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Isotopes of sulfur
Isotopes of sulfur
Isotopes of sulfur
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Isotopes of sulfur (16S)
Main isotopes[1] Decay
Isotope abun­dance half-life (t1/2) mode pro­duct
32S 94.8% stable
33S 0.760% stable
34S 4.37% stable
35S trace 87.37 d β− 35Cl
36S 0.02% stable
34S abundances vary greatly (between 3.96 and 4.77 percent) in natural samples.
Standard atomic weight Ar°(S)

Sulfur (16S) has 23 known isotopes with mass numbers ranging from 27 to 49, four of which are stable: 32S (94.85%), 33S (0.76%), 34S (4.37%), and 36S (0.016%). The preponderance of sulfur-32 is explained by its production from carbon-12 plus successive fusion capture of five helium-4 nuclei in the alpha process of nucleosynthesis.

The main radioisotope 35S is formed from cosmic ray spallation of 40Ar in the atmosphere. Other radioactive isotopes of sulfur are all comparatively short-lived. The next longest-lived radioisotope is sulfur-38, with a half-life of 170 minutes. Isotopes lighter than 32S mostly decay to isotopes of phosphorus or silicon, while 35S and heavier radioisotopes decay to isotopes of chlorine.

The beams of several radioactive isotopes (such as those of 44S) have been studied theoretically within the framework of the synthesis of superheavy elements, especially those ones in the vicinity of island of stability.[4][5]

When sulfide minerals are precipitated, isotopic equilibration among solids and liquid may cause small differences in the δ34S values of co-genetic minerals. The differences between minerals can be used to estimate the temperature of equilibration. The δ13C and δ34S of coexisting carbonates and sulfides can be used to determine the pH and oxygen fugacity of the ore-bearing fluid during ore formation.[citation needed]

In most forest ecosystems, sulfate is derived mostly from the atmosphere; weathering of ore minerals and evaporites also contribute some sulfur. Sulfur with a distinctive isotopic composition has been used to identify pollution sources, and enriched sulfur has been added as a tracer in hydrologic studies. Differences in the natural abundances can also be used in systems where there is sufficient variation in the 34S of ecosystem components. Rocky Mountain lakes thought to be dominated by atmospheric sources of sulfate have been found to have different δ34S values from oceans believed to be dominated by watershed sources of sulfate.[citation needed]

List of isotopes

[edit]


Nuclide
[n 1] 		Z N Isotopic mass (Da)[6]
[n 2][n 3] 		Half-life[1]
 Decay
mode[1]
[n 4] 		Daughter
isotope
[n 5] 		Spin and
parity[1]
[n 6][n 7] 		Natural abundance (mole fraction)
Excitation energy Normal proportion[1] Range of variation
27S 16 11 27.01878(43)# 16.3(2) ms β+, p (61%) 26Si (5/2+)
β+ (36%) 27P
β+, 2p (3.0%) 25Al
28S 16 12 28.00437(17) 125(10) ms β+ (79.3%) 28P 0+
β+, p (20.7%) 27Si
29S 16 13 28.996678(14) 188(4) ms β+ (53.6%) 29P 5/2+#
β+, p (46.4%) 28Si
30S 16 14 29.98490677(22) 1.1798(3) s β+ 30P 0+
31S 16 15 30.97955700(25) 2.5534(18) s β+ 31P 1/2+
32S[n 8] 16 16 31.9720711735(14) Stable 0+ 0.9485(255)
33S 16 17 32.9714589086(14) Stable 3/2+ 0.00763(20)
34S 16 18 33.967867011(47) Stable 0+ 0.04365(235)
35S 16 19 34.969032321(43) 87.37(4) d β− 35Cl 3/2+ Trace[n 9]
36S 16 20 35.96708069(20) Stable 0+ 1.58(17)×10−4
37S 16 21 36.97112550(21) 5.05(2) min β− 37Cl 7/2−
38S 16 22 37.9711633(77) 170.3(7) min β− 38Cl 0+
39S 16 23 38.975134(54) 11.5(5) s β− 39Cl (7/2)−
40S 16 24 39.9754826(43) 8.8(22) s β− 40Cl 0+
41S 16 25 40.9795935(44) 1.99(5) s β− 41Cl 7/2−#
42S 16 26 41.9810651(30) 1.016(15) s β− (>96%) 42Cl 0+
β−, n (<1%) 41Cl
43S 16 27 42.9869076(53) 265(13) ms β− (60%) 43Cl 3/2−
β−, n (40%) 42Cl
43mS 320.7(5) keV 415.0(26) ns IT 43S (7/2−)
44S 16 28 43.9901188(56) 100(1) ms β− (82%) 44Cl 0+
β−, n (18%) 43Cl
44mS 1365.0(8) keV 2.619(26) μs IT 44S 0+
45S 16 29 44.99641(32)# 68(2) ms β−, n (54%) 44Cl 3/2−#
β− (46%) 45Cl
46S 16 30 46.00069(43)# 50(8) ms β− 46Cl 0+
47S 16 31 47.00773(43)# 24# ms
[>200 ns] 		3/2−#
48S 16 32 48.01330(54)# 10# ms
[>200 ns] 		0+
49S 16 33 49.02189(63)# 4# ms
[>400 ns] 		1/2−#
This table header & footer:
  1. ^ mS – Excited nuclear isomer.
  2. ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. ^ Modes of decay:
    IT: Isomeric transition
    n: Neutron emission
    p: Proton emission
  5. ^ Bold symbol as daughter – Daughter product is stable.
  6. ^ ( ) spin value – Indicates spin with weak assignment arguments.
  7. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  8. ^ Heaviest theoretically stable nuclide with equal numbers of protons and neutrons
  9. ^ Cosmogenic

