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Breeder reactor
Breeder reactor
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Assembly of the core of Experimental Breeder Reactor I in Idaho, United States, 1951

A breeder reactor is a nuclear reactor that generates more fissile material than it consumes.[1] These reactors can be fueled with more-commonly available isotopes of uranium and thorium, such as uranium-238 and thorium-232, as opposed to the rare uranium-235 which is used in conventional reactors. These materials are called fertile materials since they can be bred into fuel by these breeder reactors.

Breeder reactors achieve this because their neutron economy is high enough to create more fissile fuel than they use. These extra neutrons are absorbed by the fertile material that is loaded into the reactor along with fissile fuel. This irradiated fertile material in turn transmutes into fissile material which can undergo fission reactions.

Breeders were at first found attractive because they made more complete use of uranium fuel than light-water reactors, but interest declined after the 1960s as more uranium reserves were found[2] and new methods of uranium enrichment reduced fuel costs.

Types

[edit]
Production of heavy transuranic actinides in current thermal-neutron fission reactors through neutron capture and decays. Starting at uranium-238, isotopes of plutonium, americium, and curium are all produced. In a fast neutron-breeder reactor, all these isotopes may be burned as fuel.

Many types of breeder reactor are possible:

A "breeder" is simply a nuclear reactor designed for very high neutron economy with an associated conversion rate higher than 1.0. In principle, almost any reactor design could be tweaked to become a breeder. For example, the light-water reactor, a heavily moderated thermal design, evolved into the RMWR concept, using light water in a low-density supercritical form to increase the neutron economy enough to allow breeding.

Aside from water-cooled, there are many other types of breeder reactor currently envisioned as possible. These include molten-salt cooled, gas cooled, and liquid-metal cooled designs in many variations. Almost any of these basic design types may be fueled by uranium, plutonium, many minor actinides, or thorium, and they may be designed for many different goals, such as creating more fissile fuel, long-term steady-state operation, or active burning of nuclear wastes.

Extant reactor designs are sometimes divided into two broad categories based upon their neutron spectrum, which generally separates those designed to use primarily uranium and transuranics from those designed to use thorium and avoid transuranics. These designs are:

  • Fast breeder reactors (FBRs) which use 'fast' (i.e. unmoderated) neutrons to breed fissile plutonium (and possibly higher transuranics) from fertile uranium-238. The fast spectrum is flexible enough that it can also breed fissile uranium-233 from thorium, if desired.
  • Thermal breeder reactors which use 'thermal-spectrum' or 'slow' (i.e. moderated) neutrons to breed fissile uranium-233 from thorium. Due to the behavior of the various nuclear fuels, a thermal breeder is thought commercially feasible only with thorium fuel, which avoids the buildup of the heavier transuranics.

Fast breeder reactor

[edit]
Schematic diagram showing the difference between the Loop and Pool types of LMFBR

All current[when?] large-scale FBR power stations were liquid metal fast breeder reactors (LMFBR) cooled by liquid sodium. These have been of one of two designs:[1]: 43 

  • Loop type, in which the primary coolant is circulated through primary heat exchangers outside the reactor tank (but inside the biological shield due to radioactive 24Na in the primary coolant)
    Experimental Breeder Reactor II, which served as the prototype for the Integral Fast Reactor
  • Pool type, in which the primary heat exchangers and pumps are immersed in the reactor tank

There are only two commercially operating breeder reactors as of 2017: the BN-600 reactor, at 560 MWe, and the BN-800 reactor, at 880 MWe. Both are Russian sodium-cooled reactors. The designs use liquid metal as the primary coolant, to transfer heat from the core to steam used to power the electricity generating turbines. FBRs have been built cooled by liquid metals other than sodium—some early FBRs used mercury; other experimental reactors have used a sodium-potassium alloy. Both have the advantage that they are liquids at room temperature, which is convenient for experimental rigs but less important for pilot or full-scale power stations.

Three of the proposed generation IV reactor types are FBRs:[3]

FBRs usually use a mixed oxide fuel core of up to 20% plutonium dioxide (PuO2) and at least 80% uranium dioxide (UO2). Another fuel option is metal alloys, typically a blend of uranium, plutonium, and zirconium (used because it is "transparent" to neutrons). Enriched uranium can be used on its own.

Many designs surround the reactor core in a blanket of tubes that contain non-fissile uranium-238, which, by capturing fast neutrons from the reaction in the core, converts to fissile plutonium-239 (as is some of the uranium in the core), which is then reprocessed and used as nuclear fuel. Other FBR designs rely on the geometry of the fuel (which also contains uranium-238), arranged to attain sufficient fast neutron capture. The plutonium-239 (or the fissile uranium-235) fissile cross-section is much smaller in a fast spectrum than in a thermal spectrum, as is the ratio between the 239Pu/235U fission cross-section and the 238U absorption cross-section. This increases the concentration of 239Pu/235U needed to sustain a chain reaction, as well as the ratio of breeding to fission.[4] On the other hand, a fast reactor needs no moderator to slow down the neutrons at all, taking advantage of the fast neutrons producing a greater number of neutrons per fission than slow neutrons. For this reason ordinary liquid water, being a moderator and neutron absorber, is an undesirable primary coolant for fast reactors. Because large amounts of water in the core are required to cool the reactor, the yield of neutrons and therefore breeding of 239Pu are strongly affected. Theoretical work has been done on reduced moderation water reactors, which may have a sufficiently fast spectrum to provide a breeding ratio slightly over 1. This would likely result in an unacceptable power derating and high costs in a liquid-water-cooled reactor, but the supercritical water coolant of the supercritical water reactor (SCWR) has sufficient heat capacity to allow adequate cooling with less water, making a fast-spectrum water-cooled reactor a practical possibility.[5]

The type of coolants, temperatures, and fast neutron spectrum puts the fuel cladding material (normally austenitic stainless or ferritic-martensitic steels) under extreme conditions. The understanding of the radiation damage, coolant interactions, stresses, and temperatures are necessary for the safe operation of any reactor core. All materials used to date in sodium-cooled fast reactors have known limits.[6] Oxide dispersion-strengthened alloy steel is viewed as the long-term radiation resistant fuel-cladding material that can overcome the shortcomings of today's material choices.

Integral fast reactor

[edit]

One design of fast neutron reactor, specifically conceived to address the waste disposal and plutonium issues, was the integral fast reactor (IFR, also known as an integral fast breeder reactor, although the original reactor was designed to not breed a net surplus of fissile material).[7][8]

To solve the waste disposal problem, the IFR had an on-site electrowinning fuel-reprocessing unit that recycled the uranium and all the transuranics (not just plutonium) via electroplating, leaving just short-half-life fission products in the waste. Some of these fission products could later be separated for industrial or medical uses and the rest sent to a waste repository. The IFR pyroprocessing system uses molten cadmium cathodes and electrorefiners to reprocess metallic fuel directly on-site at the reactor.[9] Such systems co-mingle all the minor actinides with both uranium and plutonium. The systems are compact and self-contained, so that no plutonium-containing material needs to be transported away from the site of the breeder reactor. Breeder reactors incorporating such technology would most likely be designed with breeding ratios very close to 1.00, so that after an initial loading of enriched uranium and/or plutonium fuel, the reactor would then be refueled only with small deliveries of natural uranium. A quantity of natural uranium equivalent to a block about the size of a milk crate delivered once per month would be all the fuel such a 1 gigawatt reactor would need.[10] Such self-contained breeders are currently envisioned as the final self-contained and self-supporting ultimate goal of nuclear reactor designers.[11][4] The project was canceled in 1994 by United States Secretary of Energy Hazel O'Leary.[12][13]

Other fast reactors

[edit]
The graphite core of the Molten Salt Reactor Experiment

The first fast reactor built and operated was the Los Alamos Plutonium Fast Reactor ("Clementine") in Los Alamos, NM.[14] Clementine was fueled by Ga-stabilized delta-phase Pu and cooled with mercury. It contained a 'window' of Th-232 in anticipation of breeding experiments, but no reports were made available regarding this feature.

Another proposed fast reactor is a fast molten salt reactor, in which the molten salt's moderating properties are insignificant. This is typically achieved by replacing the light metal fluorides (e.g. LiF, BeF2) in the salt carrier with heavier metal chlorides (e.g., KCl, RbCl, ZrCl4).

Several prototype FBRs have been built, ranging in electrical output from a few light bulbs' equivalent (EBR-I, 1951) to over 1,000 MWe. As of 2006, the technology is not economically competitive to thermal reactor technology, but India, Japan, China, South Korea, and Russia are all committing substantial research funds to further development of fast breeder reactors, anticipating that rising uranium prices will change this in the long term. Germany, in contrast, abandoned the technology due to safety concerns. The SNR-300 fast breeder reactor was finished after 19 years despite cost overruns summing up to a total of 3.6 billion, only to then be abandoned.[15]

Thermal breeder reactor

[edit]
The Shippingport Reactor, used as a prototype light water breeder for five years beginning in August 1977

The advanced heavy-water reactor is one of the few proposed large-scale uses of thorium.[16] India is developing this technology, motivated by substantial thorium reserves; almost a third of the world's thorium reserves are in India, which lacks significant uranium reserves.

