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Lamprophyre
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Lamprophyres (from Ancient Greek λαμπρός (lamprós) 'bright' and φύρω (phúrō) 'to mix') are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium.
Lamprophyres occur throughout all geologic eras. Archaean examples are commonly associated with lode gold deposits. Cenozoic examples include magnesian rocks in Mexico and South America, and young ultramafic lamprophyres from Gympie in Australia with 18.5% MgO at ~250 Ma.
Petrology
[edit]Modern science treats lamprophyres as a catch-all term for ultrapotassic mafic igneous rocks which have primary mineralogy consisting of amphibole or biotite, and with feldspar in the groundmass.
Lamprophyres are not amenable to classification according to modal proportions, such as the system QAPF, because of their peculiar mineralogy, nor compositional discrimination diagrams, such as TAS, because of their peculiar geochemistry. They are classified under the IUGS Nomenclature for Igneous Rocks (Le Maitre et al., 1989) separately; this is primarily because they are rare, have peculiar mineralogy and do not fit classical classification schemes. For example, the TAS scheme is inappropriate due to the control of mineralogy by potassium, not by calcium or sodium.
Mitchell[1] has suggested that rocks belonging to the "lamprophyre facies" are characterized by the presence of phenocrysts of mica and/or amphibole together with lesser clinopyroxene and/or melilite set in a groundmass which may consist (either singly or in various combinations) of plagioclase, alkali feldspar, feldspathoids, carbonate, monticellite, melilite, mica, amphibole, pyroxene, perovskite, Fe-Ti oxides and glass.
Classification schemes which include genetic information may be required to properly describe lamprophyres (Tappe et al., 2005).
Genesis
[edit]Rock[2] considered lamprophyres to be part of a "clan" of rocks, with similar mineralogy, textures and genesis. Lamprophyres are similar to lamproites and kimberlites. While modern concepts see orangeites, lamproites and kimberlites as separate, a vast majority of lamprophyres have similar origins to these other rock types (Tappe et al., 2005).
Mitchell considered the lamprophyres as a "facies" of igneous rocks created by a set of conditions (generally; late, highly volatile differentiates of other rock types). Either scheme may apply to some, but not all, occurrences and variations of the broader group of rocks known as lamprophyres and melilitic rocks.
Leaving aside complex petrogenetic arguments, the essential components in lamprophyre genesis are:
- high depth of melting, which yields more mafic magmas;
- low degrees of partial melting, which yields magmas rich in the alkalis (particularly potassium);
- lithophile element (K, Ba, Cs, Rb) enrichment, high Ni and Cr,
- high potassium and sodium concentrations (silica undersaturation is common)
- some form of volatile enrichment, to provide the biotite (phlogopite) and amphibole (pargasite) mineralogy
- lack of fractional crystallisation (generally; there are exceptions)
- high Mg# (MgO/(FeO + MgO))
Individual examples thus may have a wide variety of mineralogy and mechanisms for formation. Rock considered lamprophyres to be derived from deep, volatile-driven melting in a subduction zone setting. Others such as Mitchell consider them to be late offshoots of plutons, etc., though this can be difficult to reconcile with their primitive melt chemistry and mineralogy.
Petrography
[edit]
Lamprophyres are a group of rocks containing phenocrysts, usually of biotite and amphibole (with bright cleavage surfaces), and pyroxene, but not of feldspar. They are thus distinguished from the porphyries and porphyrites in which the feldspar has crystallized in two generations. They are essentially dike rocks, occurring as dikes and thin sills, and are also found as marginal facies of plutonic intrusions. They are usually dark in color, owing to the abundance of ferro-magnesian silicates, of high specific gravity and liable to decomposition. For these reasons they have been defined as a melanocrate series (rich in the dark minerals); and they are often accompanied by a complementary leucocrate series (rich in the white minerals feldspar and quartz) such as aplites, porphyries and felsites.[1]
Biotite (usually phlogopite) and amphibole (usually pargasite or other magnesian hornblende) are panidiomorphic; all are euhedral, well formed. Feldspar is restricted to the ground mass. In many lamprophyres the pale quartz and felspathic ingredients tend to occur in rounded spots, or ocelli, in which there has been progressive crystallization from the margins towards the center. These spots may consist of radiate or brush-like feldspars (with some phlogopite and hornblende) or of quartz and feldspar. A central area of quartz or of analcite probably represents an original miarolitic cavity infilled at a later period.[1]
The presence or absence of the four dominant minerals, orthoclase, plagioclase, biotite and hornblende, determines the species:[2]
- Minette contains biotite and orthoclase.[3]
- Kersantite contains biotite and plagioclase.
- Vogesite contains hornblende and orthoclase.
- Spessartite contains hornblende and plagioclase.
- Monchiquite contains no feldspar, has a glassy or feldspathoid-bearing groundmass, and contains amphibole phenocrysts.
