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Atomism
Atomism
from Wikipedia

Atomism (from Ancient Greek ἄτομον (atomon) 'uncuttable, indivisible')[1][2][3] is a natural philosophy proposing that the physical universe is composed of fundamental indivisible components known as atoms.

References to the concept of atomism and its atoms appeared in both ancient Greek and ancient Indian philosophical traditions. Leucippus is the earliest figure whose commitment to atomism is well attested and he is usually credited with inventing atomism.[4] He and other ancient Greek atomists theorized that nature consists of two fundamental principles: atom and void. Clusters of different shapes, arrangements, and positions give rise to the various macroscopic substances in the world.[5][4]

Indian Buddhists, such as Dharmakirti (fl. c. 6th or 7th century) and others, developed distinctive theories of atomism, for example, involving momentary (instantaneous) atoms (kalapas) that flash in and out of existence.

The particles of chemical matter for which chemists and other natural philosophers of the early 19th century found experimental evidence were thought to be indivisible, and therefore were given by John Dalton the name "atom", long used by the atomist philosophy. Although the connection to historical atomism is at best tenuous, elementary particles have become a modern analogue of philosophical atoms.

Reductionism

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Philosophical atomism is a reductive argument, proposing not only that everything is composed of atoms and void, but that nothing they compose really exists: the only things that really exist are atoms ricocheting off each other mechanistically in an otherwise empty void. One proponent of this theory was the Greek philosopher Democritus.[6]

By convention sweet is sweet, by convention bitter is bitter, by convention hot is hot, by convention cold is cold, by convention color is color. But in reality there are atoms and the void.

Atomism stands in contrast to a substance theory wherein a prime material continuum remains qualitatively invariant under division (for example, the ratio of the four classical elements would be the same in any portion of a homogeneous material).

Antiquity

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Greek atomism

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Democritus

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Democritus

In the 5th century BC, Leucippus and his pupil Democritus proposed that all matter was composed of small indivisible particles which they called "atoms".[7][8][9][10] Nothing whatsoever is known about Leucippus except that he was the teacher of Democritus.[10] Democritus, by contrast, wrote prolifically, producing over eighty known treatises, none of which have survived to the present day complete.[10] However, a massive number of fragments and quotations of his writings have survived.[10] These are the main source of information on his teachings about atoms.[10] Democritus's argument for the existence of atoms hinged on the idea that it is impossible to keep dividing matter infinitely - and that matter must therefore be made up of extremely tiny particles.[10] The atomistic theory aimed to remove the "distinction which the Eleatic school drew between the Absolute, or the only real existence, and the world of change around us."[11]

Democritus believed that atoms are too small for human senses to detect, that they are infinitely many, that they come in infinitely many varieties, and that they have always existed.[10] They float in a vacuum, which Democritus called the "void",[10] and they vary in form, order, and posture.[10] Some atoms, he maintained, are convex, others concave, some shaped like hooks, and others like eyes.[10] They are constantly moving and colliding into each other.[10] Democritus wrote that atoms and void are the only things that exist and that all other things are merely said to exist by social convention.[10] The objects humans see in everyday life are composed of many atoms united by random collisions and their forms and materials are determined by what kinds of atom make them up.[10] Likewise, human perceptions are caused by atoms as well.[10] Bitterness is caused by small, angular, jagged atoms passing across the tongue;[10] whereas sweetness is caused by larger, smoother, more rounded atoms passing across the tongue.[10]

Previously, Parmenides had denied the existence of motion, change and void. He believed all existence to be a single, all-encompassing and unchanging mass (a concept known as monism), and that change and motion were mere illusions. He explicitly rejected sensory experience as the path to an understanding of the universe and instead used purely abstract reasoning. He believed there is no such thing as void, equating it with non-being. This in turn meant that motion is impossible, because there is no void to move into.[12] Parmenides doesn't mention or explicitly deny the existence of the void, stating instead that what is not does not exist.[13][14][15] He also wrote all that is must be an indivisible unity, for if it were manifold, then there would have to be a void that could divide it. Finally, he stated that the all encompassing Unity is unchanging, for the Unity already encompasses all that is and can be.[12]

Democritus rejected Parmenides' belief that change is an illusion. He believed change was real, and if it was not then at least the illusion had to be explained. He thus supported the concept of void, and stated that the universe is made up of many Parmenidean entities that move around in the void.[12] The void is infinite and provides the space in which the atoms can pack or scatter differently. The different possible packings and scatterings within the void make up the shifting outlines and bulk of the objects that organisms feel, see, eat, hear, smell, and taste. While organisms may feel hot or cold, hot and cold actually have no real existence. They are simply sensations produced in organisms by the different packings and scatterings of the atoms in the void that compose the object that organisms sense as being "hot" or "cold".

