency slurries. Looking ahead, slurry ice holds potential in pipeline pigging, where ice-water mixtures effectively remove biofilms and in water mains without full disassembly, and in storage, integrating with solar and sources to enhance HVAC flexibility and decarbonization efforts. These advancements prioritize reliable production, improved storage stability, and non-invasive monitoring to broaden across sectors.

Applications

Food Preservation and Processing

Slurry ice is widely employed in the preservation of perishable foods, particularly seafood, where it facilitates rapid direct-contact chilling to temperatures around -1°C, effectively slowing enzymatic activity and microbial proliferation while preserving texture and freshness. This approach achieves cooling rates 5-6 times faster than conventional chilled water immersion, enabling efficient heat removal without inducing freezing damage to the product. By lowering storage temperatures from approximately 1.5°C to -1.5°C, slurry ice reduces bacterial growth by about 50% relative to traditional icing methods, thereby extending shelf life and minimizing spoilage in species such as shrimp, salmon, and tuna. Studies on Pacific white shrimp demonstrate that slurry ice storage inhibits total viable bacterial counts to levels around 5.29 log CFU/g by day 6 of refrigeration, significantly lower than in controls using crushed ice or standard cold storage, while also delaying melanosis and maintaining umami taste profiles. In and , slurry ice provides even, non-abrasive cooling that conforms to product shapes, filling voids to ensure uniform temperature distribution without causing bruising or structural damage. For , it reduces pathogens like by approximately 0.44 log10 CFU/g on skin surfaces during chilling, supporting compliance with hygiene standards and enhancing overall quality through minimized contamination risks in spin chillers. Similar benefits apply to fresh produce, where the fluid nature of slurry ice allows gentle that preserves integrity and reduces , outperforming static methods by promoting consistent and contact. Beyond initial preservation, slurry ice integrates into food processing workflows, such as dough cooling in bakery applications, where it outperforms dry ice by delivering faster, more controlled temperature reduction to optimize texture and fermentation without excessive moisture loss. In beverage production, it supports rapid chilling of liquids and mixtures, leveraging its high heat transfer efficiency—stemming from the latent heat of ice crystals—for efficient temperature management during bottling and packaging. Practical implementations include onboard fishing vessels for immediate post-harvest treatment of catch, ensuring quality retention during transit, and supermarket display cases for seafood and poultry, where continuous slurry circulation extends shelf life by maintaining sub-zero conditions and reducing drip loss. These applications highlight slurry ice's versatility in direct-contact techniques, which exploit its superior thermal properties for targeted biological preservation across the food supply chain.

Industrial and HVAC Systems

In (HVAC) systems, slurry ice serves as a for , enabling peak-load shifting by producing and storing cold during off-peak hours when electricity rates are lower. This approach allows buildings to discharge stored cooling during high-demand periods, reducing overall electricity costs by 30-50% compared to conventional systems through higher coefficients of performance (4-6 versus 2.5-4). For instance, integration in setups has demonstrated up to 40% peak load reduction, as seen in studies on microencapsulated phase-change slurries. Beyond HVAC, slurry ice finds applications in industrial cooling, particularly for operations where it provides indirect contact cooling to maintain equipment temperatures in harsh environments, such as gold mines requiring stable low temperatures. A 2025 at the LW Bogdanka SA mine in utilized ice slurry for , showcasing its effectiveness in underground environments. In maintenance, ice pigging employs a semi-solid slurry to form a plug that scrapes biofilms and sediments from pipe walls without chemicals, using only 1.5 pipe volumes of water and adapting to complex geometries like bends and valves. For chemical processing, slurry ice enhances cooling efficiency due to its high and constant low temperature, outperforming single-phase fluids in processes needing rapid, uniform heat removal. System integration of slurry ice into existing infrastructures is straightforward, as it can be pumped through conventional lines to boost cooling efficiency by up to 200% without major retrofits, thanks to its high (334 kJ/kg) and reduced pumping energy (about 40% lower). This results in smaller pipe diameters (down to one-third of chilled systems) and tank sizes (one-tenth), minimizing installation costs while maintaining flowability at ice concentrations around 20-35%. Representative examples include supermarket , where secondary loop systems using ice slurry reduce refrigerant charge by up to 90% and pumping power via utilization, supporting medium-temperature display cases efficiently. In district networks, slurry ice delivers 4-6 times the of chilled water, enabling smaller pipelines and lower operating expenses for multi-building applications like campuses or urban centers. An emerging application is artificial snow production for ski resorts, where slurry ice generates softer, more uniform by serving as a in blowing systems, suitable for larger indoor or outdoor facilities to extend seasons amid variable weather.