The third and final core of the Shippingport Atomic Power Station 60 MWe reactor was a light water thorium breeder, which began operating in 1977.[17] It used pellets made of thorium dioxide and uranium-233 oxide; initially, the U-233 content of the pellets was 5–6% in the seed region, 1.5–3% in the blanket region, and none in the reflector region. It operated at 236 MWt, generating 60 MWe, and ultimately produced over 2.1 billion kilowatt hours of electricity. After five years, the core was removed and found to contain nearly 1.4% more fissile material than when it was installed, demonstrating that breeding from thorium had occurred.[18][19]

A liquid fluoride thorium reactor is also planned as a thorium thermal breeder. Liquid-fluoride reactors may have attractive features, such as inherent safety, no need to manufacture fuel rods, and possibly simpler reprocessing of the liquid fuel. This concept was first investigated at the Oak Ridge National Laboratory Molten-Salt Reactor Experiment in the 1960s. From 2012 it became the subject of renewed interest worldwide.[20]

Fuel resources

[edit]

Breeder reactors could, in principle, extract almost all of the energy contained in uranium or thorium, decreasing fuel requirements by a factor of 100 compared to widely used once-through light water reactors, which extract less than 1% of the energy in the actinide metal (uranium or thorium) mined from the earth.[11] The high fuel-efficiency of breeder reactors could greatly reduce concerns about fuel supply, energy used in mining, and storage of radioactive waste. With seawater uranium extraction (currently too expensive to be economical), there is enough fuel for breeder reactors to satisfy the world's energy needs for 5 billion years at 1983's total energy consumption rate, thus making nuclear energy effectively a renewable energy.[21][22] In addition to seawater, the average crustal granite rocks contain significant quantities of uranium and thorium that with breeder reactors can supply abundant energy for the remaining lifespan of the sun on the main sequence of stellar evolution.[23]

Nuclear waste

[edit]
Actinides[24] by decay chain Half-life
range (a)
Fission products of 235U by yield[25]
4n
(Thorium)
4n + 1
(Neptunium)
4n + 2
(Radium)
4n + 3
(Actinium)
4.5–7% 0.04–1.25% <0.001%
228Ra 4–6 a 155Euþ
248Bk[26] > 9 a
244Cmƒ 241Puƒ 250Cf 227Ac 10–29 a 90Sr 85Kr 113mCdþ
232Uƒ 238Puƒ 243Cmƒ 29–97 a 137Cs 151Smþ 121mSn
249Cfƒ 242mAmƒ 141–351 a

No fission products have a half-life
in the range of 100 a–210 ka ...

241Amƒ 251Cfƒ[27] 430–900 a
226Ra 247Bk 1.3–1.6 ka
240Pu 229Th 246Cmƒ 243Amƒ 4.7–7.4 ka
245Cmƒ 250Cm 8.3–8.5 ka
239Puƒ 24.1 ka
230Th 231Pa 32–76 ka
236Npƒ 233Uƒ 234U 150–250 ka 99Tc 126Sn
248Cm 242Pu 327–375 ka 79Se
1.33 Ma 135Cs
237Npƒ 1.61–6.5 Ma 93Zr 107Pd
236U 247Cmƒ 15–24 Ma 129I
244Pu 80 Ma

... nor beyond 15.7 Ma[28]

232Th 238U 235Uƒ№ 0.7–14.1 Ga

In broad terms, spent nuclear fuel has three main components. The first consists of fission products, the leftover fragments of fuel atoms after they have been split to release energy. Fission products come in dozens of elements and hundreds of isotopes, all of them lighter than uranium. The second main component of spent fuel is transuranics (atoms heavier than uranium), which are generated from uranium or heavier atoms in the fuel when they absorb neutrons but do not undergo fission. All transuranic isotopes fall within the actinide series on the periodic table, and so they are frequently referred to as the actinides. The largest component is the remaining uranium which is around 98.25% uranium-238, 1.1% uranium-235, and 0.65% uranium-236. The U-236 comes from the non-fission capture reaction where U-235 absorbs a neutron but releases only a high energy gamma ray instead of undergoing fission.

The physical behavior of the fission products is markedly different from that of the actinides. In particular, fission products do not undergo fission and therefore cannot be used as nuclear fuel. Indeed, because fission products are often neutron poisons (absorbing neutrons that could be used to sustain a chain reaction), fission products are viewed as nuclear 'ashes' left over from consuming fissile materials. Furthermore, only seven long-lived fission product isotopes have half-lives longer than a hundred years, which makes their geological storage or disposal less problematic than for transuranic materials.[29]

With increased concerns about nuclear waste, breeding fuel cycles came under renewed interest as they can reduce actinide wastes, particularly plutonium and minor actinides.[30] Breeder reactors are designed to fission the actinide wastes as fuel and thus convert them to more fission products. After spent nuclear fuel is removed from a light water reactor, it undergoes a complex decay profile as each nuclide decays at a different rate. There is a large gap in the decay half-lives of fission products compared to transuranic isotopes. If the transuranics are left in the spent fuel, after 1,000 to 100,000 years the slow decay of these transuranics would generate most of the radioactivity in that spent fuel. Thus, removing the transuranics from the waste eliminates much of the long-term radioactivity of spent nuclear fuel.[31]

Today's commercial light-water reactors do breed some new fissile material, mostly in the form of plutonium. Because commercial reactors were never designed as breeders, they do not convert enough uranium-238 into plutonium to replace the uranium-235 consumed. Nonetheless, at least one-third of the power produced by commercial nuclear reactors comes from fission of plutonium generated within the fuel.[32] Even with this level of plutonium consumption, light water reactors consume only part of the plutonium and minor actinides they produce, and nonfissile isotopes of plutonium build up, along with significant quantities of other minor actinides.[33]

Breeding fuel cycles attracted renewed interest because of their potential to reduce actinide wastes, particularly various isotopes of plutonium and the minor actinides (neptunium, americium, curium, etc.).[30] Since breeder reactors on a closed fuel cycle would use nearly all of the isotopes of these actinides fed into them as fuel, their fuel requirements would be reduced by a factor of about 100. The volume of waste they generate would be reduced by a factor of about 100 as well. While there is a huge reduction in the volume of waste from a breeder reactor, the activity of the waste is about the same as that produced by a light-water reactor.[34]

Waste from a breeder reactor has a different decay behavior because it is made up of different materials. Breeder reactor waste is mostly fission products, while light-water reactor waste is mostly unused uranium isotopes and a large quantity of transuranics. After spent nuclear fuel has been removed from a light-water reactor for longer than 100,000 years, the transuranics would be the main source of radioactivity. Eliminating them would eliminate much of the long-term radioactivity from the spent fuel.[31]

In principle, breeder fuel cycles can recycle and consume all actinides,[21] leaving only fission products. As the graphic in this section indicates, fission products have a peculiar "gap" in their aggregate half-lives, such that no fission products have a half-life between 91 and 200,000 years. As a result of this physical oddity, after several hundred years in storage, the activity of the radioactive waste from an FBR would quickly drop to the low level of the long-lived fission products. However, to obtain this benefit requires the highly efficient separation of transuranics from spent fuel. If the fuel reprocessing methods used leave a large fraction of the transuranics in the final waste stream, this advantage would be greatly reduced.[11]

The FBR's fast neutrons can fission actinide nuclei with even numbers of both protons and neutrons. Such nuclei usually lack the low-speed "thermal neutron" resonances of fissile fuels used in LWRs.[35] The thorium fuel cycle inherently produces lower levels of heavy actinides. The fertile material in the thorium fuel cycle has an atomic weight of 232, while the fertile material in the uranium fuel cycle has an atomic weight of 238. That mass difference means that thorium-232 requires six more neutron capture events per nucleus before the transuranic elements can be produced. In addition to this simple mass difference, the reactor gets two chances to fission the nuclei as the mass increases: First as the effective fuel nuclei U233, and as it absorbs two more neutrons, again as the fuel nuclei U235.[36][37]

A reactor whose main purpose is to destroy actinides rather than increasing fissile fuel-stocks is sometimes known as a burner reactor. Both breeding and burning depend on good neutron economy, and many designs can do either. Breeding designs surround the core by a breeding blanket of fertile material. Waste burners surround the core with non-fertile wastes to be destroyed. Some designs add neutron reflectors or absorbers.[4]

Design

[edit]
Fission probabilities of selected actinides, thermal vs. fast neutrons.[38][39] The percentages of thermal and fast fission indicate the fraction of nuclei fissioned when hit by a respective neutron. The remainder undergoes neutron capture.
Isotope Thermal fission
cross section
Thermal
fission
%
Fast fission
cross section
Fast
fission
%
Th-232 53.71 microbarn 1 n 79.94 millibarn 3 n
U-232 76.52 barn 59 2.063 barn 95
U-233 531.3 barn 89 1.908 barn 93
U-235 585.1 barn 81 1.218 barn 80
U-238 16.8 microbarn 1 n 306.4 millibarn 11
Np-237 20.19 millibarn 3 n 1.336 barn 27
Pu-238 17.77 barn 7 1.968 barn 70
Pu-239 747.4 barn 63 1.802 barn 85
Pu-240 36.21 millibarn 1 n 1.328 barn 55
Pu-241 1012 barn 75 1.626 barn 87
Pu-242 2.436 millibarn 1 n 1.151 barn 53
Am-241 3.122 barn 1 n 1.395 barn 21
Am-242m 6401 barn 75 1.834 barn 94
Am-243 81.58 millibarn 1 n 1.081 barn 23
Cm-242 4.665 barn 1 n 1.775 barn 10
Cm-243 587.4 barn 78 2.432 barn 94
Cm-244 1.022 barn 4 n 1.733 barn 33
n=non-fissile

Conversion ratio

[edit]

One measure of a reactor's performance is the "conversion ratio", defined as the ratio of new fissile atoms produced to fissile atoms consumed. All proposed nuclear reactors except specially designed and operated actinide burners[4] experience some degree of conversion. As long as there is any amount of a fertile material within the neutron flux of the reactor, some new fissile material is always created. When the conversion ratio is greater than 1, it is often called the "breeding ratio".