The work of Democritus survives only in secondhand reports, some of which are unreliable or conflicting. Much of the best evidence of Democritus' theory of atomism is reported by Aristotle (384–322 BCE) in his discussions of Democritus' and Plato's contrasting views on the types of indivisibles composing the natural world.[16]

Unit-point atomism

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According to some twentieth-century philosophers,[17] unit-point atomism was the philosophy of the Pythagoreans, a conscious repudiation of Parmenides and the Eleatics. It stated that atoms were infinitesimally small ("point") yet possessed corporeality. It was a predecessor of Democritean atomism. Most recent students of presocratic philosophy, such as Kurt von Fritz, Walter Burkert, Gregory Vlastos, Jonathan Barnes, and Daniel W. Graham have rejected that any form of atomism can be applied to the early Pythagoreans (before Ecphantus of Syracuse).[18]

Unit-point atomism was invoked in order to make sense of a statement ascribed to Zeno of Elea in Plato's Parmenides: "these writings of mine were meant to protect the arguments of Parmenides against those who make fun of him. . . My answer is addressed to the partisans of the many. . ."[19] The anti-Parmenidean pluralists were supposedly unit-point atomists whose philosophy was essentially a reaction against the Eleatics. This hypothesis, however, to explain Zeno's paradoxes, has been thoroughly discredited.[citation needed]

Geometry and atoms

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Plato (c. 427c. 347 BCE) argued that atoms just crashing into other atoms could never produce the beauty and form of the world. In Plato's Timaeus (28b–29a) the character of Timeaus insisted that the cosmos was not eternal but was created, although its creator framed it after an eternal, unchanging model.[20]

Element Polyhedron Number of Faces Number of Triangles
Fire Tetrahedron

(Animation)

Tetrahedron 4 24
Air Octahedron

(Animation)

Octahedron 8 48
Water Icosahedron

(Animation)

Icosahedron 20 120
Earth Cube

(Animation)

Hexahedron (cube) 6 24
Geometrical simple bodies according to Plato

One part of that creation were the four simple bodies of fire, air, water, and earth. But Plato did not consider these corpuscles to be the most basic level of reality, for in his view they were made up of an unchanging level of reality, which was mathematical. These simple bodies were geometric solids, the faces of which were, in turn, made up of triangles. The square faces of the cube were each made up of four isosceles right-angled triangles and the triangular faces of the tetrahedron, octahedron, and icosahedron were each made up of six right-angled triangles.

Plato postulated the geometric structure of the simple bodies of the four elements as summarized in the adjacent table. The cube, with its flat base and stability, was assigned to earth; the tetrahedron was assigned to fire because its penetrating points and sharp edges made it mobile. The points and edges of the octahedron and icosahedron were blunter and so these less mobile bodies were assigned to air and water. Since the simple bodies could be decomposed into triangles, and the triangles reassembled into atoms of different elements, Plato's model offered a plausible account of changes among the primary substances.[21][22]

Rejection in Aristotelianism

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Sometime before 330 BC Aristotle asserted that the elements of fire, air, earth, and water were not made of atoms, but were continuous. Aristotle considered the existence of a void, which was required by atomic theories, to violate physical principles. Change took place not by the rearrangement of atoms to make new structures, but by transformation of matter from what it was in potential to a new actuality. A piece of wet clay, when acted upon by a potter, takes on its potential to be an actual drinking mug. Aristotle has often been criticized for rejecting atomism, but in ancient Greece the atomic theories of Democritus remained "pure speculations, incapable of being put to any experimental test".[23][24][unbalanced opinion?]

Aristotle theorized minima naturalia as the smallest parts into which a homogeneous natural substance (e.g., flesh, bone, or wood) could be divided and still retain its essential character. Unlike the atomism of Democritus, these Aristotelian "natural minima" were not conceptualized as physically indivisible. Instead, Aristotle's concept was rooted in his hylomorphic worldview, which held that every physical thing is a compound of matter (Greek hyle) and of an immaterial substantial form (Greek morphe) that imparts its essential nature and structure. To use an analogy we could pose a rubber ball: we could imagine the rubber to be the matter that gives the ball the ability to take on another form, and the spherical shape to be the form that gives it its identity of "ball". Using this analogy, though, we should keep in mind that in fact rubber itself would already be considered a composite of form and matter, as it has identity and determinacy to a certain extent, pure or primary matter is completely unformed, unintelligible and with infinite potential to undergo change.

Aristotle's intuition was that there is some smallest size beyond which matter could no longer be structured as flesh, or bone, or wood, or some other such organic substance that for Aristotle (living before the invention of the microscope) could be considered homogeneous. For instance, if flesh were divided beyond its natural minimum, what would be left might be a large amount of the element water, and smaller amounts of the other elements. But whatever water or other elements were left, they would no longer have the "nature" of flesh: in hylomorphic terms, they would no longer be matter structured by the form of flesh; instead the remaining water, e.g., would be matter structured by the form of water, not by the form of flesh.

Epicurus

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Epicurus

Epicurus (341–270 BCE) studied atomism with Nausiphanes who had been a student of Democritus. Although Epicurus was certain of the existence of atoms and the void, he was less sure we could adequately explain specific natural phenomena such as earthquakes, lightning, comets, or the phases of the Moon.[25] Few of Epicurus' writings survive, and those that do reflect his interest in applying Democritus' theories to assist people in taking responsibility for themselves and for their own happiness—since he held there are no gods around that can help them. (Epicurus regarded the role of gods as exemplifying moral ideals.)

