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Silex
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Look up silex in Wiktionary, the free dictionary.
Silex is any of various forms of ground stone. In modern contexts the word refers to a finely ground, nearly pure form of silica or silicate.
In the late 16th century, it meant powdered or ground up "flints" (i.e. stones, generally meaning the class of "hard rocks").[1]
It was later used in 1787 when describing experiments in a published paper by Antoine Lavoisier where such earths are mentioned as the source of his isolation of the element silicon. Silex is now most commonly used to describe finely ground silicates used as pigments in paint.
Archaic and foreign uses
[edit]- The word silex was previously used to refer to flint and chert and sometimes other hard rocks.
- In Latin silex originally referred to any hard rock, although now it often refers specifically to flint.[2]
- In many Romance languages, silex or a similar word is used to refer to flint. Although the modern English word silex has the same etymology, its current meaning has changed. These are false friends.
- FK Sileks is a football club based in Kratovo, North Macedonia whose name literally means 'flint'.
References
[edit]- ^ Dictionary.com Unabridged (v 1.1), Origin: 1585–95; < L silex, s. silic- hard stone, flint, boulder]
- ^ Vitruvius De Arch 1.5.8.5 http://latin.packhum.org/loc/1056/1/9/4230-4235
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Silex
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Definition and Etymology
Definition
Silex refers to various forms of siliceous materials, primarily a hard rock composed of microcrystalline quartz (SiO₂), often synonymous with flint or chert in geological and historical contexts.[1][2] In modern industrial applications, silex denotes a finely ground, nearly pure form of silica, typically in powder form with particle sizes ranging from 1 to 100 microns and purity levels exceeding 99% SiO₂.[4][5][6] Unlike raw silica sand, which consists of coarser grains often containing impurities, industrial silex undergoes refinement for uniformity in specialized uses. Common forms include amorphous varieties, such as powdered tripoli, and ground crystalline silica.[1][4]Etymology
The term "silex" originates from the Latin word sīlex (genitive silicis), denoting a hard stone, flint, or pebble.[1] This usage appears in classical Latin texts, including Pliny the Elder's Naturalis Historia (1st century AD), where silex refers to various hard stones employed in construction and tools, such as river-found flint noted for its damp quality.[7] In the evolution of Romance languages, the Latin sīlex influenced terms for flint and similar hard stones. In French, it directly yielded silex, retaining the sense of flint.[8] Italian developed selce from sīlex, commonly used for flint.[9] Spanish uses sílex for flint, alongside pedernal derived from other influences, with sílex common in scientific contexts.[10] The word entered scientific nomenclature in the 18th century, particularly in chemistry, where silex designated siliceous or vitrifiable earths—proto-references to silica compounds. This adoption is evident in the 1787 Méthode de nomenclature chimique by Guyton de Morveau, Lavoisier, Berthollet, and Fourcroy, which listed "silex" among simple substances to standardize chemical terms.[11]Properties
Physical Properties
Silex, as a quartz-based material primarily composed of silicon dioxide (SiO₂), possesses a density of approximately 2.65 g/cm³, which contributes to its effectiveness as a dense grinding medium.[12] This density is characteristic of high-purity quartz forms used in industrial applications.[13] The material exhibits a hardness of 7 on the Mohs scale, owing to its dominant quartz content, enabling it to withstand abrasive conditions without significant wear.[13] In processed grades, silex is ground to controlled particle size distributions, typically yielding 325 mesh (44 microns) or finer particles to suit precise mixing requirements.[14] Silex appears as a white to colorless powder in its finely divided form and is non-porous when pure, facilitating clean and efficient material handling.[15] Thermally, it demonstrates stability below 573°C with a high melting point around 1710°C and low thermal expansion; however, it undergoes an alpha-to-beta phase transition at approximately 573°C, resulting in a volume change that can cause deformation or cracking under certain conditions.[16]Chemical Properties
