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Systematic element name
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A systematic element name is the temporary name assigned to an unknown or recently synthesized chemical element. A systematic symbol is also derived from this name.
In chemistry, a transuranic element receives a permanent name and symbol only after its synthesis has been confirmed. In some cases, such as the Transfermium Wars, controversies over the formal name and symbol have been protracted and highly political. In order to discuss such elements without ambiguity, the International Union of Pure and Applied Chemistry (IUPAC) uses a set of rules, adopted in 1978, to assign a temporary systematic name and symbol to each such element. This approach to naming originated in the successful development of regular rules for the naming of organic compounds.
IUPAC rules
[edit]The temporary names derive systematically from the element's atomic number, and apply only to 101 ≤ Z ≤ 999.[1] Each digit is translated into a "numerical root" according to the table. The roots are concatenated, and the name is completed by the suffix -ium. Some of the roots are Latin and others are Greek, to avoid two digits starting with the same letter (for example, the Greek-derived pent is used instead of the Latin-derived quint to avoid confusion with quad for 4). There are two elision rules designed to prevent odd-looking names.
Traditionally the suffix -ium was used only for metals (or at least elements that were expected to be metallic), and other elements used different suffixes: halogens used -ine and noble gases used -on instead. However, the systematic names use -ium for all elements regardless of group. Thus, elements 117 and 118 were ununseptium and ununoctium, not ununseptine and ununocton.[2] This does not apply to the trivial names these elements receive once confirmed; thus, elements 117 and 118 are now tennessine and oganesson, respectively. For these trivial names, all elements receive the suffix -ium except those in group 17, which receive -ine (like the halogens), and those in group 18, which receive -on (like the noble gases).[2] (That being said, tennessine and oganesson are expected to behave quite differently from their lighter congeners.)
The systematic symbol is formed by taking the first letter of each root, converting the first to uppercase. This results in three-letter symbols instead of the one- or two-letter symbols used for named elements. The rationale is that any scheme producing two-letter symbols will have to deviate from full systematicity to avoid collisions with the symbols of the permanently named elements.
The Recommendations for the Naming of Elements of Atomic Numbers Greater than 100 can be found here.
| Digit | Root | Etymology | Symbol | Pronunciation | Example | |
|---|---|---|---|---|---|---|
| 0 | nil | Latin nihil ("zero") | n | /nɪl/ | unbinilium | |
| 1 | un | Latin unus ("one") | u | /uːn/ | unbiunium | |
| 2 | bi | Latin bis ("twice") | b | /baɪ/ | unbibium | |
| 3 | tri | Latin tres ("three") Greek tria ("three") |
t | /traɪ/ | unbitrium | |
| 4 | quad | Latin quattuor ("four") | q | /kwɒd/ | unbiquadium | |
| 5 | pent | Greek pente ("five") | p | /pɛnt/ | unbipentium | |
| 6 | hex | Greek hex ("six") | h | /hɛks/ | unbihexium | |
| 7 | sept | Latin septem ("seven") | s | /sɛpt/ | unbiseptium | |
| 8 | oct | Latin octo ("eight") Greek okto ("eight") |
o | /ɒkt/ | unbioctium | |
| 9 | en(n) | Greek ennea ("nine") | e | /ɛn/ | unbiennium | |
| Suffix | -(i)um | Latin -um (neuter singular) | none | /-iəm/ | ||
| ||||||
As of 2019[update], all 118 discovered elements have received individual permanent names and symbols.[3] Therefore, systematic names and symbols are now used only for the undiscovered elements beyond element 118, oganesson. When such an element is discovered, it will keep its systematic name and symbol until its discovery meets the criteria of and is accepted by the IUPAC/IUPAP Joint Working Party, upon which the discoverers are invited to propose a permanent name and symbol. Once this name and symbol is proposed, there is still a comment period before they become official and replace the systematic name and symbol.