Ancient Indian atomism

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Preliminary instances of atomism are found in the works of Vedic sage Aruni, who lived in the 8th century BCE,[dubiousdiscuss] especially his proposition that "particles too small to be seen mass together into the substances and objects of experience" known as kaṇa.[26] Although kana refers to "particles" not atoms (paramanu). Some scholars such as Hermann Jacobi and Randall Collins have compared Aruni to Thales of Miletus in their scientific methodology, calling them both as "primitive physicists" or "proto-materialist thinkers".[27] Later, the Charvaka,[28][29] and Ajivika schools of atomism originated as early as the 7th century BCE.[30][31][32] Bhattacharya posits that Charvaka may have been one of several atheistic, materialist schools that existed in ancient India.[33][34]

The NyayaVaisesika school developed theories on how kaṇas combined into more complex objects.[35]; scholars[who?] date the Nyaya and Vaisesika texts from the 9th to 4th centuries BCE. Vaisesika atomists posited the four elemental atom types, but in Vaisesika physics atoms had 25 different possible qualities, divided between general extensive properties and specific (intensive) properties. The Nyaya–Vaisesika atomists had elaborate theories of how atoms combine. In Vaisesika atomism, atoms first combine into tryaṇukas (triads) and Dvyaṇuka (dyad) before they aggregate into bodies of a kind that can be perceived.[36]

Several of these doctrines of atomism are, in some respects, "suggestively similar" to that of Democritus.[37] McEvilley (2002) assumes that such similarities are due to extensive cultural contact and diffusion, probably in both directions.[38]

Late Roman Republic

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Lucretius revives Epicurus

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Lucretius

Epicurus' ideas re-appear in the works of his Roman follower Lucretius (c. 99 BC – c. 55 BC), who wrote On the Nature of Things. This Classical Latin scientific work in poetic form illustrates several segments of Epicurean theory on how the universe came into its current stage; it shows that the phenomena we perceive are actually composite forms. The atoms and the void are eternal and in constant motion. Atomic collisions create objects, which are still composed of the same eternal atoms whose motion for a while is incorporated into the created entity. Lucretius also explains human sensations and meteorological phenomena in terms of atomic motion.

"Atoms" and "vacuum" vs. religion
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In his epic poem On the Nature of Things, Lucretius depicts Epicurus as the hero who crushed the monster Religion through educating the people in what was possible in atoms and what was not possible in atoms. However,[non sequitur] Epicurus expressed a non-aggressive attitude characterized by his statement:[39]

The man who best knows how to meet external threats makes into one family all the creatures he can; and those he can not, he at any rate does not treat as aliens; and where he finds even this impossible, he avoids all dealings, and, so far as is advantageous, excludes them from his life.

However, according to science historian Charles Coulston Gillispie:

Encased in the Epicurean philosophy, the atomic doctrine could never be welcome to moral authority. ... Epicurean gods neither created the world nor paid it ... attention. "Nature," says Lucretius, "is free and uncontrolled by proud masters and runs the universe by herself without the aid of gods." Only the atomists among ... Greek science ... was the one view of nature quite incompatible with theology. Like a pair of eighteenth-century philosophers, Epicurus and Lucretius introduced atomism as a vehicle of enlightenment. They meant to refute the pretensions of religion ... and release men from superstition and the undignified fear of capricious gods. Consequently, a hint of Epicureanism came to seem the mark of the beast in Christian Europe. No thinker, unless it is Machiavelli, has been more maligned by misrepresentation.[40]

The possibility of a vacuum was accepted—or rejected—together with atoms and atomism, for the vacuum was part of that same theory.

Democritus and Lucretius denied the impossibility of a vacuum, being of the opinion that there must be a vacuum between the discrete particles (atoms) of which, they thought, all matter is composed. In general, however, the belief that a vacuum is impossible was almost universally held until the end of the sixteenth century.[41] ... The time was certainly ripe for the revival of the belief in the possibility of a vacuum, but to the clerics the very name of the vacuum was anathema, being associated with the atomistic theories of Epicurus and Lucretius, which were felt to be heretical.[42]

Roman Empire

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Galen

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Galen

While Aristotelian philosophy eclipsed the importance of the atomists in late Roman and medieval Europe, their work was still preserved and exposited through commentaries on the works of Aristotle. In the 2nd century, Galen (AD 129–216) presented extensive discussions of the Greek atomists, especially Epicurus, in his Aristotle commentaries.

Middle Ages

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Medieval Hinduism

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Ajivika is a "Nastika" school of thought whose metaphysics included a theory of atoms or atomism which was later adapted in the Vaiśeṣika school, which postulated that all objects in the physical universe are reducible to paramāṇu (atoms), and one's experiences are derived from the interplay of substance (a function of atoms, their number and their spatial arrangements), quality, activity, commonness, particularity and inherence.[43] Everything was composed of atoms, qualities emerged from aggregates of atoms, but the aggregation and nature of these atoms was predetermined by cosmic forces.[44] The school founder's traditional name Kanada means 'atom eater',[45] and he is known for developing the foundations of an atomistic approach to physics and philosophy in the Sanskrit text Vaiśeṣika Sūtra.[46] His text is also known as Kanada Sutras, or Aphorisms of Kanada.[47][48]

Medieval Buddhism

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Statue of Dignagi, Golden Abode of Shakyamuni Buddha, Elista, Kalmykia
Dignāga

