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Isotopes of potassium
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| Standard atomic weight Ar°(K) | ||||||||||||||||||||||||||||||
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Potassium (
19K) has 25 known isotopes from 34
K to 57
K as well as 31
K, as well as an unconfirmed report of 59
K.[3] Three of those isotopes occur naturally: the two stable forms 39
K (93.26%) and 41
K (6.72%), and the long-lived radioisotope 40
K (0.012%).
Naturally occurring radioactive 40
K decays with a half-life of 1.248×109 years. 89% of those decays are to stable 40
Ca by beta decay, whilst 11% are to 40
Ar by either electron capture or positron emission. This latter decay branch has produced an isotopic abundance of argon on Earth which differs greatly from that seen in gas giants and stellar spectra. 40
K has the longest known half-life for any positron-emitting nuclide.[4] The long half-life of this primordial radioisotope is caused by a highly spin-forbidden transition: 40
K has a nuclear spin of 4, while both of its decay daughters are even–even isotopes with spins of 0.
40
K occurs in natural potassium in sufficient quantity that large bags of potassium chloride commercial salt substitutes can be used as a radioactive source for classroom demonstrations.[citation needed] 40
K is the largest source of natural radioactivity in healthy animals and humans, greater even than 14
C. In a human body of 70 kg mass, about 4300 nuclei of 40
K decay per second.[5]
The decay of 40
K to 40
Ar is used in potassium-argon dating of rocks. Minerals are dated by measurement of the concentration of potassium and the amount of radiogenic 40
Ar that has accumulated. 40
K has also been extensively used as a radioactive tracer in studies of weathering.[citation needed]
All other potassium isotopes have half-lives under a day, most under a minute. The unbound 31
K was discovered in 2019 and emits three protons; its half-life was measured to be shorter than 10 picoseconds.[6][7]
Stable potassium isotopes have been used for several nutrient cycling studies since potassium is a macronutrient required for life.[8]
List of isotopes
[edit]
| Nuclide [n 1] |
Z | N | Isotopic mass (Da)[9] [n 2][n 3] |
Half-life[10] [n 4] |
Decay mode[10] |
Daughter isotope [n 5] |
Spin and parity[10] [n 6][n 4] |
Natural abundance (mole fraction) | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Excitation energy[n 4] | Normal proportion[10] | Range of variation | |||||||||||||||||
| 31 K[6][7] |
19 | 12 | 31.03678(32)# | <10 ps | 3p | 28S | 3/2+# | ||||||||||||
| 34K[11] | 19 | 15 | 33.998404(18) | p | 33Ar | ||||||||||||||
| 35K | 19 | 16 | 34.98800541(55) | 175.2(19) ms | β+ (99.63%) | 35Ar | 3/2+ | ||||||||||||
| β+, p (0.37%) | 34Cl | ||||||||||||||||||
| 36K | 19 | 17 | 35.98130189(35) | 341(3) ms | β+ (99.95%) | 36Ar | 2+ | ||||||||||||
| β+, p (0.048%) | 35Cl | ||||||||||||||||||
| β+, α (0.0034%) | 32S | ||||||||||||||||||
| 37K | 19 | 18 | 36.97337589(10) | 1.23651(94) s | β+ | 37Ar | 3/2+ | ||||||||||||