At the time the systematic names were recommended (1978), names had already been officially given to all elements up to atomic number 103, lawrencium. While systematic names were given for elements 101 (mendelevium), 102 (nobelium), and 103 (lawrencium), these were only as "minor alternatives to the trivial names already approved by IUPAC".[1] The following elements for some time only had systematic names as approved names, until their final replacement with trivial names after their discoveries were accepted.
| Z | Systematic | Formal | Year | |||
|---|---|---|---|---|---|---|
| Symbol | Name | Symbol | Name | Undisputed synthesis first published | Named | |
| 104 | Unq | Unnilquadium | Rf | Rutherfordium | 1969 | 1997 |
| 105 | Unp | Unnilpentium | Db | Dubnium | 1970 | 1997 |
| 106 | Unh | Unnilhexium | Sg | Seaborgium | 1974 | 1997 |
| 107 | Uns | Unnilseptium | Bh | Bohrium | 1981 | 1997 |
| 108 | Uno | Unniloctium | Hs | Hassium | 1984 | 1997 |
| 109 | Une | Unnilennium | Mt | Meitnerium | 1982 | 1997 |
| 110 | Uun | Ununnilium | Ds | Darmstadtium | 1995 | 2003 |
| 111 | Uuu | Unununium | Rg | Roentgenium | 1995 | 2004 |
| 112 | Uub | Ununbium | Cn | Copernicium | 1996 | 2010 |
| 113 | Uut | Ununtrium | Nh | Nihonium | 2004 | 2016 |
| 114 | Uuq | Ununquadium | Fl | Flerovium | 1999 | 2012 |
| 115 | Uup | Ununpentium | Mc | Moscovium | 2004 | 2016 |
| 116 | Uuh | Ununhexium | Lv | Livermorium | 2000 | 2012 |
| 117 | Uus | Ununseptium | Ts | Tennessine | 2010 | 2016 |
| 118 | Uuo | Ununoctium | Og | Oganesson | 2006 | 2016 |
See also
[edit]- Mendeleev's predicted elements – a much earlier (1869) system of naming undiscovered elements
References
[edit]- ^ a b "Element names >100".
- ^ a b Koppenol, W. (2016). "How to name new chemical elements" (PDF). Pure and Applied Chemistry. DeGruyter. doi:10.1515/pac-2015-0802. hdl:10045/55935. S2CID 102245448.
- ^ "IUPAC Announces the Names of the Elements 113, 115, 117, and 118". IUPAC. 2016-11-30. Retrieved 2016-11-30.
External links
[edit]- IUPAC Provisional Recommendations: IR-3: Elements and Groups of Elements (PDF) (Report). IUPAC. March 2004.
Systematic element name
View on GrokipediaDefinition and Purpose
Core Concept and Rationale
The systematic element name functions as a provisional placeholder for chemical elements, constructed strictly from the atomic number via a sequence of Latin and Greek roots representing each digit (such as "nil-" for 0 and "un-" for 1), terminated by the suffix "-ium" to yield a neutral, number-derived identifier like "unnilquadium" for atomic number 104. This nomenclature ensures referential clarity in scientific communication for elements whose existence or properties remain under verification, avoiding reliance on disputed syntheses or honorific proposals. The core rationale lies in upholding empirical rigor by deferring permanent naming until independent replication confirms the causal chain of discovery, thereby mitigating risks of premature endorsement that could conflate institutional claims with objective evidence. In superheavy element synthesis, where detection often hinges on fleeting decay signatures rather than bulk properties, multiple laboratories may assert priority, as evidenced by historical rivalries in transuranic production; systematic names sidestep these by enforcing a data-driven hierarchy over prestige-based adjudication. This framework aligns with principles of causal realism in nomenclature, privileging reproducible atomic number assignment—grounded in spectroscopic or genetic lineage data—over narrative-driven attributions, thus fostering consensus in a field prone to geopolitical contention.Distinction from Permanent Names
