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Fermi liquid theory
Fermi liquid theory
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Fermi liquid theory (also known as Landau's Fermi-liquid theory) is a theoretical model of interacting fermions that describes the normal state of the conduction electrons in most metals at sufficiently low temperatures.[1] The theory describes the behavior of many-body systems of particles in which the interactions between particles may be strong. The phenomenological theory of Fermi liquids was introduced by the Soviet physicist Lev Davidovich Landau in 1956,[2] and later developed by Alexei Abrikosov and Isaak Khalatnikov using diagrammatic perturbation theory.[3] The theory explains why some of the properties of an interacting fermion system are very similar to those of the ideal Fermi gas (collection of non-interacting fermions), and why other properties differ.

Fermi liquid theory applies most notably to conduction electrons in normal (non-superconducting) metals, and to liquid helium-3.[4] Liquid helium-3 is a Fermi liquid at low temperatures (but not low enough to be in its superfluid phase). An atom of helium-3 has two protons, one neutron and two electrons, giving an odd number of fermions, so the atom itself is a fermion. Fermi liquid theory also describes the low-temperature behavior of electrons in heavy fermion materials, which are metallic rare-earth alloys having partially filled f orbitals. The effective mass of electrons in these materials is much larger than the free-electron mass because of interactions with other electrons, so these systems are known as heavy Fermi liquids. Strontium ruthenate displays some key properties of Fermi liquids, despite being a strongly correlated material that is similar to high temperature superconductors such as the cuprates.[5] The low-momentum interactions of nucleons (protons and neutrons) in atomic nuclei are also described by Fermi liquid theory.[6]

Description

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The key ideas behind Landau's theory are the notion of adiabaticity and the Pauli exclusion principle.[7] Consider a non-interacting fermion system (a Fermi gas), and suppose we "turn on" the interaction slowly. Landau argued that in this situation, the ground state of the Fermi gas would adiabatically transform into the ground state of the interacting system.

By Pauli's exclusion principle, the ground state of a Fermi gas consists of fermions occupying all momentum states corresponding to momentum with all higher momentum states unoccupied. As the interaction is turned on, the spin, charge and momentum of the fermions corresponding to the occupied states remain unchanged, while their dynamical properties, such as their mass, magnetic moment etc. are renormalized to new values.[7] Thus, there is a one-to-one correspondence between the elementary excitations of a Fermi gas system and a Fermi liquid system. In the context of Fermi liquids, these excitations are called "quasiparticles".[1]

Landau quasiparticles are long-lived excitations with a lifetime that satisfies where is the quasiparticle energy (measured from the Fermi energy). At finite temperature, is on the order of the thermal energy , and the condition for Landau quasiparticles can be reformulated as .

For this system, the many-body Green's function can be written[8] (near its poles) in the form

where is the chemical potential, is the energy corresponding to the given momentum state and is called the quasiparticle residue or renormalisation constant which is very characteristic of Fermi liquid theory. The spectral function for the system can be directly observed via angle-resolved photoemission spectroscopy (ARPES), and can be written (in the limit of low-lying excitations) in the form:

where is the Fermi velocity.[9]

Physically, we can say that a propagating fermion interacts with its surrounding in such a way that the net effect of the interactions is to make the fermion behave as a "dressed" fermion, altering its effective mass and other dynamical properties. These "dressed" fermions are what we think of as "quasiparticles".[10]

Another important property of Fermi liquids is related to the scattering cross section for electrons. Suppose we have an electron with energy above the Fermi surface, and suppose it scatters with a particle in the Fermi sea with energy . By Pauli's exclusion principle, both the particles after scattering have to lie above the Fermi surface, with energies . Now, suppose the initial electron has energy very close to the Fermi surface Then, we have that also have to be very close to the Fermi surface. This reduces the phase space volume of the possible states after scattering, and hence, by Fermi's golden rule, the scattering cross section goes to zero. Thus we can say that the lifetime of particles at the Fermi surface goes to infinity.[1]

Similarities to Fermi gas

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The Fermi liquid is qualitatively analogous to the non-interacting Fermi gas, in the following sense: The system's dynamics and thermodynamics at low excitation energies and temperatures may be described by substituting the non-interacting fermions with interacting quasiparticles, each of which carries the same spin, charge and momentum as the original particles. Physically these may be thought of as being particles whose motion is disturbed by the surrounding particles and which themselves perturb the particles in their vicinity. Each many-particle excited state of the interacting system may be described by listing all occupied momentum states, just as in the non-interacting system. As a consequence, quantities such as the heat capacity of the Fermi liquid behave qualitatively in the same way as in the Fermi gas (e.g. the heat capacity rises linearly with temperature).

