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Atomic battery
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An atomic battery, nuclear battery, radioisotope battery or radioisotope generator uses energy from the decay of a radioactive isotope to generate electricity. Like a nuclear reactor, it generates electricity from nuclear energy, but it differs by not using a chain reaction. Although commonly called batteries, atomic batteries are technically not electrochemical and cannot be charged or recharged. Although they are very costly, they have extremely long lives and high energy density, so they are typically used as power sources for equipment that must operate unattended for long periods, such as spacecraft, pacemakers, underwater systems, and automated scientific stations in remote parts of the world.[1][2][3]
Nuclear batteries began in 1913, when Henry Moseley first demonstrated a current generated by charged-particle radiation. In the 1950s and 1960s, this field of research got much attention for applications requiring long-life power sources for spacecraft. In 1954, RCA researched a small atomic battery for small radio receivers and hearing aids.[4] Since RCA's initial research and development in the early 1950s, many types and methods have been designed to extract electrical energy from nuclear sources. The scientific principles are well known, but modern nano-scale technology and new wide-bandgap semiconductors have allowed the making of new devices and interesting material properties not previously available.
Nuclear batteries can be classified by their means of energy conversion into two main groups: thermal converters and non-thermal converters. The thermal types convert some of the heat generated by the nuclear decay into electricity; an example is the radioisotope thermoelectric generator (RTG), often used in spacecraft. The non-thermal converters, such as betavoltaic cells, extract energy directly from the emitted radiation, before it is degraded into heat; they are easier to miniaturize and do not need a thermal gradient to operate, so they can be used in small machines.
Atomic batteries usually have an efficiency of 0.1–5%. High-efficiency betavoltaic devices can reach 6–8% efficiency.[5]
Thermal conversion
[edit]Thermionic conversion
[edit]A thermionic converter consists of a hot electrode, which thermionically emits electrons over a space-charge barrier to a cooler electrode, producing a useful power output. Caesium vapor is used to optimize the electrode work functions and provide an ion supply (by surface ionization) to neutralize the electron space charge.[6]
Thermoelectric conversion
[edit]
A radioisotope thermoelectric generator (RTG) uses thermocouples. Each thermocouple is formed from two wires of different metals (or other materials). A temperature gradient along the length of each wire produces a voltage gradient from one end of the wire to the other; but the different materials produce different voltages per degree of temperature difference. By connecting the wires at one end, heating that end but cooling the other end, a usable, but small (millivolts), voltage is generated between the unconnected wire ends. In practice, many are connected in series (or in parallel) to generate a larger voltage (or current) from the same heat source, as heat flows from the hot ends to the cold ends. Metal thermocouples have low thermal-to-electrical efficiency. However, the carrier density and charge can be adjusted in semiconductor materials such as bismuth telluride and silicon germanium to achieve much higher conversion efficiencies.[7]
Thermophotovoltaic conversion
[edit]Thermophotovoltaic (TPV) cells work by the same principles as a photovoltaic cell, except that they convert infrared light (rather than visible light) emitted by a hot surface, into electricity. Thermophotovoltaic cells have an efficiency slightly higher than thermoelectric couples and can be overlaid on thermoelectric couples, potentially doubling efficiency. The University of Houston TPV Radioisotope Power Conversion Technology development effort is aiming at combining thermophotovoltaic cells concurrently with thermocouples to provide a 3- to 4-fold improvement in system efficiency over current thermoelectric radioisotope generators. [citation needed]
Stirling generators
[edit]A Stirling radioisotope generator is a Stirling engine driven by the temperature difference produced by a radioisotope. A more efficient version, the advanced Stirling radioisotope generator, was under development by NASA, but was cancelled in 2013 due to large-scale cost overruns.[8]
Non-thermal conversion
[edit]Non-thermal converters extract energy from emitted radiation before it is degraded into heat. Unlike thermoelectric and thermionic converters their output does not depend on the temperature difference. Non-thermal generators can be classified by the type of particle used and by the mechanism by which their energy is converted.
Electrostatic conversion
[edit]Energy can be extracted from emitted charged particles when their charge builds up in a conductor, thus creating an electrostatic potential. Without a dissipation mode the voltage can increase up to the energy of the radiated particles, which may range from several kilovolts (for beta radiation) up to megavolts (alpha radiation). The built up electrostatic energy can be turned into usable electricity in one of the following ways.
Direct-charging generator
[edit]A direct-charging generator consists of a capacitor charged by the current of charged particles from a radioactive layer deposited on one of the electrodes. Spacing can be either vacuum or dielectric. Negatively charged beta particles or positively charged alpha particles, positrons or fission fragments may be utilized. Although this form of nuclear-electric generator dates back to 1913, few applications have been found in the past for the extremely low currents and inconveniently high voltages provided by direct-charging generators. Oscillator/transformer systems are employed to reduce the voltages, then rectifiers are used to transform the AC power back to direct current.
English physicist H. G. J. Moseley constructed the first of these. Moseley's apparatus consisted of a glass globe silvered on the inside with a radium emitter mounted on the tip of a wire at the center. The charged particles from the radium created a flow of electricity as they moved quickly from the radium to the inside surface of the sphere. As late as 1945 the Moseley model guided other efforts to build experimental batteries generating electricity from the emissions of radioactive elements.
Electromechanical conversion
[edit]Electromechanical atomic batteries use the buildup of charge between two plates to pull one bendable plate towards the other, until the two plates touch, discharge, equalizing the electrostatic buildup, and spring back. The mechanical motion produced can be used to produce electricity through flexing of a piezoelectric material or through a linear generator. Milliwatts of power are produced in pulses depending on the charge rate, in some cases multiple times per second (35 Hz).[9]
Radiovoltaic conversion
[edit]A radiovoltaic (RV) device converts the energy of ionizing radiation directly into electricity using a semiconductor junction, similar to the conversion of photons into electricity in a photovoltaic cell. Depending on the type of radiation targeted, these devices are called alphavoltaic (AV, αV), betavoltaic (BV, βV) and/or gammavoltaic (GV, γV). Betavoltaics have traditionally received the most attention since (low-energy) beta emitters cause the least amount of radiative damage, thus allowing a longer operating life and less shielding. Interest in alphavoltaic and (more recently) gammavoltaic devices is driven by their potential higher efficiency.
Alphavoltaic conversion
[edit]Alphavoltaic devices use a semiconductor junction to produce electrical energy from energetic alpha particles.[10][11]
Betavoltaic conversion
[edit]Betavoltaic devices use a semiconductor junction to produce electrical energy from energetic beta particles (electrons). A commonly used source is the hydrogen isotope tritium, which is employed in City Labs' NanoTritium batteries.