Each variety of lamprophyre may and often does contain all four minerals but is named according to the two which predominate.[1]
These rocks contain also iron oxides (usually titaniferous), apatite, sometimes sphene, augite, and olivine. The hornblende and biotite are brown or greenish-brown, and as a rule their crystals even when small are very perfect and give the thin section views an easily recognizable character. Green hornblende occurs in some of these rocks. Augite exists as euhedral crystals of pale green color, often zonal and readily weathering. Olivine in the fresh state is rare; it forms rounded, corroded grains; in many cases it is decomposed to green or colorless hornblende in radiating nests (pilite). The plagioclase occurs as small rectangular crystals; orthoclase may have similar shapes or may be fibrous and grouped in sheaf-like aggregates that are narrow in the middle and spread out towards both ends. As all lamprophyres are prone to alteration by weathering a great abundance of secondary minerals is usually found in them; the principal are calcite and other carbonates, limonite, chlorite, quartz and kaolin.[1]
Ocellar structure is common; the ocelli consist mainly of orthoclase and quartz, and may be up to one quarter of an inch in diameter. Another feature of these rocks is the presence of large foreign crystals, or xenocrysts, of feldspar and of quartz. Their forms are rounded, indicating partial resorption and the quartz may be surrounded by corrosion borders of minerals such as augite and hornblende produced where the magma is attacking the crystal.[1]
Lamprophyres (including minette) traditionally have been defined as:[4]
- normally occurring as porphyritic dikes
- containing matrix restricted feldspars and/or feldspathoids if present
- biotite or phlogopite is an essential mineral phase
- commonly extensively hydrothermally altered
- may contain primary calcite, zeolites and other more typically hydrothermal minerals
- higher than normal contents of K2O and/or Na2O, H2O, CO2, S, P2O5, and Ba
On a purely chemical basis, an extrusive lamprophyre (sp. minette) might be classified as potassic trachybasalt, shoshonite, or latite using the total alkali-silica diagram (see TAS classification), or as absarokite, shoshonite, or banakite using a classification sometimes applied to potassium-rich lavas. Such chemical classifications ignore the distinctive textures and mineralogies of lamprophyres.
Nomenclature
[edit]The naming and classification of lamprophyres has had several revisions, and much argument within the geological community. Nicholas Rock and colleagues devoted much time to a complicated descriptive system of nomenclature which took after a series of nomenclature based on regional examples of the very diverse mineralogical expression of lamprophyres. This system was based on a somewhat provincial, rustic system of naming after French villages nearby were found the first described examples of various species of lamprophyre (Vosges being the prime example).
Modern nomenclature has been derived from an attempt to constrain some genetic parameters of lamprophyre genesis.[5] This has, by and large, dispensed with the previous provincial names of lamprophyre species, in favor of a mineralogical name. The old names are still used for convenience.
Vogesite
[edit]Vogesite was first described from the Vosges mountains, France, where rocks of this type (actually, minette) were described in the early 20th century.
Minette
[edit]
A historical view of minette was provided by Johannsen (1937). He wrote that the name was " ... used by the miners in the Vosges apparently for oolitic or granular iron ore, and possibly derived from the valley of Minkette, where it occurs...."
Examples include minettes in the Navajo Volcanic Field (e.g. dikes near Shiprock and Mitten Rock, NM) of the Colorado Plateau[6] and in the Mexican Volcanic Belt.[7]
Kersantite
[edit]Kersantite is named after the village of Kersanton, Brittany, France, where the rock was first identified. An obsolete name for kersantite is kersanton.[8]
Distribution
[edit]Lamprophyres are usually associated with voluminous granodiorite intrusive episodes.[9] They occur as marginal facies to some granites, though usually as dikes and sills marginal to and crosscutting the granites and diorites.[10] In other districts where granites are abundant no rocks of this class are known. It is rare to find only one member of the group present, but minettes, vogesites, kersantites, etc., all appear and there are usually transitional forms.[1]
Lamprophyres are also known to be spatially and temporally associated with gold mineralisation, for example orogenic gold deposits.[11] Rock (1991) considered lamprophyres to be possible source rocks for the gold,[9] but this view is not generally supported. The more reasonable explanation for the correlation is that lamprophyres, representing "wet" melts of the asthenosphere and mantle, correlate with a period of high fluid flow from the mantle through the crust, during subduction-related metamorphism, which drives gold mineralisation.[12]
Non-melilitic lamprophyres are found in many districts where granites and diorites occur, such as the Scottish Highlands and Southern Uplands of Scotland;[13][14] the Lake District of northwest England; Ireland; the Vosges Mountains of France; the Black Forest and Harz mountain regions of Germany; Mascota, Mexico; Jamaica[10] and in certain locations of British Columbia, Canada.[15]
References
[edit]- ^ a b c d e f Flett 1911, p. 135.
- ^ Le Bas, M. J.; Streckeisen, A. L. (1991). "The IUGS systematics of igneous rocks". Journal of the Geological Society. 148 (5): 825–833. Bibcode:1991JGSoc.148..825L. CiteSeerX 10.1.1.692.4446. doi:10.1144/gsjgs.148.5.0825. S2CID 28548230.
- ^ Johannsen, A., 1937, A Descriptive Petrography of the Igneous Rocks: Volume III, The Intermediate Rocks. University of Chicago Press, Chicago, Illinois
- ^ Le Maitre, R. W., editor, 2002, Igneous Rocks: A Classification and Glossary of Terms. Recommendations of the International Union of Geological Sciences, Subcommission of the Systematics of Igneous Rocks. Cambridge University Press.
- ^ Mitchell, R.H., 1994b. Suggestions for revisions to the terminology of kimberlites and lamprophyres from a genetic viewpoint. In Proc. Fifth Int. Kimberlite Conf. 1. Kimberlites and Related Rocks and Mantle Xenoliths (H.O.A. Meyer & O.H. Leonardos, eds.). Companhia de Pesquisa de Recursos Minerais (Brasilia), Spec. Publ. 1/A, 15-26.