| 38K | 19 | 19 | 37.96908111(21) | 7.651(19) min | β+ | 38Ar | 3+ | ||||||||||||
| 38m1K | 130.15(4) keV | 924.35(12) ms | β+ (99.97%) | 38Ar | 0+ | ||||||||||||||
| IT (0.0330%) | 38K | ||||||||||||||||||
| 38m2K | 3458.10(17) keV | 21.95(11) μs | IT | 38K | (7)+ | ||||||||||||||
| 39K | 19 | 20 | 38.9637064848(49) | Stable | 3/2+ | 0.932581(44) | |||||||||||||
| 40K[n 7][n 8] | 19 | 21 | 39.963998165(60) | 1.248(3)×109 y | β− (89.28%) | 40Ca | 4− | 1.17(1)×10−4 | |||||||||||
| EC (10.72%) | 40Ar | ||||||||||||||||||
| β+ (0.001%)[12] | |||||||||||||||||||
| 40mK | 1643.638(11) keV | 336(12) ns | IT | 40K | 0+ | ||||||||||||||
| 41K | 19 | 22 | 40.9618252561(40) | Stable | 3/2+ | 0.067302(44) | |||||||||||||
| 42K | 19 | 23 | 41.96240231(11) | 12.355(7) h | β− | 42Ca | 2− | ||||||||||||
| 43K | 19 | 24 | 42.96073470(44) | 22.3(1) h | β− | 43Ca | 3/2+ | ||||||||||||
| 43mK | 738.30(6) keV | 200(5) ns | IT | 43K | 7/2− | ||||||||||||||
| 44K | 19 | 25 | 43.96158698(45) | 22.13(19) min | β− | 44Ca | 2− | ||||||||||||
| 45K | 19 | 26 | 44.96069149(56) | 17.8(6) min | β− | 45Ca | 3/2+ | ||||||||||||
| 46K | 19 | 27 | 45.96198158(78) | 96.30(8) s | β− | 46Ca | 2− | ||||||||||||
| 47K | 19 | 28 | 46.9616616(15) | 17.38(3) s | β− | 47Ca | 1/2+ | ||||||||||||
| 48K | 19 | 29 | 47.96534118(83) | 6.83(14) s | β− (98.86%) | 48Ca | 1− | ||||||||||||
| β−, n (1.14%) | 47Ca | ||||||||||||||||||
| 49K | 19 | 30 | 48.96821075(86) | 1.26(5) s | β−, n (86%) | 48Ca | 1/2+ | ||||||||||||
| β− (14%) | 49Ca | ||||||||||||||||||
| 50K | 19 | 31 | 49.9723800(83) | 472(4) ms | β− (71.4%) | 50Ca | 0− | ||||||||||||
| β−, n (28.6%) | 49Ca | ||||||||||||||||||
| β−, 2n? | 48Ca | ||||||||||||||||||
| 50mK | 172.0(4) keV | 125(40) ns | IT | 50K | (2−) | ||||||||||||||
| 51K | 19 | 32 | 50.975828(14) | 365(5) ms | β−, n (65%) | 50Ca | 3/2+ | ||||||||||||
| β− (35%) | 51Ca | ||||||||||||||||||
| β−, 2n? | 49Ca | ||||||||||||||||||
| 52K | 19 | 33 | 51.981602(36) | 110(4) ms | β−, n (72.2%) | 51Ca | 2−# | ||||||||||||
| β− (25.5%) | 52Ca | ||||||||||||||||||
| β−, 2n (2.3%) | 50Ca | ||||||||||||||||||
| 53K | 19 | 34 | 52.98680(12) | 30(5) ms | β−, n (64%) | 52Ca | 3/2+ | ||||||||||||
| β− (26%) | 53Ca | ||||||||||||||||||
| β−, 2n (10%) | 51Ca | ||||||||||||||||||
| 54K | 19 | 35 | 53.99447(43)# | 10(5) ms | β− | 54Ca | 2−# | ||||||||||||
| β−, n? | 53Ca | ||||||||||||||||||
| β−, 2n? | 52Ca | ||||||||||||||||||
| 55K | 19 | 36 | 55.00051(54)# | 10# ms [>620 ns] |
β−? | 55Ca | 3/2+# | ||||||||||||
| β−, n? | 54Ca | ||||||||||||||||||
| β−, 2n? | 53Ca | ||||||||||||||||||
| 56K | 19 | 37 | 56.00857(64)# | 5# ms [>620 ns] |
β−? | 56Ca | 2−# | ||||||||||||
| β−, n? | 55Ca | ||||||||||||||||||
| β−, 2n? | 54Ca | ||||||||||||||||||
| 57K | 19 | 38 | 57.01517(64)# | 2# ms [>400 ns] |
β−? | 57Ca | 3/2+# | ||||||||||||
| β−, n? | 56Ca | ||||||||||||||||||
| β−, 2n? | 55Ca | ||||||||||||||||||
| 59K[3][n 9] | 19 | 40 | 59.03086(86)# | 1# ms [>400 ns] |
β−? | 59Ca | 3/2+# | ||||||||||||
| β−, n? | 58Ca | ||||||||||||||||||
| β−, 2n? | 57Ca | ||||||||||||||||||
| This table header & footer: | |||||||||||||||||||
- ^ mK – Excited nuclear isomer.
- ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- ^ a b c # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
- ^ Bold symbol as daughter – Daughter product is stable.
- ^ ( ) spin value – Indicates spin with weak assignment arguments.
- ^ Used in potassium-argon dating
- ^ Primordial radionuclide
- ^ Discovery of this isotope is unconfirmed.
See also
[edit]Daughter products other than potassium
References
[edit]- ^ "Standard Atomic Weights: Potassium". CIAAW. 1979.
- ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
- ^ a b Neufcourt, Léo; Cao, Yuchen; Nazarewicz, Witold; et al. (14 February 2019). "Neutron Drip Line in the Ca Region from Bayesian Model Averaging". Physical Review Letters. 122 (6) 062502. arXiv:1901.07632. Bibcode:2019PhRvL.122f2502N. doi:10.1103/PhysRevLett.122.062502. PMID 30822058.
- ^ Of longer ones, only 50V and 138La are theoretically capable of it, but they are still more forbidden and have very low energy release.
- ^ Rowland RE. "The Radioactivity of the Normal Adult Body". rerowland.com. Archived from the original on 2011-02-05.
- ^ a b "A peculiar atom shakes up assumptions of nuclear structure". Nature. 573 (7773): 167. 6 September 2019. Bibcode:2019Natur.573T.167.. doi:10.1038/d41586-019-02655-9. PMID 31506620.
- ^ a b Kostyleva, D.; et al. (2019). "Towards the Limits of Existence of Nuclear Structure: Observation and First Spectroscopy of the Isotope 31K by Measuring Its Three-Proton Decay". Physical Review Letters. 123 (9) 092502. arXiv:1905.08154. Bibcode:2019PhRvL.123i2502K. doi:10.1103/PhysRevLett.123.092502. PMID 31524489. S2CID 159041565.
- ^ "Soil potassium isotope composition during four million years of ecosystem development in Hawaiʻi". par.nsf.gov. June 2022.
- ^ Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3) 030003. doi:10.1088/1674-1137/abddaf.
- ^ a b c d Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3) 030001. doi:10.1088/1674-1137/abddae.
- ^ Dronchi, N.; Charity, R. J.; Sobotka, L. G.; Brown, B. A.; Weisshaar, D.; Gade, A.; Brown, K. W.; Reviol, W.; Bazin, D.; Farris, P. J.; Hill, A. M.; Li, J.; Longfellow, B.; Rhodes, D.; Paneru, S. N.; Gillespie, S. A.; Anthony, A. K.; Rubino, E.; Biswas, S. (2024-09-12). "Evolution of shell gaps in the neutron-poor calcium region from invariant-mass spectroscopy of 37,38Sc, 35Ca, and 34K". Physical Review C. 110 (3). doi:10.1103/PhysRevC.110.L031302. ISSN 2469-9985. OSTI 2441307.
- ^ Engelkemeir, D. W.; Flynn, K. F.; Glendenin, L. E. (1962). "Positron Emission in the Decay of K40". Physical Review. 126 (5): 1818. Bibcode:1962PhRv..126.1818E. doi:10.1103/PhysRev.126.1818.
