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Alan J. Heeger
Alan J. Heeger
Alan J. Heeger
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Alan Jay Heeger (born January 22, 1936) is an American physicist, academic and Nobel Prize laureate in chemistry.

Key Information

Heeger was elected as a member into the National Academy of Engineering in 2002 for co-founding the field of conducting polymers and for pioneering work in making these novel materials available for technological applications.

Life and career

[edit]

Heeger was born in Sioux City, Iowa, into a Jewish family. He grew up in Akron, Iowa, where his father owned a general store. At age nine, following his father's death, the family moved to Sioux City.[1]

Heeger earned a B.S. in physics and mathematics from the University of Nebraska in 1957, and a Ph.D in physics from the University of California, Berkeley in 1961. From 1962 to 1982 he was on the faculty of the University of Pennsylvania. In 1982 he commenced his present appointment as a professor in the Physics Department and the Materials Department at the University of California, Santa Barbara. His research has led to the formation of numerous start-up companies including Uniax, Konarka, and Sirigen, founded in 2003 by Guillermo C. Bazan, Patrick J. Dietzen, Brent S. Gaylord. Alan Heeger was a founder of Uniax, which was acquired by DuPont.

He won the Nobel Prize for Chemistry in 2000 along with Alan G. MacDiarmid and Hideki Shirakawa "for their discovery and development of conductive polymers"; They published their results on polyacetylene a conductive polymer in 1977.[2][3] This led to the construction of the Su–Schrieffer–Heeger model, a simple model for topological insulators.

He had won the Oliver E. Buckley Prize of the American Physical Society in 1983 and, in 1995, the Balzan Prize for Science of Non-Biological Materials.

His sons are the neuroscientist David Heeger and the immunologist Peter Heeger.

In October 2010, Heeger participated in the USA Science and Engineering Festival's Lunch with a Laureate program where middle and high school students engage in an informal conversation with a Nobel Prize-winning scientist over a brown-bag lunch.[4] Heeger is also a member of the USA Science and Engineering Festival's Advisory Board.[5] Heeger has been a judge of the STAGE International Script Competition three times (2006, 2007, 2010).[6]

"Perhaps the greatest pleasure of being a scientist is to have an abstract idea, then to do an experiment (more often a series of experiments is required) that demonstrates the idea was correct; that is, Nature actually behaves as conceived in the mind of the scientist. This process is the essence of creativity in science. I have been fortunate to have experienced this intense pleasure many times in my life." Alan J Heeger, Never Lose Your Nerve![7]

Publication list

[edit]

Journal Articles:

  • Heeger, Alan (1977). "One-Dimensional Phonons and "Phase-Ordering" Phase Transition in Hg3-deltaAsF6". Physical Review Letters. 39 (23): 1484–1487. Bibcode:1977PhRvL..39.1484H. doi:10.1103/PhysRevLett.39.1484.
  • Heeger, Alan (1977). "Electrical Conductivity in Doped Polyacetylene". Physical Review Letters. 39 (17): 1098–1101. Bibcode:1977PhRvL..39.1098C. doi:10.1103/PhysRevLett.39.1098.

Technical Reports:

Autobiography

[edit]

Heeger, Alan J (2015). Never Lose Your Nerve!. doi:10.1142/9724. ISBN 978-981-4704-85-4., World Scientific Publishing, ISBN 978-981-4704-85-4

See also

[edit]

References

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[edit]
Revisions and contributorsEdit on WikipediaRead on Wikipedia