For example, commonly used light water reactors have a conversion ratio of approximately 0.6. Pressurized heavy-water reactors running on natural uranium have a conversion ratio of 0.8.[40] In a breeder reactor, the conversion ratio is higher than 1. "Break-even" is achieved when the conversion ratio reaches 1.0 and the reactor produces as much fissile material as it uses.

Doubling time

[edit]

The doubling time is the amount of time it would take for a breeder reactor to produce enough new fissile material to replace the original fuel and additionally produce an equivalent amount of fuel for another nuclear reactor. This was considered an important measure of breeder performance in early years, when uranium was thought to be scarce. However, since uranium is more abundant than thought in the early days of nuclear reactor development, and given the amount of plutonium available in spent reactor fuel, doubling time has become a less important metric in modern breeder-reactor design.[41][42]

Burnup

[edit]

"Burnup" is a measure of how much energy has been extracted from a given mass of heavy metal in fuel, often expressed (for power reactors) in terms of gigawatt-days per ton of heavy metal. Burnup is an important factor in determining the types and abundances of isotopes produced by a fission reactor. Breeder reactors by design have high burnup compared to a conventional reactor, as breeder reactors produce more of their waste in the form of fission products, while most or all of the actinides are meant to be fissioned and destroyed.[43]

In the past, breeder-reactor development focused on reactors with low breeding ratios, from 1.01 for the Shippingport Reactor[44][45] running on thorium fuel and cooled by conventional light water to over 1.2 for the Soviet BN-350 liquid-metal-cooled reactor.[46] Theoretical models of breeders with liquid sodium coolant flowing through tubes inside fuel elements ("tube-in-shell" construction) suggest breeding ratios of at least 1.8 are possible on an industrial scale.[47] The Soviet BR-1 test reactor achieved a breeding ratio of 2.5 under non-commercial conditions.[48]

Reprocessing

[edit]

Fission of the nuclear fuel in any reactor unavoidably produces neutron-absorbing fission products. The fertile material from a breeder reactor then needs to be reprocessed to remove those neutron poisons. This step is required to fully utilize the ability to breed as much or more fuel than is consumed. All reprocessing can present a proliferation concern, since it can extract weapons-usable material from spent fuel.[49] The most common reprocessing technique, PUREX, presents a particular concern since it was expressly designed to separate plutonium. Early proposals for the breeder-reactor fuel cycle posed an even greater proliferation concern because they would use PUREX to separate plutonium in a highly attractive isotopic form for use in nuclear weapons.[50][51]

Several countries are developing reprocessing methods that do not separate the plutonium from the other actinides. For instance, the non-water-based pyrometallurgical electrowinning process, when used to reprocess fuel from an integral fast reactor, leaves large amounts of radioactive actinides in the reactor fuel.[11] More conventional water-based reprocessing systems include SANEX, UNEX, DIAMEX, COEX, and TRUEX, and proposals to combine PUREX with those and other co-processes. All these systems have moderately better proliferation resistance than PUREX, though their adoption rate is low.[52][53][54]

In the thorium cycle, thorium-232 breeds by converting first to protactinium-233, which then decays to uranium-233. If the protactinium remains in the reactor, small amounts of uranium-232 are also produced, which has the strong gamma emitter thallium-208 in its decay chain. Similar to uranium-fueled designs, the longer the fuel and fertile material remain in the reactor, the more of these undesirable elements build up. In the envisioned commercial thorium reactors, high levels of uranium-232 would be allowed to accumulate, leading to extremely high gamma-radiation doses from any uranium derived from thorium. These gamma rays complicate the safe handling of a weapon and the design of its electronics; this explains why uranium-233 has never been pursued for weapons beyond proof-of-concept demonstrations.[55]

While the thorium cycle may be proliferation-resistant with regard to uranium-233 extraction from fuel (because of the presence of uranium-232), it poses a proliferation risk from an alternate route of uranium-233 extraction, which involves chemically extracting protactinium-233 and allowing it to decay to pure uranium-233 outside of the reactor. This process is an obvious chemical operation which is not required for normal operation of these reactor designs, but it could feasibly happen beyond the oversight of organizations such as the International Atomic Energy Agency (IAEA), and thus must be safeguarded against.[56]

Production

[edit]

Like many aspects of nuclear power, fast breeder reactors have been subject to much controversy over the years. In 2010 the International Panel on Fissile Materials said "After six decades and the expenditure of the equivalent of tens of billions of dollars, the promise of breeder reactors remains largely unfulfilled and efforts to commercialize them have been steadily cut back in most countries". In Germany, the United Kingdom, and the United States, breeder reactor development programs have been abandoned.[57][58] The rationale for pursuing breeder reactors—sometimes explicit and sometimes implicit—was based on the following key assumptions:[58][59]

  • It was expected that uranium would be scarce and high-grade deposits would quickly become depleted if fission power were deployed on a large scale; the reality, however, is that since the end of the Cold War, uranium has been much cheaper and more abundant than early designers expected.[60]
  • It was expected that breeder reactors would quickly become economically competitive with the light-water reactors that dominate nuclear power today, but the reality is that capital costs are at least 25% more than water-cooled reactors.
  • It was thought that breeder reactors could be as safe and reliable as light-water reactors, but safety issues are cited as a concern with fast reactors that use a sodium coolant, where a leak could lead to a sodium fire.
  • It was expected that the proliferation risks posed by breeders and their "closed" fuel cycle, in which plutonium would be recycled, could be managed. But since plutonium-breeding reactors produce plutonium from U238, and thorium reactors produce fissile U233 from thorium, all breeding cycles could theoretically pose proliferation risks.[61] However U-232, which is always present in U-233 produced in breeder reactors, is a strong gamma-emitter via its daughter products, and would make weapon handling extremely hazardous and the weapon easy to detect.[62]

Some past anti-nuclear advocates have become pro-nuclear power as a clean source of electricity since breeder reactors effectively recycle most of their waste. This solves one of the most-important negative issues of nuclear power. In the documentary Pandora's Promise, a case is made for breeder reactors because they provide a real high-kW alternative to fossil fuel energy. According to the movie, one pound of uranium provides as much energy as 5,000 barrels of oil.[63]

Notable reactors

[edit]
Notable breeder reactors[14][64][65][66][67]
Reactor Country
when built
Started Shut down Design
MWe
Final
MWe
Thermal
Power MWt
Capacity
factor
Number of
coolant leaks
Neutron
temperature
Coolant Reactor class
DFR UK 1962 1977 14 11 65 34% 7 Fast NaK Test
China Experimental Fast Reactor China 2012 operating 20 22 65 40% 8 Fast Sodium Test[68]
CFR-600 China 2017 commissioning/2023 642 682 1882 34% 27 Fast Sodium Commercial[69]
BN-350 Soviet Union 1973 1999 350 52 750 43% 15 Fast Sodium Prototype
Rapsodie France 1967 1983 0 40 2 Fast Sodium Test
Phénix France 1975 2010 233 130 563 40.5% 31 Fast Sodium Prototype
PFR UK 1976 1994 234 234 650 26.9% 20 Fast Sodium Prototype
KNK II Germany 1977 1991 18 17 58 17.1% 21 Fast Sodium Research/Test
SNR-300 Germany 1985 1991 327 non-nuclear tests only Fast Sodium Prototype/Commercial
BN-600 Soviet Union 1981 operating 560 560 1470 74.2% 27 Fast Sodium Prototype/Commercial (Gen2)
FFTF US 1982 1993 0 400 1 Fast Sodium Test
Superphénix France 1985 1998 1200 1200 3000 7.9% 7 Fast Sodium Prototype/Commercial (Gen2)
FBTR India 1985 operating 13 40 6 Fast Sodium Test
PFBR India 2004 2024 500 1250 Fast Sodium Prototype/Commercial (Gen3)
Jōyō Japan 1977 2007 0 150 Fast Sodium Test
Monju Japan 1995 2017 246 246 714 trial only 1 Fast Sodium Prototype
BN-800 Russia 2015 operating 789 880 2100 73.4% Fast Sodium Prototype/Commercial (Gen3)
MSRE US 1965 1969 0 7.4 Epithermal Molten salt (FLiBe) Test
Clementine US 1946 1952 0 0.025 Fast Mercury World's First Fast Reactor[14]
EBR-1 US 1951 1964 0.2 0.2 1.4 Fast NaK First Power Reactor
Fermi-1 US 1963 1972 66 66 200 Fast Sodium Prototype
EBR-2 US 1964 1994 19 19 62.5 Fast Sodium Experimental/Test
Shippingport US 1977
as breeder
1982 60 60 236 Thermal Light Water Experimental-Core3

The Soviet Union constructed a series of fast reactors, the first being mercury-cooled and fueled with plutonium metal, and the later plants sodium-cooled and fueled with plutonium oxide. BR-1 (1955) was 100W (thermal) was followed by BR-2 at 100 kW and then the 5 MW BR-5.[48] BOR-60 (first criticality 1969) was 60 MW, with construction started in 1965.[70]

Future plants

[edit]
The Chinese Experimental Fast Reactor is a 65 MW (thermal), 20 MW (electric), sodium-cooled, pool-type reactor with a 30-year design lifetime and a target burnup of 100 MWd/kg.