Medieval Buddhist atomism, flourishing around the 7th century, was very different from the atomist doctrines taught in early Buddhism. Medieval Buddhist philosophers Dharmakirti and Dignāga considered atoms to be point-sized, durationless, and made of energy. In discussing the two systems, Fyodor Shcherbatskoy (1930) stresses their commonality, the postulate of "absolute qualities" (guna-dharma) underlying all empirical phenomena.[49]

Still later, the Abhidhammattha-sangaha, a text dated to the 11th or 12th century, postulates the existence of rupa-kalapa, imagined as the smallest units of the physical world, of varying elementary composition.[50] Invisible under normal circumstances, the rupa-kalapa are said to become visible as a result of meditative samadhi.[51]

Medieval Islam

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Atomistic philosophies are found very early in Islamic philosophy and were influenced originally by earlier Greek and, to some extent, Indian philosophy.[52][53][54] Islamic speculative theology in general approached issues in physics from an atomistic framework.[55]

Mu'tazilite atomism

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Atomism in Mu'tazilism as an early Islamic theology is a cosmological concept that emphasizes that the universe consists of discrete (juz’ lā yatajazzā) or undivided parts created by God. This concept is also the basis for Mu'tazila's rejection of determinism. With an atomized nature, humans are considered capable of creating actions independently (mubasharah), so they deserve rewards or punishments according to their actions. This is in line with the principle that good and bad are rational and inherent in the essence of the action itself, not just the result of God's decision. The Mu'tazilah theologians and philosophers who are famous for their atomism concepts are Abu al-Hudhayl Al-'Allaf and Al-Jubba'i. While there are also Mu'tazilah theologians who are skeptical of atomism such as Ibrahim al-Nazzam.[56][57][58]

Al-Ghazali and Asharite atomism

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Al-Ghazali

The most successful form of Islamic atomism was in the Asharite school of Islamic theology, most notably in the work of the theologian al-Ghazali (1058–1111). In Asharite atomism, atoms are the only perpetual, material things in existence, and all else in the world is "accidental" meaning something that lasts for only an instant. Nothing accidental can be the cause of anything else, except perception, as it exists for a moment. Contingent events are not subject to natural physical causes, but are the direct result of God's constant intervention, without which nothing could happen. Thus nature is completely dependent on God, which meshes with other Asharite Islamic ideas on causation, or the lack thereof (Gardet 2001). Al-Ghazali also used the theory to support his theory of occasionalism. In a sense, the Asharite theory of atomism has far more in common with Indian atomism than it does with Greek atomism.[59]

Averroes rejects atomism

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Other traditions in Islam rejected the atomism of the Asharites and expounded on many Greek texts, especially those of Aristotle. An active school of philosophers in Al-Andalus, including the noted commentator Averroes (1126–1198 CE) explicitly rejected the thought of al-Ghazali and turned to an extensive evaluation of the thought of Aristotle. Averroes commented in detail on most of the works of Aristotle and his commentaries became very influential in Jewish and Christian scholastic thought.

Medieval Christendom

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According to historian of atomism Joshua Gregory, no serious work was done with atomism from the time of Galen until Isaac Beeckman, Gassendi and Descartes resurrected it in the 17th century; "the gap between these two 'modern naturalists' and the ancient Atomists marked "the exile of the atom" and "it is universally admitted that the Middle Ages had abandoned Atomism, and virtually lost it."

Scholasticism

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Although the ancient atomists' works were unavailable, scholastic thinkers gradually became aware of Aristotle's critiques of atomism as Averroes's commentaries were translated into Latin. Although the atomism of Epicurus had fallen out of favor in the centuries of Scholasticism, the minima naturalia of Aristotelianism received extensive consideration. Speculation on minima naturalia provided philosophical background for the mechanistic philosophy of early modern thinkers such as Descartes, and for the alchemical works of Geber and Daniel Sennert, who in turn influenced the corpuscularian alchemist Robert Boyle, one of the founders of modern chemistry.[60][61]

A chief theme in late Roman and Scholastic commentary on this concept was reconciling minima naturalia with the general Aristotelian principle of infinite divisibility. Commentators like John Philoponus and Thomas Aquinas reconciled these aspects of Aristotle's thought by distinguishing between mathematical and "natural" divisibility. With few exceptions, much of the curriculum in the universities of Europe was based on such Aristotelianism for most of the Middle Ages.[62]

Nicholas of Autrecourt

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Nicholas of Autrecourt

In medieval universities there were, however, expressions of atomism. For example, in the 14th century Nicholas of Autrecourt considered that matter, space, and time were all made up of indivisible atoms, points, and instants and that all generation and corruption took place by the rearrangement of material atoms. The similarities of his ideas with those of al-Ghazali suggest that Nicholas may have been familiar with Ghazali's work, perhaps through Averroes' refutation of it.[63]

Atomist renaissance

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17th century

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In the 17th century, a renewed interest arose in Epicurean atomism and corpuscularianism as a hybrid or an alternative to Aristotelian physics. The main figures in the rebirth of atomism were Isaac Beeckman, René Descartes, Pierre Gassendi, and Robert Boyle, as well as other notable figures.