See also

[edit]

Daughter products other than sulfur

References

[edit]
[edit]
Revisions and contributorsEdit on WikipediaRead on Wikipedia

Isotopes of sulfur

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Sulfur, with 16, has 25 known isotopes ranging in mass number from 26 to 49, four of which—^{32}S, ^{33}S, ^{34}S, and ^{36}S—are stable and constitute all naturally occurring sulfur on . These stable isotopes exhibit natural abundances of 94.99% for ^{32}S, 0.75% for ^{33}S, 4.25% for ^{34}S, and 0.01% for ^{36}S, yielding a interval of [32.059, 32.076]. The remaining isotopes are radioactive, with ^{35}S being the most notable due to its relatively long of 87.37 days, making it suitable for applications in tracer studies. Sulfur isotopes play a crucial role in and , where variations in their ratios—particularly δ^{34}S—reveal insights into processes like deposition, microbial reduction, and biogeochemical . For instance, isotopic during equilibration allows estimation of formation temperatures in fluids, while differences in δ^{13}C and δ^{34}S can indicate and oxygen levels in geological systems. In and tracing, the distinct isotopic signatures of sources help track contaminant movement through ecosystems. Additionally, enriched stable isotopes such as ^{33}S and ^{34}S, along with ^{35}S, are produced for research in fields including and .

Background

Sulfur Element Overview

Sulfur is a with 16 and the [Ne] 3s² 3p⁴. It belongs to group 16 of the periodic table, known as the chalcogens, and is classified as a . Sulfur plays a vital role in various chemical processes due to its position in the p-block, enabling it to form diverse compounds essential in both natural and industrial contexts./Descriptive_Chemistry/Elements_Organized_by_Group/Group_16:The_Oxygen_Family/Z016_Chemistry_of_Sulfur(Z16)) Sulfur exhibits common oxidation states of +6, +4, 0, and -2, allowing it to participate in a wide range of bonding scenarios from sulfides to sulfates./Descriptive_Chemistry/Elements_Organized_by_Group/Group_16:The_Oxygen_Family/Z016_Chemistry_of_Sulfur(Z16)) The element exists in several allotropes, including the stable rhombic form (α-sulfur), the monoclinic form (β-sulfur), and the amorphous plastic sulfur, each with distinct structures and physical properties. These allotropes influence sulfur's reactivity and applications, with rhombic sulfur being the most common at standard conditions./Descriptive_Chemistry/Elements_Organized_by_Group/Group_16:The_Oxygen_Family/Z016_Chemistry_of_Sulfur(Z16)) In nature, sulfur occurs abundantly in minerals such as (FeS₂) and (CaSO₄·2H₂O), often extracted from volcanic deposits or sedimentary rocks. The of sulfur is [32.059, 32.076] u, primarily determined by the prevalence of its most abundant isotope, ^{32}S, with variations due to isotopic abundances in different samples. Sulfur has been recognized since ancient times, mentioned in the Bible and utilized by civilizations in , , and for fumigation and purification. It served key roles in for treating skin ailments, in the production of as a fuel component in Chinese inventions from the , and in early dyeing processes through sulfur-based compounds.