Alan J. Heeger

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from Grokipedia
Alan J. Heeger (born January 22, 1936) is an American physicist and best known for co-discovering and developing conductive polymers, a breakthrough that revolutionized by enabling plastics to conduct like metals or semiconductors. He shared the 2000 with Alan G. MacDiarmid and Hideki Shirakawa for this work, which began in the late 1970s with experiments on doped that demonstrated metallic conductivity in organic materials. Born in , to Jewish parents from immigrant families from , Heeger grew up in , after his family moved there following his father's early death; he completed high school early and earned a B.S. in physics and mathematics from the University of Nebraska in 1957. He obtained his Ph.D. in physics from the , in 1961 under Alan Portis, focusing on experimental . Early in his career, Heeger joined the as a faculty member in 1962, where he conducted groundbreaking research on organic conductors like TTF-TCNQ and collaborated with MacDiarmid on the conductivity of , leading to the identification of solitons as charge carriers in these polymers. In 1982, Heeger moved to the University of California, Santa Barbara (UCSB), where he founded the Institute for Polymers and Organic Solids and advanced applications of semiconducting polymers, including the invention of polymer light-emitting diodes (LEDs) and bulk heterojunction photovoltaic cells. As Professor Emeritus of physics and materials at UCSB, his ongoing research emphasizes high-mobility field-effect transistors, plastic solar cells, and biosensors for detecting DNA, proteins, and small molecules. He has co-founded several companies to commercialize these technologies, including UNIAX Corporation (acquired by DuPont in 2000), Konarka Technologies, and others focused on organic electronics and biotechnology. Heeger's contributions extend beyond academia; he is a member of the U.S. and , as well as foreign academies in Korea and , and has received prestigious awards such as the Oliver E. Buckley Prize in and the . With over 1,000 peer-reviewed publications and more than 50 patents, his work has enabled innovations in , energy-efficient displays, and devices. Heeger is married to Ruth, whom he met in high school, and they have two sons, both academics, and four grandchildren.

Early Life and Education

Family Background and Childhood

Alan J. Heeger was born on January 22, 1936, in , into a Jewish family of Eastern European descent. His father had immigrated from as a young child in 1904, while his mother was born in , to Jewish parents who had also emigrated from to escape and economic hardship. He spent his early childhood in Akron, , a rural town of about 1,000 residents located 35 miles from Sioux City, where his father managed a that served the surrounding farming community. This setting immersed Heeger in the rhythms of rural life, including interactions with farmers and an appreciation for the hard work required in agricultural environments. When Heeger was nine years old, his father died suddenly at age 45 from heart disease on April 12, 1945—the same day as U.S. President . The family then relocated to , to be closer to his mother's relatives, leaving his mother to raise Heeger and his younger brother, Gerald, on her own. She emphasized the importance of education as a means of advancement, shaping their future paths despite the challenges of single parenthood. In Omaha, Heeger attended , graduating one year early in 1953, motivated by his desire to advance his education more quickly.

University Studies and PhD

Heeger earned a Bachelor of Science degree in physics and mathematics from the University of Nebraska in 1957, graduating with high distinction. He pursued graduate studies in physics at the University of California, Berkeley, where he completed his PhD in 1961 under the supervision of Alan M. Portis. His doctoral thesis, titled "Studies on the Magnetic Properties of Canted Antiferromagnets," examined the magnetic behavior of transition metal compounds through experimental techniques, including measurements on KMnF₃, an insulating antiferromagnet. Throughout his graduate work at Berkeley, Heeger immersed himself in experimental , focusing on and antiferromagnetic systems, which honed his skills in low-temperature measurements and theoretical interpretations of magnetic interactions. Following his PhD, Heeger served as a in the Physics Department at the , from 1961 to 1962, where he extended his research on the magnetic properties of antiferroelectric antiferromagnets.