Northumberland circle

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Francis Bacon

One of the first groups of atomists in England was a cadre of amateur scientists known as the Northumberland circle, led by Henry Percy, 9th Earl of Northumberland (1564–1632). Although they published little of account, they helped to disseminate atomistic ideas among the burgeoning scientific culture of England, and may have been particularly influential to Francis Bacon, who became an atomist around 1605, though he later rejected some of the claims of atomism. Though they revived the classical form of atomism, this group was among the scientific avant-garde: the Northumberland circle contained nearly half of the confirmed Copernicans prior to 1610 (the year of Galileo's The Starry Messenger). Other influential atomists of late 16th and early 17th centuries include Giordano Bruno, Thomas Hobbes (who also changed his stance on atomism late in his career), and Thomas Hariot. A number of different atomistic theories were blossoming in France at this time, as well (Clericuzio 2000).

Galileo Galilei

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Galileo Galilei

Galileo Galilei (1564–1642) was an advocate of atomism in his 1612 Discourse on Floating Bodies (Redondi 1969). In The Assayer, Galileo offered a more complete physical system based on a corpuscular theory of matter, in which all phenomena—with the exception of sound—are produced by "matter in motion".

Perceived vs. real properties
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Atomism was associated by its leading proponents with the idea that some of the apparent properties of objects are artifacts of the perceiving mind, that is, "secondary" qualities as distinguished from "primary" qualities.[64] Galileo identified some basic problems with Aristotelian physics through his experiments. He utilized a theory of atomism as a partial replacement, but he was never unequivocally committed to it. For example, his experiments with falling bodies and inclined planes led him to the concepts of circular inertial motion and accelerating free-fall. The current Aristotelian theories of impetus and terrestrial motion were inadequate to explain these. While atomism did not explain the law of fall either, it was a more promising framework in which to develop an explanation because motion was conserved in ancient atomism (unlike Aristotelian physics).

René Descartes

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Portrait of René Descartes
René Descartes

René Descartes' (1596–1650) "mechanical" philosophy of corpuscularism had much in common with atomism, and is considered, in some senses, to be a different version of it. Descartes thought everything physical in the universe to be made of tiny vortices of matter. Like the ancient atomists, Descartes claimed that sensations, such as taste or temperature, are caused by the shape and size of tiny pieces of matter. In Principles of Philosophy (1644) he writes: "The nature of body consists just in extension—not in weight, hardness, colour or the like."[65] The main difference between atomism and Descartes' concept was the existence of the void. For him, there could be no vacuum, and all matter was constantly swirling to prevent a void as corpuscles moved through other matter. Another key distinction between Descartes' view and classical atomism is the mind/body duality of Descartes, which allowed for an independent realm of existence for thought, soul, and most importantly, God.

Pierre Gassendi

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Pierre Gassendi

Pierre Gassendi (1592–1655) was a Catholic priest from France who was also an avid natural philosopher. Gassendi's concept of atomism was closer to classical atomism, but with no atheistic overtone. He was particularly intrigued by the Greek atomists, so he set out to "purify" atomism from its heretical and atheistic philosophical conclusions (Dijksterhius 1969). Gassendi formulated his atomistic conception of mechanical philosophy partly in response to Descartes; he particularly opposed Descartes' reductionist view that only purely mechanical explanations of physics are valid, as well as the application of geometry to the whole of physics (Clericuzio 2000).

Johann Chrysostom Magnenus

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Burning incense

Johann Chrysostom Magnenus (c. 1590c. 1679) published his Democritus reviviscens in 1646. Magnenus was the first to arrive at a scientific estimate of the size of an "atom" (i.e. of what would today be called a molecule). Measuring how much incense had to be burned before it could be smelled everywhere in a large church, he calculated the number of molecules in a grain of incense to be of the order 1018, only about one order of magnitude below the actual figure.[66]

Atomism and corpuscularianism

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Robert Boyle

Corpuscularianism is similar to atomism, except that where atoms were supposed to be indivisible, corpuscles could in principle be divided. In this manner, for example, it was theorized that mercury could penetrate into metals and modify their inner structure, a step on the way towards transmutative production of gold. Corpuscularianism was associated by its leading proponents with the idea that some of the properties that objects appear to have are artifacts of the perceiving mind: 'secondary' qualities as distinguished from 'primary' qualities.[67] Not all corpuscularianism made use of the primary-secondary quality distinction, however. An influential tradition in medieval and early modern alchemy argued that chemical analysis revealed the existence of robust corpuscles that retained their identity in chemical compounds (to use the modern term). William R. Newman has dubbed this approach to matter theory "chymical atomism," and has argued for its significance to both the mechanical philosophy and to the chemical atomism that emerged in the early 19th century.[68][69]

Isaac Newton

Corpuscularianism stayed a dominant theory over the next several hundred years and retained its links with alchemy in the work of scientists such as Robert Boyle (1627–1692) and Isaac Newton in the 17th century.[70][71] It was used by Newton, for instance, in his development of the corpuscular theory of light. The form that came to be accepted by most English scientists after Robert Boyle was an amalgam of the systems of Descartes and Gassendi. In The Sceptical Chymist (1661), Boyle demonstrates problems that arise from chemistry, and offers up atomism as a possible explanation. The unifying principle that would eventually lead to the acceptance of a hybrid corpuscular–atomism was mechanical philosophy, which became widely accepted by physical sciences. Boyle referred to indivisible particles as minima naturalia or prima naturalia, and only very rarely used the term "atom".[72]

Mikhail Lomonosov

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Mikhail Lomonosov

In his 1744 paper Meditations on the Cause of Heat and Cold, Russian polymath Mikhail Lomonosov specifically defined corpuscles as composite particles: "An element is part of a body which is not composed of any other smaller body ... A corpuscle is a collection of elements which constitute one small mass.."[73] In a later study (1748), he uses the term "atom" instead of "element", and "particula" (particle) or "molecule" instead of "corpuscle."