Systematic element names function as provisional designations derived algorithmically from an element's atomic number, employing Latin and Greek numerical roots (e.g., un- for one, bi- for two) combined with the suffix -ium, to provide a neutral, objective reference prior to formal approval.[6] These names eschew any cultural, historical, or personal connotations, grounding identification strictly in the sequential atomic property verified through synthesis and decay chain analysis. Permanent names, by contrast, adhere to IUPAC criteria permitting derivations from mythological figures, astronomical objects, minerals, properties, places of discovery, or scientists' contributions, but only after multiple independent confirmations of the element's production, typically spanning years of experimental validation.[6] For instance, element 116 transitioned from the systematic ununhexium (reflecting atomic number 116 as "one-one-six-ium") to livermorium, honoring the Lawrence Livermore National Laboratory where key syntheses occurred, following IUPAC ratification on May 31, 2012.[7] Similarly, element 118 shifted from ununoctium to oganesson on November 28, 2016, recognizing physicist Yuri Oganessian's role in superheavy element research.[7] This bifurcation enforces causal prioritization in nomenclature: systematic names anchor discourse to verifiable atomic sequencing and empirical properties during uncertainty, circumventing disputes over subjective attributions that could arise from unconfirmed claims, as seen in historical rivalries over transuranic discoveries.[8] Permanent naming introduces interpretive flexibility only post-confirmation, aligning with the physical reality of stable isotope production rather than provisional hypotheses.Historical Development
Early Naming Challenges in Transuranic Elements
The discovery of neptunium (element 93) in 1940 by Edwin McMillan and Philip Abelson at the University of California, Berkeley, through neutron irradiation of uranium-238, led to its naming after the planet Neptune to continue the celestial theme from uranium.[9] Plutonium (element 94), synthesized shortly thereafter in late 1940 by Glenn Seaborg and colleagues via deuteron bombardment of uranium-238, was similarly named after Pluto in 1941, reflecting institutional priorities at Berkeley's radiation laboratory rather than a standardized process.[10] These early transuranic elements received names tied to discoverers' locations and mythological extensions, but without international verification protocols, setting a precedent for later conflicts where synthesis claims lacked independent replication. Tensions escalated in the 1960s with element 104, as Soviet physicists at the Joint Institute for Nuclear Research in Dubna claimed its synthesis in 1964 through calcium-48 bombardment of plutonium-242 and proposed the name kurchatovium (Ku) after Soviet nuclear pioneer Igor Kurchatov.[11] American researchers at Berkeley contested this in 1969, reporting their own production via carbon-12 and carbon-13 ions on californium-249 and advocating rutherfordium (Rf) in honor of Ernest Rutherford, highlighting discrepancies in experimental data and isotopic identification that undermined mutual acceptance.[12] Such nationalistic naming, often preceding conclusive evidence of reproducible decay chains, prioritized institutional narratives over empirical confirmation, eroding trust in journals and fostering prolonged disputes. The ensuing Transfermium Wars, spanning the 1960s to 1990s, intensified over elements 104 through 106, with rival U.S. and Soviet teams advancing unverified priority claims amid Cold War rivalry, resulting in parallel publications and rejected nomenclature proposals that delayed unified periodic table assignments.[13] For instance, element 105 saw Berkeley's hahnium contested by Dubna's nielsbohrium, while element 106 proposals further entangled personal and national honors without resolving synthesis ambiguities. These ad hoc practices exposed a deficit in causal rigor, as names were affixed to preliminary detections rather than cross-verified production methods, prompting international skepticism and the eventual push for neutral, data-driven alternatives to avert diplomatic stalemates in atomic research.[13]IUPAC Formalization in the 1970s