Differences from Fermi gas

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The following differences to the non-interacting Fermi gas arise:

Energy

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The energy of a many-particle state is not simply a sum of the single-particle energies of all occupied states. Instead, the change in energy for a given change in occupation of states contains terms both linear and quadratic in (for the Fermi gas, it would only be linear, , where denotes the single-particle energies). The linear contribution corresponds to renormalized single-particle energies, which involve, e.g., a change in the effective mass of particles. The quadratic terms correspond to a sort of "mean-field" interaction between quasiparticles, which is parametrized by so-called Landau Fermi liquid parameters and determines the behaviour of density oscillations (and spin-density oscillations) in the Fermi liquid. Still, these mean-field interactions do not lead to a scattering of quasi-particles with a transfer of particles between different momentum states.

The renormalization of the mass of a fluid of interacting fermions can be calculated from first principles using many-body computational techniques. For the two-dimensional homogeneous electron gas, GW calculations[11] and quantum Monte Carlo methods[12][13][14] have been used to calculate renormalized quasiparticle effective masses.

Specific heat and compressibility

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Specific heat, compressibility, spin-susceptibility and other quantities show the same qualitative behaviour (e.g. dependence on temperature) as in the Fermi gas, but the magnitude is (sometimes strongly) changed.

Interactions

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In addition to the mean-field interactions, some weak interactions between quasiparticles remain, which lead to scattering of quasiparticles off each other. Therefore, quasiparticles acquire a finite lifetime. However, at low enough energies above the Fermi surface, this lifetime becomes very long, such that the product of excitation energy (expressed in frequency) and lifetime is much larger than one. In this sense, the quasiparticle energy is still well-defined (in the opposite limit, Heisenberg's uncertainty relation would prevent an accurate definition of the energy).

Structure

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The structure of the "bare" particles (as opposed to quasiparticle) many-body Green's function is similar to that in the Fermi gas (where, for a given momentum, the Green's function in frequency space is a delta peak at the respective single-particle energy). The delta peak in the density-of-states is broadened (with a width given by the quasiparticle lifetime). In addition (and in contrast to the quasiparticle Green's function), its weight (integral over frequency) is suppressed by a quasiparticle weight factor . The remainder of the total weight is in a broad "incoherent background", corresponding to the strong effects of interactions on the fermions at short time scales.

Distribution

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The distribution of particles (as opposed to quasiparticles) over momentum states at zero temperature still shows a discontinuous jump at the Fermi surface (as in the Fermi gas), but it does not drop from 1 to 0: the step is only of size .

Electrical resistivity

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In a metal the resistivity at low temperatures is dominated by electron–electron scattering in combination with umklapp scattering. For a Fermi liquid, the resistivity from this mechanism varies as , which is often taken as an experimental check for Fermi liquid behaviour (in addition to the linear temperature-dependence of the specific heat), although it only arises in combination with the lattice. In certain cases, umklapp scattering is not required. For example, the resistivity of compensated semimetals scales as because of mutual scattering of electron and hole. This is known as the Baber mechanism.[15]

Optical response

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Fermi liquid theory predicts that the scattering rate, which governs the optical response of metals, not only depends quadratically on temperature (thus causing the dependence of the DC resistance), but it also depends quadratically on frequency.[16][17][18] This is in contrast to the Drude prediction for non-interacting metallic electrons, where the scattering rate is a constant as a function of frequency. One material in which optical Fermi liquid behavior was experimentally observed is the low-temperature metallic phase of Sr2RuO4.[19]

Instabilities

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The experimental observation of exotic phases in strongly correlated systems has triggered an enormous effort from the theoretical community to try to understand their microscopic origin. One possible route to detect instabilities of a Fermi liquid is precisely the analysis done by Isaak Pomeranchuk.[20] Due to that, the Pomeranchuk instability has been studied by several authors [21] with different techniques in the last few years and in particular, the instability of the Fermi liquid towards the nematic phase was investigated for several models.

