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Electrical conductor
Electrical conductor
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Overhead conductors carry electric power from generating stations to customers.

In physics and electrical engineering, a conductor is an object or type of material that allows the flow of charge (electric current) in one or more directions. Materials made of metal are common electrical conductors. The flow of negatively charged electrons generates electric current, positively charged holes, and positive or negative ions in some cases.

In order for current to flow within a closed electrical circuit, one charged particle does not need to travel from the component producing the current (the current source) to those consuming it (the loads). Instead, the charged particle simply needs to nudge its neighbor a finite amount, who will nudge its neighbor, and on and on until a particle is nudged into the consumer, thus powering it. Essentially what is occurring is a long chain of momentum transfer between mobile charge carriers; the Drude model of conduction describes this process more rigorously. This momentum transfer model makes metal an ideal choice for a conductor; metals, characteristically, possess a delocalized sea of electrons which gives the electrons enough mobility to collide and thus affect a momentum transfer.

As discussed above, electrons are the primary mover in metals; however, other devices such as the cationic electrolyte(s) of a battery, or the mobile protons of the proton conductor of a fuel cell rely on positive charge carriers. Insulators are non-conducting materials with few mobile charges that support only insignificant electric currents.

Resistance and conductance

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A piece of resistive material with electrical contacts on both ends

The resistance of a given conductor depends on the material it is made of, and on its dimensions. For a given material, the resistance is inversely proportional to the cross-sectional area.[1] For example, a thick copper wire has lower resistance than an otherwise-identical thin copper wire. Also, for a given material, the resistance is proportional to the length; for example, a long copper wire has higher resistance than an otherwise-identical short copper wire. The resistance R and conductance G of a conductor of uniform cross section, therefore, can be computed as[1]

where is the length of the conductor, measured in metres [m], A is the cross-section area of the conductor measured in square metres [m2], σ (sigma) is the electrical conductivity measured in siemens per meter (S·m−1), and ρ (rho) is the electrical resistivity (also called specific electrical resistance) of the material, measured in ohm-metres (Ω·m). The resistivity and conductivity are proportionality constants, and therefore depend only on the material the wire is made of, not the geometry of the wire. Resistivity and conductivity are reciprocals: . Resistivity is a measure of the material's ability to oppose electric current.

This formula is not exact: It assumes the current density is totally uniform in the conductor, which is not always true in practical situation. However, this formula still provides a good approximation for long thin conductors such as wires.

Another situation this formula is not exact for is with alternating current (AC), because the skin effect inhibits current flow near the center of the conductor. Then, the geometrical cross-section is different from the effective cross-section in which current actually flows, so the resistance is higher than expected. Similarly, if two conductors are near each other carrying AC current, their resistances increase due to the proximity effect. At commercial power frequency, these effects are significant for large conductors carrying large currents, such as busbars in an electrical substation,[2] or large power cables carrying more than a few hundred amperes.

Aside from the geometry of the wire, temperature also has a significant effect on the efficacy of conductors. Temperature affects conductors in two main ways, the first is that materials may expand under the application of heat. The amount that the material will expand is governed by the thermal expansion coefficient specific to the material. Such an expansion (or contraction) will change the geometry of the conductor and therefore its characteristic resistance. However, this effect is generally small, on the order of 10−6. An increase in temperature will also increase the number of phonons generated within the material. A phonon is essentially a lattice vibration, or rather a small, harmonic kinetic movement of the atoms of the material. Much like the shaking of a pinball machine, phonons serve to disrupt the path of electrons, causing them to scatter. This electron scattering will decrease the number of electron collisions and therefore will decrease the total amount of current transferred.

Conductor materials

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Material ρ [Ω·m] at 20 °C σ [S/m] at 20 °C
Silver, Ag 1.59 × 10−8 6.30 × 107
Copper, Cu 1.68 × 10−8 5.96 × 107
Aluminum, Al 2.82 × 10−8 3.50 × 107

Conduction materials include metals, electrolytes, superconductors, semiconductors, plasmas and some nonmetallic conductors such as graphite and conductive polymers.

Copper has a high conductivity. Annealed copper is the international standard to which all other electrical conductors are compared; the International Annealed Copper Standard conductivity is 58 MS/m, although ultra-pure copper can slightly exceed 101% IACS. The main grade of copper used for electrical applications, such as building wire, motor windings, cables and busbars, is electrolytic-tough pitch (ETP) copper (CW004A or ASTM designation C100140). If high conductivity copper must be welded or brazed or used in a reducing atmosphere, then oxygen-free high conductivity copper (CW008A or ASTM designation C10100) may be used.[3] Because of its ease of connection by soldering or clamping, copper is still the most common choice for most light-gauge wires.