Isotopes of potassium
View on GrokipediaIntroduction and history
Overview of potassium isotopes
Potassium, with atomic number 19, has 25 known isotopes from K and K to K, along with an unconfirmed report of K.[7] These isotopes differ by their neutron numbers, which vary from 12 (for K) to 38 (for K).[7] The nuclear properties of these isotopes, including their masses and decay characteristics, are documented in comprehensive evaluations such as NUBASE2020.[7] Only three isotopes occur naturally: K, K, and K, which constitute essentially all terrestrial potassium.[8] Their isotopic abundances are K at 93.2581%, K at 0.0117%, and K at 6.7302%.[9] Due to its odd atomic number, potassium lacks fully stable isotopes in the absolute sense, as the unpaired proton contributes to potential decay pathways influenced by nucleon binding energies; however, K and K are effectively stable, while K is a primordial radioactive isotope with a half-life of 1.248(3) years. The stability of potassium isotopes aligns with the semi-empirical mass formula, where binding energies per nucleon peak near the valley of stability for this Z, favoring even-neutron configurations for the long-lived species.[7] The standard atomic weight of potassium is the abundance-weighted average of the masses of its natural isotopes: where is the fractional abundance of isotope and is its mass number (or more precisely, atomic mass).[8] This yields .[8]Historical development
The element potassium was first isolated in 1807 by British chemist Humphry Davy through electrolysis of potassium hydroxide (caustic potash), marking the inaugural use of electrolysis to extract a metal from its compound.[10] In 1921, Francis William Aston identified the stable isotopes ^{39}K and ^{41}K using his newly developed mass spectrograph at the Cavendish Laboratory, resolving discrepancies in potassium's atomic weight and confirming the existence of isotopic variations among elements. Radioactivity in natural potassium samples had been observed as early as 1908 by N. R. Campbell, though its isotopic origin remained unidentified until later.[11][12] The radioactive nature of ^{40}K was established in 1935, when Alfred O. C. Nier provided mass spectrometric evidence for its existence as a minor isotope of potassium, and subsequent studies by H. Walke attributed the long-observed beta decay activity in natural potassium samples specifically to ^{40}K.[13] Following World War II, significant progress in isotope production occurred in the late 1940s and 1950s, with nuclear reactors and particle accelerators enabling the synthesis and separation of unstable potassium isotopes such as ^{42}K and ^{43}K for research purposes, building on wartime technologies developed for uranium enrichment.[14] Measurements of the ^{40}K half-life were refined during the 1950s and 1960s through improved beta-counting and mass spectrometric techniques, yielding values converging around 1.25 billion years; notable contributions included T. P. Kohman's 1956 compilation estimating 1.35 ± 0.05 billion years and J. C. Emery's 1961 determination of 1.27 ± 0.05 billion years, which enhanced the accuracy of geochronological applications.[12]Natural composition
Abundance in nature
Potassium occurs naturally as a mixture of three isotopes: ^{39}K, which constitutes 93.2581% of the total, ^{40}K at 0.0117%, and ^{41}K at 6.7302%.[1] These proportions reflect the primordial isotopic composition established during Earth's formation, with minor adjustments over geological timescales due to the radioactive decay of ^{40}K, which has a half-life of approximately 1.25 billion years and thus results in only subtle depletion of this isotope relative to the stable ones.[15] In the Earth's crust, potassium is the seventh most abundant element, comprising about 2.6% by weight, primarily in minerals such as feldspars and micas.[16] In seawater, its concentration averages around 380 mg/L (or roughly 10 mmol/kg), while in soils, total potassium content typically ranges from 1.5% to 2.5% by weight, depending on parent material and weathering processes.[17][18] Across these reservoirs, the isotopic ratios of potassium generally adhere to the primordial values, as cosmic ray spallation produces negligible quantities of lighter isotopes in terrestrial environments compared to extraterrestrial materials like meteorites.[19] Slight variations in the ^{41}K/^{39}K ratio, on the order of 0.1% to 1%, arise from isotopic fractionation processes, including biological uptake by plants and microorganisms, which preferentially incorporate lighter isotopes, and evaporation in surface waters or high-temperature geological settings, where heavier isotopes are enriched in the vapor phase.[19][20] These effects are minor and do not significantly alter the overall natural abundance. The standard atomic weight of potassium, 39.0983(1), is calculated directly from these isotopic abundances and masses, providing a weighted average used in chemical and physical calculations.[1]Stable and primordial radioactive isotopes
