Rotational molding (BrE: moulding) involves a heated mold which is filled with a charge or shot weight of the material. It is then slowly rotated (usually around two perpendicular axes), causing the softened material to disperse and stick to the walls of the mold forming a hollow part. In order to form an even thickness throughout the part, the mold rotates at all times during the heating phase, and then continues to rotate during the cooling phase to avoid sagging or deformation. The process was applied to plastics in the 1950s but in the early years was little used because it was a slow process restricted to a small number of plastics. Over time, improvements in process control and developments with plastic powders have resulted in increased use.

Rotocasting (also known as rotacasting), by comparison, uses self-curing or UV-curable resins (as opposed to thermoplastics) in an unheated mould, but shares slow rotational speeds in common with rotational molding. This kind of rotocasting should not be confused with centrifugal casting.

In 1855 a patent taken out by R. Peters in Britain documented the first use of a rotating mechanism producing "two centrifugal motions at right angles to each other" by means of beveled gearing, and heat. This rotational molding process was used to create artillery shells and other hollow vessels, the main purpose of which was to create consistency in wall thickness and density. In a U.S. patent in 1905, F.A. Voelke described a method including a polymer for the production of articles using paraffin wax. Development led to G.S. Baker's and G.W. Perks' process of producing hollow chocolate Easter eggs in 1910. Rotational molding had developed further when R.J. Powell made mention of the commonly used ratio of 4:1 between major and minor axes of rotation at slow rotation speeds. His patent covered this process for molding hollow objects from plaster of Paris in the 1920s. These early methods using different materials directed the advances in the way rotational molding is used today with plastics.

Plastics were introduced to the rotational molding process in the early 1950s. One of the first applications was to manufacture doll heads. The machinery was made of an E Blue box-oven machine, inspired by a General Motors rear axle, powered by an external electric motor and heated by floor-mounted gas burners. The mold was made of electroformed nickel-copper and the plastic was a liquid polyvinyl chloride (PVC) plastisol. The cooling method consisted of placing the mold into cold water. This process of rotational molding led to the creation of other plastic toys. As demand for and popularity of this process increased, it was used to create other products such as road cones, marine buoys, and car armrests. This popularity led to the development of larger machinery. A new system of heating was also created, going from the original direct gas jets to the current indirect high velocity air system. In Europe during the 1960s the Engel process was developed. This allowed large hollow containers to be manufactured in low-density polyethylene. The cooling method consisted of turning off the burners and allowing the plastic to harden while still rocking in the mold.

In 1976, the Association of Rotational Molders (ARM) was founded in Chicago as a worldwide trade association. The main objective of this association is to increase awareness of the rotational molding technology and process.

In the 1980s, new plastics, such as polycarbonate, polyester, and nylon, were introduced to rotational molding. This has led to new uses for this process, such as the creation of fuel tanks and industrial moldings. The research that has been done since the late 1980s at Queen's University Belfast has led to the development of more precise monitoring and control of the cooling processes based on their development of the "Rotolog system".

Rotational molding machines are made in a wide range of sizes. They normally consist of molds, an oven, a cooling chamber, and mold spindles. The spindles are mounted on a rotating axis, which provides a uniform coating of the plastic inside each mold.

Molds (or tooling) are either fabricated from welded sheet steel or cast. The fabrication method is often driven by part size and complexity; most intricate parts are likely made with cast tooling. Molds are typically manufactured from stainless steel or aluminum. Aluminum molds are usually much thicker than equivalent steel molds, as it is a softer metal. This thickness does not much affect cycle times because aluminum's thermal conductivity is many times greater than steel's. Owing to the need to develop a model prior to casting, cast molds tend to have additional costs associated with the manufacturing of the tooling, whereas fabricated steel or aluminum molds, particularly when used for less complex parts, are less expensive. However, some molds contain both aluminum and steel. This allows for variable thicknesses in the walls of the product. While this process is not as precise as injection molding, it does provide the designer with more options. The aluminum addition to the steel provides more heat capacity, causing the melt-flow to stay in a fluid state for a longer period.