Silver is 6% more conductive than copper, but due to cost it is not practical in most cases. However, it is used in specialized equipment, such as satellites, and as a thin plating to mitigate skin effect losses at high frequencies. Famously, 14,700 short tons (13,300 t) of silver on loan from the United States Treasury were used in the making of the calutron magnets during World War II due to wartime shortages of copper.[4]

Aluminum wire is the most common metal in electric power transmission and distribution. Although only 61% of the conductivity of copper by cross-sectional area, its lower density makes it twice as conductive by mass. As aluminum is roughly one-third the cost of copper by weight, the economic advantages are considerable when large conductors are required.

The disadvantages of aluminum wiring lie in its mechanical and chemical properties. It readily forms an insulating oxide, making connections heat up. Its larger coefficient of thermal expansion than the brass materials used for connectors causes connections to loosen. Aluminum can also "creep", slowly deforming under load, which also loosens connections. These effects can be mitigated with suitably designed connectors and extra care in installation, but they have made aluminum building wiring unpopular past the service drop.

Very few organic compounds conduct electricity. For example, hydrocarbon oils, such as octane, are a common transformer insulator. Typical organic compounds do not conduct because they lack charge carriers. They are uncharged molecules, unable to perform ionic conduction; and their electrons are imperturbable at low energy, localized to relatively inert covalent bonds. Rare organic conductors arise from a failure of either condition: certain ionic liquids conduct through ion transport and conductive polymers delocalize a substantial portion of their electrons in a π system.

While pure water is not an electrical conductor, even a small portion of ionic impurities, such as salt, can rapidly transform it into a conductor.

Wire size

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Wires are measured by their cross sectional area. In many countries, the size is expressed in square millimetres. In North America, conductors are measured by American wire gauge for smaller ones, and circular mils for larger ones.

Conductor ampacity

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The ampacity of a conductor, that is, the amount of current it can carry, is related to its electrical resistance: a lower-resistance conductor can carry a larger value of current. The resistance, in turn, is determined by the material the conductor is made from (as described above) and the conductor's size. For a given material, conductors with a larger cross-sectional area have less resistance than conductors with a smaller cross-sectional area.

For bare conductors, the ultimate limit is the point at which power lost to resistance causes the conductor to melt. Aside from fuses, most conductors in the real world are operated far below this limit, however. For example, household wiring is usually insulated with PVC insulation that is only rated to operate to about 60 °C, therefore, the current in such wires must be limited so that it never heats the copper conductor above 60 °C, causing a risk of fire. Other, more expensive insulation such as Teflon or fiberglass may allow operation at much higher temperatures.

Isotropy

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If an electric field is applied to a material, and the resulting induced electric current is in the same direction, the material is said to be an isotropic electrical conductor. If the resulting electric current is in a different direction from the applied electric field, the material is said to be an anisotropic electrical conductor.

See also

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Classification of materials based on permittivity
εr/εr Current conduction Field propagation
0 perfect dielectric
lossless medium
low-conductivity material
poor conductor
low-loss medium
good dielectric
lossy conducting material lossy propagation medium
high-conductivity material
good conductor
high-loss medium
poor dielectric
perfect conductor

References

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Further reading

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Revisions and contributorsEdit on WikipediaRead on Wikipedia
from Grokipedia
An electrical conductor is a substance that permits the flow of through it relatively freely, primarily due to the presence of unbound free electrons or ions that can move under an applied . In such materials, charge carriers like electrons in solids or ions in liquids migrate, enabling the transmission of while encountering minimal opposition from the atomic structure. Electrical conductors are broadly categorized into types based on their composition and behavior: metallic conductors, such as and silver, which rely on delocalized valence electrons for conduction; electrolytic conductors, like saltwater solutions, where ions serve as charge carriers; and semiconductors, which exhibit intermediate conductivity that can be modulated by doping or . Notable examples of highly conductive metals include silver (the best conductor at ), (widely used in wiring due to its balance of conductivity and cost), ( prized for corrosion resistance), and aluminum (common in lines). Superconductors represent an extreme case, achieving zero electrical resistance below a critical , as seen in materials like mercury or high-temperature ceramics, though they require cryogenic conditions for practical use. Key properties of electrical conductors include electrical conductivity (measured in siemens per meter, quantifying ease of charge flow) and resistivity (its inverse, indicating opposition to current), both influenced by factors such as material purity, , and structure—conductivity typically decreases with rising in metals due to increased . These properties make conductors essential in applications ranging from power distribution and to electrochemical processes, where they facilitate efficient energy transfer without significant loss.