India

[edit]

India has been trying to develop fast breeder reactors for decades but suffered repeated delays.[71] By December 2024 the Prototype Fast Breeder Reactor is due to be completed and commissioned.[72][73][74] The program is intended to use fertile thorium-232 to breed fissile uranium-233. India is also pursuing thorium thermal breeder reactor technology. India's focus on thorium is due to the nation's large reserves, though known worldwide reserves of thorium are four times those of uranium. India's Department of Atomic Energy said in 2007 that it would simultaneously construct four more breeder reactors of 500 MWe each including two at Kalpakkam.[75][needs update]

BHAVINI, an Indian nuclear power company, was established in 2003 to construct, commission, and operate all stage II fast breeder reactors outlined in India's three-stage nuclear power programme. To advance these plans, the FBR-600 is a pool-type sodium-cooled reactor with a rating of 600 MWe.[76][77][74]

China

[edit]

The China Experimental Fast Reactor is a 25 MW(e) prototype for the planned China Prototype Fast Reactor.[78] It started generating power in 2011.[79] China initiated a research and development project in thorium molten-salt thermal breeder-reactor technology (liquid fluoride thorium reactor), formally announced at the Chinese Academy of Sciences annual conference in 2011. Its ultimate target was to investigate and develop a thorium-based molten salt nuclear system over about 20 years.[80][81][needs update]

South Korea

[edit]

South Korea is developing a design for a standardized modular FBR for export, to complement the standardized pressurized water reactor and CANDU designs they have already developed and built, but has not yet committed to building a prototype.

A cutaway model of the BN-600 reactor, superseded by the BN-800 reactor family
Construction of the BN-800 reactor

Russia

[edit]

Russia has a plan for increasing its fleet of fast breeder reactors significantly. A BN-800 reactor (800 MWe) at Beloyarsk was completed in 2012, succeeding a smaller BN-600.[82] It reached its full power production in 2016.[83] Plans for the construction of a larger BN-1200 reactor (1,200 MWe) was scheduled for completion in 2018, with two additional BN-1200 reactors built by the end of 2030.[84] However, in 2015 Rosenergoatom postponed construction indefinitely to allow fuel design to be improved after more experience of operating the BN-800 reactor, and among cost concerns.[85]

An experimental lead-cooled fast reactor, BREST-300 will be built at the Siberian Chemical Combine in Seversk. The BREST (Russian: bystry reaktor so svintsovym teplonositelem, English: fast reactor with lead coolant) design is seen as a successor to the BN series and the 300 MWe unit at the SCC could be the forerunner to a 1,200 MWe version for wide deployment as a commercial power generation unit. The development program is as part of an Advanced Nuclear Technologies Federal Program 2010–2020 that seeks to exploit fast reactors for uranium efficiency while 'burning' radioactive substances that would otherwise be disposed of as waste. Its core would measure about 2.3 metres in diameter by 1.1 metres in height and contain 16 tonnes of fuel. The unit would be refuelled every year, with each fuel element spending five years in total within the core. Lead coolant temperature would be around 540 °C, giving a high efficiency of 43%, primary heat production of 700 MWt yielding electrical power of 300 MWe. The operational lifespan of the unit could be 60 years. The design was expected to be completed by NIKIET in 2014 for construction between 2016 and 2020.[86] By the end of 2024 the cooling tower had been built, and the target for starting operation was 2026.[citation needed]

Japan

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In 2006 the United States, France, and Japan signed an "arrangement" to research and develop sodium-cooled fast reactors in support of the Global Nuclear Energy Partnership.[87] In 2007 the Japanese government selected Mitsubishi Heavy Industries as the "core company in FBR development in Japan". Shortly thereafter, Mitsubishi FBR Systems was launched to develop and eventually sell FBR technology.[88]

The Marcoule Nuclear Site in France, location of the Phénix (on the left)

France

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In 2010 the French government allocated 651.6 million to the Commissariat à l'énergie atomique to finalize the design of ASTRID (Advanced Sodium Technological Reactor for Industrial Demonstration), a 600 MW fourth-generation reactor design to be finalized in 2020.[89][90] As of 2013 the UK had shown interest in the PRISM reactor and was working in concert with France to develop ASTRID. In 2019, CEA announced this design would not be built before mid-century.[91]

United States

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Kirk Sorensen, former NASA scientist and chief nuclear technologist at Teledyne Brown Engineering, has long been a promoter of thorium fuel cycle and particularly liquid fluoride thorium reactors. In 2011, Sorensen founded Flibe Energy, a company aimed to develop 20–50 MW LFTR reactor designs to power military bases.[92][93][94][95]

In October 2010 GE Hitachi Nuclear Energy signed a memorandum of understanding with the operators of the US Department of Energy's Savannah River Site, which should allow the construction of a demonstration plant based on the company's S-PRISM fast breeder reactor prior to the design receiving full Nuclear Regulatory Commission licensing approval.[96] In October 2011 The Independent reported that the UK Nuclear Decommissioning Authority (NDA) and senior advisers within the Department for Energy and Climate Change (DECC) had asked for technical and financial details of PRISM, partly as a means of reducing the country's plutonium stockpile.[97]

The traveling wave reactor proposed in a patent by Intellectual Ventures is a fast breeder reactor designed to not need fuel reprocessing during the decades-long lifetime of the reactor. The breed-burn wave in the TWR design does not move from one end of the reactor to the other but gradually from the inside out. Moreover, as the fuel's composition changes through nuclear transmutation, fuel rods are continually reshuffled within the core to optimize the neutron flux and fuel usage at any given point in time. Thus, instead of letting the wave propagate through the fuel, the fuel itself is moved through a largely stationary burn wave. This is contrary to many media reports, which have popularized the concept as a candle-like reactor with a burn region that moves down a stick of fuel. By replacing a static core configuration with an actively managed "standing wave" or "soliton" core, TerraPower's design avoids the problem of cooling a highly variable burn region. Under this scenario, the reconfiguration of fuel rods is accomplished remotely by robotic devices; the containment vessel remains closed during the procedure, and there is no associated downtime.[98]

See also

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References

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Revisions and contributorsEdit on WikipediaRead on Wikipedia
from Grokipedia
A breeder reactor is a nuclear fission reactor engineered such that the rate of fissile material production surpasses its consumption, primarily by employing fast neutrons to transmute fertile isotopes like uranium-238 into fissile plutonium-239 through neutron capture and subsequent beta decay. This breeding process enables the reactor to generate additional nuclear fuel alongside energy production, contrasting with conventional thermal reactors that primarily burn pre-existing fissile isotopes such as uranium-235. The concept emerged from early nuclear research aimed at maximizing uranium resource utilization, with the Experimental Breeder Reactor-I (EBR-I) achieving the first demonstration of breeding in 1953 and generating usable from in 1951. Subsequent developments included liquid-metal-cooled fast breeder designs, which offer advantages in fuel efficiency by extracting energy from over 60 times more than light-water reactors through the fission of bred . However, challenges such as the handling of reactive coolants like sodium, higher capital costs, and potential proliferation risks from separated have limited widespread commercialization. As of 2025, operational breeder reactors persist in with the BN-600 and BN-800 units, while India's nears commissioning, underscoring ongoing efforts to harness breeding for sustainable despite technical hurdles.

Definition and Principles

Breeding Mechanism

In breeder reactors, the breeding mechanism entails the neutron-induced transmutation of fertile isotopes—non-fissile nuclides such as (U-238) or (Th-232)—into fissile isotopes capable of sustaining fission chain reactions, such as (Pu-239) or (U-233). This occurs through followed by beta-minus decays: for the uranium-plutonium cycle, U-238 absorbs a to form U-239, which decays (half-life 23.5 minutes) to neptunium-239 (Np-239) and then to Pu-239 ( 2.36 days); similarly, Th-232 captures a to yield protactinium-233 (Pa-233, 27 days) before becoming U-233. The process leverages excess neutrons from fission events, where each fission typically releases 2.4–2.9 neutrons on average, allowing some to propagate the chain reaction while others drive breeding. The breeding ratio, defined as the ratio of fissile atoms produced to fissile atoms consumed (primarily via fission or parasitic capture), must exceed unity for net fissile gain; values above 1.1–1.2 are targeted in designs to account for reprocessing losses and ensure . Neutron economy is central: the average neutrons emitted per absorption in fissile material (η) must surpass 2 to support both criticality and breeding after accounting for leakage, structural captures, and fission product buildup. In fast-spectrum breeders, high-energy neutrons minimize parasitic absorption in coolant or cladding while enhancing η for Pu-239 (≈2.9 for fast neutrons versus ≈2.1 for thermal), enabling efficient U-238 utilization—over 60 times more energy extractable from compared to once-through light-water cycles. Thermal-spectrum breeding, as in thorium-fueled designs, relies on moderated neutrons but requires precise fuel blanketing to achieve ratios near 1, historically limited by higher parasitic captures; experimental evidence from the Shippingport Light Water Breeder Reactor (1977–1982) demonstrated a seed-blanket core yielding a conversion ratio of 1.07 using Th-232 and U-233. Overall, breeding extends fuel resources by converting the 99.3% abundant U-238 in , but demands advanced fuels, reprocessing, and safeguards against proliferation risks from separated Pu-239.