Academic and Professional Career

Tenure at University of Pennsylvania

In 1962, shortly after completing his PhD in at the , Alan J. Heeger joined the as an in the Department of Physics. He advanced rapidly through the ranks, becoming in 1964 and full professor in 1967, a position he held until 1982. He also served as Acting Vice-Provost for Research from 1981 to 1982. During this period, Heeger established a prominent research group at Penn, emphasizing investigations into low-dimensional materials and magnetic systems, including topics such as spin-wave theory, metal physics, the , and in magnetic materials. His leadership extended to serving as director of the Laboratory for Research on the Structure of Matter (LRSM) from 1974 to 1981, fostering interdisciplinary collaborations in . In the early , Heeger began a pivotal collaboration with chemist Alan G. MacDiarmid, also at Penn, exploring the electronic properties of organic materials as an extension of his work on low-dimensional systems. This partnership drew on Heeger's expertise in and MacDiarmid's in synthetic chemistry, initially focusing on conjugated polymers like to understand their potential for tunable conductivity. The collaboration culminated in groundbreaking experiments in 1977, where Heeger, MacDiarmid, and visiting researcher Hideki Shirakawa demonstrated that chemical doping of with or could transform the insulating into a metallic conductor. These studies revealed a dramatic increase in electrical conductivity by up to eight orders of magnitude—from approximately 10−510^{-5} (Ω⋅cm)−1(\Omega \cdot \text{cm})^{-1} in the undoped state to as high as 10310^{3} (Ω⋅cm)−1(\Omega \cdot \text{cm})^{-1} in heavily doped samples—marking the first observation of metallic behavior in an organic and laying the foundation for the field of conductive polymers. This discovery, conducted within Heeger's Penn laboratory, highlighted the potential of organic materials for applications and stemmed directly from the interdisciplinary environment he cultivated.

Role at University of California, Santa Barbara

In 1982, Alan J. Heeger joined the (UCSB) as a of physics, marking the beginning of his senior career phase focused on institutional leadership and applied research in . He was also appointed of materials in the College of Engineering in 1987, reflecting his interdisciplinary expertise. That same year, Heeger co-founded the Institute for Polymers and Organic Solids (IPOS) with chemist Fred Wudl, serving as its director from 1982 until 1999. Under his leadership, the institute expanded from a small research group into a major international center for , fostering interdisciplinary collaboration across physics, chemistry, and while attracting funding, faculty, and global researchers to advance studies on conjugated polymers and related technologies. The institute was renamed the Center for Polymers and Organic Solids (CPOS) in 2000, continuing its prominence in the field. During his tenure at UCSB, Heeger mentored a large number of graduate students and postdoctoral researchers, contributing to a prolific output that includes over 1,000 co-authored publications in peer-reviewed journals. This mentorship helped build a robust pipeline of scientists advancing organic materials . Heeger's work at UCSB also extended to industry translation, where he founded Uniax Corporation in 1990 to commercialize conducting polymer applications, which was acquired by in 2000. He co-founded Konarka Technologies in 2001, a company dedicated to developing organic photovoltaic solar cells, though it filed for in 2012 amid funding challenges. Additionally, his underpinned the 2003 founding of Sirigen Group, a UCSB spinout focused on polymer-based diagnostics, which was acquired by Becton, Dickinson and Company in 2012.

Scientific Contributions

Discovery and Development of Conductive Polymers

In 1977, Alan J. Heeger, collaborating with Alan G. MacDiarmid at the and Hideki Shirakawa, made a groundbreaking observation: exposing films to iodine vapor transformed the from an electrical insulator, with conductivity around 10−910^{-9} S/cm, to a material exhibiting metal-like conductivity. This serendipitous experiment, stemming from Shirakawa's earlier synthesis of shiny, metallic-looking films, revealed that oxidation doping introduced charge carriers into the conjugated backbone, enabling tunable electrical properties. Their key publication in detailed the doping process using arsenic pentafluoride (AsF5), achieving conductivities up to approximately 220 S/cm, with comparable results for iodine and other , thereby challenging the that organic polymers could only serve as insulators rather than semiconductors or conductors. Through further refinements, including mechanical stretching of the films to enhance chain alignment, the team elevated iodine-doped polyacetylene's conductivity to over 10510^5 S/cm by the early 1980s, rivaling that of metals like carbon and demonstrating the potential for organic materials in . In the late 1970s, Heeger and colleagues systematized chemical doping methods, such as vapor-phase exposure to iodine or , which oxidize the polymer via charge-transfer reactions, systematically varying conductivity over more than ten orders of magnitude from insulator to metal regimes. By the , they pioneered electrochemical doping techniques, first reported in , allowing reversible and precise control of dopant concentration through anodic oxidation or cathodic reduction in solutions, where counterions balance the injected charges. These methods not only improved stability and processability but also enabled the creation of p-type and n-type doped films with metallic characteristics. Central to explaining charge transport in these systems was the concept of solitons, topological defects in the chain that act as localized excitations bridging regions of alternating single and double bonds. Upon doping, charged solitons form mid-gap states that store and transport charge with minimal energy penalty, unlike conventional band carriers in inorganic semiconductors, thereby accounting for the observed high conductivities and low activation energies in doped .