Silex is predominantly composed of silicon dioxide (SiO₂), with content ranging from 96.9% to 99.5%, accompanied by trace impurities such as aluminum oxide (Al₂O₃) up to 0.34% and iron oxide (Fe₂O₃) up to 0.29%.[17] This composition reflects its derivation from high-purity natural quartz sources.[17] Under standard conditions, silex demonstrates chemical inertness and remains insoluble in water, exhibiting a solubility of approximately 0.01 g/100 mL at 20°C.[18] Its stability stems from the strong covalent bonds in the SiO₂ network structure.[19] At elevated temperatures, silex becomes reactive, fusing with fluxes to form various silicate compounds.[20] It also reacts with strong bases, such as sodium hydroxide (NaOH), particularly under heating, to produce sodium silicate.[19] The silica in silex behaves as a weakly acidic oxide, reacting with strong bases but resistant to most acids except hydrofluoric acid.[21]Sources and Production
Natural Sources
Silex, a cryptocrystalline form of silica (SiO₂), occurs primarily as nodules, layers, or beds within sedimentary rocks, especially limestones and chalks formed during the Late Cretaceous period through the accumulation and diagenetic recrystallization of biogenic silica from marine organisms such as sponges, diatoms, and radiolarians.[2][3] These deposits exhibit high silica content, typically 98–99% SiO₂, with impurities including iron oxides and fossil fragments. Unlike macrocrystalline quartz from igneous or metamorphic sources, silex forms via replacement of calcium carbonate in limestones under low-temperature conditions, concentrating silica in irregular concretions or tabular layers.[2] Globally, prominent sources include Cretaceous chalk formations in Europe, such as the black flint beds of Norfolk and the Cliffs of Dover in England, and similar deposits in northern France and Germany. In North America, notable occurrences are the Alibates Flint Quarries in Texas (Upper Triassic) and chert beds in the Midcontinent region. For finely divided forms used industrially, silex derives from tripoli deposits—microcrystalline silica resulting from the weathering and leaching of chert, novaculite, or siliceous limestones—primarily in the United States, including the Ouachita Mountains and Ozark Plateaus of Arkansas (Mississippian novaculite) and southern Illinois (silicified Paleozoic rocks).[2][22][23] These tripoli sources yield material with particle sizes of 0.1–10 micrometers and purity exceeding 99% SiO₂.[22] While silica resources overall are abundant worldwide, high-quality silex and tripoli deposits are more localized to specific sedimentary basins with suitable biogenic silica accumulation.[24]Production Methods
Production of silex, whether as raw rock for historical uses or ground powder for modern applications, begins with mining from sedimentary deposits using open-pit methods for surface exposures or underground techniques for deeper beds, as seen in Neolithic sites like Grime's Graves or modern tripoli operations.[2][22] In contemporary industrial production, particularly for powdered silex (tripoli), raw material is extracted via open-pit or underground mining in regions like Arkansas, followed by initial drying to remove moisture.[24] The ore is then crushed and pulverized using jaw crushers, hammer mills, or ball mills to achieve fine particle sizes, typically 10–325 mesh (44–2000 micrometers) for fillers and abrasives. Grinding often employs silica-based media to avoid contamination, with energy consumption around 50–100 kWh per ton depending on target fineness.[24][22] Classification follows via air flotation, screening, or hydrocyclones to separate size fractions, yielding uniform grades for applications like paints or dental materials. Final drying in rotary kilns reduces moisture to below 0.5%, and the powder is packaged to maintain purity, typically above 99% SiO₂ without chemical leaching.[24] In the United States, tripoli production reached approximately 79,700 tons in 2018, primarily from Arkansas and other states, supporting uses as inert fillers and abrasives.[24]Applications
Industrial Applications
Silex, a high-purity form of silica, plays a central role in glass production, accounting for about 70% of the raw material batch in soda-lime glass manufacturing, where it functions as the primary network former, flux, and clarifier to promote melting and gas removal for improved clarity.[25][26] In specialty glass applications, such as optical fibers and continuous filament glass, silex with impurity levels below 10 ppm is essential to minimize light scattering and ensure superior optical properties.[27] In ceramics and refractories, silex serves as a key additive in porcelain formulations and high-temperature bricks, contributing up to 30% of the body composition to enhance vitrification, reduce shrinkage, and improve overall mechanical strength and thermal stability.[20] Silex gravel is widely employed in filtration systems for industrial water treatment, acting as an effective support and filtering medium to remove turbidity and particulates through mechanical straining and adsorption processes.[28] As an abrasive material, silex is incorporated into sandblasting media for surface cleaning and preparation in metalworking, as well as polishing compounds for metallurgical applications, leveraging its hardness to achieve precise finishes without excessive material removal.[29] Global demand for silex in these industrial sectors is estimated at approximately 370 million tons annually, with a market value of around $12.2 billion based on 2023 figures.[30]Agricultural and Other Applications