Neutron Economy and Reactor Physics

In breeder reactors, neutron economy refers to the balance between neutrons produced via fission and those consumed or lost, which must exceed requirements for criticality to enable net fissile material production. Fission of isotopes like plutonium-239 yields approximately 2.9 neutrons per event in a fast spectrum, providing the surplus needed for both sustaining the chain reaction (requiring one neutron per fission for k_eff ≈ 1) and breeding via capture in fertile materials such as uranium-238. Parasitic losses from leakage, structural absorption, and coolant interactions must be minimized to achieve a breeding ratio greater than unity, where fissile atoms produced exceed those consumed. The fast neutron spectrum, typically with energies above 1 MeV and lacking a moderator, enhances neutron economy by reducing non-fissile captures and increasing the probability of fission over absorption (lower alpha, the capture-to-fission ratio). For , the reproduction factor eta—s produced per absorption in the fuel—reaches about 2.1 to 2.3 in fast conditions, compared to lower values in thermal spectra due to higher resonance captures. This efficiency allows excess s to transmute fertile isotopes: a fast captured by U-238 forms U-239, which beta-decays to neptunium-239 and then , with the process optimized in a surrounding region. In contrast, thermal spectra suffer poorer economy from moderator absorptions and softer energies that favor capture without fission in actinides. Reactor physics in breeders hinges on achieving k_eff > 1 while maximizing the breeding gain, often quantified as BR = (fissile produced / fissile destroyed), targeting values of 1.05 to 1.3 in operational designs. The neutron balance equation incorporates production (νΣ_f φ, where ν is neutrons per fission, Σ_f fission cross-section, φ ), absorption in and non-fuel, and leakage; fast spectra minimize coolant and cladding captures (e.g., sodium's low macroscopic absorption cross-section aids this). of resonances provides negative reactivity feedback as temperature rises, stabilizing the core against power excursions, while the hard spectrum enables higher (up to 20% or more) by sustaining fission of transuranics. Thermal breeder concepts, such as cycles, demand exceptional economy (e.g., via moderation) but yield marginal BR near 1.0 due to inherent thermal losses.

Historical Development

Origins and Early Experiments (1940s-1950s)

The concept of a breeder reactor, which generates more than it consumes, originated during the early 1940s amid the ' wartime atomic energy program under the . Scientists, including those at the in , identified the potential to utilize abundant through fast neutron-induced fission and transmutation into , addressing the scarcity of naturally occurring uranium-235. This insight stemmed from fundamental calculations showing that fast spectrum reactors could achieve a breeding ratio greater than one, unlike thermal reactors limited to conversion ratios below unity. Post-World War II, the Atomic Energy Commission (AEC), established in 1946, prioritized experimental fast reactors to validate breeding principles. A precursor effort was the reactor at , the world's first plutonium-fueled fast neutron spectrum reactor, which achieved criticality on November 1, 1946, and operated until 1952 using mercury . primarily tested fast reactor physics, fuel behavior, and neutronics essential for future breeders, operating at up to 25 kilowatts thermal without demonstrating net breeding but confirming key fast flux characteristics. The landmark advancement came with the (EBR-I), designed by and constructed at the National Reactor Testing Station in starting in 1949. This achieved initial criticality on August 20, 1951, using fuel. On December 20, 1951, EBR-I generated sufficient to illuminate four 200-watt light bulbs, marking the first production of usable electrical power from a and demonstrating fast reactor viability at 1.4 megawatts thermal. EBR-I's breeding capability was experimentally verified on June 4, 1953, when isotopic analysis confirmed the production of fissile plutonium exceeding consumption, achieving a breeding ratio of approximately 1.0 in initial tests with a core of uranium-235 surrounded by a uranium-238 blanket. Operating until 1963, it produced over 500,000 hours of data on fast reactor operations, coolant performance, and fuel cycles, informing subsequent designs despite challenges like sodium leaks and fuel handling. These experiments established empirical proof of breeding's feasibility, grounded in precise neutron economy measurements, though scalability to commercial power remained unproven.

Proliferation of Prototypes (1960s-1980s)

During the 1960s to 1980s, multiple nations constructed experimental and prototype fast breeder reactors to validate breeding principles, test fuel cycles, and explore commercial scalability, driven by projections of shortages and interest in plutonium recycling. These efforts proliferated sodium-cooled designs, reflecting convergence on coolants for their transparency and heat transfer properties, though sodium's chemical reactivity posed persistent engineering challenges. In the United States, the Experimental Breeder Reactor-II (EBR-II) reached criticality in November 1963 with a power of 62.5 MW and electrical output of 20 MW, operating until 1994 and demonstrating passive features alongside onsite reprocessing. The Atomic Power Plant (Fermi 1), a 200 MW prototype, began operation in 1963 but suffered a partial meltdown in 1966 due to assembly blockage, leading to shutdown in 1972 after low capacity factors and repair costs exceeding $100 million. Later, the Fast Flux Test Facility (FFTF) started in 1980 at 400 MW for and materials , running until 1992 without power generation focus. The United Kingdom's Prototype Fast Reactor (PFR) at achieved grid connection in 1975 with 250 MW electrical capacity, but cumulative load factors remained below 10% due to steam generator leaks and extended outages, ceasing operations in 1994 amid funding cuts. France's Phénix prototype, operational from 1973 at 250 MW electrical (563 MW thermal), accumulated over 35 years of runtime with a 44.6% lifetime load factor, validating high-burnup and breeding ratios near 1.1, though it experienced reactivity transients and sodium leaks. followed in 1985 as a 1200 MW electrical demonstration, but achieved less than 7% lifetime load factor before closure in 1997 from technical failures and political opposition. Soviet prototypes included BN-350 in , grid-connected in 1972 at nominal 350 MW electrical (750 MW thermal, effective ~135 MW due to issues), which operated until 1999 while supporting and enduring a 1973 sodium fire. The BN-600 at Beloyarsk, reaching criticality in 1980 with 600 MW electrical output, demonstrated pool-type reliability with a 71.5% load factor despite 27 sodium leaks and 14 fires by 1997, incorporating tests. Other efforts encompassed Germany's KNK-II (1972-1991, 20 MW electrical) for component testing and Japan's Joyo experimental reactor (1977, 100 MW thermal), which served as an irradiation facility with limited runtime.
CountryReactorCriticality YearElectrical Power (MWe)Operational PeriodKey Challenge
USAEBR-II1963201963-1994Reliability in reprocessing integration
USAFermi 11963611963-1972Partial meltdown and blockages
UKPFR19742501974-1994Steam generator leaks
FrancePhénix19732501973-2009Sodium leaks and transients
USSRBN-3501972350 (nominal)1972-1999Sodium fire in 1973
USSRBN-60019806001980-presentMultiple sodium incidents
These prototypes collectively generated operational data on neutron economies achieving breeding ratios exceeding 1.0 in several cases, yet recurring sodium-related incidents underscored material incompatibilities and control complexities, tempering enthusiasm for rapid commercialization.

Setbacks and Continued Efforts (1990s-Present)

The French Superphénix fast breeder reactor, operational from 1986, faced repeated technical incidents including a sodium fire in 1990 and turbine hall collapse in 1990, contributing to an overall low capacity factor of approximately 14%. Public opposition, cost overruns exceeding initial estimates, and political decisions led to its definitive shutdown in 1997, with formal decommissioning decreed in December 1998. In the United States, the Integral Fast Reactor (IFR) program at Argonne National Laboratory, which demonstrated advanced fuel recycling and inherent safety features through tests at EBR-II up to 1994, was abruptly canceled by Congress that year for budgetary and non-technical policy reasons, halting progress toward commercialization despite successful whole-core passive shutdown demonstrations. Japan's Monju prototype, achieving criticality in 1994, suffered a major sodium coolant leak and fire in December 1995, followed by cover-up scandals, equipment failures such as a refueling machine drop in 1997, and regulatory halts; after limited restarts, it was decommissioned in December 2016 after accumulating only 250 full-power days. These closures reflected broader challenges including sodium handling risks, high capital costs relative to light-water reactors, and heightened anti-nuclear sentiment amplified by events like Chernobyl in 1986, which prioritized short-term economics and safety perceptions over long-term fuel cycle benefits. Russia sustained operations with the at Beloyarsk, which entered commercial service in 1980 and received a extension to 2025, accumulating over 40 years of experience in management. The BN-800 unit at the same site achieved grid connection in 2015, full commercial operation by November 2016, and transitioned to 100% mixed oxide ( loading in 2023, demonstrating breeding capabilities with a conversion ratio exceeding 1.0. commissioned its first prototype in province, reaching low-power operation by mid-2023 as part of Generation IV development for enhanced uranium utilization and waste transmutation, with a second unit under construction since 2020 and grid connection anticipated by 2025. In , the 500 MWe (PFBR) at advanced to integrated commissioning stages by 2024, receiving regulatory approval for fuel loading and targeting first criticality in 2025-2026 despite construction delays from 2004, aiming to breed from in a closed thorium-uranium cycle. These efforts underscore persistent interest in fast breeders for extending fissile resources—potentially multiplying uranium efficiency by 60 times through breeding—and reducing long-lived waste via fission, as outlined in IAEA assessments of fast reactor . Ongoing R&D focuses on mitigating sodium risks through alternative coolants like lead or gas in some designs, alongside pyroprocessing for proliferation-resistant reprocessing, though economic viability hinges on scaling beyond prototypes amid fluctuating markets.