Betavoltaic devices are particularly well-suited to low-power electrical applications where long life of the energy source is needed, such as implantable medical devices or military and space applications.[12]
The Chinese startup Betavolt claimed in January 2024 to have a miniature device in the pilot testing stage.[13] It is allegedly generating 100 microwatts of power and a voltage of 3V and has a lifetime of 50 years without any need for charging or maintenance.[13] Betavolt claims it to be the first such miniaturised device ever developed.[13] It gains its energy from the isotope nickel-63, held in a module the size of a very small coin.[14] As it is consumed, the nickel-63 decays into stable, non-radioactive isotopes of copper, which pose no environmental threat.[14] It contains a thin wafer of nickel-63 providing beta particle electrons sandwiched between two thin crystallographic diamond semiconductor layers.[15][16]
Gammavoltaic conversion
[edit]Gammavoltaic devices use a semiconductor junction to produce electrical energy from energetic gamma particles (high-energy photons). They have only been considered in the 2010s[17][18][19][20] but were proposed as early as 1981.[21]
A gammavoltaic effect has been reported in perovskite solar cells.[17] Another patented design involves scattering of the gamma particle until its energy has decreased enough to be absorbed in a conventional photovoltaic cell.[18] Gammavoltaic designs using diamond and Schottky diodes are also being investigated.[19][20]
Radiophotovoltaic (optoelectric) conversion
[edit]In a radiophotovoltaic (RPV) device the energy conversion is indirect: the emitted particles are first converted into light using a radioluminescent material (a scintillator or phosphor), and the light is then converted into electricity using a photovoltaic cell. Depending on the type of particle targeted, the conversion type can be more precisely specified as alphaphotovoltaic (APV or α-PV),[22] betaphotovoltaic (BPV or β-PV)[23] or gammaphotovoltaic (GPV or γ-PV).[24]
Radiophotovoltaic conversion can be combined with radiovoltaic conversion to increase the conversion efficiency.[25]
Pacemakers
[edit]Medtronic and Alcatel developed a plutonium-powered pacemaker, the Numec NU-5, powered by a 2.5 Ci slug of plutonium 238, first implanted in a human patient in 1970. The 139 Numec NU-5 nuclear pacemakers implanted in the 1970s are expected to never need replacing, an advantage over non-nuclear pacemakers, which require surgical replacement of their batteries every 5 to 10 years. The plutonium "batteries" are expected to produce enough power to drive the circuit for longer than the 88-year halflife of the plutonium-238.[26][27][28][29] The last of these units was implanted in 1988, as lithium-powered pacemakers, which had an expected lifespan of 10 or more years without the disadvantages of radiation concerns and regulatory hurdles, made these units obsolete.
Betavoltaic batteries are also being considered as long-lasting power sources for lead-free pacemakers.[30]
Radioisotopes used
[edit]Atomic batteries use radioisotopes that produce low energy beta particles or sometimes alpha particles of varying energies. Low energy beta particles are needed to prevent the production of high energy penetrating Bremsstrahlung radiation that would require heavy shielding. Radioisotopes such as tritium, nickel-63, promethium-147, and technetium-99 have been tested. Plutonium-238, curium-242, curium-244 and strontium-90 have been used.[31] Besides the nuclear properties of the used isotope, there are also the issues of chemical properties and availability. A product deliberately produced via neutron irradiation or in a particle accelerator is more difficult to obtain than a fission product easily extracted from spent nuclear fuel.
Plutonium-238 must be deliberately produced via neutron irradiation of neptunium-237 but it can be easily converted into a stable plutonium oxide ceramic. Strontium-90 is easily extracted from spent nuclear fuel but must be converted into the perovskite form strontium titanate to reduce its chemical mobility, cutting power density in half. Caesium-137, another high yield nuclear fission product, is rarely used in atomic batteries because it is difficult to convert into chemically inert substances. Another undesirable property of Cs-137 extracted from spent nuclear fuel is that it is contaminated with other isotopes of caesium which reduce power density further.
Micro-batteries
[edit]In the field of microelectromechanical systems (MEMS), nuclear engineers at the University of Wisconsin, Madison have explored the possibilities of producing minuscule batteries which exploit radioactive nuclei of substances such as polonium or curium to produce electric energy.[citation needed] As an example of an integrated, self-powered application, the researchers have created an oscillating cantilever beam that is capable of consistent, periodic oscillations over very long time periods without the need for refueling. Ongoing work demonstrate that this cantilever is capable of radio frequency transmission, allowing MEMS devices to communicate with one another wirelessly.
These micro-batteries are very light and deliver enough energy to function as power supply for use in MEMS devices and further for supply for nanodevices.[32]
The radiation energy released is transformed into electric energy, which is restricted to the area of the device that contains the processor and the micro-battery that supplies it with energy.[33]: 180–181
See also
[edit]- Button cell – Small battery
- Induced gamma emission – Bombarding atomic nuclei to give off very short-wavelength light
- List of battery types
- Nuclear electric rocket – Type of spacecraft propulsion system
- Radioisotope heater unit – Device that provides heat through radioactive decay
- Radioisotope rocket
References
[edit]- ^ "A nuclear battery the size and thickness of a penny". Gizmag, 9 October 2009.
- ^ "Tiny 'nuclear batteries' unveiled". BBC News, Thursday, 8 October 2009.
- ^ "NanoTritium™ Battery Technology". City Labs. Retrieved 25 May 2023.
- ^ "Atomic Battery Converts Radioactivity Directly into Electricity". Popular Mechanics, April 1954, p. 87.
- ^ "Thermoelectric Generators". electronicbus.com. Archived from the original on 10 January 2016. Retrieved 23 February 2015.
- ^ Fitzpatrick, G. O. (19 May 1987). "Thermionic converter". Office of Scientific and Technical Information. OSTI 6377296.
- ^ McCoy, J.C (October 1995). An overview of the Radioisotope Thermoelectric Generator Transportation System Program. STAIF 96: space technology and applications international forum, Albuquerque, NM (United States), 7-11 Jan 1996. OSTI 168371.
- ^ The ASRG Cancellation in Context Future Planetary Exploration
- ^ Lal, Amit; Rajesh Duggirala; Hui Li (2005). "Pervasive Power:A Radioisotope-Powered Piezoelectric Generator" (PDF). IEEE Pervasive Computing. 4: 53–61. doi:10.1109/MPRV.2005.21. S2CID 18891519. Archived from the original (PDF) on 21 June 2007.
- ^ NASA Glenn Research Center, Alpha- and Beta-voltaics Archived 18 October 2011 at the Wayback Machine (accessed 4 October 2011)
- ^ Sheila G. Bailey, David M. Wilt, Ryne P. Raffaelle, and Stephanie L. Castro, Alpha-Voltaic Power Source Designs Investigated Archived 16 July 2010 at the Wayback Machine, Research and Technology 2005, NASA TM-2006-214016, (accessed 4 October 2011)
- ^ "Tritium Batteries as a Source of Nuclear Power". City Labs. Retrieved 25 May 2023.
- ^ a b c Anthony Cuthbertson (12 January 2024). "Nuclear battery produces power for 50 years without needing to charge". The Independent. Retrieved 14 January 2024.
- ^ a b Mark Tyson (13 January 2024). "Chinese-developed nuclear battery has a 50-year lifespan — Betavolt BV100 built with Nickel-63 isotope and diamond semiconductor material". Tom's Hardware. Retrieved 17 January 2024.
- ^ "Betavolt says its diamond nuclear battery can power devices for 50 years". David Szondy for New Atlas, 16 January 2024. Accessed 17 January 2024.
- ^ "贝塔伏特公司成功研制民用原子能电池" ('Betavolt successfully develops atomic energy battery for civilian use'), on Betavolt website (in Chinese). Accessed 17 January 2024.
- ^ a b Hiroshi Segawa; Ludmila Cojocaru; Satoshi Uchida (7 November 2016). "Gammavoltaic Property of Perovskite Solar Cell - Toward the Novel Nuclear Power Generation". Proceedings of International Conference Asia-Pacific Hybrid and Organic Photovoltaics. Retrieved 1 September 2020.
- ^ a b 20180350482, Ryan, Michael Doyle, "Gamma Voltaic Cell", issued 6 December 2018
- ^ a b MacKenzie, Gordon (October 2017). "A Diamond Gammavoltaic Cell". UK Research and Innovation. Archived from the original on 16 April 2021. Retrieved 1 September 2020.
- ^ a b Mackenzie, Robbie (19 June 2020). "Diamond Gammavoltaic Cells for Biasless Gamma Dosimetry". South West Nuclear Hub. Retrieved 1 September 2020.
- ^ "Popular Science". January 1981.