In agriculture, silex, primarily in the form of soluble silicates such as potassium silicate blends with an NPK ratio of 0-0-12, serves as a bio-available silica supplement to enhance plant resilience. These supplements strengthen plant cell walls by depositing silica in epidermal tissues, improving structural integrity and resistance to biotic stresses like pests and fungal pathogens, as well as abiotic factors such as drought and salinity. For instance, foliar or soil applications of potassium silicate have been shown to significantly reduce rice blast incidence through induced plant defense mechanisms.[31] Beyond agriculture, silex functions as a key precursor in electronics for producing high-purity silicon used in semiconductor wafers. Through carbothermic reduction of silica sand (SiO₂) at temperatures exceeding 1500°C, metallurgical-grade silicon is obtained and further purified via the Siemens process to achieve electronic-grade silicon with impurity levels below 1 ppb.[32] This silicon is then grown into single-crystal ingots via the Czochralski method and sliced into wafers essential for integrated circuits and photovoltaic cells.[33] In cosmetics and pharmaceuticals, precipitated or fumed silex acts as a multifunctional excipient, serving as a thickener to improve product viscosity and an anti-caking agent to prevent powder clumping.[34] In cosmetic formulations, silica microspheres provide a soft-focus effect and oil absorption, enhancing texture in foundations and powders at concentrations up to 15%.[35][36] Similarly, in pharmaceuticals, it ensures free-flowing properties in tablet coatings and powdered drugs, with the U.S. FDA recognizing silica as GRAS for such uses.[37] Environmentally, silex-based amendments, particularly silicate-rich materials, are applied to contaminated soils to immobilize heavy metals through adsorption and precipitation. These amendments increase soil pH and provide negatively charged surfaces that bind cations like Cd²⁺, Pb²⁺, and Zn²⁺, reducing their bioavailability to plants by 13-30% in amended soils.[38] For example, silicon-rich biochar derived from silica sources has demonstrated effective stabilization of multiple heavy metals in wheat cultivation, minimizing uptake into edible parts. Emerging applications of silex post-2020 include its integration into 3D printing filaments and lithium-ion battery anodes, with ongoing advancements as of 2025. In additive manufacturing, silica-infused polymer filaments, such as polycarbonate-silica composites, enhance mechanical strength and thermal stability for producing durable prototypes and ceramics.[39] These filaments exhibit up to 20% improved tensile strength compared to pure polymers, enabling high-resolution printing of silica-based scaffolds for biomedical uses.[40] For energy storage, silica serves as a precursor or buffer in silicon anodes, where nanostructured SiO₂ coatings mitigate volume expansion during lithiation, achieving cycle life improvements of over 500 cycles at capacities exceeding 1000 mAh/g.[41] Recent advancements, such as SiOₓ-based anodes with metal oxide doping, have boosted initial Coulombic efficiency to 85%, addressing commercialization barriers for high-energy-density batteries.[42][43]History
Archaic and Early Uses
In the Paleolithic era, beginning around 2.6 million years ago, early humans knapped flint, known as silex in Latin, into sharp tools such as knives, scrapers, and projectile points, marking one of the earliest uses of this hard siliceous rock for practical purposes.[44] These tools, produced through lithic reduction techniques like the Levallois method in later Paleolithic phases, enabled hunting, butchering, and woodworking, with evidence from sites across Europe and Africa showing flint's prevalence due to its conchoidal fracture that yielded keen edges.[45] By the Neolithic period, around 3000 BCE, flint extraction intensified for more specialized implements, as seen at Grime's Graves in Norfolk, England, where miners dug over 400 shafts up to 15 meters deep to access high-quality nodules for crafting polished axes, adzes, and sickles used in agriculture and construction.