Advantages and Limitations

Operational Benefits

Slurry ice offers significant efficiency gains in systems compared to traditional methods, primarily due to its phase-change properties that leverage for higher . Systems utilizing slurry ice can achieve up to 4-6 times the of chilled , reducing the required charge and enabling lower dependency on primary refrigerants like . Additionally, pumping consumption is reduced by approximately 40% relative to single-phase fluids, as the high density—around 334 kJ/kg from ice fusion—allows for fewer operational cycles and smaller equipment sizes, such as tanks one-tenth the volume of those for chilled . These factors contribute to overall use that is 15-25% lower in select applications, translating to substantial operational cost reductions. The cooling advantages of slurry ice stem from its ability to provide maximum surface contact through small, spherical crystals (0.2-0.8 in diameter), resulting in rates 2-3 times faster than conventional flake ice or . This rapid, uniform distribution eliminates hot spots by fully surrounding the target material, enhancing cooling efficiency without the uneven performance of solid forms. The rounded crystal shape, derived from controlled in production, further protects sensitive products by minimizing mechanical damage, in contrast to the sharp edges of flake ice that can cause bruising or abrasion. Cost savings are realized through slurry ice's high , typically 900-1100 kg/m³ depending on the carrier liquid, allowing for compact storage and reduced transportation volumes compared to bulkier ice types. Its compatibility with retrofit installations in existing infrastructure further lowers capital expenses, as it integrates easily with standard piping and pumps. Versatility is a key operational benefit, with slurry ice being pumpable at ice fractions up to 40%, enabling automated distribution in closed-loop systems. Food-grade variants, produced with potable or approved additives, support direct contact applications without risks, facilitating seamless use in hygiene-sensitive environments.

Potential Drawbacks

One significant operational challenge with slurry ice systems is the risk of pipe blockages caused by the agglomeration of ice particles, which becomes pronounced when the ice exceeds approximately 30% by , leading to increased and flow resistance. To mitigate this, anti-agglomerants such as additives are commonly incorporated to maintain particle suspension and prevent clumping during transport. Maintenance requirements for slurry ice systems are elevated due to corrosion issues arising from salt-based slurries, such as those using or , which accelerate material degradation in pipes and equipment unless corrosion-resistant alloys are employed. Furthermore, the upfront for slurry ice generators are substantially higher than those for conventional chillers, often due to specialized components for ice formation and handling, though long-term operational savings may offset this in certain applications. Environmental concerns include the potential for leaks in direct-contact production methods, where the refrigerant mixes directly with the , risking and release of harmful substances if not properly contained. Additionally, slurry ice production consumes considerable volumes of as the primary carrier fluid, contributing to resource demands in large-scale operations. As of 2025, advancements include AI-integrated sensors for real-time monitoring to prevent blockages. Recent advancements include the use of eco-friendly freezing point depressants like to reduce and environmental impact while maintaining flow properties. Integrated monitoring systems, including real-time sensors for ice fraction and , have also been developed to preempt agglomeration and optimize system performance. Despite reported energy savings of up to 32% in production, these drawbacks necessitate careful system design and .