Su-Schrieffer-Heeger Model

The Su-Schrieffer-Heeger (SSH) model was developed between 1979 and 1980 by Wu-Pei Su, John R. Schrieffer, and Alan J. Heeger to provide a theoretical framework for the π-electron system in trans-, explaining its electronic properties and the mechanism behind its conductivity upon doping. The model treats as a one-dimensional chain of carbon atoms with alternating single and double bonds, incorporating electron-phonon coupling to capture lattice distortions and their impact on electron hopping. This theoretical advance complemented earlier experimental observations of conductivity in doped , offering a quantum mechanical description of how structural defects enable charge transport. At its core, the SSH model is described by a tight-binding Hamiltonian for spinless electrons, coupled to lattice vibrations, but in the adiabatic approximation, the electronic part takes the form: H=−∑n[tn,n+1(cn+1†cn+h.c.)+Δn2(cn+1†cn−h.c.)],H = -\sum_n \left[ t_{n,n+1} (c^\dagger_{n+1} c_n + \mathrm{h.c.}) + \frac{\Delta_n}{2} (c^\dagger_{n+1} c_n - \mathrm{h.c.}) \right], where tn,n+1t_{n,n+1} is the hopping integral between sites nn and n+1n+1, Δn\Delta_n represents the dimerization gap arising from bond alternation, cn†c^\dagger_n (cnc_n) creates (annihilates) an electron at site nn, and h.c. denotes the Hermitian conjugate. The parameter tt is typically around 2.5 eV, reflecting the strength of π-electron overlap, while Δ\Delta quantifies the energy gap opened by lattice dimerization. This formulation allows for the inclusion of phonon modes through the dependence of tn,n+1t_{n,n+1} on atomic displacements, enabling the study of dynamic lattice effects on the band structure. The model elucidates the Peierls instability in one-dimensional systems, where electron-phonon interactions drive a spontaneous lattice distortion, leading to bond alternation that doubles the unit cell and opens a bandgap of approximately 1.5 eV in undoped trans-polyacetylene, converting a hypothetical metallic state into a . This instability results in two degenerate ground states with alternating bond lengths, and excitations such as solitons—topological defects that serve as domain walls between these states—act as the primary charge carriers upon doping. Neutral solitons carry , while charged solitons carry charge ±e, with a spatial extent of about 14 carbon atoms, allowing for efficient transport without strong scattering. The SSH model predicts the formation of mid-gap electronic states associated with these solitons, lying at the center of the bandgap and enabling optical transitions and spin . These predictions were experimentally verified through optical , which revealed subgap absorption features around 0.7-1.0 eV in doped samples, attributed to transitions involving soliton states. Additionally, measurements of in trans-polyacetylene confirmed the presence of spin-1/2 neutral solitons, with susceptibility values aligning quantitatively with the model's estimate of soliton density.