[46] Concurrently, ground flint or quartz served as a key component in ancient ceramics; in Egypt from approximately 3000 BCE, it formed the siliceous body of faience, a glazed non-clay material molded into beads, amulets, and vessels, where crushed quartz particles (92-99% silica) were mixed with lime and alkali salts before firing to create a durable, turquoise-hued surface.[47] In the Roman era, ground silex contributed to hydraulic mortars like opus signinum, a lime-based mixture incorporating crushed stone aggregates, including flint in regions with local availability, to waterproof floors, walls, and cisterns for enhanced durability against moisture.[48] During the medieval period, silex stones, valued for their hardness, were employed in rotary querns—hand-operated mills consisting of two circular stones—for grinding grains into flour, a practice evident in European archaeological finds where flint or quartzite upper stones rotated against lower bases to process cereals efficiently in households and small communities. As alchemy emerged in the 16th and 17th centuries, "earth of silex" denoted calcined flint or purified silica powder, integrated into glassmaking recipes to form the vitreous base; Italian alchemist and glassmaker Antonio Neri, in his 1612 treatise L'Arte Vetraria, described using such preparations with alkalis and metal oxides to produce clear cristallo glass, bridging empirical craft with proto-chemical experimentation.Modern Developments
In the late 18th century, advancements in chemical analysis marked a pivotal shift in understanding silex, or silica. In 1787, French chemist Antoine Lavoisier conducted experiments on silica, proposing it as an oxide of an unknown element and adopting the term "silex" from Latin to denote this "siliceous earth," which laid the groundwork for recognizing silica's elemental composition.[49] This insight culminated in 1824 when Swedish chemist Jöns Jacob Berzelius isolated elemental silicon by heating potassium fluorosilicate with potassium, confirming silica as silicon dioxide and enabling further scientific exploration of silex's properties.[50] Berzelius's work transitioned silex from a rudimentary material to a subject of systematic chemistry, influencing subsequent industrial applications. The 19th century saw the Industrial Revolution drive mechanized production of silex, particularly for the burgeoning glass industry. Innovations in steam-powered machinery facilitated large-scale grinding of flint and quartz silex into fine abrasives, essential for polishing and cutting glass on an unprecedented scale, which supported the era's expansion in window, bottle, and optical glass manufacturing.[51] This scale-up not only reduced manual labor but also improved uniformity in glass quality, aligning with broader mechanization trends that transformed silex from artisanal tool material to industrial staple. By the mid-20th century, demands for higher purity propelled innovations in silex processing for emerging electronics. Starting in the 1950s, acid-leaching techniques were developed to purify silica sands and quartz, removing impurities like iron and aluminum to produce high-grade silex suitable for semiconductor production, coinciding with the transistor's commercialization and the need for ultra-pure silicon dioxide insulators.[52] These methods enhanced silex's role in electronics, enabling reliable dielectric layers in integrated circuits. Post-2000 developments emphasized sustainability and advanced applications of silex derivatives. Nano-silex, or silica nanoparticles, gained prominence in biotechnology for drug delivery and regenerative medicine, with mesoporous structures allowing controlled release and biocompatibility, as demonstrated in theranostic systems for cancer imaging and treatment since the early 2000s.[53] Concurrently, environmental regulations addressed health risks from silex dust; the U.S. Occupational Safety and Health Administration (OSHA) established its initial permissible exposure limit for respirable crystalline silica in 1971 at 100 micrograms per cubic meter, prompting safer handling practices in mining and processing.[54] Sustainable sourcing initiatives, including recycled quartz and low-impact mining, have since reduced ecological footprints in silex production. Global trade in silex has shifted toward high-tech sectors, notably photovoltaics, where purified silica is vital for silicon wafers in solar panels. Since 2010, the polycrystalline silicon market—derived from silex—has expanded at a compound annual growth rate exceeding 14%, driven by solar capacity additions that reached over 1 terawatt globally by 2022, reflecting a broader transition to renewable energy technologies.[55]References
- https://en.wiktionary.org/wiki/silex#French
- https://en.wiktionary.org/wiki/silex#Italian