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Hydrogen atom

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Hydrogen atom

A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral hydrogen atom contains a single positively charged proton in the nucleus, and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen constitutes about 75% of the baryonic mass of the universe.

In everyday life on Earth, isolated hydrogen atoms (called "atomic hydrogen") are extremely rare. Instead, a hydrogen atom tends to combine with other atoms in compounds, or with another hydrogen atom to form ordinary (diatomic) hydrogen gas, H2. "Atomic hydrogen" and "hydrogen atom" in ordinary English use have overlapping, yet distinct, meanings. For example, a water molecule contains two hydrogen atoms, but does not contain atomic hydrogen (which would refer to isolated hydrogen atoms).

Atomic spectroscopy shows that there is a discrete infinite set of states in which a hydrogen (or any) atom can exist, contrary to the predictions of classical physics. Attempts to develop a theoretical understanding of the states of the hydrogen atom have been important to the history of quantum mechanics, since all other atoms can be roughly understood by knowing in detail about this simplest atomic structure.

The most abundant isotope, protium (1H), or light hydrogen, contains no neutrons and is simply a proton and an electron. Protium is stable and makes up 99.985% of naturally occurring hydrogen atoms.

Deuterium (2H) contains one neutron and one proton in its nucleus. Deuterium is stable, makes up 0.0156% of naturally occurring hydrogen, and is used in industrial processes like nuclear reactors and nuclear magnetic resonance spectroscopy.

Tritium (3H) contains two neutrons and one proton in its nucleus and is not stable, decaying with a half-life of 12.32 years. Because of its short half-life, tritium does not exist in nature except in trace amounts.

Heavier isotopes of hydrogen are only created artificially in particle accelerators and have half-lives on the order of 10−22 seconds. They are unbound resonances located beyond the neutron drip line; this results in prompt emission of a neutron.

The formulas below are valid for all three isotopes of hydrogen, but slightly different values of the Rydberg constant (correction formula given below) must be used for each hydrogen isotope.

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atom of element hydrogen
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