Isotopes and Their Relevance

Isotopes are atoms of the same chemical element that possess the same atomic number (Z), which determines the number of protons, but differ in their mass number (A), due to varying numbers of neutrons in the nucleus. For sulfur, with Z = 16, isotopes are denoted using nuclide notation as ^{A}{16}\text{S}, such as ^{32}{16}\text{S} for the most common variant. Sulfur has four stable isotopes—^{32}\text{S}, ^{33}\text{S}, ^{34}\text{S}, and ^{36}\text{S}—along with 21 radioactive isotopes, resulting in a total of 25 known isotopes spanning mass numbers from 26 to 49. The presence of multiple stable sulfur isotopes enables precise measurements of their ratios, which are crucial for tracing geochemical and biological processes such as sulfate reduction, oxidation, and formation. These ratios are typically expressed using delta notation, for example δ^{34}\text{S}, which quantifies deviations in the ^{34}\text{S}/^{32}\text{S} ratio relative to a standard, revealing isotopic effects driven by reaction kinetics or equilibrium. A distinctive feature of sulfur isotopes is mass-independent fractionation (MIF), where anomalies in ^{33}\text{S} and ^{36}\text{S} relative to mass-dependent expectations occur, providing insights into ancient atmospheric conditions, such as low oxygen levels on , through photochemical reactions in an anoxic environment.

Natural Occurrence

Terrestrial Abundance

Sulfur is unevenly distributed across Earth's terrestrial reservoirs, with the crust serving as the primary long-term storage site at approximately 0.03–0.04 wt%, equivalent to about 350 ppm. Within the crust, sulfur concentrates in minerals such as (FeS₂) and (CuFeS₂), minerals including (CaSO₄·2H₂O) and barite (BaSO₄), and volcanic emissions like SO₂ and H₂S, which account for localized enrichments in geothermal and ore deposit settings. In the oceans, sulfur exists mainly as dissolved (SO₄²⁻) at concentrations of roughly 28 mmol/L (2.8 g/L), comprising over 90% of mobile sulfur and influencing global geochemical cycles. Atmospheric sulfur is dilute, primarily as SO₂ gas and aerosols, with background SO₂ levels around 0.1–0.5 ppb in remote regions, though episodic volcanic injections can elevate concentrations to several ppm. The holds a smaller fraction, integrated into organic compounds like (cysteine and ), where sulfur constitutes 0.2–0.5% of dry weight in terrestrial plants and animals, facilitating metabolic processes. The baseline isotopic composition of terrestrial , defined by the Vienna-Canyon Diablo (V-CDT) standard, reflects the average bulk ratio: 95.02% ³²S, 0.75% ³³S, 4.21% ³⁴S, and 0.02% ³⁶S. This standard underpins measurements across reservoirs, with deviations expressed as δ³⁴S (per mil deviations from V-CDT). Oceanic sulfate closely mirrors this average but shows consistent enrichment, with δ³⁴S ≈ +21‰, due to long-term buffering. Atmospheric sulfur isotopes align near 0‰ for volcanic SO₂ but vary with biogenic (DMS) inputs from marine , which carry δ³⁴S signatures similar to . In the , and plant sulfur typically ranges from δ³⁴S -5‰ to +15‰, reflecting uptake from crustal and atmospheric sources. Crustal sulfides in sedimentary environments exhibit broader variability, but the V-CDT remains the reference for global normalization. Geological processes induce isotopic heterogeneity in crustal sulfur. Evaporites, formed from concentrated sulfate in arid basins, display ³⁴S enrichment, with δ³⁴S values often 15–25‰, as seen in Permian and Eocene deposits. Conversely, mantle-derived rocks like peridotites and basalts show ³⁴S depletion relative to the standard, with δ³⁴S near 0‰ ± 2‰, indicative of minimal processing from deep sources. These variations highlight sulfur's role in tracing lithospheric , with evaporites preserving marine signals and mantle materials reflecting primordial compositions. Anthropogenic activities, especially fossil fuel combustion, perturb local sulfur isotope distributions. Coal and petroleum sources yield SO₂ with δ³⁴S spanning -35‰ to +33‰ (mean ≈ +3‰), differing from natural crustal baselines and causing 5–20‰ shifts in atmospheric, precipitation, and soil δ³⁴S near emission sites. Such alterations, prominent since the Industrial Revolution, overlay geological signals in urban and industrial zones, complicating environmental tracing but enabling source apportionment studies.