Production Methods

Scraped Surface Generators

Scraped-surface generators represent the earliest and most established method for producing slurry ice, utilizing a specialized design to facilitate controlled formation. The core mechanism involves a cylindrical or plate-style where a rotating shaft equipped with blades or augers continuously scrapes the cooled inner surface, preventing excessive buildup and dislodging fine layers into the circulating carrier . This mechanical action promotes the and growth of small crystals, typically ranging from 0.1 to 1 mm in diameter, ensuring a uniform with minimal agglomeration. In the production process, a carrier liquid such as a saltwater is pumped through the exchanger, where it is cooled by a circulating in the outer jacket, typically reaching temperatures around -2°C to initiate freezing. As the fluid passes over the chilled surface, crystals form and are immediately scraped off, mixing back into the flow to gradually increase the ice fraction to 20-30% by weight. This continuous circulation maintains a homogeneous , with the process operating in either batch or continuous modes depending on the system scale. The resulting slurry achieves enhanced thermal properties, such as higher capacity compared to chilled alone. This technology offers unique reliability for producing slurry from high-viscosity brines, as the scraping action enhances and prevents in thicker fluids that might otherwise reduce efficiency in standard exchangers. The method traces its origins to pioneering patents filed in 1976 by Sunwell Technologies Inc. (now associated with Deepchill Systems), marking the first commercial development of slurry ice generators. Systems like those from Sunwell exemplify this approach, providing robust performance in demanding environments. Scraped-surface generators are highly scalable, with capacities ranging from 3 to 400 tons of ice per day, making them suitable for installation on vessels where space and reliability are critical. Energy consumption for ice production typically falls in the range of 50-100 kWh per ton, influenced by factors such as concentration and operating conditions, with (COP) values around 2.4 achievable under optimized settings.

Direct Contact Generators

Direct contact generators produce slurry ice through the direct interaction of an immiscible with the carrier liquid, typically or a solution, allowing for rapid without intermediate surfaces. In this method, a liquid such as (CO2) or hydrocarbons like (R600) is injected into the , where it evaporates upon contact, absorbing and nucleating fine ice crystals throughout the volume. This evaporation-driven cooling process promotes uniform ice formation, distinguishing it from indirect methods by eliminating thermal barriers associated with heat exchangers. The production process involves injecting the at controlled rates into a containment vessel, such as a or column, where it disperses as bubbles or droplets to maximize contact area. As the evaporates, the temperature of the carrier liquid drops below its freezing point, leading to the formation of ice crystals with typical fractions of 10-40% by volume, depending on operational parameters like injection and flow rates. Following , the gaseous is separated from the resulting , often via venting or mechanical means, to prevent accumulation and maintain system purity. This method was historically prominent in the early for large-scale industrial cooling applications, offering a compact alternative to traditional ice-making systems during the initial of technologies. Despite its advantages in heat transfer intensity, direct contact generation faces challenges related to refrigerant management and overall efficiency. Residual refrigerant can become trapped within the ice crystals or brine, necessitating downstream purification steps to avoid contamination in applications like food processing. Energy consumption for this process typically ranges from 40-60 kWh per ton of ice produced, lower than some indirect methods due to enhanced heat transfer but limited by incomplete evaporation and separation losses. To address mixing inefficiencies, variants such as bubble column systems—where rising refrigerant bubbles enhance circulation—or spray injection configurations have been developed, improving uniformity and ice crystal distribution (typically 0.1-1 mm in size). These adaptations have sustained interest in direct contact approaches for specialized cooling needs, though modern systems often favor hybrid designs to mitigate separation issues.