Modern atomic theory

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Late 18th century

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Roger Boscovich

By the late 18th century, the useful practices of engineering and technology began to influence philosophical explanations of the composition of matter. Those who speculated on the ultimate nature of matter began to verify their "thought experiments" with some repeatable demonstrations, when they could.

Ragusan polymath Roger Boscovich (1711–1787) provided the first general mathematical theory of atomism based on the ideas of Newton and Leibniz, but transforming them so as to provide a programme for atomic physics.[74]

19th century

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John Dalton

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John Dalton

In 1808, English physicist John Dalton (1766–1844) assimilated the known experimental work of many people to summarize the empirical evidence on the composition of matter.[75] He noticed that distilled water everywhere analyzed to the same elements, hydrogen and oxygen. Similarly, other purified substances decomposed to the same elements in the same proportions by weight.

Therefore we may conclude that the ultimate particles of all homogeneous bodies are perfectly alike in weight, figure, etc. In other words, every particle of water is like every other particle of water; every particle of hydrogen is like every other particle of hydrogen, etc.

Furthermore, he concluded that there was a unique atom for each element, using Lavoisier's definition of an element as a substance that could not be analyzed into something simpler. Thus, Dalton concluded the following.

Chemical analysis and synthesis go no farther than to the separation of particles one from another, and to their reunion. No new creation or destruction of matter is within the reach of chemical agency. We might as well attempt to introduce a new planet into the solar system, or to annihilate one already in existence, as to create or destroy a particle of hydrogen. All the changes we can produce, consist in separating particles that are in a state of cohesion or combination, and joining those that were previously at a distance.
John Dalton's alternative formulae for water and ammonia

And then he proceeded to give a list of relative weights in the compositions of several common compounds, summarizing:[76]

1st. That water is a binary compound of hydrogen and oxygen, and the relative weights of the two elementary atoms are as 1:7, nearly;
2nd. That ammonia is a binary compound of hydrogen and azote nitrogen, and the relative weights of the two atoms are as 1:5, nearly...

Dalton concluded that the fixed proportions of elements by weight suggested that the atoms of one element combined with only a limited number of atoms of the other elements to form the substances that he listed.

Atomic theory debate

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Alexander William Williamson

Dalton's atomic theory remained controversial throughout the 19th century.[77] Whilst the Law of definite proportion was accepted, the hypothesis that this was due to atoms was not so widely accepted. For example, in 1826 when Sir Humphry Davy presented Dalton the Royal Medal from the Royal Society, Davy said that the theory only became useful when the atomic conjecture was ignored.[78] English chemist Sir Benjamin Collins Brodie in 1866 published the first part of his Calculus of Chemical Operations[79] as a non-atomic alternative to the atomic theory. He described atomic theory as a 'Thoroughly materialistic bit of joiners work'.[80] English chemist Alexander Williamson used his Presidential Address to the London Chemical Society in 1869[81] to defend the atomic theory against its critics and doubters. This in turn led to further meetings at which the positivists again attacked the supposition that there were atoms. The matter was finally resolved in Dalton's favour in the early 20th century with the rise of atomic physics.

20th century

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Experimental verification

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Photo of Jean Perrin
Jean Perrin

Atoms and molecules had long been theorized as the constituents of matter, and Albert Einstein published a paper in 1905 that explained how the motion that Scottish botanist Robert Brown had observed was a result of the pollen being moved by individual water molecules, making one of his first contributions to science. This explanation of Brownian motion served as convincing evidence that atoms and molecules exist, and was further verified experimentally by French physicist Jean Perrin (1870–1942) in 1908. Perrin was awarded the Nobel Prize in Physics in 1926 "for his work on the discontinuous structure of matter". The direction of the force of atomic bombardment is constantly changing, and at different times the particle is hit more on one side than another, leading to the seemingly random nature of the motion.