Fundamentals

Definition and principles

An electrical conductor is a substance that permits the flow of with minimal opposition, primarily due to the presence of free electrons that can move relatively freely through the material. Typically, these are metals where valence electrons are delocalized, enabling efficient charge transport under an applied . In contrast, insulators exhibit tightly bound electrons that resist charge movement, while semiconductors occupy an intermediate state with conductivity modulated by factors like or doping. In electrical circuits, conductors serve as essential pathways for the directed movement of electrons, forming components such as wires and busbars that connect power sources to loads in devices ranging from simple batteries to . This role ensures the completion of the circuit, allowing current to flow and enabling the conversion of into other forms, such as or motion, while preventing unintended leakage that insulators help to avoid. The fundamental physics of conduction in metals is described by the , where valence electrons behave as a gas of non-interacting particles within a lattice of positive ions, drifting under an to produce current. In this classical framework, electrons accelerate between collisions with lattice ions, resulting in a net proportional to the field strength, which underpins the material's ability to carry charge. Resistivity, a key material property, arises from these scattering events and quantifies the opposition to flow. Early observations of electrical phenomena trace back to around 600 BCE, when noted that rubbed amber could attract lightweight objects, hinting at charge effects without understanding conduction. This evolved in 1600 with William Gilbert's systematic experiments on electrification, distinguishing electrical attraction from and laying groundwork for later theories by demonstrating conduction in various substances. These insights culminated in the with Georg Simon Ohm's empirical relation, stating that the voltage drop across a conductor equals the product of current and resistance (V = IR), providing a foundational principle for analyzing conductive behavior.

Conductivity and resistivity

Electrical conductivity, denoted by the symbol σ, is a measure of a material's ability to conduct , quantifying how easily free electrons or ions can move under an applied . In the of metals, conductivity arises from the drift of conduction electrons and is given by the equation σ = n e μ, where n is the (number of free electrons per unit volume), e is the , and μ is the (average per unit electric field strength). The SI unit of conductivity is the siemens per meter (S/m), reflecting its role as a material-specific property that determines J = σ E, where E is the . Electrical resistivity, denoted by ρ, is the reciprocal of conductivity, defined as ρ = 1/σ, and represents the intrinsic opposition of a material to the flow of . Its SI unit is the ohm-meter (Ω·m), a measure that normalizes resistance to account for material properties alone. Resistivity exhibits a strong dependence in most conductors, particularly metals, where it increases with rising due to enhanced lattice vibrations charge carriers; this is approximated by the ρ(T) = ρ₀ (1 + α ΔT), with ρ₀ as the resistivity at a reference , α as the of resistivity (typically positive for metals, around 0.0039 K⁻¹ for ), and ΔT as the change. Resistivity values are influenced by factors such as , which modulates , and impurities or defects, which introduce additional sites that elevate ρ beyond the pure baseline. For precise of resistivity, especially in thin films or bulk samples, the four-point probe technique is widely used; it involves passing a known current through two outer probes while measuring the across two inner probes, thereby eliminating errors and yielding accurate sheet or bulk resistivity via geometric correction factors. This method adheres to SI standards and is essential for applications requiring high precision, such as . Unlike resistance, which depends on a conductor's dimensions ( and cross-sectional area), resistivity is a bulk intrinsic property independent of , allowing direct comparison across materials regardless of sample shape; this stems from its definition as the resistance of a unit cube of the material under unit field conditions. The following table compares room-temperature (20°C) resistivity values for selected common metallic conductors, highlighting silver's superior performance:
MaterialResistivity (Ω·m) at 20°C
Silver1.59 × 10⁻⁸
1.68 × 10⁻⁸
2.44 × 10⁻⁸
Aluminum2.65 × 10⁻⁸
Iron9.71 × 10⁻⁸
These values underscore why silver and dominate electrical applications, with differences arising from and scattering rates.

Electrical Properties

Resistance and conductance

In electrical circuits, resistance represents the total opposition to the flow of through a conductor, quantified by the R=ρLAR = \rho \frac{L}{A}, where ρ\rho is the resistivity of the material, LL is the length of the conductor, and AA is its cross-sectional area. This relationship arises from , V=IRV = IR, combined with the material's intrinsic properties, and it scales directly with length while inversely with area, meaning longer or thinner conductors exhibit higher resistance./University_Physics_II_-Thermodynamics_Electricity_and_Magnetism(OpenStax)/09%3A_Current_and_Resistance/9.02%3A_Resistivity_and_Resistance) Microscopically, resistance derives from the J=σE\vec{J} = \sigma \vec{E}
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