Non-Fermi liquids

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Non-Fermi liquids are systems in which the Fermi-liquid behaviour breaks down. The simplest example is a system of interacting fermions in one dimension, called the Luttinger liquid.[4] Although Luttinger liquids are physically similar to Fermi liquids, the restriction to one dimension gives rise to several qualitative differences such as the absence of a quasiparticle peak in the momentum dependent spectral function, and the presence of spin-charge separation and of spin-density waves. One cannot ignore the existence of interactions in one dimension and has to describe the problem with a non-Fermi theory, where Luttinger liquid is one of them. At small finite spin temperatures in one dimension the ground state of the system is described by spin-incoherent Luttinger liquid (SILL).[22]

Another example of non-Fermi-liquid behaviour is observed at quantum critical points of certain second-order phase transitions, such as heavy fermion criticality, Mott criticality and high- cuprate phase transitions.[9] The ground state of such transitions is characterized by the presence of a sharp Fermi surface, although there may not be well-defined quasiparticles. That is, on approaching the critical point, it is observed that the quasiparticle residue .

In optimally doped cuprates and iron-based superconductors, the normal state above the critical temperature shows signs of non-Fermi liquid behaviour, and is often called a strange metal. In this region of phase diagram, resistivity increases linearly in temperature and the Hall coefficient is found to depend on temperature.[23][24]

Understanding the behaviour of non-Fermi liquids is an important problem in condensed matter physics. Approaches towards explaining these phenomena include the treatment of marginal Fermi liquids; attempts to understand critical points and derive scaling relations; and descriptions using emergent gauge theories with techniques of holographic gauge/gravity duality.[25][26][27]

See also

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References

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Further reading

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Revisions and contributorsEdit on WikipediaRead on Wikipedia
from Grokipedia
Fermi liquid theory is a phenomenological framework developed by Soviet physicist Lev Davidovich Landau in 1956 to describe the behavior of strongly interacting fermionic systems at low temperatures, positing that such systems can be effectively mapped onto a non-interacting Fermi gas through the introduction of long-lived quasiparticle excitations with renormalized properties like effective mass and interaction parameters. The theory applies to a wide range of materials, including liquid helium-3 and conduction electrons in metals, where interactions do not destroy the underlying Fermi surface but modify its characteristics, enabling the prediction of thermodynamic and transport properties such as specific heat and electrical resistivity. At the core of the theory is the representation of the system's energy as a functional of the distribution function f(p)f(\mathbf{p}), where quasiparticles carry the quantum numbers ( and spin) of the original fermions but have a ϵ(p)vF(ppF)\epsilon(\mathbf{p}) \approx v_F (|\mathbf{p}| - p_F) near the Fermi pFp_F, with Fermi vFv_F and effective m=pF/vFm^* = p_F / v_F. Interactions between quasiparticles are encoded in the Landau interaction function f(p,p)f(\mathbf{p}, \mathbf{p}'), which is expanded in to yield dimensionless parameters Fls/aF_l^{s/a} for symmetric and antisymmetric spin channels, influencing modes like zero and stability conditions (e.g., 1+F0s>01 + F_0^s > 0 for ). This framework reveals that Fermi liquids are adiabatically connected to free Fermi gases, preserving low-energy excitations while accounting for strong correlations without requiring full microscopic many-body calculations. Key predictions include a linear specific heat γm\gamma \propto m^*, enhanced by factors of 2–10 in typical metals and up to 100–1000 in heavy-fermion systems, alongside a T2T^2 dependence in resistivity due to quasiparticle-quasiparticle . The spin susceptibility χ\chi and orbital effects are similarly renormalized, with χ/χ0=(m/m)/(1+F0a)\chi / \chi_0 = (m^*/m) / (1 + F_0^a), explaining observed enhancements in paramagnetic metals. Historically, Landau's approach was motivated by discrepancies in and liquid experiments, where traditional models failed, and it has since been extended to dilute matter and ultracold atomic gases, though breakdowns occur in low dimensions or near quantum critical points leading to non-Fermi liquid behavior.