Potassium possesses two stable isotopes, ³⁹K and ⁴¹K, alongside the primordial radioactive isotope ⁴⁰K, which together constitute the natural isotopic composition of the element. These isotopes exhibit distinct nuclear properties that influence their roles in geochemical and geochronological processes. The isotope ³⁹K is the most abundant stable form of potassium, with an atomic mass of 38.9637064864(49) u and a ground-state nuclear spin and parity of 3/2⁺. As a stable nuclide, ³⁹K does not undergo radioactive decay and dominates the weighted average atomic mass of potassium.[1][21] The less abundant stable isotope ⁴¹K has an atomic mass of 40.9618252579(41) u and a ground-state spin and parity of 3/2⁺, rendering it non-radioactive. It serves as a key tracer in stable isotope ratio studies, particularly for investigating fractionation processes in geological and biological systems due to its distinct mass difference from ³⁹K.[1][21][22] In contrast, ⁴⁰K is a long-lived radioactive isotope with an atomic mass of 39.963998166(60) u and a ground-state spin and parity of 4⁻. It has a half-life of 1.2522(27) × 10⁹ years and decays via two primary branches: β⁻ emission to ⁴⁰Ca with a branching ratio of 89.56(7)% and an endpoint energy (E_max) of 1.312 MeV, and electron capture (primarily to an excited state of ⁴⁰Ar) with a total branching ratio of approximately 10.44%, corresponding to a Q-value of 1.505 MeV (β⁺ branching is negligible at 0.001%). The decay modes are represented by the following equations: (for β⁻ decay, 89.56(7)% branch) (for electron capture, ~10.44% branch).[1][15] ⁴⁰K is primordial in origin, produced primarily through nucleosynthesis in type II supernovae explosions that enriched the presolar molecular cloud from which the Solar System formed approximately 4.6 billion years ago. Its ongoing decay contributes significantly to Earth's internal heat budget, generating approximately 4 TW of radiogenic power through the release of decay energy in the crust and mantle.[23][24]Synthetic isotopes
Methods of synthesis
Artificial potassium isotopes are synthesized primarily through charged-particle induced nuclear reactions in accelerators, neutron irradiation in reactors, and high-energy spallation processes at specialized facilities. These methods allow for the production of neutron-deficient and neutron-rich isotopes beyond those occurring naturally, enabling research and applications in nuclear physics and medicine.[25] Proton and deuteron bombardment of target materials such as calcium and argon in cyclotrons is a common technique for generating neutron-deficient potassium isotopes. For instance, the reaction ^{35}Cl(α,n)^{38}K on NaCl targets, using alpha particle energies around 14.7 MeV, yields significant amounts of ^{38}K suitable for positron emission tomography studies, with production rates up to 20-30 mCi per irradiation.[26] Similarly, the ^{38}Ar(p,n)^{38}K reaction on enriched ^{38}Ar targets at lower energies (16-12 MeV) provides high-purity output, achieving saturation yields of approximately 21 mCi/μA·h in compact medical cyclotrons. Deuteron reactions on calcium targets, such as ^{40}Ca(d,α)^{38}K, have also been employed historically for short-lived isotopes. These cyclotron-based methods rely on water-cooled gas or solid targets, followed by chemical processing to isolate the product.[27][28] Neutron-rich potassium isotopes are produced via radiative capture reactions in nuclear reactors. The ^{41}K(n,\gamma)^{42}K reaction on enriched potassium targets, such as potassium chloride, is irradiated under thermal neutron fluxes (typically 10^{13}-10^{15} n/cm²/s) for periods ranging from hours to weeks, depending on desired activity. This method, standard since the mid-20th century, generates ^{42}K as a beta-emitter for tracer studies, with post-irradiation purification involving dissolution and ion-exchange chromatography to remove impurities like ^{82}Br. Reactor production favors neutron excess due to the abundance of thermal neutrons, contrasting with accelerator methods for proton-rich nuclides.