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Aramid

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Aramid

Aramid, or aromatic polyamide fibers are a class of strong, heat-resistant, synthetic fibers, commonly used in aerospace and military applications - e.g., ballistic-rated body armor fabric and ballistic composites, marine cordage and hull reinforcement - as a substitute for asbestos, and in lightweight consumer items, such as phone cases and tennis rackets.

Individual amide molecules forming the aramid chain polymerise in the direction of the fiber axis, lending greater structural integrity to the resulting fiber. This is due to the higher proportion of chemical bonds which contribute to the physical strength and thermal resistance (melting point >500 °C (932 °F)) versus other synthetic fibres, such as nylon.

Notable brands of aramid fiber include Kevlar, Nomex, and Twaron.

The term aramid is shortened from aromatic polyamide. It was introduced in 1972, accepted in 1974 by the Federal Trade Commission of the USA as the name of a generic category of fiber distinct from nylon, and adopted by the International Organization for Standardization in 1977.[citation needed]

Aromatic in the longer name refers to the presence of aromatic rings of six carbon atoms. In aramids these rings are connected via amide linkages each comprising a CO group attached to an NH group.

In order to meet the FTC definition of an aramid, at least 85% of these linkages must be attached to two aromatic rings. Below 85%, the material is instead classed as nylon.

Aramids are divided into two main types according to where the linkages attach to the rings. Numbering the carbon atoms sequentially around a ring, para-aramids have the linkages attached at positions 1 and 4, while meta-aramids have them at positions 1 and 3. That is, the attachment points are diametrically opposite each other in para-aramids, and two atoms apart in meta-aramids. The illustration thus shows a para-aramid.

Aromatic polyamides were first introduced in commercial applications in the early 1960s, with a meta-aramid fiber produced by DuPont as HT-1 and then under the trade name Nomex. This fiber, which handles similarly to normal textile apparel fibers, is characterized by its excellent resistance to heat, as it neither melts nor ignites in normal levels of oxygen. It is used extensively in the production of protective apparel, air filtration, thermal and electrical insulation, and as a substitute for asbestos.

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