In the early 1970s, disputes over the discovery and naming of transuranic elements, particularly element 104 synthesized independently by American and Soviet teams in 1964–1969, highlighted the need for an objective interim nomenclature to avoid endorsing unverified claims of priority. The IUPAC Commission on the Nomenclature of Inorganic Chemistry, chaired by J. Chatt, initiated work on systematic naming procedures to prioritize the atomic number as the defining identifier, decoupling nomenclature from contested historical attributions and enabling empirical discussion in scientific literature.[14] Between 1971 and 1978, the commission formulated rules for elements with atomic numbers greater than 100, drawing on the Mendeleev-era principle that atomic number governs elemental identity while extending it to provisional placeholders for undiscovered or unconfirmed species.[3] These guidelines specified derivation from Latin numerical roots followed by the suffix "-ium," ensuring neutrality and universality without implying permanence.[14] The recommendations were officially approved in 1978 and published in 1979, marking the first standardized application to higher transuranics and facilitating their reference in publications pending rigorous verification of syntheses.[14] This approach underscored causal realism by grounding identification in verifiable atomic properties rather than provisional discoverer preferences, thereby mitigating barriers to consensus in an era of accelerating superheavy element research.Construction Rules
Numerical Prefix System
The numerical prefix system in systematic element nomenclature encodes each digit of the atomic number using a specific root derived from classical Latin and Greek numerical terms, ensuring a precise, unambiguous, and internationally neutral representation. This mapping applies to digits 0 through 9 as follows:| Digit | Root |
|---|---|
| 0 | nil |
| 1 | un |
| 2 | bi |
| 3 | tri |
| 4 | quad |
| 5 | pent |
| 6 | hex |
| 7 | sept |
| 8 | oct |
| 9 | enn |
Name Assembly and Grammatical Rules
The systematic element name is constructed by sequentially concatenating the numerical root prefixes for the hundreds, tens, and units digits of the atomic number—in that descending order—directly without hyphens, spaces, or other separators, followed by the suffix "-ium". To ensure phonetic smoothness, elision rules eliminate redundancy: the terminal "n" in "enn" (denoting 9) is omitted before "nil" (denoting 0), and the terminal "i" in "bi" (2) or "tri" (3) is omitted before "-ium". These assembly procedures enforce a standardized, unambiguous format that prioritizes direct derivation from the atomic number over linguistic aesthetics or national conventions, as codified in IUPAC recommendations approved in 1978 and published in Pure and Applied Chemistry in 1979.[1][15] This concatenation method, distinct from symbol formation (which uses initial letters of each root without hyphens), supports precise empirical referencing in international scientific communication by yielding unique, numerically explicit names that minimize interpretive errors in data reporting and chemical notation.[1] Grammatical rules mandate singular form for all systematic names, enabling seamless incorporation into chemical formulas, compounds, and reactions without pluralization or case adjustments that could introduce variability. The invariant "-ium" termination draws from Latin neuter noun conventions prevalent in classical element nomenclature, promoting uniformity across inflected languages and averting disputes over gender agreement (e.g., masculine in some Romance languages, neuter in others for traditional elements), thereby facilitating causal analysis and empirical consistency in global research.[15][1]Symbol Derivation
The symbols for systematic element names are formed by selecting the initial letter of each numerical root prefix in the constructed name, excluding the terminal "-ium" suffix, to yield a three-letter code: the first letter is uppercase, and the following letters are lowercase. For example, the name ununnilium for atomic number 110 produces the symbol Uun, from 'U' (un-), 'u' (un-), and 'n' (nil-). This derivation directly reflects the atomic number's decimal representation, as the prefixes encode its digits (0 as nil-, 1 as un-, etc.), ensuring visual and structural alignment between name, symbol, and position in the periodic table.