- ^ Purbandari, Dessy; Ferdiansjah, Ferdiansjah; Sujitno, Tjipto (2019). "Optimization of the Alpha Energy Deposited in Radioluminescence Thin Film for Alphaphotovoltaic Application". Proceeding International Conference on Science and Engineering. 2: 41–44. doi:10.14421/icse.v2.52. S2CID 141390756.
- ^ Berman, Veronika; Litz, Marc Stuart; Russo, Johnny (2018). "Investigation of Electrical Power Degradation in Beta Photovoltaic (βPV) and Beta Voltaic (βV) Power Sources Using 63Ni and 147Pm". Defense Technical Information Center. S2CID 139545450.
- ^ LIAKOS, John K. (1 December 2011). "Gamma-Ray-Driven Photovoltaic Cells via a Scintillator Interface". Journal of Nuclear Science and Technology. 48 (12): 1428–1436. doi:10.1080/18811248.2011.9711836. ISSN 0022-3131. S2CID 98136174.
- ^ Guo, Xiao; Liu, Yunpeng; Xu, Zhiheng; Jin, Zhangang; Liu, Kai; Yuan, Zicheng; Gong, Pin; Tang, Xiaobin (1 June 2018). "Multi-level radioisotope batteries based on 60Co γ source and Radio-voltaic/Radio-photovoltaic dual effects". Sensors and Actuators A: Physical. 275: 119–128. doi:10.1016/j.sna.2018.04.010. ISSN 0924-4247. S2CID 117568424.
- ^ "MedTech Memoirs: The Plutonium-Powered Pacemaker".
- ^ "Nuclear pacemaker still energized after 34 years".
- ^ R L Shoup."Nuclear-Powered Cardiac Pacemakers".
- ^ Crystal Phend."Extra Battery Life Not Always a Plus for Nuclear-Powered Pacemaker".
- ^ "Pacemaker Batteries for Leadless Pacemakers". City Labs. Retrieved 25 May 2023.
- ^ Bindu, K.C.; Harmon, Frank; Starovoitova, Valeriia; Stoner, Jon; Wells, Douglas (2013). "Optimization of commercial scale photonuclear production of radioisotopes". AIP Conference Proceedings. 1525 (1): 407–411. Bibcode:2013AIPC.1525..407B. doi:10.1063/1.4802359.
- ^ Waldner, Jean-Baptiste (2007). Inventer l'Ordinateur du XXIème Siècle. London: Hermes Science. p. 172. ISBN 978-2-7462-1516-0.
- ^ Waldner, Jean-Baptiste (2008). Nanocomputers and Swarm Intelligence. London: ISTE John Wiley & Sons. ISBN 978-1-84704-002-2.
radioactive nuclei releases electrons that shoot the negative pole of the battery
External links
[edit]- Betavoltaic Historical Review, 2017
- Cantilever Electromechanical Atomic Battery, 2002
- Radioisotope Batteries for MEMS
- Americium Battery Concept Proposed for Space Applications- TFOT article
- Nuclear Batteries (25 MW)
- Tiny 'nuclear batteries' unveiled, BBC article about the research of Jae Wan Kwon et al. from the University of Missouri.
Atomic battery
View on GrokipediaFundamentals
Definition and Principles
An atomic battery, also referred to as a nuclear battery or radioisotope generator, is a device that harnesses energy from the radioactive decay of isotopes to produce electrical power directly, without involving chemical reactions or moving mechanical parts.[5] This distinguishes it from conventional power sources like nuclear reactors, which rely on fission chain reactions, and from electrochemical batteries, which depend on reversible chemical processes. The core mechanism involves capturing the energy released during alpha, beta, or gamma decay, where unstable atomic nuclei emit particles or radiation, liberating kinetic energy or heat that can be converted to electricity.[6] The fundamental principle governing atomic batteries is the predictable rate of radioactive decay, which provides a constant energy source over extended periods. The power generated, , is determined by the equation where is the decay constant (specific to the isotope and related to its half-life), is the initial number of radioactive atoms, and is the average energy released per decay event./University_Physics_III_-Optics_and_Modern_Physics(OpenStax)/10%3A__Nuclear_Physics/10.04%3A_Radioactive_Decay) This decay-driven output typically yields conversion efficiencies of 5-10%, depending on the method used to transform the decay energy—such as direct particle interaction or thermal gradients—resulting in power levels from microwatts for compact devices to several watts for larger systems. These batteries maintain reliable operation for 10-50 years or longer, as the power diminishes gradually according to the isotope's half-life, without the need for maintenance or recharging.[5] In comparison to traditional chemical batteries, atomic batteries offer exceptional longevity and energy density on a per-mass basis due to the immense energy stored in nuclear bonds, but they provide lower instantaneous power density and are more expensive to produce.[8] Terminology for these devices has evolved historically, with "atomic battery" serving as a broad descriptor, "nuclear battery" highlighting the nuclear decay process, and isotope-specific terms like "tritium battery" or "plutonium battery" reflecting the radioactive material employed.[5]Radioactive Decay Mechanisms
Atomic batteries, also known as radioisotope batteries, harness energy from the radioactive decay of isotopes through various mechanisms, primarily alpha, beta, and gamma decay. Alpha decay involves the emission of alpha particles, which are helium-4 nuclei consisting of two protons and two neutrons, typically carrying energies around 4 to 8 MeV.[9] These particles have a short range in matter, traveling only a few centimeters in air or micrometers in solids due to their high mass and charge, leading to rapid energy deposition through ionization.[10] Beta decay, in contrast, emits beta particles—high-energy electrons (beta-minus) or positrons (beta-plus)—with energies generally ranging from 0.1 to several MeV, though the spectrum is continuous up to a maximum value.[11] Beta particles possess moderate penetrating power, traveling tens of centimeters in air but being stopped by a few millimeters of plastic or aluminum, and they interact via ionization and bremsstrahlung radiation.[12] Gamma decay releases high-energy photons with variable energies often in the keV to MeV range, exhibiting strong penetrating ability that requires dense materials like lead for effective shielding.[13] The energy released in these decay processes transfers to surrounding materials primarily through ionization and atomic excitation, where charged particles or photons strip electrons from atoms, creating ion pairs and potentially generating heat via thermalization or charge separation in semiconductors.[14] In alpha and beta decays, the particles' interactions cause dense ionization tracks, converting kinetic energy into thermal vibrations or electron-hole pairs, while gamma rays produce secondary electrons (Compton scattering or photoelectric effect) that further ionize the medium.[9] This energy deposition is crucial for the sustained power output in atomic batteries, though the efficiency depends on the decay type and material properties. The longevity of power generation is governed by the isotope's half-life, which determines the exponential decline in decay rate. The power output at time follows , where is the initial power and is the decay constant, with being the half-life.[15] Isotopes with long half-lives, such as plutonium-238 ( years), provide relatively stable output over decades, minimizing the rate of power degradation.[16] Shielding requirements vary by decay type: alpha particles are readily stopped by thin paper or skin, beta particles by lightweight metals or plastics, and gamma rays necessitate heavy, dense absorbers like lead or concrete to attenuate penetration. At the quantum level, beta decay is described by Fermi's theory, proposed in 1934, which models the process as a weak interaction involving the emission of an electron and an antineutrino to conserve energy, momentum, and angular momentum, resolving the continuous energy spectrum observed in beta particles.[17] This theory laid the foundation for understanding weak nuclear forces without delving into detailed matrix elements or selection rules.History and Development
Early Innovations