Introduction

Historical Context

Fermi liquid theory originated in the mid-1950s through the work of Soviet physicist , who sought to describe the low-temperature properties of interacting fermionic systems such as liquid helium-3 and the conduction electrons in metals, where the free-electron model failed to account for observed behaviors due to electron-electron interactions. 's motivation stemmed from experimental discrepancies in real metals, including enhanced specific heat coefficients and magnetic susceptibilities compared to predictions from the ideal , indicating that interactions renormalize key parameters without fundamentally altering the fermionic excitation spectrum. The theory built upon earlier foundations in quantum many-body physics, particularly Enrico Fermi's 1926 development of Fermi-Dirac statistics for indistinguishable fermions, which established the ideal as a baseline for non-interacting systems, and the Hartree-Fock approximation introduced in the late 1920s, which provided a mean-field treatment of interactions in atomic and solid-state systems. These precursors highlighted the need for a more general framework to handle strong correlations while preserving the qualitative features of free fermions at low energies. Key milestones include Landau's seminal 1956 paper, "The Theory of a Fermi Liquid," which introduced the concept as a phenomenological tool for excitations in interacting systems, followed by his 1958 elaboration on the theory's implications for transport and thermodynamic properties. The framework was further developed and popularized in the 1966 book The Theory of Quantum Liquids, Volume I: Normal Fermi Liquids by and Philippe Nozières, which provided microscopic justifications and applications to both neutral and charged systems. Landau, who received the 1962 for his earlier theory of in liquid , applied similar phenomenological insights to fermionic in within the Fermi liquid paradigm, though the prize recognized his bosonic work as distinct yet foundational to his broader contributions in quantum fluids.

Core Concepts

provides a theoretical framework for understanding the behavior of weakly interacting fermionic systems at low temperatures, where the effects of interactions can be incorporated through the concept of quasiparticles. These quasiparticles are long-lived excitations that closely resemble the free particles of a non-interacting but possess renormalized properties, such as an effective mass and Fermi velocity, due to the influence of interparticle interactions. Developed by , this theory posits that the low-energy physics of the interacting system can be mapped onto an effective non-interacting model, allowing for the description of thermodynamic and transport properties without solving the full . A key assumption underlying the theory is the principle of adiabatic continuity, which asserts that as interactions are gradually turned on from zero strength, the ground state and low-lying excitations of the system evolve smoothly without crossing any phase transitions. This continuity holds for systems with weak, short-range interactions, ensuring that the quantum numbers like momentum and spin remain well-defined for the quasiparticles. The validity of this assumption is particularly relevant near the Fermi surface, where the density of states is high, and perturbations do not drastically alter the overall structure of the Fermi sea. The central theorem of Fermi liquid theory states that both the and the low-energy excitations of the interacting fermionic system can be effectively described by an ideal whose parameters—such as the effective mass mm^*, Fermi velocity vFv_F, and Landau parameters characterizing interactions—have been renormalized by the presence of interactions. This mapping preserves the essential features of the non-interacting case while accounting for effects, enabling predictions of observables like specific heat and susceptibility in terms of these modified parameters. In the context of , the theory elucidates the normal metallic state of electrons in solids, where it successfully explains phenomena such as the linear temperature dependence of specific heat and electrical conductivity, provided strong correlations or elevated temperatures do not invalidate the weak-coupling regime. Unlike bosonic systems, where interactions can lead to Bose-Einstein condensation and collective modes like superfluidity, Fermi liquid theory maintains the Pauli exclusion principle for quasiparticles, ensuring fermionic statistics and a filled Fermi sea at zero temperature. This preservation of exclusion statistics distinguishes the excitation spectrum and thermodynamic behavior of fermionic liquids from their bosonic counterparts. Originally motivated by the need to explain the anomalous properties of liquid 3^3He, such as its enhanced specific heat compared to a free gas, the theory has broad applicability to electron gases in metals.