See also

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References

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Revisions and contributorsEdit on WikipediaRead on Wikipedia
from Grokipedia
Atomism is a philosophical doctrine originating in ancient Greece that posits the universe consists of two fundamental principles: indivisible and eternal particles known as atoms, and the empty space or void through which they move. Similar ideas of indivisible particles developed independently in ancient Indian philosophy. Developed primarily by Leucippus (active around 440–430 BCE, possibly from Abdera or Miletus) and elaborated by his younger contemporary Democritus (c. 460–c. 370 BCE, from Abdera), atomism sought to resolve paradoxes of earlier Presocratic thinkers, such as Parmenides' denial of change and plurality, by explaining all phenomena through the mechanical interactions of atoms differing only in shape, size, position, and arrangement. According to surviving fragments, Leucippus described the cosmos as "both the empty [void] and the full," with atoms turning around one another in infinite motion governed by necessity rather than chance. Democritus expanded this framework, asserting that sensible qualities like color, taste, and sweetness are mere conventions arising from atomic configurations interacting with human senses, while in reality, "atoms and void" alone exist. He envisioned infinite atoms colliding and entangling in the void to form compounds, accounting for the coming-to-be and passing-away of objects without invoking divine intervention or . Although no complete works survive—only fragments preserved in later authors like and —their ideas emphasized a materialist, deterministic where everything occurs "as a result of a reason and by necessity." In the , (341–270 BCE) adapted atomism to support his ethical philosophy of pleasure and , introducing the concept of the "swerve"—a spontaneous deviation in atomic motion—to undermine strict determinism and allow for . Unlike , who viewed atoms as moving solely by necessity, Epicurus affirmed the reality of sensory perceptions and argued that atoms possess inherent weight, causing them to fall eternally through the void until collisions occur. This modified atomism influenced Roman poet , whose (1st century BCE) popularized the theory, portraying it as a liberating alternative to superstitious beliefs in gods and fate. Atomism's legacy extends beyond antiquity, inspiring thinkers and contributing to the , though ancient versions remained metaphysical rather than empirical models of . It provided a foundational materialist ontology that contrasted with idealist philosophies, emphasizing plurality, motion, and contingency in explaining the natural world.

Core Concepts

Reductionism and Atomistic Principles

Atomism is the philosophical doctrine that all consists of indivisible particles known as atoms, which differ only in , , position, and , moving through the void that provides the necessary empty space for their interactions and changes. The term derives from the word atomos, meaning "uncuttable" or "indivisible," reflecting the idea of fundamental units that cannot be further divided. Central to atomism are the principles that atoms are eternal, uncreated, and indestructible, preserving the fundamental building blocks of across all transformations. Atomic motion through the void accounts for all natural change and diversity, operating without divine intervention or causes in physical processes. Atomism exemplifies by positing that complex phenomena, including sensory qualities such as color and taste, emerge solely from the combinations, collisions, and arrangements of atoms, rather than existing as inherent or holistic properties of wholes. This approach contrasts with views that treat such qualities as irreducible or primordially unified, insisting instead that "in reality atoms and void" underlie all appearances. A successful atomistic explanation thus concludes with the material simplicity of atoms and void alone. Atomistic principles imply a deterministic framework for , where outcomes arise necessarily from prior atomic motions and configurations, and entail a rejection of by eliminating purpose, final causes, or directed design from natural explanations. This doctrine first emerged in as a materialist response to earlier cosmological debates.

Distinctions from Other Philosophical Views

Atomism fundamentally diverged from in its conception of matter and causation. While atomists like posited the universe as composed of discrete, indivisible atoms moving through void, Aristotle advocated for a continuous, infinitely divisible material substrate known as prime matter, which serves as the potentiality for forms but lacks independent existence. This contrast extended to explanatory frameworks: atomism relied on mechanistic interactions of atoms governed by necessity, rejecting Aristotle's —particularly the final cause, or teleological purpose—whereas Aristotle viewed natural processes as directed toward inherent ends, criticizing atomism for reducing all change to random collisions without qualitative differences in matter. In opposition to , early atomism emphasized a purely without recourse to transcendent ideal forms. Plato's cosmology in the Timaeus constructed elemental bodies from geometric solids built of indivisible triangles, allowing for transformation through reconfiguration of these mathematical primitives, but ultimately envisioning a continuous receptacle filled with forms rather than discrete particles. Atomists, by contrast, treated atoms as solid, unchangeable physical entities devoid of mathematical idealism, focusing on sensory qualities emerging from atomic shapes and arrangements rather than eternal, non- archetypes. This ist stance in atomism avoided Plato's dualism, where the sensible world imperfectly imitates an intelligible realm of perfect forms. Atomism also stood in stark contrast to hylomorphism, Aristotle's doctrine that substances arise from the union of matter and form as a single, unified composite. In hylomorphism, matter provides the substrate for substantial form, which actualizes potentialities and ensures the unity of the object—such as the soul informing the body in living beings—while rejecting the notion of atoms as self-subsistent primaries. Atomists, however, regarded atoms as the fundamental, independent building blocks of reality, with macroscopic properties and changes resulting solely from their aggregation and motion, without invoking a unifying form to bridge matter and essence. This reduction of composites to atomic parts challenged hylomorphism's emphasis on emergent, holistic substances over mere sums of discrete units. Early criticisms of atomism often portrayed it as atheistic and ethically subversive due to its material determinism. Detractors, including and later Platonists, accused atomists of denying by explaining cosmic order through blind necessity rather than purposeful intelligence, leading to charges of against figures like and . The deterministic implications—where all events stem from atomic collisions—were seen as undermining and , suggesting human actions as inevitable outcomes of material causes without room for ethical agency or divine intervention. attempted to counter this by introducing the "swerve" of atoms to introduce and preserve voluntariness, yet critics like the Stoics argued it failed to adequately support ethical accountability. Atomism's rejection of profoundly influenced later philosophical views by promoting a mechanistic that challenged purpose-driven explanations of nature. By attributing natural phenomena to the random motions and collisions of atoms, atomists like and supplanted Aristotelian and Platonic —where entities exist for specific ends—with a non-purposive , paving the way for materialist interpretations that prioritized efficient causes over final ones. This shift encouraged subsequent thinkers to view the universe as a self-regulating governed by physical laws, diminishing reliance on anthropocentric or divine designs in .