Later Research on Organic Electronics

Following his Nobel recognition, Heeger's research shifted toward practical device applications of semiconducting polymers, particularly in for flexible and low-cost technologies. At the (UCSB), he led efforts to integrate these materials into functional devices, building on their semiconducting properties to enable innovations in and . A major focus was the development of bulk heterojunction (BHJ) solar cells using blends of conjugated polymers and fullerenes, such as poly(3-hexylthiophene) (P3HT) with [6,6]-phenyl-C61-butyric acid methyl ester (PCBM), to create nanoscale interpenetrating networks that facilitate efficient dissociation and charge transport. In a seminal 2006 study, Heeger and collaborators outlined design rules for donor polymers to optimize and fill factor, projecting pathways to 10% power conversion efficiency (PCE) by tailoring bandgap and ionization potential. By 2010, these BHJ devices had achieved PCEs exceeding 8%, with Heeger's group demonstrating further enhancements through morphology control via processing additives, approaching the 10% threshold and highlighting the potential for lightweight, roll-to-roll fabricated plastic solar cells. Heeger also advanced polymer light-emitting diodes (PLEDs) and organic field-effect transistors (OFETs) for , emphasizing improved charge injection and mobility. For PLEDs, his post-2000 work included incorporating conjugated polyelectrolytes as injection layers, which reduced turn-on voltage and boosted external quantum efficiency to over 5% in devices with emissive s like polyfluorene derivatives. In OFETs, Heeger's UCSB team developed high-mobility devices using aligned semiconducting s, achieving field-effect mobilities above 0.1 cm²/V·s through electrolyte gating that induced insulator-to-metal transitions, enabling applications in flexible displays and sensors. These efforts extended to exploring topological aspects in , where gate-induced transitions in channels revealed behaviors akin to topological insulators, providing insights into robust edge-state conduction for next-generation electronics. At UCSB's Center for Polymers and Organic Solids, Heeger's research yielded patents on inkjet-printable polymer formulations, such as soluble conjugated polymers for direct deposition in thin-film devices, facilitating scalable patterning without processing. For instance, US Patent 6,300,612 described compositions amenable to techniques for image sensors and diodes. Complementing this, Heeger's involvement with Konarka Technologies, co-founded in 2001, addressed key challenges in plastic solar cells, including stability through encapsulation methods that extended operational lifetimes to over 3 years under accelerated testing and scalability via roll-to-roll production of BHJ modules up to 1 m². These advancements underscored the transition from lab prototypes to industrially viable , with Konarka's efforts demonstrating PCEs above 5% in large-area flexible panels.

Awards and Honors

Pre-Nobel Recognitions

In 1968, Heeger was elected a Fellow of the in recognition of his early contributions to , particularly in the study of magnetic and electronic properties of materials. This honor marked his growing influence in during his tenure at the . Heeger's pioneering work on conducting polymers earned him the Oliver E. Buckley Condensed Matter Physics Prize from the in 1983, awarded for "seminal contributions to the understanding of the electronic properties of conducting polymers." The prize highlighted his role in demonstrating that doped exhibits metallic conductivity, a breakthrough that bridged physics and . In 1989, Heeger received the John Scott Award from the City of for his innovations in synthetic metals, underscoring the practical implications of his research on electronically conducting polymers developed at the . The for the Science of New Non-Biological Materials was bestowed upon Heeger in 1995 by the International Balzan Foundation, honoring his "outstanding contributions to the science of materials and especially for his discovery of conducting polymers." This $300,000 award emphasized the revolutionary potential of these polymers for electronic devices, reflecting advancements made during his time at the . In 1996, Heeger was awarded an honorary Doctor of Technology by the University of Linköping in , acknowledging his leadership in polymer electronics research.

Nobel Prize in Chemistry

On October 10, 2000, the Royal Swedish Academy of Sciences awarded the jointly to Alan J. Heeger, Alan G. MacDiarmid, and Hideki Shirakawa "for the discovery and development of conductive polymers." This recognition honored their pioneering work in the late 1970s, which demonstrated that common plastics could be rendered electrically conductive through chemical doping, transforming insulators into materials rivaling metals in conductivity. The prize citation emphasized the profound implications of this breakthrough, noting how conductive polymers opened doors to innovative technologies, including light-emitting diodes for displays, solar cells, , and . By enabling the integration of electronic functionality into lightweight, processable plastics, their discovery bridged chemistry and physics, fostering advancements in molecular electronics and . Heeger presented his Nobel Lecture, titled "Semiconducting and Metallic Polymers: The Fourth Generation of Polymeric Materials," on December 8, 2000, at , where he outlined the evolution of these materials from insulators to versatile semiconductors and metals. The award elevated public awareness of , validating decades of interdisciplinary research and highlighting its commercial viability for applications like efficient displays and sensors.