- ^ Roden, M. F. and Smith, D., 1979, Field geology, chemistry, and petrology of Buell Park minette diatreme, Apache County, Arizona: In Kimberlites, Diatremes, and Diamonds: Their Geology, Petrology, and Geochemistry, Boyd, F. R., and Meyer, H. O. A., eds., American Geophysical Union: Proceedings of the Second International Kimberlite Conference, v 1, pp. 364–381.
- ^ Wallace, P., and Carmichael, I. S. E., 1989, Minette lavas and associated leucitites from the Western Front of the Mexican Volcanic Belt: petrology, chemistry, and origin. Contributions to Mineralogy and Petrology, v 103, pp. 470–492.
- ^ Le Maitre, R. W., ed. (13 January 2005). Igneous Rocks: A Classification and Glossary of Terms. Cambridge University Press. p. 97. ISBN 9780521662154. Retrieved 7 October 2020.
- ^ a b Rock, N.M.S., 1991, Lamprophyres, Blackie, Glasgow, UK ISBN 978-0442303969
- ^ a b Jackson, T. A., Lewis, J. F., Scot, P. W., Manning, P. A. S., 1998, The Petrology of Lamprophyre Dykes in the Above Rocks Granitoid, Jamaica: Evidence of rifting above a subduction zone during the early Tertiary. Caribbean Journal of Science, volume 34, no. 1-2, pp. 1-11, 1998.
- ^ Müller D., Groves D.I. (2019) Potassic igneous rocks and associated gold-copper mineralization (5th edition). Mineral Resource Reviews. Springer-Verlag Heidelberg, 398 pp
- ^ Kenworthy, Shane; Hagemann, Steffen G. (2005). Mineral Deposit Research: Meeting the Global Challenge. Springer, Berlin, Heidelberg. pp. 987–990. doi:10.1007/3-540-27946-6_252. ISBN 978-3540279464.
- ^ Thorpe R.S., Gaskarth J.W. & Henney P.J., 1993. Composite Ordovician lamprophyre (spessartite) intrusions around the Midlands Microcraton in central Britain. Geological Magazine, volume 130, pp. 657-663, 1993.
- ^ Rock, N.M.S, Gaskarth J.W., Rundle C.C., 1986. Late Caledonian dyke-swarms in southern Scotland: A regional zone of primitive K-rich Lamprophyres and associated vents. Journal of Geology, volume 94, pp. 505-522, 1986.
- ^ Adams , M., Lentz, D.R., Shaw, C., Williams, P., Archibald, D.A., Cousens, B., 2005. Eocene Lamprophyre Dykes intruding the Monashee Complex, B.C.: Petrochemical to Petrogenetic Relationships with the Kamloops Group Volcanic Sequence. Canadian Journal of Earth Sciences, v. 42, p. 11-24.
- This article incorporates text from a publication now in the public domain: Flett, John Smith (1911). "Lamprophyres". In Chisholm, Hugh (ed.). Encyclopædia Britannica. Vol. 16 (11th ed.). Cambridge University Press. pp. 135–136.
- Tappe, S., Foley, S.F., Jenner, G.A. and Kjarsgaard, B.A., 2005. Integrating ultramafic lamprophyres into the IUGS classification of igneous rocks: Rational and implications. Journal of Petrology, 46(9): 1893-1900.
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[edit]Lamprophyre
View on GrokipediaDefinition and Characteristics
Definition
Lamprophyres are uncommon, small-volume igneous rocks, typically alkaline or ultrapotassic, ranging from mafic to ultramafic in composition. They are characterized by a porphyritic texture with mafic phenocrysts set in a fine-grained groundmass. These rocks primarily occur as small-volume intrusive bodies such as dikes, sills, stocks, and plugs.[6] They are alkaline and silica-undersaturated in nature, with characteristically high MgO contents (>3 wt%), elevated K₂O (>3 wt%), high Na₂O, and enrichments in compatible elements like Ni and Cr.[7] These rocks exhibit a panoramic temporal range spanning from the Archaean era (approximately 2.7 Ga) to recent times. Lamprophyres are distinguished from related rock types such as kimberlites and lamproites based on differences in mineralogy and geochemistry; unlike lamproites, which have low Na₂O and high K₂O/Al₂O₃ ratios, lamprophyres typically feature higher Na₂O and lower K₂O/Al₂O₃ values.[7]General Properties
Lamprophyres are characteristically dark-colored igneous rocks, ranging from black to dark green, due to their high content of mafic minerals such as biotite and amphibole. This coloration reflects their melanocratic to mesocratic nature, making them visually distinct in hand specimens. Additionally, these rocks often display a greasy luster, primarily imparted by the platy cleavage and reflective surfaces of biotite or the fibrous habit of amphibole phenocrysts.[8][2] A defining macroscopic feature of lamprophyres is their porphyritic habit, where large, euhedral to subhedral phenocrysts—typically up to 5 mm in diameter—are embedded in a fine-grained, aphanitic groundmass. This texture arises from rapid crystallization in hypabyssal environments, resulting in prominent mafic crystals contrasting against the darker matrix. Physically, lamprophyres exhibit a density of 2.8–3.2 g/cm³, a hardness of 5–6 on the Mohs scale, and variable magnetic susceptibility depending on magnetite content, often ranging from 95 to 130 × 10⁻⁶ CGS units. These properties facilitate their identification in the field or during basic petrophysical assessments.[8][9][10] Under the microscope in thin section, lamprophyres reveal distinctive optical properties that aid in their recognition. Micas and amphiboles display high birefringence, producing bright interference colors under crossed polars, while pleochroism—color changes upon rotation— is prominent in amphiboles, shifting between greens and browns. If present, perovskite appears isotropic with low relief, remaining dark under crossed polars. These traits highlight the rock's volatile-rich crystallization history without delving into mineral specifics.[11] In field settings, lamprophyres are frequently observed as narrow, cross-cutting dikes or sills intruding older country rocks, often forming linear outcrops or float trains due to differential weathering. They are associated with volatile-induced alterations, such as serpentinization of adjacent ultramafic materials, which can produce greenish halos or sheared margins around the intrusions. These characteristics enable geologists to distinguish lamprophyres during mapping, particularly in orogenic or rift-related terrains.[13][14]Petrography