Stellar Nucleosynthesis

Sulfur isotopes are synthesized primarily in the late evolutionary stages of massive stars with initial masses exceeding 8 solar masses (M⊙), where processes in the and explosive events drive the production of elements beyond oxygen. During hydrostatic silicon burning, which occurs at core temperatures around 3–4 billion , alpha-particle captures on -28 and other intermediates lead to the formation of sulfur-32 as the dominant isotope, alongside smaller amounts of silicon-28 and iron-group nuclei. This phase builds up significant quantities of ³²S in the silicon-burning shell, but much of the final yield is released through the explosive silicon burning triggered by the core-collapse supernova explosion of these stars. Core-collapse supernovae from progenitors in this mass range are the main astrophysical sites for injecting ³²S into the , contributing the bulk of cosmic . Heavier sulfur isotopes, including ³³S, ³⁴S, and ³⁶S, arise predominantly from reactions during the explosive phases in these e. In the high-entropy, neutron-rich environments of the —particularly in the neutrino-driven wind and outer layers—slow s (s-process-like conditions) and incomplete explosive burning processes incorporate s onto seed nuclei like ³²S, producing isotopic variations. For instance, ³⁴S forms via on ³³S followed by , while ³⁶S results from further captures, though yields are sensitive to the and temperature profiles in the explosion. These processes occur on timescales of seconds to minutes post-collapse, with Type II e serving as key contributors to the heavier isotopes' abundances. In the solar system, the cosmic abundance of relative to is approximately 1.5 × 10⁻⁵ (by number), reflecting the integrated yields from generations of massive star , with ³²S comprising about 95% of the total sulfur inventory. This dominance underscores the efficiency of alpha-capture pathways in producing ³²S, while processes contribute the remaining ~5% to ³³S, ³⁴S, and ³⁶S. Observations of in meteorites provide direct evidence of these origins, revealing isotopic anomalies such as enrichments in ³³S (up to several times solar ratios) in grains linked to ejecta. These signatures, preserved in grains that survived and solar system formation, confirm heterogeneous sulfur isotope distributions from individual events and highlight the role of explosive in seeding the early solar nebula.

Stable Isotopes

Properties and Abundances

Sulfur has four stable isotopes: ^{32}S, ^{33}S, ^{34}S, and ^{36}S. These isotopes exhibit distinct nuclear properties, including atomic masses and nuclear spins, which influence their roles in scientific applications. Their relative natural abundances reflect primordial nucleosynthetic processes and subsequent mass-dependent fractionations in Earth's geochemical cycles. ^{32}S, with an atomic mass of 31.972 u and nuclear spin of 0, is the most abundant stable isotope of sulfur at 94.99%. As the predominant isotope, it forms the basis for most sulfur-containing biomolecules, such as the amino acid cysteine, where it constitutes the majority of sulfur atoms due to its high natural prevalence. ^{33}S has an of 32.971 u and a nuclear spin of 3/2, with a relative abundance of 0.75%. Its odd number of nucleons provides a non-zero spin, enabling (NMR) studies of compounds at natural abundance, though low sensitivity requires high-field spectrometers. ^{34}S possesses an of 33.968 u and nuclear spin of 0, occurring at 4.25% abundance. This even-mass isotope is central to geochemical analyses, particularly δ^{34}S measurements, which track cycling in environmental and biological systems by quantifying deviations from the standard ^{32}S/^{34}S ratio. ^{36}S, the heaviest stable isotope, has an atomic mass of 35.967 u and nuclear spin of 0, with the lowest abundance at 0.01%. As the rarest stable sulfur isotope, it serves as a sensitive indicator of mass-dependent isotopic effects in fractionation processes. The standard atomic weight of sulfur varies between 32.059 and 32.076 u, reflecting natural isotopic variability due to shifts in these abundances across different reservoirs. While baseline abundances are fixed, isotopic fractionation can alter local ratios in specific environments.