[25] Lighter, more exotic potassium isotopes (e.g., ^{34}K to ^{38}K) are synthesized through spallation and fragmentation at high-energy proton accelerators. Facilities like ISOLDE at CERN use 1.4 GeV proton beams incident on thick targets such as uranium carbide (UC_x), inducing spallation to fragment heavy nuclei into a broad distribution of light isotopes, including potassium. The resulting ions are thermalized, ionized, and separated on-line via mass spectrometry for beam delivery. This technique, evolved from earlier fragmentation experiments, excels in producing rare, short-lived species for nuclear structure studies.[29] Enrichment of stable potassium isotopes (^{39}K and ^{41}K) for use as targets or tracers employs separation techniques including electromagnetic isotope separation (calutrons), chemical exchange, and laser methods. Calutrons, developed in the 1940s, ionize potassium salts and separate isotopes in magnetic fields based on mass-to-charge ratios, achieving high enrichment for research quantities. Chemical isotope exchange between aqueous solutions of potassium halides (e.g., bromide and iodide) exploits slight fractionation differences, while modern magneto-optical approaches use laser pumping to selectively excite and separate atomic states of specific isotopes, offering scalability for preparative amounts. Production has shifted from early 1940s reactor and calutron setups to contemporary high-intensity accelerators like ISOLDE, improving yield and purity for exotic isotopes.[30][31][32]Key synthetic isotopes and their half-lives
Synthetic isotopes of potassium are artificially produced radioactive nuclides that do not occur naturally in significant quantities, spanning a range from proton-rich lighter isotopes to neutron-rich heavier ones. Among the key mid-mass synthetic isotopes, ^{42}K has a half-life of 12.36(1) hours and undergoes β⁻ decay to ^{42}Ca with a maximum electron energy of 3.525(2) MeV.[33] This isotope is commonly produced via the neutron capture reaction ^{41}K(n,γ)^{42}K in nuclear reactors.[34] Similarly, ^{43}K possesses a half-life of 22.3(1) hours and decays primarily by β⁻ emission to ^{43}Ca with E_max = 1.833(5) MeV; it is synthesized through the (n,p) reaction on ^{43}Ca targets.[33][35] Lighter synthetic isotopes, such as ^{35}K, exhibit very short half-lives and are valuable for probing nuclear structure. ^{35}K has a half-life of 178(8) ms and decays via β⁺ emission and proton decay to ^{34}Cl, with a total Q-value of 11.874(9) MeV.[33] These proton-rich isotopes are typically generated in high-energy projectile fragmentation reactions or spallation processes at particle accelerators. On the neutron-rich side, heavier isotopes like ^{52}K have a half-life of 110(6) ms and decay predominantly by β⁻ emission to ^{52}Ca (23.7%), accompanied by neutron emission branches (β⁻,n to ^{51}Ca at 74% and β⁻,2n to ^{50}Ca at 2.3%), with Q = 17.13(3) MeV.[33] Such isotopes are observed and produced via projectile fragmentation of heavy targets, such as uranium, with high-energy protons at facilities like ISOLDE.[36] Overall, half-lives of synthetic potassium isotopes decrease from hours in the mid-mass region (around A ≈ 42–45) to milliseconds or shorter at the extremes (A < 38 or A > 50), reflecting increasing instability far from the line of β-stability. Decay modes are primarily β⁻ for neutron-rich isotopes, facilitating proton-to-neutron conversion, while proton-rich isotopes favor β⁺/electron capture and, in lighter cases, proton emission.[33] The following table summarizes selected key synthetic isotopes, highlighting their mass number, half-life, primary decay mode, and a representative production reaction where characteristically documented:| Mass Number | Half-Life | Decay Mode | Production Reaction Example |
|---|---|---|---|
| ^{35}K | 178(8) ms | β⁺, p (to ^{34}Cl) | Projectile fragmentation |
| ^{36}K | 341(3) ms | β⁺/EC, p, α (to ^{36}Ar) | High-energy spallation |
| ^{37}K | 1.225(7) s | β⁺ (to ^{37}Ar) | Projectile fragmentation |
| ^{38}K | 7.651(19) min | β⁺/EC (to ^{38}Ar) | ^{38}Ar(p,n) or photonuclear |
| ^{42}K | 12.36(1) h | β⁻ (to ^{42}Ca) | ^{41}K(n,γ) |
| ^{43}K | 22.3(1) h | β⁻ (to ^{43}Ca) | ^{43}Ca(n,p) |
| ^{44}K | 22.13(19) min | β⁻ (to ^{44}Ca) | ^{44}Ca(n,p) or ^{45}Sc(p,n) |
| ^{45}K | 17.81(61) min | β⁻ (to ^{45}Ca) | ^{46}Sc(p,2n) or neutron rxn. |
| ^{46}K | 105(10) s | β⁻ (to ^{46}Ca) | Neutron-induced reactions |
| ^{47}K | 17.50(24) s | β⁻ (to ^{47}Ca) | Neutron-induced reactions |
| ^{48}K | 6.8(2) s | β⁻, β⁻ n (to ^{48,47}Ca) | Projectile fragmentation |
| ^{49}K | 1.26(5) s | β⁻, β⁻ n (to ^{49,48}Ca) | Projectile fragmentation |
| ^{50}K | 472(4) ms | β⁻, β⁻ n (to ^{50,49}Ca) | Projectile fragmentation |
| ^{52}K | 110(6) ms | β⁻, β⁻ n, β⁻ 2n (to ^{52,51,50}Ca) | Proton-induced fragmentation of U |