Texture and Structure
Lamprophyres are characterized by a predominant porphyritic texture, featuring phenocrysts of hydrous mafic minerals such as biotite and amphibole that constitute 20-50 vol.% of the rock, set within a fine-grained holocrystalline to hypocrystalline groundmass.[6][15] This texture arises from rapid crystallization of early-formed large crystals in a quickly cooling magma, distinguishing lamprophyres from equigranular ultramafic rocks.[16] The phenocrysts exhibit a panidiomorphic habit, with well-formed crystal faces, while the groundmass often displays a hyalopilitic structure composed of felted microlites of plagioclase and alkali feldspar intergrown with mafic minerals.[17][18] This fine, interlocking fabric reflects the viscous nature of the lamprophyric magma and contributes to the rock's overall melanocratic to mesocratic appearance. In some variants, glomeroporphyritic clusters of phenocrysts occur, where multiple crystals are aggregated together, enhancing the porphyritic character without forming cumulate layering.[13][19] A distinctive feature in many lamprophyres is the presence of ocellar structures, which are rounded to subspherical segregations of leucocratic minerals, typically comprising alkali feldspar, plagioclase, and calcite, with diameters up to 1 cm.[20][21] These ocelli, often resembling frog spawn due to their clustered, globular arrangement, form through immiscible liquid segregation or late-stage crystallization and are commonly zoned with a central core of carbonate or analcime surrounded by a feldspar-rich rim.[22][23] Structural variations in lamprophyres, particularly in dike intrusions, include flow banding defined by aligned phenocrysts and groundmass minerals, indicative of magmatic flow during emplacement.[13] Cumulate textures are notably absent, as the rocks lack the gravitational settling of crystals typical of layered intrusions. Post-emplacement alteration can modify these textures, with chloritization of mafic phenocrysts producing green hues and carbonatization filling ocelli or veins, thereby enhancing the rock's susceptibility to weathering.[24][25]Mineral Assemblage
Lamprophyres exhibit a characteristic mineral assemblage dominated by mafic to ultramafic phenocrysts set in a fine-grained, often holocrystalline groundmass, reflecting their hybrid mantle-crustal origins as observed in numerous petrographic studies.[26] The essential phenocrysts include phlogopite or biotite, which can constitute up to 30 vol.% and are typically Ti-rich, along with amphiboles such as pargasitic hornblende or kaersutite, and clinopyroxene varieties like diopside to titanian augite.[13] These mafic phases often display euhedral to subhedral habits and may show zoning or resorption textures indicative of magma evolution.[27] The groundmass is primarily composed of alkali feldspar, such as sanidine or anorthoclase, intergrown with plagioclase ranging from oligoclase to andesine, alongside accessory apatite and opaque oxides like magnetite-ilmenite.[26] These felsic components typically form a microlitic or felted matrix, with the oxides appearing as disseminated grains or late-stage interstitial phases.[13] Apatite occurs as prismatic crystals throughout the rock, often exceeding 1 vol.% in abundance.[28] Accessory primary phases include forsteritic olivine, which is commonly altered to serpentine, as well as perovskite, sphene (titanite), and zircon, present in trace amounts (<1 vol.%).[13] Secondary alteration minerals such as calcite, chlorite, and epidote are widespread, replacing primary mafics and feldspars due to post-emplacement hydrothermal processes.[27] These accessories highlight the volatile-rich nature of lamprophyric magmas.[28] Modal variations occur across subtypes; for instance, minettes feature biotite exceeding amphibole in abundance, while some alkaline varieties lack primary quartz or olivine.[26] Mineral chemistry underscores these distinctions, with biotite often containing >5 wt.% TiO₂, reflecting high-temperature crystallization, and amphiboles enriched in Al₂O₃ (up to 12 wt.%), indicative of calc-alkaline affinities.[29][27]Petrology and Geochemistry
Bulk Composition
Lamprophyres exhibit a wide range in major element compositions, reflecting their diverse subtypes, but are generally characterized by silica undersaturation with SiO₂ contents of 30–55 wt%, elevated MgO (3–18 wt%), high potassium (K₂O 3–8 wt%), and sodium (Na₂O 1–5 wt%), alongside relatively low CaO compared to total alkalis in many potassic varieties.[30][31][32] Al₂O₃ typically ranges from 3–17 wt%, TiO₂ from 2–4 wt%, and FeO_total from 8–14 wt%, with these values contributing to their mafic to ultramafic nature and distinction from more evolved igneous rocks (calc-alkaline subtypes often 12–17 wt% Al₂O₃; ultramafic/alkaline 3–9 wt%).[31][33][6] In comparison to typical basalts, lamprophyres show lower SiO₂ and higher MgO, emphasizing their mantle-derived, primitive character.[30]| Major Element | Lamprophyre Range (wt%) | Typical Basalt Range (wt%) |
|---|---|---|
| SiO₂ | 30–55 | 45–52 |
| MgO | 3–18 | 5–10 |
| K₂O | 3–8 | 0.5–2 |
| Na₂O | 1–5 | 2–4 |
| CaO | 5–20 | 8–12 |
| Al₂O₃ | 3–17 | 14–18 |
Geochemical Signatures