Types of Breeder Reactors

Fast Breeder Reactors

Fast breeder reactors (FBRs) operate in the fast spectrum without a moderator, enabling a breeding greater than unity by converting fertile into fissile more efficiently than in thermal reactors. The fast reduces parasitic and enhances fission in , allowing the core to be surrounded by a uranium blanket where breeding occurs predominantly. This design achieves higher neutron economy, with potential energy extraction from increased by a factor of 60 to 70 compared to light-water reactors. FBRs feature compact cores with high , necessitating liquid coolants such as sodium for effective heat removal due to its high thermal conductivity and low neutron absorption. Sodium-cooled fast reactors (SFRs), the predominant type, maintain coolant temperatures around 550°C, enabling high thermodynamic efficiency but introducing challenges like sodium's reactivity with water and air, leading to potential leaks and fires. Alternative coolants like lead or lead-bismuth eutectic mitigate some sodium issues but pose and opacity concerns. Fuel typically consists of mixed oxide (MOX) of and in the core, with blankets for breeding; reprocessing recovers plutonium for recycling in a closed cycle. The Experimental Breeder Reactor-I (EBR-I) in the United States achieved criticality in 1951 and generated 200 kW of electricity on December 20, 1951, marking the first demonstration of breeding. Operational examples include Russia's BN-600, a 600 MWe sodium-cooled connected to the grid in 1980 and still producing power as of 2021, using MOX . Other prototypes faced setbacks: France's (1200 MWe) operated intermittently from 1986 but was decommissioned in 1997 after sodium leaks and ; Japan's Monju suffered multiple sodium fires and was defueled in 2016. These incidents highlight sodium handling difficulties, including and void coefficient reactivity effects requiring passive features like natural circulation cooling. Despite technical viability demonstrated in long-running units like BN-600, commercial deployment has been limited by high capital costs, reprocessing infrastructure needs, and proliferation risks from separated . Ongoing developments, such as Russia's BN-800 (operational since 2016), aim for improved and through advanced designs. FBRs offer sustainability benefits, including extended uranium resource utilization and transmutation of minor actinides to reduce long-lived waste, but realization depends on overcoming economic hurdles and demonstrating reliable closed-cycle operation. Approximately 20 fast neutron reactors have operated worldwide since the 1950s, with current focus on Generation IV concepts emphasizing and .

Thermal Breeder Reactors

Thermal breeder reactors sustain fission chain reactions using thermalized s while generating more than they consume, primarily through the conversion of to . This contrasts with uranium-plutonium cycles dominant in fast breeders, as captures s inefficiently in thermal spectra due to parasitic absorptions exceeding breeding gains. Achieving a breeding ratio greater than unity demands exceptional neutron economy, with fission yielding approximately 2.28 s per fission to offset losses in moderators, , and control materials. The sole full-scale demonstration occurred at the Shippingport Atomic Power Station's Light Water Breeder Reactor (LWBR) core, a 60 MWe pressurized water design operational from August 1977 to October 1982. It employed a seed-blanket configuration: highly enriched (over 98% U-233) pins as the fissile seed interspersed with oxide blankets to capture neutrons and produce U-233 via of protactinium-233. Post-irradiation confirmed a net breeding gain, with a measured breeding ratio of 1.01, indicating slight excess fissile production after accounting for initial loading and fissioned material. The core accumulated 29,047 effective full-power hours at a 65% , validating thermal breeding feasibility despite cladding defects in two rods. Conceptual designs for thermal breeders, such as liquid fluoride reactors (LFTRs), propose fuels to enable online reprocessing, mitigating protactinium-233 absorption losses that degrade economy in solid-fuel systems. These liquid-fueled approaches theoretically support breeding ratios exceeding 1.05 by continuously extracting fission products and breeding intermediates, though no operational prototypes have achieved sustained power generation. Challenges include from , precise isotopic separation for proliferation-resistant U-233 recovery, and the narrow margin for error in balance, where even minor increases in absorption cross-sections preclude breeding. Experimental efforts, like the U.S. (1965-1969), demonstrated U-233 operation and irradiation but fell short of full breeding due to incomplete fuel cycles. Current pursuits, including China's 2 MWth molten salt reactor started in 2021, focus on proof-of-concept rather than commercial breeding, highlighting persistent hurdles in scaling thermal designs amid preferences for established fast breeder technologies. Thermal breeders offer potential advantages in fuel abundance via reserves but require innovations in materials and processing to overcome inherent economy limitations compared to fast spectra.

Core Design Parameters

Breeding and Conversion Ratios

The breeding ratio (BR) in a nuclear reactor is defined as the number of fissile atoms produced per fissile atom consumed through fission, typically via neutron capture in fertile isotopes such as or thorium-232. In breeder reactors, a BR greater than 1 indicates net production of fissile material, enabling the reactor to generate more than it consumes over its operational cycle. This metric is crucial for assessing the reactor's potential to extend nuclear resources, as it quantifies the efficiency of transmuting fertile isotopes into fissile ones like or primarily in the reactor's blanket region. The conversion ratio (CR), closely related to BR, measures the rate of fertile-to-fissile conversion relative to fissile consumption but is often applied more broadly to non-breeding systems where CR < 1, distinguishing converters from breeders. While some literature uses the terms interchangeably in breeder contexts, BR emphasizes net gain (BR > 1) for , whereas CR can describe partial conversion in reactors, typically around 0.6 for light-water designs. Calculation of both involves : BR = (s absorbed in leading to fissile production) / (s causing fission in ), influenced by factors like , composition, and core-blanket . Fast spectra in breeders enhance BR by reducing parasitic captures compared to spectra. Achieving high BR requires optimizing neutron leakage to the blanket and minimizing losses to structural materials or coolant; for instance, sodium-cooled fast breeders can attain BR ≈ 1.3 due to low neutron moderation and high fast-fission cross-sections. Demonstrated examples include the proposed Breeder Reactor, designed for BR of 1.20 at start-of-life rising to 1.23 at end-of-cycle through optimized plutonium-uranium oxide . Gas-cooled fast breeders target BR up to 1.4, while thermal breeders like thorium-based systems achieve marginal gains closer to 1.0-1.02 over extended cycles, limited by higher parasitic absorption. Variations in BR over a reactor's life reflect burnup and reprocessing, with equilibrium BR stabilizing after initial loading adjustments.

Doubling Time and Fuel Efficiency Metrics

The doubling time of a breeder reactor quantifies the duration required to generate sufficient excess to double the initial fissile inventory, enabling the fueling of an additional identical reactor while sustaining the original. It is inversely related to the breeding ratio (BR), defined as the ratio of fissile atoms produced to those consumed, with net production rate determining the pace: approximately DT = (initial fissile mass × ln(2)) / (annual net fissile gain), where gains stem from transmutation via and subsequent . Shorter doubling times facilitate rapid fleet expansion but demand high BR values, often above 1.1, balanced against neutron economy losses from parasitic captures. Historical prototypes illustrate variability: the French Phénix reactor achieved a measured BR of about 1.16, implying a under 20 years under operational conditions, though design targets varied with fuel loading and . The proposed U.S. Breeder Reactor projected BRs of 1.20 at cycle start and 1.23 at end, corresponding to s of roughly 10-15 years depending on reprocessing efficiency and power output. Advanced designs, such as those with metallic fuels, have modeled s as low as 6-7 years at BR up to 1.9, though real-world deployment has rarely approached these due to material durability constraints. Compound system , accounting for multi-reactor growth, extends these figures by factoring in reprocessing delays and inventory buildup. Fuel efficiency in breeders surpasses light-water reactors (LWRs) through higher utilization of , the predominant isotope in , via fast neutron-induced breeding to for fission. LWRs achieve conversion ratios around 0.6, extracting energy primarily from enriched U-235 and leaving over 90% of uranium unused, whereas breeders with BR >1 enable near-complete resource exploitation, yielding 60-70 times more energy per tonne of . Key metrics include specific (gigawatt-days per tonne, often exceeding 100 GWd/t in fast breeders versus 40-50 GWd/t in LWRs) and closed-cycle fissile rates, which minimize waste actinides and enhance overall thermodynamic efficiency by sustaining high flux without frequent refueling.
MetricFast Breeder ReactorsLight-Water Reactors
Breeding/Conversion Ratio1.1-1.5 typical~0.6
8-20 yearsN/A (consumes fuel)
Uranium Utilization FactorUp to 60x natural U~1% of natural U
(GWd/t)100+40-50
These metrics underscore breeders' potential for resource extension, though actual efficiency hinges on reprocessing fidelity, with losses from incomplete separation reducing effective BR by 5-10%.