Supercooling Generators

Supercooling generators represent an emerging method for producing slurry ice by exploiting the metastable state of supercooled water, where the liquid is cooled below its freezing point without initiating crystallization. In this process, water is typically supercooled to temperatures ranging from -2°C to -5°C using specialized heat exchangers, often enhanced with icephobic coatings to prevent heterogeneous nucleation on surfaces. Once supercooled, nucleation is deliberately triggered through mechanical agitation, ultrasonic waves, or thermal shock in a separate crystallizer, leading to rapid, simultaneous formation and growth of fine ice crystals. This approach avoids the need for refrigerants in direct contact with the water, distinguishing it from other generator types, and relies on passive supercooling dynamics for energy efficiency. The production can operate in batch or continuous modes, starting with an initial ice fraction of 2-5% upon nucleation release, which is then scalable through recirculation or additional crystallization stages to reach up to 30% ice content. For instance, continuous systems pump supercooled water at flow rates of 500-1000 kg/h through brazed plate heat exchangers (around 10 kW capacity) before directing it to the crystallizer, enabling stable operation without core moving parts and decoupling ice generation from storage. Experimental setups have demonstrated consistent supercooling degrees of 3-4 K for up to 3 hours, with ice fractions building progressively in storage tanks. The absence of mechanical scraping or agitation in the primary cooling stage minimizes wear and simplifies design. Key advantages include enhanced energy efficiency, with systems achieving coefficients of performance (COP) up to 1.6—approximately 14% higher than indirect methods—and estimated 20% overall improvement over traditional ice-on-coil generators. Power consumption in tested prototypes reaches around 6.5 kW for 3.2 tons/h of slurry (yielding roughly 80 kWh per ton of at low fractions), supported by reduced areas and lower operational costs (8-17% savings versus conventional systems). Research on this method has gained traction since the , driven by advancements in icephobic materials that boost stability by 30-40%. However, unique risks involve spontaneous freezing and blockages in pipelines or exchangers if exceeds safe thresholds or flow velocities drop below 2.1 m/s, necessitating controls like reheating or velocity monitoring. In the 2020s, generators have seen integrations in HVAC systems for and ice storage , as well as medical applications requiring precise temperature control, such as therapeutic . These developments leverage the method's ability to maintain stable low temperatures without excessive cold loss, enhancing overall system reliability.

Fluidized Bed Generators

Fluidized bed generators produce by circulating a carrier through a of particles, such as small balls, which are fluidized by the flow to enhance and prevent ice adhesion to the cooled walls. The system typically employs a vertical column or where the particle is cooled indirectly by a in the jacket, promoting and growth of crystals in the phase as the particles agitate the . This method ensures uniform distribution of fine particles (0.1-1 mm) without agglomeration, achieving fractions up to 20-30% by . The process operates continuously, with the carrier fluid (e.g., water or ) pumped upward through the bed at velocities sufficient to suspend the particles (typically 0.5-2 m/s), facilitating efficient cooling and formation. crystals form around or between the particles and are carried into the slurry stream. Developed in the late 1990s, notably by researchers at , this approach is valued for its high rates and suitability for secondary cooling loops in systems. Energy consumption is comparable to scraped-surface methods, around 50-80 kWh per ton of , with COP values of 2-3 depending on and flow conditions. Challenges include maintaining particle circulation to avoid settling and ensuring compatibility with food-grade applications.

Vacuum Aggregation Generators

Vacuum aggregation generators, also known as flash evaporation systems, produce slurry ice by reducing the pressure over the carrier liquid to below its , causing partial that cools the remaining liquid below its freezing point and induces formation through and aggregation. No external is required, as the process relies on the of ; the vapor is condensed separately to recover energy or maintain . This method generates fine crystals (0.5-2 mm) that aggregate into a pumpable slurry with ice fractions of 5-25% by . In operation, or a dilute solution is introduced into a (pressures around 0.6-1 kPa, corresponding to 0-10°C saturation temperature), where flash boiling occurs, followed by , , and growth phases. The slurry is then discharged while vapor is compressed and condensed. Emerging in research since the , this technique offers high energy efficiency for off-grid or renewable-integrated systems, with consumption as low as 30-50 kWh per ton of due to minimal mechanical input. COP can exceed 4 in optimized setups. Limitations include the need for pumps and condensers, potential for uneven sizes, and scalability challenges for large volumes, though prototypes have demonstrated viability for thermal storage and food chilling.

References

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