The concept of an atomic battery originated in 1913 when British physicist Henry G. J. Moseley demonstrated the first device capable of generating electrical current from charged-particle radiation emitted by radioactive decay. Moseley's prototype, often referred to as a beta cell or radium battery, consisted of a silver-lined glass globe containing radium, generating high potentials up to approximately 150,000 volts through charge buildup from beta particles depositing on the silver lining, demonstrating the foundational principle of direct conversion from nuclear decay to electricity. This early innovation laid the groundwork for non-thermal energy harvesting from radioisotopes, though it remained experimental due to the limited availability and hazards of radium.[1][18] Practical developments accelerated in the 1950s amid the post-World War II nuclear research boom, with the invention of the first radioisotope thermoelectric generator (RTG) in 1954 by Kenneth C. Jordan and John H. Birden at the U.S. Atomic Energy Commission's Mound Laboratories. Their prototype utilized polonium-210 as a heat source to drive chromel-constantan thermocouples, producing a modest electrical output while demonstrating reliable long-term power generation for remote applications. In 1953, RCA's Paul Rappaport developed the first betavoltaic prototype employing strontium-90 to emit beta particles that generated electron-hole pairs in a semiconductor junction, yielding small-scale power suitable for devices like hearing aids and radios, with an efficiency around 0.2%; by 1954, an improved version exceeded 1%. These milestones shifted atomic batteries from theoretical curiosities to viable prototypes, focusing on both thermal and direct conversion methods.[19][20][21] The 1960s saw key applications in space exploration and medicine, exemplified by the SNAP-3 RTG, producing approximately 2.7 W, which successfully powered early U.S. satellites like Transit 4A in 1961 and validated RTG reliability in harsh environments. Larger SNAP-19 RTGs were intended for Nimbus B-1 in 1968, though the launch failed shortly after liftoff. In medicine, plutonium-238 fueled pacemakers emerged, with the Numec NU-5 model—a thermoelectric unit encapsulating a 2.5 Ci Pu-238 source—implanted in over 200 patients between 1966 and 1972, providing decade-long operation without battery replacement. Meanwhile, the Soviet Union developed the Beta-M RTG in the late 1960s and 1970s, employing strontium-90 titanate to generate 10-30 W for remote beacons and lighthouses, deploying over 1,000 units across Arctic regions by the decade's end.[22][23] Despite these innovations, early atomic batteries faced significant limitations, including conversion efficiencies below 5%, prohibitive manufacturing costs due to isotopic processing and shielding, and growing radiation safety concerns that prompted regulatory scrutiny. In medical use, these issues culminated in the phase-out of nuclear pacemakers by the early 1980s, as lithium-iodine batteries offered comparable longevity with reduced risks, though space applications persisted due to the unmatched reliability in extreme conditions.[24][25]Recent Advancements
Recent advancements in atomic batteries from 2020 to 2025 have focused on enhancing conversion efficiencies and developing novel prototypes that leverage nuclear waste and safer isotopes, addressing longstanding limitations in power output and safety. Betavoltaic devices, a primary type of atomic battery, have achieved efficiencies of 10-20% through the adoption of wide-bandgap semiconductors such as silicon carbide (SiC) and gallium nitride (GaN), which improve electron-hole pair collection and radiation resistance compared to traditional silicon-based designs.[26][27] For instance, SiC betavoltaics have demonstrated up to 14.88% efficiency under simulated beta irradiation, enabling higher energy conversion from radioisotope decay while minimizing self-absorption losses.[28] Key innovations include Infinity Power's 2024 electrochemical nuclear battery, which utilizes dissolved radioisotopes in an electrolyte to achieve high power density and up to 60% overall efficiency, surpassing conventional solid-state betavoltaics in output for compact applications.[29] In 2025, Japan's Atomic Energy Agency developed the world's first rechargeable battery from depleted uranium waste, employing uranium's redox properties in a non-aqueous system to deliver stable cycling at 1.3 V, transforming nuclear byproducts into viable energy storage with potential for renewable integration.[30] Concurrently, radiocarbon-14 (C-14) batteries emerged as a safer alternative due to their exclusive beta emissions, reducing shielding needs and enabling miniaturization for long-term, low-power devices.[31] Diamond batteries represent a significant breakthrough, with the University of Bristol producing prototypes from 2021 to 2025 that embed C-14 within synthetic diamond semiconductors, yielding lifespans exceeding 5,000 years based on the isotope's 5,730-year half-life and power outputs around 1 µW/cm². As of November 2025, ongoing commercialization efforts for these batteries continue, with prototypes demonstrating stable low-power output for potential deployment in remote sensors by 2026.[32] These devices convert beta particles directly into electricity via the diamond's wide bandgap, offering radiation-hardened, maintenance-free power for remote sensors.[33] Further progress involves 3D nanostructured designs, such as multi-groove P+PNN architectures in SiC betavoltaics, which increase surface area for beta capture and boost output by up to 50% without additional material, facilitating higher energy densities in microscale formats.[34] Market trends indicate robust growth, with the betavoltaic segment projected to reach $11.4 million by 2030, propelled by demands in space exploration and Internet of Things (IoT) devices for reliable, long-duration power.[35] Companies like City Labs are commercializing tritium-based betavoltaics, such as NanoTritium batteries, which provide microwatt-level power for decades in aerospace and medical implants.[36]Conversion Technologies
Thermal Conversion Methods
Thermal conversion methods in atomic batteries first transform the energy released from radioactive decay into heat, primarily through the absorption of alpha and gamma particles within shielding or encapsulating materials, before employing various heat-to-electricity cycles to generate power. These approaches are particularly suited for applications requiring watts-level output over extended periods, with overall system efficiencies typically ranging from 5% to 15%, limited by the Carnot efficiency ceiling and practical material constraints.[37] The most established thermal conversion technique is thermoelectric generation, which exploits the Seebeck effect at junctions formed by dissimilar semiconductor materials to produce electricity directly from a temperature gradient. In radioisotope thermoelectric generators (RTGs), heat from the radioisotope source creates a hot junction, while the cold junction is maintained by radiative cooling, generating a voltage , where is the Seebeck coefficient and is the temperature difference across the junction. Materials such as lead telluride (PbTe) for lower temperatures and silicon-germanium (SiGe) alloys for higher operating regimes (up to 1000 K) are favored for their favorable Seebeck coefficients and thermal stability in RTG designs.[38][39] Thermionic conversion represents an alternative dynamic process, where thermal energy liberates electrons from a heated cathode, allowing them to traverse a vacuum gap to a cooler anode, thereby producing current while overcoming the material's work function barrier—the energy required to escape the surface. The emitted electron current density follows the Richardson-Dushman equation:where is the Richardson constant (approximately 120 A/cm²K² for many metals), is the cathode temperature in Kelvin, is the work function in electron volts, is Boltzmann's constant, and the exponential term governs the temperature sensitivity of emission. This method has been explored for nuclear power systems due to its potential for higher efficiencies at elevated temperatures (above 1500 K), though space-charge limitations in the interelectrode gap often necessitate cesium vapor for neutralization.[40] Thermophotovoltaic (TPV) conversion bridges thermal and photonic processes by using the decay heat to drive an emitter that radiates infrared photons, which are subsequently captured and converted to electricity by specialized photovoltaic cells with bandgaps matched to the emitter's spectrum. Spectral control elements, such as photonic filters or selective emitters, enhance efficiency by recycling sub-bandgap photons and suppressing losses, enabling demonstrated module efficiencies of around 19% at emitter temperatures of 1350 K and theoretical potentials exceeding 20% under optimized conditions. InGaAsSb-based cells have shown promise for radioisotope TPV systems, offering broader spectral response than traditional silicon photovoltaics.[41][42] Stirling engine-based conversion employs a closed-cycle reciprocating heat engine, typically using helium as the working fluid due to its high thermal conductivity and low molecular weight, to cyclically expand and compress the gas between hot and cold reservoirs, producing mechanical work that drives an integrated alternator for electrical output. In advanced designs like the Advanced Stirling Radioisotope Generator (ASRG), this configuration achieves peak thermal-to-electric efficiencies of 28% to 32%, significantly outperforming traditional RTGs by reducing the required radioisotope mass by a factor of four while maintaining reliable operation over mission lifetimes exceeding a decade.[43] These thermal methods excel in reliability for demanding environments like space, where their solid-state or low-moving-part designs ensure longevity without maintenance, but they suffer from bulkier configurations compared to non-thermal alternatives and demand precise heat management to sustain the necessary temperature gradients, often via passive radiators or insulation to mitigate radiative losses.[37][39]