Reprocessing and Closed Fuel Cycle

Reprocessing of spent from breeder reactors extracts , , and minor s for , enabling a closed fuel cycle that contrasts with the open once-through approach used in most light-water reactors. In this cycle, recovered materials are refabricated into new assemblies, allowing breeders to achieve net fuel production through fission of fertile isotopes like uranium-238. Fast breeder reactors, in particular, support full actinide , burning long-lived isotopes together to minimize volume and radiotoxicity. The predominant reprocessing technique is , a hydrometallurgical process involving dissolution of fuel in followed by solvent extraction with to separate and plutonium. Adapted for mixed oxide (MOX) fuels common in breeders, PUREX has supported operations like France's Superphénix, where plutonium from spent fuel was recycled into fast reactor cores. Commercial PUREX capacity stands at approximately 2100 tonnes per year for fuel equivalents, with facilities like France's processing 1700 tonnes annually. For advanced closed cycles, modifications partition minor actinides like , , and for transmutation in fast spectrum reactors, reducing waste decay times from hundreds of thousands to hundreds of years. Pyroprocessing offers an alternative for metallic fuels in sodium-cooled fast reactors, using high-temperature molten salts for electrochemical separation that co-extracts actinides without isolating pure , thereby addressing proliferation concerns. Developed at since the 1980s, pyroprocessing integrates with reactors like GE Hitachi's design, recycling transuranics directly on-site. Russia's employs pyroprocessed vibropacked incorporating recycled and minor actinides. This method simplifies by vitrifying fission products separately and supports breeding ratios around 1.0 or higher in equilibrium cycles. Operational examples demonstrate feasibility: France's Phénix reactor reprocessed 25 tonnes of fuel, recycling plutonium multiple times between 1973 and 2009, while testing minor actinide burning from 2007 to 2009. India's (PFBR) at incorporates a closed thorium-uranium cycle with aqueous reprocessing, aiming for breeding ratios exceeding 1.0. Russia's BREST-OD-300 lead-cooled design features integrated pyrochemical reprocessing to recycle all actinides without aqueous separation. These systems enable utilization of stocks—estimated at 1.2 million tonnes globally as of 2018—as fertile material, extending uranium resources by factors of 60 compared to thermal reactors. In a fully closed cycle, up to 97% of heavy metal in spent fuel can be reused through repeated recycling, contrasting with the 3% utilization in open cycles.

Fuel Utilization and Sustainability

Maximizing Uranium Resources

Breeder reactors achieve superior uranium utilization by leveraging on the fertile isotope , which constitutes 99.3% of , to produce fissile , thereby accessing energy potential inaccessible to thermal reactors that primarily fission the scarce 0.7% content. In conventional light-water reactors operating on a once-through cycle, less than 1% of mined 's latent energy is extracted before the fuel is discarded as waste, whereas designs with breeding ratios greater than 1 enable the production of additional fissile material, supporting sustained chain reactions and fuel . This process effectively multiplies the usable energy from a given quantity of by factors of 60 to 100, depending on cycle efficiency and neutron economy. The fast neutron spectrum in liquid-metal-cooled fast breeder reactors minimizes parasitic neutron absorption and enhances plutonium fission cross-sections, allowing for high burnups exceeding 100 GWd/t and the transmutation of depleted uranium tails—typically containing 0.2-0.3% U-235 after enrichment—into viable fuel. Closed fuel cycles involving pyrochemical reprocessing further amplify this by recovering over 99% of actinides for reuse, reducing the need for fresh uranium mining and extending identified reserves from decades to millennia at current consumption rates. Experimental validation from the U.S. Experimental Breeder Reactor-II (EBR-II), operational from 1964 to 1994, confirmed intrinsic breeding gains through integral fast reactor testing, where self-sustained operation on recycled fuel demonstrated utilization rates far beyond thermal benchmarks. Thermal breeder variants, such as heavy-water moderated designs, offer modest extensions via thorium- cycles but achieve lower multiplication factors (around 10-20) due to softer spectra that favor capture over fission in ; however, fast systems predominate for maximal resource leverage, as evidenced by international assessments projecting global self-sufficiency for breeder fleets. These capabilities underscore breeder reactors' role in causal resource optimization, decoupling from enrichment dependency while empirical prototypes affirm absent systemic deployment barriers.

Nuclear Waste Reduction via Transmutation

Breeder reactors, particularly fast neutron variants, reduce nuclear waste by transmuting long-lived s into shorter-lived isotopes or stable elements through neutron-induced fission and capture. Minor s (MAs) such as neptunium-237, , and curium-244, which constitute less than 1% of spent fuel mass but account for over 99% of long-term radiotoxicity, exhibit fission cross-sections in fast neutron spectra that are orders of magnitude higher than in spectra, enabling their effective destruction. In sodium-cooled fast reactors (SFRs), this transmutation occurs alongside breeding, where excess neutrons from the core sustain the process without compromising fuel production. Transmutation strategies include homogeneous recycling, where MAs are blended into oxide or metallic fuel matrices, and heterogeneous approaches using dedicated targets in blanket or core peripheral regions to optimize neutron economy. Feasibility studies for SFRs demonstrate that multi-recycle closed fuel cycles can reduce MA inventory by 50-90% per pass, depending on loading fractions up to 5-10 wt% without significant neutronic penalties. This yields a potential 100-fold decrease in waste radiotoxicity after 200-300 years, compared to millennia for untreated spent fuel, by converting alpha-emitting MAs into beta/gamma-emitting fission products with half-lives under 30 years. While long-lived fission products (LLFPs) like and pose additional challenges due to lower capture cross-sections, fast breeders can partially address them via tailored core designs with moderated peripheral zones to enhance thermalization for capture reactions. Overall, integrating transmutation in breeder systems supports sustainable by minimizing geologic repository demands, with projected heat load reductions of 80-95% in advanced scenarios. Empirical data from test irradiations in reactors like Phenix confirm MA fission yields aligning with model predictions, validating scalability.

Technical Advantages

Enhanced Energy Yield and Resource Independence

Breeder reactors achieve enhanced energy yield through their ability to convert fertile isotopes, such as , into fissile via and subsequent , enabling a closed where more fissile material is produced than consumed. This process leverages fast neutron spectra in most designs, which have lower absorption cross-sections for fertile materials, facilitating breeding ratios exceeding 1.0. In contrast to light-water reactors, which primarily fission the 0.7% content of and discard the remainder as depleted tails, breeders utilize over 99% of the energy potential in uranium by recycling bred and minor actinides. Quantitative assessments confirm this superiority: fast breeder reactors can extract 60 to 100 times more energy per unit of natural uranium than thermal spectrum reactors operating in open fuel cycles. For instance, the International Atomic Energy Agency notes that the fast neutron spectrum increases energy yield from natural uranium by a factor of 60 to 70 relative to thermal reactors. Similarly, U.S. Department of Energy analyses indicate up to 100-fold improvement in fuel efficiency, reducing uranium requirements dramatically for equivalent energy output. Thermal breeder concepts, such as those using thorium-232 to breed uranium-233, offer comparable multiplication factors when integrated with reprocessing, though they have seen limited deployment. This heightened efficiency fosters resource independence by extending the viable lifespan of global uranium reserves from centuries under once-through cycles to thousands of years under breeding regimes. Known recoverable resources, estimated at around 6 million tonnes, could thus support sustained nuclear power generation indefinitely with minimal new mining, leveraging existing depleted uranium stockpiles exceeding 1.5 million tonnes worldwide. Such capabilities diminish reliance on concentrated uranium suppliers like and , which dominate current market supply, and enable utilization of abundant reserves—over 6 million tonnes identified—for alternative breeding cycles, further insulating from geopolitical fluctuations.

Environmental and Safety Superiorities Over Alternatives

Breeder reactors demonstrate environmental superiorities over light-water reactors (LWRs) through substantially higher , which minimizes requirements and associated ecological disruptions. Fast breeder reactors can extract up to 60 times more energy from than LWRs operating in once-through cycles, primarily by converting the abundant U-238 isotope (99.3% of ) into fissile Pu-239 via , thereby extending global uranium resources from centuries to millennia at current consumption rates. This reduced mining footprint lowers land disturbance, water usage, and tailings generation; for instance, LWRs require approximately 200 tonnes of per gigawatt-year of electricity, whereas breeders achieve equivalent output from recycled fuel with minimal new ore input. A core environmental benefit lies in waste minimization via closed fuel cycles and transmutation. Breeders fission minor s (e.g., , ) and isotopes that dominate long-term radiotoxicity in LWR spent fuel, reducing waste volume by factors of 50-100 and duration from over 300,000 years to around 500 years in full actinide recycle scenarios. Unlike LWRs, which leave 95% of extracted energy untapped in tails and spent fuel, breeders enable near-complete utilization, decreasing the mass of per terawatt-hour by up to 80% through reprocessing and recycling. On safety, breeder reactors offer advantages in reduced long-term storage risks due to lower waste inventories and enhanced , which diminishes the heat load and potential for criticality accidents in geological repositories compared to LWR spent fuel assemblies. Certain designs, such as sodium-cooled fast reactors, operate at without high-pressure vessels, mitigating risks inherent in LWRs and enabling passive removal via natural convection, as demonstrated in prototypes like the Experimental Breeder Reactor-II, where inherent feedback mechanisms halted excursions without operator intervention in tests. However, these benefits must be weighed against coolant-specific hazards, though empirical operational data from facilities like Russia's BN-600, with over 40 years of incident-free power generation as of 2021, indicate core damage probabilities below 10^{-6} per reactor-year, comparable to or lower than advanced LWR baselines when accounting for full lifecycle waste safety.