Relation to Non-Interacting Fermi Gas

Shared Ground-State Features

In the ground state of a Fermi liquid, the system forms a filled Fermi sea, where all single-particle momentum states up to the Fermi momentum kFk_F (corresponding to the Fermi energy EFE_F) are occupied at absolute zero temperature, precisely mirroring the structure of a non-interacting Fermi gas. This configuration enforces the fermionic statistics through the Pauli exclusion principle, ensuring that no two particles share the same quantum state below EFE_F. The resulting ground state is characterized by translational invariance and a well-defined Fermi surface, which separates occupied and unoccupied states. The total ground-state energy E0E_0 scales proportionally to NEFN E_F, where NN is the total number of particles, akin to the non-interacting case where E0=35NEFE_0 = \frac{3}{5} N E_F in three dimensions. Interactions introduce corrections to the prefactor, but the leading kinetic contribution preserves this extensive scaling, highlighting how the Fermi sea's volume dictates the energy despite particle interactions. Similarly, the at the adopts the form g(EF)mkF/2g(E_F) \propto m^* k_F / \hbar^2, with mm^* denoting the effective mass, structurally identical to the free gas expression but adapted to account for interactions without altering the foundational proportionality. At zero , the distribution function n(k)n(\mathbf{k}) displays a sharp discontinuity at k=kFk = k_F, dropping abruptly from Z to 0 for k>kFk > k_F, where Z is the residue (0 < Z ≤ 1, with Z = 1 in the non-interacting limit), a feature directly inherited from the non-interacting Fermi gas and indicative of the underlying fermionic correlations. This jump, often quantified by the residue Zk0Z_k \neq 0, underscores the persistence of Fermi surface coherence. Furthermore, the ground state in both systems exhibits stability against infinitesimal perturbations, as the Pauli principle rigidifies the filled sea, prohibiting collapse or instability for weak interactions. These shared features manifest prominently in physical realizations such as the conduction electron gas in normal metals, where the Fermi sea governs metallic properties, and in dilute liquid 3^3He at low temperatures and densities, serving as a canonical neutral Fermi liquid example.

Common Excitation Spectrum

In the low-energy regime, the excitation spectrum of a Fermi liquid mirrors that of a non-interacting Fermi gas, enabling a direct correspondence between their dynamical responses near the Fermi surface. This parallelism stems from the adiabatic continuity of low-lying excited states from the non-interacting to the interacting case, preserving the essential structure of fermionic excitations at energies well below the Fermi energy. Single-particle excitations in both systems constitute a particle-hole continuum, where promoting an electron across the creates a particle above kFk_F and a hole below it. Near the , the dispersion relation for these excitations takes the linear form ϵkvF(kkF)\epsilon_k \approx v_F (k - k_F), with vFv_F the Fermi velocity defined as vF=kF/mv_F = \hbar k_F / m in the non-interacting gas (and renormalized in the liquid). This continuum spans a range of energies starting from zero, reflecting the availability of low-momentum transfers in the degenerate electron sea. In the Fermi liquid, interactions give rise to collective excitations, particularly zero sound, as collisionless density oscillations propagating along the . These modes emerge due to the self-consistent effects of the Landau interaction function and are stabilized outside the particle-hole continuum, with a speed c>vFc > v_F for weak repulsive interactions. In contrast, the non-interacting lacks such discrete collective modes, with responses confined to the particle-hole continuum in the collisionless kinetic regime. At low temperatures, the excitations remain long-lived in both systems due to Pauli blocking, which severely restricts the for decay processes like electron-electron scattering. The resulting quasiparticle lifetime follows τ1/T2\tau \propto 1/T^2, as the available final states scale with the thermally excited carriers near the . This quadratic temperature dependence ensures that scattering rates vanish as T0T \to 0, maintaining the sharpness of the spectrum. The single-particle spectral function A(k,ω)A(\mathbf{k}, \omega), which encodes the probability of adding or removing a particle with momentum k\mathbf{k} and energy ω\omega, displays Lorentzian peaks at the poles corresponding to the dispersion ϵk\epsilon_k in the non-interacting limit, where the width vanishes to yield delta functions. In the presence of weak interactions, as in the Fermi liquid, these peaks acquire a comparable finite broadening Γ1/τ\Gamma \sim 1/\tau, reflecting the shared decay mechanisms without altering the overall lineshape significantly. This common excitation spectrum applies specifically to regimes where the excitation δEEF\delta E \ll E_F and temperature TTFT \ll T_F, with TF=EF/kBT_F = E_F / k_B the Fermi temperature, ensuring that only states near the contribute and higher-order interaction effects remain perturbative.