[1][3] Limited to three letters, these symbols provide a compact notation suitable for scientific use in chemical equations, reaction schemes, and periodic table representations, where space efficiency is essential. Unlike the one- or two-letter symbols of established elements, the three-letter format signals the provisional nature of the designation, reducing risks of misidentification in publications on superheavy element synthesis.[1] This algorithmic approach, rooted in the atomic number rather than eponyms or descriptive terms, facilitates precise referencing in empirical studies of nuclear reactions and predicted properties, enabling researchers to analyze causal relationships—such as stability trends or synthesis yields—without ambiguity from subjective naming influences.[3][1]Applications and Examples
Systematic Names for Elements 104–118
Element 104, first synthesized in 1969 at the Joint Institute for Nuclear Research (JINR) and Lawrence Berkeley National Laboratory but subject to competing claims, utilized the systematic name unnilquadium (Unq) in scientific literature during verification efforts in the 1970s and 1980s, including theoretical calculations of its ionization potentials and atomic radii.[16][1] This placeholder facilitated neutral reference amid the Transfermium Wars until IUPAC approved rutherfordium (Rf) on August 1, 1997, honoring physicist Ernest Rutherford.[17] Elements 105 through 109 followed similar patterns, employing systematic designations like unnilpentium (Unp) for 105 until their 1997 naming as dubnium (Db), seaborgium (Sg), bohrium (Bh), hassium (Hs), and meitnerium (Mt), respectively, resolving disputes between American and Soviet teams.[1] Subsequent elements synthesized primarily at the Gesellschaft für Schwerionenforschung (GSI) in Germany retained systematic names longer due to phased verifications. Element 110, confirmed in 2000, was unununium (Unu) before becoming darmstadtium (Ds) in 2003; element 111 transitioned from ununnilium (Une) to roentgenium (Rg) in 2004; and element 112, synthesized in 1996 at GSI, used ununbium (Uub) in publications through the 2000s until named copernicium (Cn) in 2010, commemorating Nicolaus Copernicus.[18][1] Element 114, produced via fusion at JINR in 1999, employed ununquadium (Uuq) during collaborative confirmation with Lawrence Livermore National Laboratory before IUPAC endorsement of flerovium (Fl) in 2012, named after the Flerov Laboratory.[19][20] Heavier elements 113, 115, 116, 117, and 118, synthesized through international efforts at RIKEN (Japan), JINR, Oak Ridge National Laboratory (USA), and Lawrence Livermore, relied on systematic nomenclature such as ununtrium (Uut) for 113 and ununoctium (Uuo) for 118 in experimental reports from the 2000s to mid-2010s, aiding cross-verification of decay chains amid rarity of production.[21][1] These transitioned en masse in 2016 to nihonium (Nh) for 113 (RIKEN discovery), moscovium (Mc) and oganesson (Og) for 115 and 118 (JINR-led), livermorium (Lv) for 116 (Joint JINR-Livermore, named 2012 alongside flerovium), and tennessine (Ts) for 117 (Oak Ridge-JINR collaboration).[17][20] The systematic phase for these elements underscored their provisional status during multi-lab reproductions essential for IUPAC consensus.[22]| Atomic Number | Systematic Name (Symbol) | Permanent Name (Symbol) | Naming Year |
|---|---|---|---|
| 104 | Unnilquadium (Unq) | Rutherfordium (Rf) | 1997 |
| 105 | Unnilpentium (Unp) | Dubnium (Db) | 1997 |
| 106 | Unnilhexium (Unh) | Seaborgium (Sg) | 1997 |
| 107 | Unnilseptium (Uns) | Bohrium (Bh) | 1997 |
| 108 | Unniloctium (Uno) | Hassium (Hs) | 1997 |
| 109 | Unnilennium (Une) | Meitnerium (Mt) | 1997 |
| 110 | Ununnilium (Unu) | Darmstadtium (Ds) | 2003 |
| 111 | Unununium (Uuu) | Roentgenium (Rg) | 2004 |
| 112 | Ununbium (Uub) | Copernicium (Cn) | 2010 |
| 113 | Ununtrium (Uut) | Nihonium (Nh) | 2016 |
| 114 | Ununquadium (Uuq) | Flerovium (Fl) | 2012 |
| 115 | Ununpentium (Uup) | Moscovium (Mc) | 2016 |
| 116 | Ununhexium (Uuh) | Livermorium (Lv) | 2012 |
| 117 | Ununseptium (Uus) | Tennessine (Ts) | 2016 |
| 118 | Ununoctium (Uuo) | Oganesson (Og) | 2016 |