Non-Thermal Conversion Methods
Non-thermal conversion methods in atomic batteries directly capture energy from radioactive decay particles or photons using solid-state devices, bypassing the generation of bulk heat and enabling compact, maintenance-free power sources with outputs typically in the microwatt range and conversion efficiencies of 1-10%. These approaches, including radiovoltaic and electrostatic techniques, leverage no moving parts for reliable operation over decades, making them suitable for miniaturized applications where thermal methods would be inefficient due to heat dissipation challenges. Unlike thermal conversion, which relies on heat engines for higher power scales, non-thermal methods prioritize direct charge carrier generation or electrostatic accumulation for low-power, long-duration needs.[44][45] Betavoltaic cells represent a primary non-thermal technique, where beta particles from radioactive decay ionize a semiconductor to produce electron-hole pairs that generate current across a p-n junction. The output current can be modeled as , where is the elementary charge, is the beta particle flux spectrum, and is the charge collection efficiency dependent on particle energy . Common isotopes include tritium (half-life 12.3 years) and nickel-63 (half-life 100.1 years), which emit low-energy betas suitable for thin semiconductor layers like silicon carbide or gallium nitride to minimize self-absorption. Demonstrated efficiencies reach up to 6.6% in GaN-based devices, with power densities around 0.5 μW/cm² under optimal conditions, though radiation-induced defects can degrade performance over time by increasing leakage currents.[46][44][47][48] Alphavoltaic cells operate on a similar principle to betavoltaics but utilize high-energy alpha particles, which deposit energy over a short range (typically 10-50 μm in solids), necessitating thin dielectric or wide-bandgap semiconductor layers such as silicon carbide to capture ionization without excessive material damage. The higher particle energy (4-9 MeV) enables potentially greater power density compared to betas, but the short range limits efficiency to around 2-5% in practical devices, as much energy is lost to backscattering or non-depleted regions. For instance, a 4H-SiC p-i-n junction alphavoltaic has achieved 2.1% efficiency with americium-241 as the source, producing nanowatts in volumes under 1 cm³, ideal for extreme environments. Aluminum-doped gallium nitride variants enhance charge collection to 61.6% in the depletion region, mitigating radiation hardening issues.[49][50][51][45] Gammavoltaic conversion captures penetrating gamma photons either directly in photovoltaic materials or indirectly via scintillators that emit visible light for subsequent photovoltaic absorption, though high penetration depths reduce efficiency to below 1% in most cases due to incomplete energy deposition. Diamond-based gammavoltaics exploit surface conductivity for charge separation, yielding open-circuit voltages up to 0.5 V from cesium-137 sources, but power outputs remain in the picowatt range per cm². Scintillator-enhanced designs, such as those pairing europium-doped scintillators with silicon PV cells, improve usability for low-flux gamma emitters like cobalt-60, though overall system efficiency is constrained by the scintillator's light yield and PV quantum efficiency. In February 2025, researchers developed a prototype battery converting nuclear waste (e.g., spent fuel) into electricity via scintillator-PV conversion, demonstrating viable low-power outputs for long-term energy storage.[52][53][54] Electrostatic or direct-charging methods collect charged decay particles (alphas or betas) on insulated electrodes, building voltage across a capacitor-like structure where the potential accumulates from the particle charge divided by capacitance . This simple design, akin to a self-charging Faraday cup, was among the earliest atomic batteries, with efficiencies around 1% limited by charge recombination and insulation breakdown under high radiation. Polonium-210 or similar alpha emitters have been used to generate voltages up to 10 kV in vacuum-sealed devices, providing steady low-current discharge for sensors, though output is typically under 1 μW and requires periodic discharge to prevent arcing.[44][55] Radiophotovoltaic cells combine radioactive decay with phosphor or scintillator materials to produce photons, which are then converted to electricity via adjacent photovoltaic elements, offering flexibility for mixed radiation types. Strontium-90-based systems with waveguide scintillators like gadolinium aluminum gallium garnet (GAGG:Ce) have demonstrated efficiencies of approximately 3% by stacking multiple conversion layers to recapture escaped light, yielding microwatts from beta-induced luminescence. This indirect approach mitigates direct radiation damage to PV materials but introduces losses from phosphor quantum yield (typically 80-90%) and spectral mismatch.[56][57] These non-thermal methods excel in longevity, often matching isotope half-lives (10-100 years), but deliver low power densities (nW to μW/cm³) constrained by decay rates and material radiation tolerance, where defects like displacement damage reduce carrier lifetimes by orders of magnitude over time. Advantages include solid-state simplicity and miniaturization potential, yet challenges persist in scaling output without increasing source mass or mitigating long-term degradation through advanced materials like diamond or perovskites.[44][46][48]Radioisotopes and Materials
Common Isotopes
Atomic batteries, also known as radioisotope batteries, primarily utilize radioisotopes that undergo alpha or beta decay to generate heat or direct electrical energy through various conversion mechanisms. The selection of isotopes depends on factors such as decay energy, half-life, and radiation type, which influence power output and device longevity. Common isotopes include those with high specific power for thermal conversion and low-energy emitters for direct conversion methods like betavoltaics.[4] Plutonium-238 (Pu-238) is a prominent alpha-decaying isotope used in radioisotope thermoelectric generators (RTGs), emitting alpha particles with an average energy of about 5.5 MeV. It has a half-life of 87.7 years and provides a specific thermal power of approximately 0.56 watts per gram, making it suitable for long-duration power sources due to its high energy density and relatively manageable shielding requirements for alpha radiation. Pu-238's decay primarily produces helium nuclei, which contribute to steady heat generation without significant penetrating radiation.[58][59] Strontium-90 (Sr-90) is a beta emitter widely employed in early atomic battery designs, decaying via beta emission with a maximum energy of 0.546 MeV and an average of 0.195 MeV, followed by its daughter yttrium-90. With a half-life of 28.8 years, it offers a specific thermal power of about 0.93 watts per gram, enabling moderate power output over decades, though its higher-energy betas require careful shielding to prevent material degradation. Sr-90's availability from nuclear fission byproducts has historically supported its use in compact generators. Tritium (H-3), a low-energy beta emitter with a maximum beta energy of 18.6 keV and an average of about 5.7 keV, has a half-life of 12.3 years and a specific power of 0.32 watts per gram. Its weak beta radiation is self-absorbed in gaseous or hydride forms, allowing safe integration into betavoltaic cells without external shielding, which enhances its suitability for miniaturized, low-power devices. Tritium's short range in materials minimizes damage to semiconductors, promoting efficient direct energy conversion.[60] Nickel-63 (Ni-63) serves as a beta source in betavoltaic batteries, with a maximum beta energy of 66.9 keV and an average of 17.4 keV, and a notably long half-life of 100.1 years. It delivers a specific power of approximately 0.006 watts per gram, prioritizing longevity over high output, and its decay to stable copper-63 avoids long-term radioactive waste. Ni-63's compatibility with diamond semiconductors enables high-efficiency cells for sensors requiring sustained, maintenance-free operation.[61][4] Carbon-14 (C-14), an emerging beta emitter for diamond-based batteries, has a maximum beta energy of 156 keV and an average of 49 keV, with an exceptionally long half-life of 5,730 years. Its specific power is low at about 0.0003 watts per gram, but the isotope's integration into synthetic diamond structures allows for ultra-long-term, low-radiation energy harvesting, leveraging C-14's natural occurrence in nuclear waste for sustainable sourcing. This makes C-14 ideal for applications demanding millennia-scale durability.