Isotopic Fractionation

Isotopic fractionation refers to the physical and chemical processes that lead to variations in the ratios of stable sulfur isotopes, primarily ^{32}S, ^{33}S, and ^{34}S, in natural systems. These processes cause preferential enrichment or depletion of specific isotopes in products relative to reactants, enabling the use of sulfur isotope ratios as tracers for environmental and biological transformations. can be mass-dependent, where the magnitude scales with differences in , or mass-independent, which deviates from expected mass-proportional relationships. The extent of fractionation is quantified using the delta (δ) notation in per mil (‰), defined as: δ33S=((33S/32S)sample(33S/32S)standard−1)×1000\delta^{33}\text{S} = \left( \frac{(^{33}\text{S}/^{32}\text{S})_{\text{sample}}}{(^{33}\text{S}/^{32}\text{S})_{\text{standard}}} - 1 \right) \times 1000 with analogous expressions for δ^{34}S and δ^{36}S, referenced to the Vienna Canyon Diablo Troilite (VCDT) standard. Mass-dependent fractionation (MDF) dominates in most modern geological and biological processes. Kinetic MDF arises during unidirectional reactions where lighter isotopes react faster due to lower zero-point energies, as seen in bacterial sulfate reduction by dissimilatory sulfate-reducing bacteria (SRB). In this process, SRB preferentially metabolize ^{32}S over heavier isotopes during sulfate activation and reduction to sulfide, resulting in H_2S enriched in ^{32}S by 15–70‰ relative to residual sulfate, depending on factors like sulfate concentration and cell-specific reduction rates. Equilibrium MDF occurs in reversible processes, such as isotope exchange or mineral precipitation, where isotopes partition according to thermodynamic equilibrium. For example, during sulfate-sulfide equilibrium at low temperatures, sulfate is enriched in ^{34}S relative to sulfide, with the fractionation factor K = (^{34}S/^{32}S){\text{sulfate}} / (^{34}S/^{32}S){\text{sulfide}} \approx 1.070 at 25°C, corresponding to approximately 70‰ enrichment in δ^{34}S for sulfate. This equilibrium also influences mineral precipitation, where growing crystals like barite (BaSO_4) or pyrite (FeS_2) incorporate sulfur with small but systematic isotopic offsets from the fluid phase. Mass-independent fractionation (MIF) produces isotopic compositions that do not follow mass-dependent scaling laws, often quantified as Δ^{33}S = δ^{33}S - 0.515 \times δ^{34}S. In the atmosphere, prior to the rise of oxygen, photochemical reactions involving SO_2 and other sulfur gases under anoxic conditions generated MIF signals through mechanisms like UV self-shielding of SO isotopes, leading to Δ^{33}S anomalies up to 20‰ preserved in ancient sulfides and sulfates. These signals vanished after the around 2.4 billion years ago, when O_2 scavenged reactive sulfur species and suppressed photochemical MIF.

Radioactive Isotopes

Key Examples and Production

Sulfur-35 (³⁵S) is the most prominent radioactive isotope of sulfur, with a of 87.37 days, decaying via β⁻ emission to chlorine-35 (³⁵Cl) with a maximum energy of 167 keV. It is primarily produced naturally through of atmospheric argon-40 (⁴⁰Ar), generating a flux of approximately 10⁴ atoms/cm²/s, which serves as a key tracer for atmospheric mixing processes. The global atmospheric inventory of ³⁵S is estimated at around 10¹⁸ atoms, reflecting its short and continuous cosmogenic replenishment. Other notable short-lived radioactive sulfur isotopes include ³¹S, with a half-life of 2.6 seconds, typically produced via charged-particle reactions in particle accelerators; ³⁷S, with a half-life of 5.05 minutes, decaying by β⁻ emission; and ³⁸S, with a half-life of 2.84 hours. These isotopes are typically generated in high-energy settings such as particle accelerators or nuclear reactors, where they arise from reactions involving lighter stable targets like ³²S or ³⁴S. Artificial production of radioactive sulfur isotopes commonly involves neutron irradiation of stable sulfur targets in nuclear reactors, such as the reaction ³⁴S(n,γ)³⁵S to yield ³⁵S. For shorter-lived isotopes like ³¹S, ³⁷S, and ³⁸S, production relies on charged particle accelerators, enabling precise control over beam energies to induce spallation or other nuclear reactions on sulfur-enriched materials. These methods leverage the abundance of stable isotopes as starting materials to generate carrier-free radionuclides for research applications.