Lamprophyres exhibit distinct geochemical patterns that facilitate their identification and discrimination from other mafic-ultramafic rocks, particularly through major and trace element ratios plotted on specialized diagrams. In the K₂O versus SiO₂ diagram, lamprophyres typically occupy the ultrapotassic field, characterized by K₂O > 3 wt% and SiO₂ < 55 wt%, reflecting their potassic to ultrapotassic affinity derived from mantle sources enriched in incompatible elements. Similarly, the Th-Hf-Nb/₂ ternary diagram serves as a robust proxy for distinguishing orogenic (subduction-related) from anorogenic (intraplate) lamprophyres, with orogenic variants plotting toward higher Th and lower Nb/₂ due to subduction-modified mantle signatures, while anorogenic types align with asthenospheric influences. For assessing mantle derivation, plots of MgO versus Ni or Cr abundances highlight primitive signatures, with lamprophyres showing MgO up to 20 wt%, Ni up to 500 ppm, and Cr up to 1000 ppm, indicating minimal crustal contamination and origin from peridotitic sources.[34] Isotopic compositions further underscore the enriched nature of lamprophyre sources, typically from variably metasomatized subcontinental lithospheric mantle. Initial ⁸⁷Sr/⁸⁶Sr ratios range from 0.703 to 0.710, often elevated due to ancient subduction-related enrichment, while εNd values span -5 to +5, reflecting mixtures of depleted and enriched mantle components without extreme radiogenic signatures.[35] These ratios, such as ⁸⁷Sr/⁸⁶Sr_i = 0.7034–0.7042 and εNd ≈ 0 to +5 in asthenospheric-derived examples, indicate low-degree partial melting of garnet lherzolite with limited crustal interaction.[36] Volatile contents are inferred to be high, with H₂O estimated at 2–5 wt% in parental melts based on amphibole stability and melt inclusion data, alongside elevated CO₂ from primary carbonate phases, promoting the hydrous, explosive emplacement typical of these rocks.[36] Rare earth element (REE) patterns are characterized by strong light REE (LREE) enrichment over heavy REE (HREE), with (La/Yb)_N ratios of 20–220 and no significant Eu anomaly, signifying garnet retention in the residue during low-degree melting (<5%).[37] Primitive mantle-normalized spider diagrams display pronounced peaks in large ion lithophile elements (LILE) like Ba and Sr, coupled with troughs in high field strength elements (HFSE) such as Nb, Ta, and Ti, hallmarks of subduction-modified mantle sources.[37] In comparison to lamproites and kimberlites, lamprophyres are geochemically differentiated by typically higher Al₂O₃ (8–17 wt%) and lower TiO₂ (<2 wt% in some), contrasting with the low-Al, high-Ti compositions of lamproites (Al₂O₃ <10 wt%, TiO₂ >3 wt%) and the more variable, often carbonate-dominated profiles of kimberlites; these distinctions are evident in ternary diagrams like MgO-K₂O-Al₂O₃, where lamprophyres plot intermediate between the other two.[38]Classification and Nomenclature
Classification Systems
The International Union of Geological Sciences (IUGS) classifies lamprophyres as a distinct group of igneous rocks, separate from the standard QAPF (quartz-alkali feldspar-plagioclase-feldspathoid) and TAS (total alkali-silica) diagrams due to their unique volatile-rich, porphyritic nature and inequigranular texture. According to the IUGS guidelines, lamprophyres are defined as mesocratic to holomelanocratic rocks featuring abundant mafic phenocrysts such as biotite, amphibole, or pyroxene, with felsic minerals (e.g., alkali feldspar or plagioclase) restricted to the fine-grained groundmass; they emphasize hydrous phenocrysts, excluding those with prominent olivine phenocrysts in certain subtypes.[39][40] Lamprophyres are further subdivided into rock series based on geochemical affinities: calc-alkaline lamprophyres, which exhibit shoshonitic characteristics with elevated potassium relative to sodium, and alkaline lamprophyres, ranging from sodic to potassic compositions. This distinction reflects their petrogenetic origins, with calc-alkaline types often linked to subduction-related settings and alkaline types to intraplate or extensional environments.[41][42] Modal classification within the IUGS framework relies on the dominant mafic phenocryst and the groundmass feldspar type, such as biotite-dominated minettes with sanidine groundmass or amphibole-rich vogesites with plagioclase. These criteria prioritize mineral proportions over chemical totals, accommodating the rocks' melanocratic bias where mafic components exceed 50% of phenocrysts.[39][8] Classification faces challenges due to overlaps with lamproites and kimberlites, which share volatile-rich and ultrapotassic traits but differ in modal olivine or leucite content; the IUGS guidelines in Le Maitre et al. (2002) address this by emphasizing petrographic exclusivity and excluding ultramafic variants initially, though later modifications integrated them via additional inequigranular steps.[39][40] The evolutionary history of lamprophyre classification began in the 19th century with regional descriptive terms for specific occurrences, such as minette in the French Massif Central, evolving through 20th-century petrographic schemes to the 1990s mineral-genetic systems that incorporated genetic clans and facies concepts for broader applicability. Recent reviews as of 2024 highlight ongoing debates regarding the integration of the "Lamprophyre clan" into IUGS frameworks, proposing refinements to address petrographic and genetic overlaps.[8][43][44]Named Varieties