[33][62] Other isotopes include americium-241 (Am-241), which undergoes alpha decay with 5.486 MeV energy and emits some gamma radiation, having a half-life of 432.2 years and a specific thermal power of 0.114 watts per gram; its availability from nuclear waste positions it as a Pu-238 alternative for extended missions. Promethium-147 (Pm-147), a beta emitter with a maximum energy of 0.225 MeV and average of 0.062 MeV, features a shorter half-life of 2.623 years and specific power around 0.32 watts per gram, suiting short-to-medium-term direct conversion needs despite faster decay. Recent prototypes, such as Japan's 2025 depleted uranium-based device, explore nuclear waste like U-238 (half-life 4.468 billion years) for chemical redox batteries, though its extremely low specific power (approximately 8.4 × 10^{-9} watts per gram from alpha decay) limits it to niche, rechargeable formats rather than pure decay-driven systems.[63][64][30] The following table summarizes key properties of these isotopes, focusing on thermal specific power, half-life, and decay type for comparative context in atomic battery design:| Isotope | Decay Type | Average Decay Energy (keV) | Half-Life (years) | Specific Thermal Power (W/g) |
|---|---|---|---|---|
| Pu-238 | Alpha | 5,500 | 87.7 | 0.56 |
| Sr-90 | Beta | 196 | 28.8 | 0.93 |
| H-3 (Tritium) | Beta | 5.7 | 12.3 | 0.32 |
| Ni-63 | Beta | 17 | 100.1 | 0.006 |
| C-14 | Beta | 49 | 5,730 | 0.0003 |
| Am-241 | Alpha | 5,443 | 432.2 | 0.114 |
| Pm-147 | Beta | 62 | 2.62 | 0.32 |
| U-238 | Alpha | 4,147 | 4.468 × 10^9 | 8.4 × 10^{-9} |
Selection and Safety Considerations
When selecting radioisotopes for atomic batteries, key criteria include matching the isotope's half-life to the intended operational duration, as shorter half-lives provide higher initial power but diminish rapidly, while longer ones ensure sustained output for extended missions.[65] Power density is another critical factor, determined by the isotope's specific activity and energy per decay, with optimal choices balancing high energy output against practical constraints like availability.[66] Emission type influences suitability, particularly for implantable devices where beta emitters such as tritium or nickel-63 are preferred due to their low-energy particles, which are easier to shield and pose minimal penetration risk to tissues.[4] Cost and scarcity also factor in; for instance, plutonium-238, valued at approximately $4,000 per gram, remains limited due to complex production processes involving nuclear reactors and reprocessing.[67] Safety in atomic battery design emphasizes features that minimize radiation exposure, such as self-absorption of beta particles within solid matrices like tritium-loaded titanium, where the metal hydride structure captures most emissions internally to reduce external flux.[68] Encapsulation in robust materials, such as quartz cells, further prevents isotopic leaching and containment breach over the device's lifespan.[69] Radiation dose limits are strictly enforced, with designs for medical implants like pacemakers targeting less than 1 mSv per year to the patient, aligning with public exposure standards and ensuring negligible health risks.[70] Shielding requirements vary by emission; for gamma-emitting isotopes, high-density materials like tungsten or lead are used, with tungsten offering equivalent protection at one-third the thickness of lead due to its higher atomic number and density.[71] Biological shielding adheres to International Commission on Radiological Protection (ICRP) guidelines, which recommend dose constraints below 1 mSv annually for the public and optimized protection for workers through layered barriers that attenuate radiation while minimizing material mass.[72] Environmental considerations focus on end-of-life management, treating depleted atomic batteries as low-level radioactive waste for secure disposal in licensed facilities to prevent soil or water contamination.[73] As of 2025, advancements in batteries utilizing recyclable isotopes from nuclear waste—such as prototypes converting ambient gamma radiation from spent fuel—offer reduced environmental footprints by repurposing existing materials, thereby lowering proliferation risks associated with fresh isotope production.[74] Regulatory oversight ensures safe deployment; in the United States, the Nuclear Regulatory Commission (NRC) approves possession and use of radioisotopes for medical and space applications under 10 CFR Part 35, while the Food and Drug Administration (FDA) evaluates integrated devices for biocompatibility and performance.[75] Certain isotopes face bans or exemptions in consumer products to mitigate unintended exposure, with NRC regulations prohibiting unlicensed distribution of high-activity sources like plutonium-238 outside controlled sectors.[76]Applications
Space Exploration
Atomic batteries, primarily in the form of radioisotope thermoelectric generators (RTGs), have played a pivotal role in space exploration by delivering consistent power and heat to spacecraft operating far from the Sun, where solar arrays are ineffective due to low light intensity. These devices convert the decay heat of plutonium-238 (Pu-238) into electricity through thermoelectric materials, enabling long-duration missions in the outer solar system and on planetary surfaces. Pu-238 is the standard isotope for such systems because its alpha decay produces substantial thermal energy—approximately 0.56 watts per gram—while also serving as a reliable heat source to maintain operational temperatures in cryogenic environments.[77] Early innovations in the United States included the SNAP-19 RTG, which powered the Nimbus III meteorological satellite launched in 1969, marking one of the first orbital uses of radioisotope power for continuous operation. This system provided about 28 watts of electricity, demonstrating the feasibility of RTGs for sustained satellite functions beyond solar limitations. In the Soviet Union, the Lunokhod rovers of the 1970s, including Lunokhod 1 (1970) and Lunokhod 2 (1973), incorporated radioisotope heater units to survive the extreme cold of lunar nights, though their primary power came from solar panels; these heaters used polonium-210 to generate warmth, supporting mobility across 10.5 km and 37 km respectively over multiple lunar days. NASA's Voyager missions, launched in 1977, utilized three Multi-Hundred Watt RTGs (MHW-RTGs) fueled by Pu-238, each delivering 158 watts at mission start for a total of 470 watts to power instruments and communication during their journey to the outer planets; as of 2025, the Voyagers remain operational after nearly 48 years, with power output declined to about 240 watts due to isotope decay. The Cassini mission to Saturn (1997–2017) employed three General Purpose Heat Source RTGs (GPHS-RTGs), providing 888 watts initially to support propulsion, scientific instruments, and the Huygens probe's descent to Titan.[78][79][77][80] More recent applications highlight RTGs' adaptability to rover missions on Mars, where dust storms and variable sunlight pose challenges. The Perseverance rover, landed in 2021, is powered by a Multi-Mission RTG (MMRTG) that generates 110 watts of electricity at launch, sufficient for driving the rover up to 200 meters per hour, operating instruments like the MOXIE oxygen generator, and collecting samples for future return. This power level aligns with typical spacecraft requirements of 100–300 watts for propulsion, avionics, and science payloads in deep space or shadowed regions. RTGs excel in these scenarios by operating reliably in the vacuum of space and temperatures as low as -200°C, independent of sunlight, with a conversion efficiency of approximately 7% that prioritizes longevity over high output.[81][82][83] NASA's Artemis program, which seeks to establish a sustainable human presence on the Moon, includes requirements for advanced radioisotope power systems (RPS) to support lunar surface operations, particularly in permanently shadowed regions where solar power is insufficient. The Harmonia-RPS, under development as of 2025, utilizes Stirling convertors for improved efficiency, providing reliable electricity and heat for habitats, rovers, and scientific instruments in the harsh lunar environment.[84] Ongoing challenges include the limited supply of Pu-238, which has constrained mission planning; for instance, production shortfalls delayed aspects of outer planet explorations and influenced decisions like the Europa Clipper mission, launched in October 2024, which opted for large solar arrays providing about 850 watts instead of an MMRTG to conserve the isotope for higher-priority deep-space targets. Despite these hurdles, RTGs' proven reliability—evidenced by over 24 successful NASA missions—continues to make them indispensable for future endeavors, such as the Dragonfly rotorcraft to Titan, underscoring their role in enabling discovery in harsh, unlit cosmic frontiers.[85][86][87]Medical Devices