Challenges and Controversies

Engineering and Operational Hurdles

Breeder reactors, particularly liquid metal fast breeder reactors (LMFBRs), encounter significant engineering challenges due to the use of liquid sodium as a , which operates at high temperatures (typically 500–550°C) and exhibits strong chemical reactivity. Sodium ignites upon contact with air or water, posing risks of fires from leaks in coolant loops; historical incidents, such as sodium leaks in prototypes, have necessitated inert gas blanketing and specialized , complicating design and maintenance. from flowing sodium accelerates material thinning above 550°C, requiring advanced alloys like stainless steels with controlled carbon and content to mitigate dissolution and carburization/ effects. Additionally, sodium's opacity hinders of core components during outages, relying instead on ultrasonic or radiographic methods, which increase operational . High fast fluxes in breeder cores (up to 10^{23} n/m² over cycles) induce severe material degradation, including void swelling from and vacancy accumulation, leading to volumetric expansion of up to 20–30% in cladding and structural steels, which compromises dimensional stability and . creep and embrittlement further exacerbate these issues, reducing and necessitating frequent component replacements; for instance, pin swelling from fission gas release demands robust canning materials, yet empirical data from test reactors show persistent challenges in predicting long-term behavior under conditions. Operational safety concerns stem from the positive coolant void coefficient in many sodium-cooled designs, where void formation (e.g., from boiling or leaks) increases reactivity by reducing neutron absorption without commensurate moderation loss, potentially triggering power excursions absent passive shutdown mechanisms. This contrasts with reactors' negative coefficients and has contributed to design iterations incorporating absorbers or subcritical margins, though full-scale validation remains limited by low prototype availability rates (often below 30% in early units like France's ). Fuel handling adds complexity, as high content (15–20% in mixed oxide fuel) elevates criticality risks during fabrication and reprocessing, requiring glovebox isolation and specialized pyrochemical methods not yet scaled commercially. Decommissioning poses further hurdles, with residual activated sodium demanding neutralization via alcohol reactions or electrical reduction, processes that generate and , prolonging timelines and costs; IAEA reviews of fast reactor experience highlight these as barriers to closing demonstration facilities efficiently. Overall, these factors have resulted in few sustained commercial operations, with programs like the U.S. project abandoned in due to unresolved integration of advanced components under high-flux conditions.

Proliferation Risks and Security Concerns

Breeder reactors, particularly fast breeder designs, generate a net surplus of fissile plutonium-239 (Pu-239) from fertile uranium-238, enabling the potential production of weapons-usable material beyond what is consumed for energy generation. This breeding process occurs in the reactor core and blanket regions, where fast neutrons convert U-238 to Pu-239 at rates exceeding consumption, necessitating reprocessing to separate and recycle the plutonium, which heightens diversion risks compared to once-through light-water reactor cycles that do not yield a net fissile gain. The separated plutonium, if maintained at low burnup levels (typically under 100 MWd/t), can achieve weapons-grade purity with over 90% Pu-239 content, suitable for efficient bomb cores without isotopic impurities that complicate reactor-grade plutonium use in implosion designs. Historical precedents underscore these risks: India's 1974 nuclear test utilized plutonium derived from its early breeder-related research and safeguards exemptions, demonstrating how breeder fuel cycles can support covert weapons development under civilian programs. Similarly, France employed its Phénix fast breeder reactor in the 1970s to irradiate low-burnup fuel specifically for weapons-grade plutonium production, yielding material directly applicable to its arsenal expansion. Contemporary examples include China's CFR-600 sodium-cooled fast reactors, each capable of breeding up to 200 kilograms of weapons-grade plutonium annually—sufficient for approximately 50 warheads—amid opaque reporting on operational parameters that could minimize Pu-240 buildup for higher fissile purity. Security concerns extend to physical protection and safeguards implementation, as breeder facilities handle bulk plutonium during reprocessing and fabrication, vulnerable to theft or insider diversion. The (IAEA) addresses these through containment and surveillance (C/S) measures, such as seals, cameras, and material accountancy tailored to fast reactors' compact cores and high fluxes, which complicate traditional nondestructive techniques. However, interim storage of separated and fresh assembly prior to reactor loading represent proliferation hotspots, where detection of anomalies relies on timely inspections that may lag behind rapid diversion scenarios in states with advanced reprocessing capabilities. Despite these protocols, critics note that breeder proliferation risks have historically deterred widespread adoption, as evidenced by program cancellations in nations like the , where net plutonium multiplication outweighed fuel efficiency gains under nonproliferation priorities.

Economic Viability and Policy Obstacles

Breeder reactors face significant economic challenges primarily due to elevated compared to light water reactors (LWRs), stemming from complex designs involving coolants, advanced materials to withstand high fluxes, and integrated reprocessing facilities. A 1975 analysis estimated that liquid metal fast breeder reactor (LMFBR) could exceed LWRs by 20-50% when accounting for specialized components like sodium pumps and intermediate heat exchangers, with total overnight costs for a 1000 MWe unit potentially reaching $2-3 billion in then-current dollars adjusted for . These higher upfront investments, often 25% or more above conventional reactors, have deterred commercial deployment, as evidenced by the U.S. cancellation of the Breeder Reactor project in 1983 after costs ballooned from an initial $700 million to over $3 billion amid stagnant electricity demand and falling prices. Fuel cycle economics offer potential long-term advantages through breeding , reducing requirements by up to 100-fold and lowering levelized fuel costs to below 1 mill/kWh in mature systems, but these benefits are offset by the expense of reprocessing spent fuel to recover and minor actinides. In , a 2012 study projected plutonium costs at approximately $145 per gram for fast breeder reactor fuel fabrication, contributing to an overall fuel cycle cost of Rs. 2,610 for initial loading in a 500 MWe prototype, though operational savings from closed cycles could yield net positives only after decades of scaling. However, proliferation-resistant reprocessing technologies remain underdeveloped and costly, with historical U.S. efforts like the program halted in 1994 partly due to reprocessing expenses exceeding $1 billion without achieving commercial breakeven. Abundant uranium reserves—estimated at over 5.3 million tonnes recoverable at under $130/kg—further diminish the urgency for breeders, as LWR fuel costs constitute less than 10% of levelized electricity costs (LCOE), rendering breeding's resource extension uneconomical under current market conditions. Policy obstacles compound these economic hurdles, with proliferation risks from plutonium production and separation during reprocessing prompting stringent international regulations and domestic bans. The U.S. Atomic Energy Act amendments and Carter administration policies in the late 1970s effectively prohibited commercial reprocessing to curb weapons-grade material diversion, a stance reinforced by the 1994 termination of breeder R&D under , prioritizing nonproliferation over despite technical safeguards like denatured fuels. European experiences, such as France's 1997 decommissioning of the reactor after €7.7 billion in costs and low capacity factors, reflect shifts toward LWR standardization amid public opposition and EU directives emphasizing waste minimization over breeding. Regulatory frameworks, including lengthy licensing for non-water-cooled designs—often exceeding 10 years per the —impose additional delays and compliance costs, while global nonproliferation treaties like the NPT indirectly discourage breeder adoption by states without advanced safeguards infrastructure. In contrast, nations like and persist with programs (e.g., BN-800 operational since 2016), viewing breeders as strategic imperatives, but widespread inertia in the West favors incremental LWR improvements over disruptive fast reactor technologies.

Implementations and Prospects

Notable Historical and Operational Reactors

The (EBR-I), developed by , achieved criticality in September 1951 and on December 20, 1951, became the world's first reactor to generate usable electricity, powering four 200-watt lightbulbs. Designed as a liquid metal-cooled fast breeder reactor using fuel, EBR-I demonstrated the breeder concept by producing more than it consumed during operation. It operated until 1963, when a partial meltdown occurred due to a fuel handling error, providing data on accident behavior without off-site consequences, after which it was decommissioned. France's Phénix prototype fast breeder reactor at Marcoule achieved first criticality in 1973 and operated intermittently until final shutdown in 2009, accumulating over 35,000 equivalent full-power days. With a net capacity of 233 MWe, Phénix validated technology, fuel cycles, and transmutation processes, contributing to data on long-term operation and minor burning. Russia's at Beloyarsk , a sodium-cooled fast breeder with 560 MWe net capacity, entered commercial operation on April 1, 1980, and has since logged over 45 years of service with a design life extended to 2040. It has demonstrated high reliability, operating with mixed ( and achieving capacity factors exceeding 80% in recent years, while serving as a platform for testing advanced fuels. The BN-800 at the same site, with 789 MWe capacity, reached full power in 2016 and operates primarily on recycled from light-water reactors, marking the first industrial-scale fast reactor to close the fuel cycle using reprocessed . As of 2023, it sustained nearly full MOX core loading with reliable performance, supporting Russia's strategy for resource-efficient .

Ongoing and Planned Projects by Country

In China, the China Fast Reactor-600 (CFR-600) project features two sodium-cooled fast breeder reactors under construction at the Xiapu site in Fujian province, each with 600 MWe capacity. The first unit attained initial low-power operation in 2023, with full commercial startup targeted for 2025, while the second unit's completion is projected for the same year. These reactors aim to validate closed fuel cycle technologies, including plutonium breeding from uranium-238, supporting China's long-term nuclear expansion. India's (PFBR), a 500 MWe sodium-cooled pool-type design at , , remains in advanced commissioning following core fuel loading initiated in 2024. Despite repeated delays from its 2019 target, official projections indicate first criticality by March 2026 and grid connection by September 2026, positioning it as a cornerstone for India's three-stage nuclear program emphasizing utilization via breeding. Russia operates the BN-800 sodium-cooled fast breeder reactor at Beloyarsk since 2016 and has commenced site preparation for the BN-1200M, a 1200 MWe evolution, with construction licensing secured in April 2025 and projected operational date of 2034. This design incorporates mixed oxide fuel for enhanced breeding ratios and extended service life of at least 60 years, underpinning Rosatom's strategy for serial fast reactor deployment amid uranium supply constraints. Other nations, including and , have curtailed breeder initiatives; France terminated the ASTRID prototype in 2019, while Japan's Monju was decommissioned without successors. In the United States, no commercial breeder projects proceed, with advanced fast-spectrum efforts like TerraPower's Natrium focusing on energy storage rather than net fuel breeding.

References

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