Lamprophyres are subdivided into several named varieties based on their dominant mafic minerals and feldspar content, primarily following the International Union of Geological Sciences (IUGS) classification scheme outlined by Rock (1991).[8] These varieties include both calc-alkaline and alkaline types, each distinguished by modal mineralogy and historically tied to their type localities in Europe and beyond.[15] The calc-alkaline varieties—minette, kersantite, vogesite, and spessartite—feature biotite or amphibole as primary mafic phases with varying proportions of K-feldspar and plagioclase, while alkaline varieties like camptonite and monchiquite emphasize amphibole and clinopyroxene in a more sodic groundmass. Minette is characterized by dominant phlogopite-biotite as the mafic phenocrysts, with a groundmass rich in K-feldspar (sanidine or orthoclase) exceeding plagioclase, and subordinate amphibole (magnesio-hastingsite to pargasite), clinopyroxene (diopside or augite), and occasionally olivine.[15] This variety represents the most potassic calc-alkaline lamprophyre, with biotite comprising over 20% of the mode in typical examples.[8] Historically named after early descriptions in the Vosges region of France, minettes gained prominence through studies of the Navajo Volcanic Field in the USA, where they form plugs and dikes associated with late Oligocene volcanism.[45] Kersantite features biotite (or phlogopite) as the principal mafic mineral, with plagioclase dominating the groundmass over K-feldspar, accompanied by accessory amphibole, clinopyroxene, and olivine.[15] The modal distinction lies in the plagioclase-rich matrix, often exceeding 50% of the felsic components, setting it apart from more potassic relatives.[8] Originating from the type locality near Kersanton in Brittany, France, kersantites were first described in the mid-19th century and are commonly emplaced as swarms of dikes in Variscan basement rocks.[46] Vogesite is defined by hornblende (magnesio-hastingsite to pargasite series) as the dominant mafic phenocryst, with K-feldspar prevailing over plagioclase in the groundmass, plus minor biotite, clinopyroxene, and olivine.[15] Amphibole typically constitutes more than 30% of the mode, emphasizing its hydrous nature compared to mica-dominated types.[8] The name derives from the Vosges Mountains in France, where such rocks were identified in the early 20th century as porphyritic intrusions cutting granitic terrains. Spessartite contains pyroxene (augite) and amphibole (hornblende) as key mafic phases, with plagioclase exceeding K-feldspar in the groundmass, and lesser biotite or olivine.[15] Its modal hallmark is the prominence of clinopyroxene alongside amphibole, often with amphibole at 20-40% of the rock.[8] Named after the Spessart region in Germany, spessartites were documented in the 19th century as dike rocks in Paleozoic sedimentary sequences of central Europe.[47] Alkaline lamprophyre varieties include camptonite, which is marked by augite and kaersutite (a titanian amphibole from the magnesio-hastingsite–pargasite–kaersutite series) as essential components, with plagioclase or K-feldspar in the groundmass and minor biotite, olivine, and clinopyroxene.[15] Kaersutite often exceeds 25% modally, reflecting higher alkalinity.[8] Monchiquite, in contrast, emphasizes olivine and Ti-rich amphibole (kaersutite) with perovskite as an accessory, in a glassy or sodic feldspathoid groundmass lacking significant plagioclase.[15] Perovskite and Ti-amphibole highlight its ultramafic, carbonatite-affiliated affinity, with olivine up to 20% in some modes.[8] Both types are exemplified by Mesozoic occurrences in Antarctica, such as the Beaver Lake region, where camptonites and monchiquites intrude Precambrian basement as part of alkaline provinces.Genesis
Petrogenetic Mechanisms
Lamprophyres are generated primarily through low-degree partial melting (typically 1-5%) of volatile-rich mantle sources, such as phlogopite-bearing peridotite or eclogite, which produces silica-undersaturated, potassic magmas enriched in incompatible elements.[48] This melting regime is facilitated by the presence of hydrous and carbonated phases in the mantle, where phlogopite and amphibole lower the solidus temperature, enabling melt generation at depths of 80-150 km under relatively low pressures.[15] The resulting melts exhibit high magnesium numbers (Mg# > 70) and primitive characteristics, reflecting minimal interaction with the overlying lithosphere during ascent.[49] The role of fluids is critical in lamprophyre petrogenesis, with H₂O and CO₂ acting to depress the mantle solidus and promote the stability of hydrous minerals like phlogopite and amphibole. Subduction-related metasomatism introduces these volatiles into the lithospheric mantle, enriching it in water (up to several wt%) and alkalis, which triggers partial melting without requiring excessively high temperatures.[15][48] This metasomatic overprint often involves fluid-mediated addition of large-ion lithophile elements (LILE), enhancing the source's fertility for low-degree melts.[50] The mantle source for lamprophyres is typically the enriched subcontinental lithospheric mantle (SCLM), characterized by EM1 or EM2 isotopic signatures (e.g., high ⁸⁷Sr/⁸⁶Sr > 0.705 and variable ¹⁴³Nd/¹⁴⁴Nd ~0.5120-0.5125), indicating contributions from recycled crustal material or subducted sediments.[51] These sources may include ancient, veined peridotites modified by earlier subduction events, leading to heterogeneous domains that yield potassic, volatile-rich magmas upon melting.[52] During ascent, lamprophyric magmas undergo a distinctive crystallization sequence, with early formation of mafic phenocrysts such as olivine, clinopyroxene, phlogopite, and amphibole, followed by late-stage groundmass crystallization of feldspars, quartz, or carbonates.[15] This porphyritic texture arises from rapid decompression and minimal fractional crystallization, driven by the magmas' low viscosity and high volatile content, which inhibit prolonged residence in crustal magma chambers.[48] Evidence from mineral compositions and geochemistry indicates high alkalinity and volatile contents consistent with derivation from a hydrous mantle source.[15] Recent studies (as of 2025) further constrain these processes, with Eocene lamprophyres in South Kalimantan revealing substantial lithospheric thinning (50–75%) post-emplacement, and discoveries of ultramafic lamprophyres in the Webb Province, Gibson, linking them to rift-related melting of metasomatized mantle.[53][54]Tectonic Associations