Atomic batteries have played a significant role in the evolution of implantable medical devices, particularly cardiac pacemakers, by providing long-lasting power sources that reduce the need for frequent surgical interventions. In the 1960s and 1970s, nuclear-powered pacemakers utilizing plutonium-238 (Pu-238) or promethium-147 (Pm-147) were developed to address the short lifespan of conventional mercury-zinc batteries, which typically lasted only 2-3 years. Companies such as Medtronic produced models like the Xyratex, which incorporated a 2.5 Ci slug of Pu-238 in a thermoelectric generator design, offering an expected operational life of up to 10-20 years due to Pu-238's 87.7-year half-life, while Pm-147-based units provided shorter 2-5 year lifespans owing to its 2.62-year half-life. These devices were implanted in thousands of patients worldwide between 1970 and the early 1980s, marking a pioneering application of radioisotope power in biomedicine.[88][89][90] Despite their reliability, these early atomic pacemakers faced regulatory hurdles that led to their phase-out by the late 1980s. Rare incidents, such as explosions during cremation in the mid-1970s—attributed to hydrogen gas buildup in non-nuclear models but raising broader safety concerns for radioisotope devices—prompted intensified FDA scrutiny and eventual bans on new implants in several countries. The emergence of lithium-iodine batteries, which offered comparable 10+ year lifespans without radiological risks, further accelerated the transition. Nonetheless, the historical use of Pu-238 and Pm-147 units demonstrated the feasibility of atomic power for low-energy medical implants, paving the way for safer modern iterations.[91][92][90] Contemporary advancements focus on betavoltaic atomic batteries using tritium or nickel-63 (Ni-63) isotopes, which promise 10-20 year or longer operational lives for implantable devices like pacemakers, insulin pumps, and neural stimulators. As of 2025, Betavolt has begun mass production of the BV100, a coin-sized Ni-63 betavoltaic cell, for integration into cardiac and drug delivery implants, leveraging Ni-63's 100-year half-life to deliver stable microwatt-level power without thermal components. These devices emphasize miniaturization, with volumes around 1 cm³ and outputs of 10-100 µW, encapsulated in biocompatible titanium or diamond-like coatings to ensure durability and prevent leakage. Radiation exposure from such systems remains below natural body background levels, primarily beta particles contained within the semiconductor structure.[4][93] The primary advantages of betavoltaic atomic batteries over traditional lithium-based ones include eliminating periodic replacement surgeries, which carry infection and recovery risks, and enabling reliable operation in remote or underserved regions where follow-up care is limited. For instance, a 20-year tritium betavoltaic could power a neural stimulator for chronic pain management without intervention, enhancing patient quality of life. However, ongoing challenges involve navigating stringent FDA regulations shaped by past nuclear incidents, requiring extensive biocompatibility testing and proof of negligible radiological impact to gain approval for widespread clinical use.[94][95]Remote Sensing and Other Uses
Atomic batteries have found applications in remote sensing, where their long operational lifespans enable continuous monitoring in inaccessible or harsh terrestrial environments without frequent maintenance. For instance, tritium-based betavoltaic devices power sensors deployed in oil wells to detect leaks and monitor conditions over extended periods, leveraging the isotope's 12.3-year half-life for reliable, unattended operation.[61] Similarly, these batteries support structural health monitoring systems on bridges and buildings, providing power for seismic detectors and strain gauges that track vibrations and integrity for up to 20 years, enhancing safety in earthquake-prone areas.[96] Advancements in the 2020s have led to nanoscale atomic batteries, particularly those using nickel-63 (Ni-63) isotopes, which offer volumes under 1 mm³ and suit integration into Internet of Things (IoT) devices and wearables. These micro-batteries deliver continuous microwatt-level power, enabling long-term data collection in environmental sensors without recharging, and their compact design facilitates embedding in smart textiles or remote monitoring nodes. City Labs' NanoTritium batteries exemplify this trend with a 100 µW output from tritium decay, supporting over 20 years of operation in low-power IoT applications like autonomous sensor networks.[36][97] In military and oceanic contexts, atomic batteries power underwater buoys and sensors for persistent surveillance, where traditional batteries fail due to corrosion or inaccessibility. These devices, often betavoltaic, provide stable microwatt power for acoustic monitoring and navigation aids in subsea environments, enduring extreme pressures and temperatures for decades. In contrast to space exploration applications like those in NASA's Artemis program, which require RPS for vacuum and radiation extremes, terrestrial uses such as deep-sea sensors and remote defense outposts leverage atomic batteries for similarly inaccessible locations on Earth, enabling long-term operations without resupply in harsh conditions like deep ocean depths or isolated military bases.[98][99] For drones, nuclear batteries enable extended missions in remote areas, scaling to higher outputs when paired with energy storage like capacitors to handle intermittent loads.[4] Beyond sensing, atomic batteries serve remote telecommunications infrastructure, powering repeaters and relays in isolated regions where grid access is limited, ensuring reliable signal transmission over lifetimes exceeding 15 years.[100] Power outputs typically range from nanowatts for microsensors to around 100 µW for more demanding remote nodes, with integration into hybrid systems allowing burst operations via capacitors.[101]Challenges and Prospects
Technical Limitations
Atomic batteries, encompassing both thermal and non-thermal conversion methods, face significant efficiency constraints rooted in the physics of radioactive decay and energy conversion processes. In non-thermal betavoltaic designs, power conversion efficiencies typically range from 0.1% to 3.6%, limited by the fact that over 90% of the beta particle energy is dissipated as heat rather than being captured for electrical output, with theoretical upper limits of 5% to 30% depending on the semiconductor bandgap matching the beta spectrum.[102] Thermal radioisotope thermoelectric generators (RTGs) achieve slightly higher efficiencies of 3% to 7%, constrained by the Carnot efficiency of the temperature differential across thermoelectric materials like PbTe or SiGe, where the figure of merit (ZT) rarely exceeds 1.0 under operational conditions.[103] Additionally, radiation-induced defects, such as displacement damage in semiconductor lattices from beta particle bombardment, further degrade performance by creating recombination centers that reduce carrier lifetime and open-circuit voltage.[104][105] Power output in atomic batteries diminishes over time due to the natural decay of the radioisotope fuel and physical changes in structural materials. For RTGs using plutonium-238, the inherent decay rate contributes approximately 0.8% annual power loss, compounded by 1% or more from thermoelectric material degradation, resulting in a total fade of 1% to 2% per year.[106][107] In betavoltaic systems, isotope half-lives dictate longer-term fade—such as 12.3 years for tritium—but material swelling from radiation-induced atomic displacement and helium accumulation in alpha-emitting designs exacerbates contact resistance and structural integrity issues.[108] Scalability poses engineering challenges, as achieving higher power outputs demands proportionally larger quantities of radioactive material, increasing overall mass and volume. For instance, a standard GPHS-RTG delivering 300 W electrical requires about 40 kg, including the heat source and conversion elements, yielding a specific power of roughly 5 W/kg at beginning-of-life.[103] Miniaturization for low-power applications, such as microdevices, is hindered by shielding requirements; while low-energy beta emitters like tritium need minimal encapsulation, higher-activity sources necessitate thicker barriers to contain radiation, limiting device size below 1 cm³ for outputs under 1 mW without compromising safety margins.[4] Non-thermal atomic batteries, despite avoiding bulk heat engines, still generate localized heat from inefficient energy capture, complicating thermal management in compact enclosures. This residual heat flux, governed by Fourier's law as , where is the heat flux, the thermal conductivity, and the temperature gradient, can elevate junction temperatures beyond 100°C, reducing semiconductor efficiency and accelerating defect formation unless dissipated via conductive substrates or microchannel cooling.[102] Durability assessments for atomic batteries rely on accelerated simulations to predict performance over decades, as real-time testing is impractical. Long-term evaluations, such as 50-year irradiation equivalents, confirm stable operation with minimal self-discharge—negligible compared to chemical batteries due to the absence of electrochemical reactions—but highlight contact degradation from radiation embrittlement and oxidation at interfaces, potentially increasing internal resistance by 10-20% over 20 years.[109][56]Regulatory and Environmental Issues