Quasiparticle Framework

Quasiparticle Definition

In Fermi liquid theory, represent the elementary excitations of the interacting Fermi system, conceptualized as coherent superpositions of many-body states that effectively behave like weakly interacting particles with well-defined k\mathbf{k} and ϵk\epsilon_{\mathbf{k}}. These excitations are generated by applying a creation operator ψk\psi^\dagger_{\mathbf{k}} to the ground state 0|0\rangle, yielding a state ψk0\psi^\dagger_{\mathbf{k}} |0\rangle that carries the k\mathbf{k} and possesses a definite ϵk\epsilon_{\mathbf{k}} relative to the μ\mu. This formulation arises from Landau's hypothesis that low-energy excitations in the interacting system maintain a one-to-one correspondence with those of a non-interacting , allowing the complex many-body correlations to be "dressed" onto effective single-particle-like entities. Quasiparticles are particularly well-defined in the vicinity of the , where the momentum deviation satisfies kkFkF|k - k_F| \ll k_F, ensuring that the excitation energy remains much smaller than the EFE_F. Their finite lifetime is characterized by a decay width Γ(ϵμ)2+(πT)2\Gamma \propto (\epsilon - \mu)^2 + (\pi T)^2, which vanishes on the at zero temperature (T=0T = 0, ϵ=μ\epsilon = \mu), implying an infinite quasiparticle lifetime under these conditions and justifying their particle-like description at low energies and temperatures. At finite temperatures or away from the , the lifetime τ=1/Γ\tau = 1/\Gamma decreases, but remains long compared to the inverse energy scale near kFk_F, preserving coherence. The occupation number nkn_{\mathbf{k}} for follows a step-like behavior, jumping discontinuously from 1 (occupied) to 0 (unoccupied) at k=kFk = k_F in the non-interacting case, though interactions introduce a smoothing of this discontinuity. A key feature of the theory is the additivity of quasiparticle excitations: the entire system, including its and low-lying states, can be described as an of these non-interacting quasiparticles, which obey standard Fermi-Dirac statistics with the renormalized energy ϵk\epsilon_{\mathbf{k}}. This additivity underpins the mapping of the interacting problem onto an effective free-particle description. Experimentally, manifest in (ARPES) as sharp peaks in the single-particle spectral function, directly revealing their dispersion ϵk\epsilon_{\mathbf{k}} and confirming the Fermi liquid picture in materials like organic metals. These peaks, corresponding to the coherent removal or addition of a , provide evidence of the well-defined excitations near the .

Effective Mass and Renormalization

In Fermi liquid theory, interactions between lead to a of the parameters, distinguishing them from the bare particle properties of the non-interacting . The effective mass mm^*, which governs the near the , is modified by inter-quasiparticle scattering effects captured through the Landau parameters. Specifically, in the phenomenological framework, the effective mass is given by m=m(1+F1s3),m^* = m \left(1 + \frac{F_1^s}{3}\right), where mm is the bare mass and F1sF_1^s is the dimensionless symmetric Landau parameter of l=1l=1, defined as F1s=N(0)f1sF_1^s = N(0) f_1^s with N(0)N(0) the at the and f1sf_1^s the corresponding interaction function. This arises from the of the system, ensuring that the total momentum response incorporates both single-particle motion and induced interactions; positive F1s>0F_1^s > 0 enhances mm^*, while negative values reduce it, though stability requires F1s>3F_1^s > -3. From a microscopic perspective, the renormalization originates in the self-energy Σ(k,ω)\Sigma(k, \omega), which accounts for many-body corrections to the single-particle propagator. The quasiparticle renormalization factor ZZ, representing the overlap between the interacting quasiparticle and the bare fermion state, is Z=(1Σ(kF,ω)ωω=0)1,Z = \left(1 - \left. \frac{\partial \Re \Sigma(k_F, \omega)}{\partial \omega}\right|_{\omega=0}\right)^{-1},
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