Lamprophyres are emplaced in a variety of tectonic environments, reflecting their derivation from mantle sources influenced by plate boundary processes and intraplate dynamics. Calc-alkaline varieties, such as minettes and vogesites, are predominantly associated with subduction zones, where they form as small-volume intrusions in continental arcs, often as offshoots of broader granitic magmatism. These rocks exhibit geochemical signatures indicative of fluid-mediated metasomatism in the mantle wedge above subducting slabs, as observed in Late Archean examples from the Yilgarn Craton in Western Australia.[55] Similarly, Late Neogene lamprophyres in the eastern Aegean region intrude above an active subduction zone, linking their formation to retreating slab dynamics.[56] Alkaline and ultramafic lamprophyres, including camptonites, monchiquites, and alnöites, are typically linked to intraplate settings characterized by rifting, hotspots, or lithospheric thinning. These occur in extensional regimes away from plate margins, such as the Cretaceous dyke swarms in the South Island of New Zealand, where they represent components of continental intraplate volcanism.[57] In Central Asia, Late Cretaceous lamprophyres reflect partial melting in an intraplate context influenced by prior subduction but dominated by extensional tectonics.[49] Lamproites, a related ultrapotassic group, also favor such environments, often in anorogenic cratonic settings like the Eastern Dharwar Craton.[26] Post-collisional settings are another key environment, particularly for potassic-ultrapotassic lamprophyres emplaced during extension following orogeny. In the Variscan orogen of Europe, lamprophyre dyke swarms intrude during post-collisional and post-orogenic stages, associated with lithospheric delamination and mantle upwelling, as seen in the Bohemian Massif.[58] Paleogene examples in western Yunnan, China, and northern Iran further illustrate this, with magmas derived from metasomatized mantle in extensional basins after India-Asia collision.[59][60] Lamprophyres in these contexts often cluster temporally, with Phanerozoic peaks such as Cretaceous swarms in East Antarctica's Beaver Lake area (110–117 Ma), contrasting with their rarity in the Archean, where isolated occurrences such as those in the Superior Province are documented.[61][62][63] Lamprophyres frequently associate with other alkaline intrusions, providing insights into shared mantle sources. They commonly precede or accompany syenites and carbonatites in rift-related complexes, as in the Gardar Province of Greenland, where lamprophyres mingle with carbonatite magmas.[64] Ultrapotassic varieties also link to A-type granites in post-collisional or intraplate settings, such as those derived from metasomatized mantle in the Damara Belt, Namibia.[65] These relations underscore lamprophyres' role as early indicators of volatile-rich melting in evolving tectonic regimes.[41]Occurrence and Significance
Global Distribution
Lamprophyres are distributed globally, with occurrences spanning from Archaean to Holocene times, though they are predominantly associated with Phanerozoic orogenic events. These rocks typically form small-volume intrusions, with individual dikes, sills, or stocks rarely exceeding 1 km³ in volume, reflecting their role as minor but widespread manifestations of alkaline magmatism.[66][15] In Europe, lamprophyres are prominent within the Variscan orogenic belts of the Late Palaeozoic, particularly during the Carboniferous period. Notable examples include dikes and sills in southwestern England (Cornwall), Scotland's Midland Valley, France's Armorican Massif, and Germany's Mid-German Crystalline Rise and Saxothuringian Zone, where they intruded post-collisionally between approximately 330 and 290 Ma. These occurrences cluster along strike-slip fault zones and are linked to late-orogenic extension following continental collision.[67][68][69] North American lamprophyres are concentrated in the Appalachian orogen and the Cordilleran belt, with ages ranging from Carboniferous to Cenozoic. In the Appalachians, mid-Carboniferous examples (~320 Ma) occur as dikes along the Cobequid Fault Zone in eastern Canada (Nova Scotia), while Cretaceous intrusions (~130–110 Ma) are documented in Vermont and the Lake Champlain Valley, often as alkaline dikes cutting metamorphic basement. Further west, in the Cordillera, Mesozoic to Cenozoic lamprophyres include mid-Tertiary (~25–21 Ma) dikes in northwestern Mexico's backarc region and Quaternary basanitic lamprophyres in the western Mexican Volcanic Belt near Colima and Mascota; Canadian examples appear in British Columbia's displaced terranes, associated with alkaline provinces.[70][71][72][73][74][75] Occurrences in Africa and Antarctica are tied to Gondwana fragments, highlighting Mesozoic rift-related magmatism. In East Antarctica's Prince Charles Mountains, ultramafic lamprophyres (damtjernites and aillikites) form sills, dikes, and plugs in the Beaver Lake area, dated to the Middle Jurassic (~170 Ma), contemporaneous with initial Gondwana breakup and linked to the Lambert Graben rift system. African examples include Cretaceous (~90 Ma) orangeites in the Kaapvaal Craton of South Africa, emplaced during post-breakup extension, preserving mantle xenoliths from subcontinental lithosphere.