The deployment of atomic batteries is governed by rigorous international and domestic regulations aimed at preventing misuse of radioactive materials and ensuring public safety. The International Atomic Energy Agency (IAEA) provides comprehensive safety standards and a code of conduct for the import and export of radioactive sources, including those used in radioisotope power systems, to establish a harmonized global control regime that minimizes risks during transboundary movements.[110] In the United States, the Nuclear Regulatory Commission (NRC) enforces controls under 10 CFR Part 110, requiring specific licenses for the export and import of fissile materials like plutonium-238 (Pu-238), with quantity limits and end-use verification to restrict transfers to authorized entities such as space agencies.[111] Exports of Pu-238, primarily for radioisotope thermoelectric generators (RTGs) in space missions, face additional scrutiny from the Department of Energy and international agreements to curb proliferation, often necessitating multilateral approvals even for cooperative programs.[112] For medical implants incorporating atomic batteries, such as historical nuclear-powered pacemakers, the Food and Drug Administration (FDA) classifies them as Class III devices, subjecting them to premarket approval processes due to their life-sustaining function and potential for serious adverse health effects.[113] Environmental issues primarily involve the management of low-level radioactive waste from decommissioned batteries and the risks of accidental releases during launch or operation. A key historical example is the 1964 SNAP-9A satellite failure, where approximately 1 kg of Pu-238 from its RTG re-entered the atmosphere and dispersed globally through high-altitude winds, contributing to background plutonium levels across continents. Assessments of this event, including soil sampling programs, have shown negligible long-term ecological or human health impacts, as the insoluble plutonium oxide form limited bioavailability and uptake in the food chain.[114][115] Modern disposal protocols treat atomic battery waste as low-level radioactive material, requiring secure encapsulation and burial in licensed facilities to prevent leaching into soil or water, with ongoing monitoring to ensure compliance with environmental protection standards.[116] Proliferation concerns drive the selection of isotopes for atomic batteries, favoring non-fissile options like carbon-14 (C-14) and tritium, which cannot be used in nuclear weapons, over Pu-238, which, despite being non-weapons-grade itself, is derived from processes linked to fissile material production. C-14, extracted from nuclear reactor graphite waste, offers a proliferation-resistant alternative for betavoltaic cells, as its beta emissions provide power without posing diversion risks. Advancements in waste recycling, such as the September 2025 agreement between Orano and Zeno Power to recover americium-241 from spent nuclear fuel for space-grade batteries, further mitigate proliferation by repurposing existing stockpiles and reducing demands for virgin isotope production.[117][118][119] Public perception of atomic batteries remains challenged by the broader stigma surrounding nuclear technologies, fueled by memories of accidents like Chernobyl and concerns over radiation exposure, which often amplify perceived risks beyond scientific assessments. To address this stigma, modern RTGs incorporate multi-layer containment systems, such as plutonium dioxide in ceramic form encased in iridium cladding and graphite impact shells, designed to survive potential launch and re-entry accidents intact, and utilize non-weaponizable fuels like plutonium-238, which cannot be used in nuclear weapons due to its high spontaneous fission rate and isotopic composition unsuitable for explosive yields.[120] This stigmatization manifests in opposition to deployments, even for beneficial uses like remote medical devices, despite evidence from surveys indicating growing acceptance when framed around clean energy benefits. Risk analyses for RTG-equipped missions, such as NASA's Perseverance rover, estimate the probability of a Pu-238 release at about 1 in 960 (0.1%), with modeled outcomes showing no exceedance of safety thresholds for public health or environmental contamination.[121][122] Ethical barriers include ensuring equitable access to atomic battery-enabled technologies, particularly in space exploration and medical implants, where high development and production costs limit availability to wealthy nations or programs, potentially widening global disparities in life-saving applications. Principles of justice in space bioethics underscore the need for inclusive policies to distribute benefits from nuclear-powered devices fairly, avoiding exclusion of underrepresented populations from advancements in long-duration missions or implantable therapies.[123][124]Future Innovations
Researchers are exploring hybrid atomic battery designs that integrate radioisotope generators with solar or lithium-ion systems to provide variable power output, particularly for space applications. For instance, a proposed hybrid microgrid combining nuclear, photovoltaic, and battery components has been developed for Mars areostationary orbit missions, enabling resilient power management in variable solar conditions expected in future explorations around 2030.[125] Advancements in materials science are focusing on enhancements like graphene and diamond structures to improve efficiency in betavoltaic cells. Reduced graphene oxide/silicon heterojunctions have demonstrated potential for higher conversion efficiencies in beta-particle harvesting, with theoretical models suggesting optimizations that could exceed current benchmarks. Similarly, diamond-based batteries incorporating carbon-14 doping offer long-term stability, while carbon nanotube-modified structures, such as TiO2 nanotubes with ZrO2 nanoparticles, have achieved energy conversion efficiencies up to 9.27% in nuclear battery prototypes.[126][62][127] In March 2025, researchers at South Korea's Daegu Gyeongbuk Institute of Science and Technology (DGIST) developed a prototype atomic battery using carbon-14 embedded in titanium dioxide semiconductors, providing stable power from beta decay for applications like medical implants and remote sensors.[128] Emerging applications for atomic batteries include powering swarm robotics, deep-sea explorers, and climate sensors, where long-duration energy is critical. NanoTritium batteries are suited for deep-sea deployments due to their thermal resilience and durability under extreme pressures. In consumer contexts, prototypes like the Betavolt BV100, which provides 100 microwatts at 3 volts for up to 50 years, target low-power applications in aerospace, medical devices, and micro-robots.[129][130] Furthermore, in the context of the emerging lunar economy, reliable power sources like atomic batteries are positioning power as an investable "frontier asset class," with projections estimating the lunar market to reach around $170 billion by 2040.[131] Ongoing research targets cost reductions to below $1,000 per unit and employs AI for optimizing isotope doping to achieve uniform decay rates. Parametric studies indicate that levelized costs for nuclear batteries could reach 20–50 USD/MWht for heat and 70–115 USD/MWhe for electricity, making them competitive in large markets through material and design efficiencies. AI-driven models at the atomic scale are enhancing battery performance by predicting optimal doping configurations for improved ion diffusion and stability.[132][133]References
- https://science.[nasa](/page/NASA).gov/planetary-science/programs/radioisotope-power-systems/power-radioisotope-thermoelectric-generators/