Personal Life and Legacy

Family and Personal Interests

Heeger married his high school sweetheart, Ruth, and the couple has enjoyed a partnership spanning over six decades. They have two sons who followed scientific careers: David Heeger, a and at specializing in human vision and brain function, and Peter Heeger, an immunologist, physician, and of medicine at , director of the Transplant Immunology Program. The family includes four grandchildren. In his personal life, Heeger and Ruth share a love for theater, frequently attending productions in Santa Barbara and on Broadway, such as In the Heights and West Side Story. Heeger himself appeared in the Ensemble Theater Company's 2010 staging of Copenhagen, portraying physicist Niels Bohr alongside fellow Nobel laureate David Gross. Additionally, Heeger has recounted enjoying hikes in California's natural landscapes, including areas around Lake Tahoe, reflecting his appreciation for outdoor activities. Heeger chronicled his life experiences, from his Iowa roots to his Nobel Prize, in his 2015 autobiography Never Lose Your Nerve!, published by World Scientific Publishing Company. Through mentoring young researchers and supporting initiatives like the Dr. Alan J. Heeger Fellowships at UC Santa Barbara's Materials Research Laboratory, which fund conference travel for graduate students and postdocs, Heeger has contributed to science education programs.

Impact on Science and Industry

Alan J. Heeger's pioneering work in conductive polymers has resulted in over 50 patents, many of which have been instrumental in the development of commercial products such as organic light-emitting diode () displays and solar panels integrated into . These patents, including innovations in semiconducting polymer heterojunctions for photovoltaic devices, have enabled scalable manufacturing techniques that enhance efficiency and flexibility in electronic components. For instance, his contributions to bulk heterojunction solar cells have been adopted in flexible photovoltaic applications, powering portable devices and contributing to the growth of the renewable energy sector. Heeger's research has profoundly inspired global efforts in , with his publications garnering over 287,000 citations, reflecting the broad adoption of his concepts in and beyond. This influence has established as a distinct interdisciplinary field, bridging physics, chemistry, and engineering to enable lightweight, bendable devices for applications ranging from to large-area displays. His foundational discoveries have shaped research trajectories worldwide, fostering innovations in printable electronics that prioritize and cost-effectiveness over traditional silicon-based alternatives. Through his role in commercializing these technologies, Heeger has directly influenced major corporations, including — which acquired his startup Uniax in 2000 to advance polymer-based electronics—and , which has incorporated organic semiconductor principles in its OLED television and smartphone displays. During his tenure at the , he co-founded companies like Uniax and Konarka Technologies, which focused on translating academic breakthroughs into viable industry solutions for displays and solar energy harvesting. Heeger's enduring legacy is evident in ongoing initiatives, such as the planned 90th birthday at UCSB on January 29, 2026, which will celebrate his contributions and underscore his continued mentorship of emerging scientists in . This event highlights how his work continues to guide the next generation toward practical advancements in sustainable technologies.

References

  1. https://www.nobelprize.org/prizes/chemistry/2000/press-release/
  2. https://www.nobelprize.org/prizes/chemistry/2000/heeger/biographical/
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  6. https://www.sciencehistory.org/education/scientific-biographies/alan-g-macdiarmid-alan-j-heeger-and-hideki-shirakawa/
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  28. https://heeger.cnsi.ucsb.edu/publications
  29. https://pubs.aip.org/aip/apl/article/93/12/123304/131866/Improved-electron-injection-in-polymer-light
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  43. https://patents.google.com/patent/US5454880A/en
  44. https://ucsolar.ucmerced.edu/inventions/uc-santa-barbara/organic-photovoltaic-cells-manufacturing-and-design-improvements
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  46. https://heeger.cnsi.ucsb.edu/members/heeger
  47. https://www.cpos.ucsb.edu/events/all/2026/symposium-celebrating-nobel-laureate-alan-heegers-90th-birthday
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