Decay Characteristics

Radioactive isotopes of sulfur exhibit decay modes determined by their neutron-to-proton ratio. Neutron-rich isotopes, such as those with mass numbers greater than 36, primarily undergo β⁻ decay, where a transforms into a proton, , and antineutrino, as exemplified by the reaction 35S→35Cl+e−+νˉe^{35}\text{S} \to ^{35}\text{Cl} + e^- + \bar{\nu}_e. Proton-rich isotopes, lighter than the stable ones, decay via β⁺ emission or (EC), converting a proton to a , as in 30S→30P^{30}\text{S} \to ^{30}\text{P}. The most significant radioactive sulfur isotope, 35S^{35}\text{S}, undergoes pure β⁻ decay to the ground state of stable 35Cl^{35}\text{Cl}, with no accompanying γ emission, making it suitable for applications requiring low-energy beta detection without penetrating radiation. Its Q-value for β⁻ decay is 167.3 keV, corresponding to the maximum electron kinetic energy, while the average beta energy is 49 keV. The half-life of 35S^{35}\text{S} is 87.37 ± 0.04 days, establishing it as the longest-lived radioactive sulfur isotope. Among shorter-lived isotopes, 38S^{38}\text{S} decays exclusively by β⁻ emission (100% branching ratio) with a half-life of 170.3 ± 0.7 minutes and multiple beta branches leading to excited states in 38Cl^{38}\text{Cl}. Extremely short-lived examples include the proton-rich 27S^{27}\text{S}, which decays primarily by with a half-life of 15.5 ms, and the neutron-rich 49S^{49}\text{S}, which undergoes with a half-life of less than 200 ns. These rapid decays highlight the instability of sulfur isotopes far from the line of stability.

Isotope Data

Stable Isotopes Table

The four stable isotopes of sulfur are summarized in the table below, including their mass numbers, atomic masses, nuclear spin and parity, natural abundances, and contributions to the (calculated as abundance fraction multiplied by isotopic mass). Data are based on IUPAC recommendations from 2021, with abundances reported to two decimal places and uncertainties noted where significant (e.g., ³²S abundance 94.99 ± 0.26%).
IsotopeMass (u)Spin/ParityNatural Abundance (%)Relative Atomic Mass Contribution (u)
³²S31.9720710⁺94.99(26)30.382
³³S32.9714583/2⁺0.75(2)0.247
³⁴S33.9678670⁺4.25(24)1.444
³⁶S35.9670810⁺0.01(1)0.004
These values reflect terrestrial isotopic compositions, which may vary slightly due to effects in natural processes.

Radioactive Isotopes Table

The radioactive isotopes of sulfur range from 27 to 49, comprising 19 known nuclides with half-lives exceeding 1 μs, as documented in IAEA Nuclear Data Services up to 2025. These isotopes exhibit proximity to the line of stability, where even-odd pairings influence decay properties, such as relatively longer half-lives for odd-neutron nuclides compared to even-even counterparts. Isotopes with half-lives shorter than 1 μs are omitted here due to their negligible persistence. The table below presents selected representative examples, highlighting key production methods and primary decay characteristics; isotopes serve as endpoints for decay chains in heavier cases.
Mass number (A)Half-lifeDecay modeDecay energy (keV)Daughter nuclideProduction note
274.4 msEC18.7^{27}AlSynthetic (projectile fragmentation)
312.56 sEC + β⁺5398^{31}PSynthetic (accelerator)
3587.37 dβ⁻167^{35}ClCosmogenic/
375.05 minβ⁻5100 (approx.)^{37}Cl ()
382.84 hβ⁻3923^{38}Cl ()
3911.5 sβ⁻13,000 (approx.)^{39}ClSynthetic (accelerator)
421.02 sβ⁻20,000 (approx.)^{42}ClSynthetic (fission fragment)
4568 msβ⁻25,000 (approx.)^{45}ClSynthetic (accelerator)
4933 msβ⁻6070^{49}ClSynthetic (projectile fragmentation)