[76][77] In Asia and Australia, lamprophyres appear along margins of large igneous provinces and in intraplate settings. Pre- and post-Trap aillikites and ultramafic lamprophyres occur in the southwestern Siberian Craton near the Siberian Traps (~252 Ma), with dikes in the Chadobets complex reflecting metasomatized mantle sources influenced by the Permian-Triassic flood basalts. In Australia, Permian ultramafic lamprophyres (~250 Ma) are documented at Gympie in Queensland's New England Orogen, featuring high-MgO compositions (up to 18.5 wt%) and forming small dike swarms.[78][79][80] Lamprophyres exhibit spatial patterns dominated by clustering in continental orogenic belts, such as the Variscides, Appalachians, and Central Asian Orogenic Belt, where they mark post-collisional or extensional phases. Oceanic occurrences are rare, limited to isolated dikes in settings like the Canary Islands or triple junctions, contrasting with their prevalence in cratonic and pericratonic margins. Ages range from Archaean (e.g., ~2.7 Ga calc-alkaline varieties in Canada's Superior Craton) to Holocene, though post-Mesozoic examples are mostly Cenozoic and Quaternary.[81][2][16][82][48]| Province/Region | Example Localities | Typical Age Range (Ma) | Volume per Body (km³) |
|---|---|---|---|
| European Variscides | Scotland, France, Germany | 330–290 | <0.5 |
| North American Appalachians | Nova Scotia, Vermont | 320–110 | <1 |
| North American Cordillera | Mexico (Hermosillo, Colima), British Columbia | 25–0 (Quaternary) | <0.5 |
| Gondwana (Africa/Antarctica) | Beaver Lake (Antarctica), Kaapvaal (South Africa) | ~200–90 (Mesozoic)* | <1 |
| Siberian Craton/Asia | Chadobets (Russia) | ~252 (Permian-Triassic) | <0.5 |
| Australia | Gympie (Queensland) | ~250 (Permian) | <0.5 |
Economic and Geological Importance
Lamprophyres play a significant role in mineral exploration due to their spatial and temporal associations with gold deposits, particularly in Archaean lode-gold systems. These rocks often serve as vectors for mineralization through the release of metasomatic fluids from their volatile-rich mantle sources, facilitating gold transport and precipitation in nearby structures. For instance, shoshonitic lamprophyres in the Yilgarn Craton of Western Australia exhibit intimate space-time relationships with mesothermal gold deposits, where their emplacement coincides with ore-forming events.[83] Similarly, in the Superior Province of Canada, lamprophyres are spatially correlated with orogenic gold occurrences, highlighting their indirect genetic links to lode-gold formation via fluid interactions.[84] Overall, such associations underscore lamprophyres' value as exploration targets in Archaean and Proterozoic terranes.[85] Although lamprophyres rarely carry diamonds directly, their ultramafic variants show promise as indicators of diamond potential in regions with kimberlite fields. These rocks, derived from similar deep mantle sources, often occur in proximity to kimberlites, providing clues to fertile lithospheric conditions. In the Wajrakarur Kimberlite Field of India, ultramafic lamprophyres coexist with kimberlites and lamproites, suggesting shared metasomatized sources that enhance prospectivity for diamond-bearing pipes.[86] Likewise, in the Wyoming Craton, ultramafic lamprophyres are mapped alongside kimberlites, aiding in the delineation of diamond windows within the subcontinental lithospheric mantle.[87] This relationship positions ultramafic lamprophyres as secondary exploration tools in established kimberlite provinces. Geologically, lamprophyres act as key indicators of lithospheric mantle evolution and subduction-related processes. Their potassic to ultrapotassic compositions reflect enrichment in the subcontinental lithospheric mantle, often resulting from metasomatism during subduction recycling of crustal materials.[88] For example, calc-alkaline lamprophyres in the South China Block derive from partial melting of subducted sediments, tracing the recycling of volatiles and incompatible elements into the mantle.[89] In regions like the North China Craton, lamprophyre dikes mark episodes of lithospheric thinning and asthenospheric upwelling, providing timelines for tectonic reconfiguration.[90] These features make lamprophyres essential for reconstructing mantle dynamics and orogenic histories. Beyond mineralization, lamprophyres have minor applications as dimension stone due to their durability and aesthetic textures in select localities, though extraction remains limited compared to other igneous rocks. More prominently, they serve as geochemical samplers of the mantle, with xenoliths and phenocrysts preserving traces of metasomatism and deep volatile fluxes.[91] Recent post-2010 research emphasizes their role in volatile cycling, using isotopic tracers to probe mantle heterogeneity. Lithium isotopes in lamprophyres, for instance, fingerprint source components linked to supercontinent assembly and dispersal.[92] Calcium and mercury isotopes further reveal volatile influences from subducted oceanic components, enhancing models of deep carbon and halogen budgets.[93][94] Recent studies, such as those from 2023 identifying ultramafic lamprophyre provinces in central Australia, continue to provide insights into rift-related magmatism and mantle processes.[54] Such studies highlight lamprophyres' ongoing importance in mantle geochemistry.[95]References
- https://www.[mindat.org](/page/Mindat.org)/min-3166.html