Applications

Geochemical and Environmental Uses

Sulfur isotopes play a crucial role in reconstructing paleoclimatic conditions, particularly through the analysis of δ³⁴S values in minerals, which serve as proxies for ancient ocean oxygenation levels. During the around 2.4 billion years ago, shifts in δ³⁴S records from sedimentary indicate a transition from anoxic to oxygenated marine environments, reflecting the rise of atmospheric oxygen produced by early photosynthetic organisms. This arises from microbial reduction under varying conditions, allowing geochemists to trace the timing and extent of global oxygenation events in rocks. In ore deposit geochemistry, the ratios of ³⁴S to ³²S in minerals help distinguish between magmatic and sedimentary sources, aiding in the and genetic modeling of deposits. Magmatic typically exhibits δ³⁴S values near 0‰, indicative of mantle-derived inputs with minimal , whereas sedimentary sources show enriched values ranging from 10‰ to 40‰ due to bacterial reduction in ancient basins. For instance, in volcanogenic massive deposits, low δ³⁴S signatures confirm hydrothermal origins, while higher values in sedimentary exhalative deposits point to evaporitic or organic-rich precursors, guiding resource assessment in mining geology. Environmental monitoring leverages sulfur isotope ratios for source attribution in atmospheric pollution and natural emissions. Sulfur isotope ratios, such as δ³⁴S, and occasionally δ³³S anomalies from stratospheric volcanic injections help differentiate natural and anthropogenic sulfur sources in atmospheric , with anthropogenic emissions typically showing mass-dependent . Additionally, the short-lived radioisotope ³⁵S, with a of 87 days, acts as a tracer for recent sulfur cycling in the atmosphere and , enabling studies of dispersion and impacts from industrial activities. A notable involves δ³³S anomalies in sedimentary rocks, which reveal mass-independent patterns signaling UV-driven photochemical reactions in an oxygen-poor early atmosphere. These anomalies, often exceeding 0.2‰ in and barite from rocks older than 2.4 Ga, indicate the absence of an , allowing radiation to split sulfur gases and produce isotopically distinct reservoirs before the shielded the planet. Such records provide direct evidence of pre-oxygenic environmental conditions and the evolution of Earth's atmosphere.

Biological and Medical Applications

Sulfur-35 (³⁵S) serves as a valuable radiotracer in biological research, particularly for studying protein synthesis through the labeling of sulfur-containing amino acids such as methionine and cysteine. By incorporating ³⁵S-labeled methionine into cell cultures using methionine-free media, researchers can track the incorporation of these amino acids into newly synthesized proteins, enabling pulse-chase experiments to determine protein half-lives and turnover rates. This method is widely used due to methionine's essential role and the low-energy beta emissions of ³⁵S, which minimize cellular damage while allowing detection via autoradiography or scintillation counting. Additionally, ³⁵S labeling supports autoradiographic techniques for mapping DNA and RNA structures, where sulfur analogs like thiouridine are incorporated into nucleic acids to visualize replication and transcription processes. Stable isotopes, notably ³⁴S, are employed in nutritional studies to trace the in and , providing insights into sulfur uptake and fertilizer efficiency. According to (IAEA) guidelines, highly enriched ³⁴S (such as 90 atom% or greater) allows precise measurement of sulfur movement from to plant tissues using , helping optimize agricultural practices to address sulfur deficiencies in crops. This approach reveals how assimilate from fertilizers versus natural sources, informing sustainable farming strategies that enhance and reduce environmental sulfur losses. In medical applications, ³⁵S-labeled sulfates are utilized to investigate the of sulfur-containing drugs, such as heparin, an derived from glycosaminoglycans. Studies in animal models have shown that intravenously administered ³⁵S-heparin undergoes rapid urinary alongside uptake in organs like the liver and , allowing quantification of its distribution, metabolism, and clearance rates through measurements. The δ³⁴S signature, derived from the ratio of ³⁴S to ³²S, is instrumental in monitoring microbial reduction rates within ecosystems, particularly in wetlands where -reducing drive biogeochemical cycling. These microbes preferentially utilize lighter ³²S, resulting in fractionations of 15–25‰ between and produced , which can be measured to estimate reduction rates and assess . Such analyses help track transformations in anoxic environments, revealing impacts on availability and from organic matter decomposition.

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