Ancient Origins

Greek Atomism

Greek atomism originated in the mid-5th century BCE with , who is credited as the founder of the theory in the Greek philosophical tradition. He proposed that all matter consists of indivisible particles called atoms (from the Greek atomos, meaning "uncuttable") moving through , or void, to explain the apparent changes and plurality in the world while preserving the Eleatic principle of the indestructibility of being. This framework addressed the paradoxes of motion and change posed by and Zeno by positing atoms as eternal, unchangeable bodies that combine and separate in the void to form observable phenomena. Leucippus's ideas were systematically developed by his associate or student (c. 460–370 BCE), from the Ionian colony of Abdera, into a comprehensive materialist cosmology. argued that atoms are infinite in number and eternal, differing only in shape, size, position, and arrangement, with no qualitative differences among them; they perpetually move in the infinite void, colliding randomly to form compounds. Sensory qualities such as color, taste, and heat are not inherent properties of atoms but "conventions" arising from atomic interactions with human senses—"By convention sweet, by convention bitter, by convention light, by convention heavy, by convention hot, by convention cold, but in reality atoms and void," as famously stated (DK 68 B9). This distinction between objective reality (atoms and void) and subjective perception laid the groundwork for a mechanistic view of nature, where all events result from atomic collisions without divine intervention. extended atomism to , advocating a cheerful that emphasized moderation and rational pursuit of pleasure to achieve euthymia (tranquility), viewing the itself as composed of fine, spherical atoms. More characteristically, incorporated geometry into atomic theory, describing atoms in various shapes—such as spheres for smooth textures, hooks and barbs for interlocking in stable compounds, and rough or jagged forms for denser materials—to explain the stability and properties of macroscopic objects like tissues or . These geometric configurations allowed atoms to hook together without fusing, ensuring the persistence of compounds while permitting dissolution through disentanglement. critiqued this in I 8, noting how atomic shapes account for qualitative differences in compounds. The Abdera school, centered in the Thracian city where both and resided, facilitated the spread of atomist ideas through their teachings and travels; reportedly journeyed widely, including to and , disseminating the doctrine. Fragments and reports preserved in later authors, such as Aristotle's Metaphysics A 4 (985b4), attest to the school's impact on subsequent before atomism waned under Aristotelian dominance.

Indian Atomism

Indian atomism emerged in ancient philosophical traditions, particularly within the school, which posited the existence of eternal, indivisible particles known as paramāṇu as the fundamental building blocks of matter. Founded by the sage around the 6th to 2nd century BCE, this school developed an atomistic ontology to explain the composition of the universe, emphasizing realism and logical analysis. 's Vaiśeṣika Sūtra outlines paramāṇu as infinitesimal, uncaused entities specific to the four elements—earth, water, fire, and air—that cannot be further divided and persist eternally without creation or destruction. These atoms combine through conjunctions to form perceptible objects, initiating processes of aggregation and dissolution that underpin cosmic cycles. The Vaisheshika framework classifies reality into six (or seven in later elaborations) categories, or padārthas: substance (dravya), quality (guṇa), action (karma), generality (sāmānya), particularity (viśeṣa), and (samavāya), with some texts adding non-existence (abhāva). Substances include the atomic paramāṇu as the primary units, alongside composite bodies and the ; qualities and actions describe attributes and motions of these substances, while generality and particularity account for shared and unique properties, respectively. Atomic combinations occur in dyads (binary pairs) and triads (ternary groups), driven by an unseen (adṛṣṭa) linked to karma, forming gross from invisible atoms and enabling empirical observation through and in and cosmology. In contrast, , particularly in the school from around the 3rd century BCE, rejected eternal substances in favor of momentary, impermanent atoms called kalāpas or paramāṇu, which arise and cease instantaneously as part of the flux of conditioned phenomena. These atoms, aggregates of dharmas (basic elements of existence), serve as the material basis for , where clusters form organs and objects, yet their transience underscores the illusion of permanence and contributes to () by fueling attachment. Drawing from texts like the Abhidharmakośa, atomists distinguished unitary atoms (dravya-paramāṇu) from composite ones (saṃghāta-paramāṇu), emphasizing that no eternal core exists, only interdependent processes aligned with the of no-self (anātman). Jain atomism conceptualizes as pudgala, an eternal substance composed of indivisible atoms (paramāṇu) that aggregate into perceptible forms through natural forces, with profound implications for karma and spiritual liberation. In Jain texts, pudgala encompasses all non-sentient material, from gross bodies to subtle karmic particles that bind to the (jīva), obscuring its innate purity and perpetuating (cycle of rebirth); atoms are point-sized, possess qualities like color and taste, and move omnidirectionally at immense speeds, forming compounds (skandhas) that constitute the . This , elaborated in works like the Tattvārthasūtra, integrates atomism with , positing that ethical conduct dissolves karmic matter, freeing the . A synthesis in the Nyāya-Vaiśeṣika tradition extended ancient atomic ideas by incorporating motion as inherent to atoms, describing vibratory (parispanda) and directional movements that enable cosmic dynamics without external causation. Later commentators like Praśastapāda refined Kaṇāda's views, positing five types of atomic motion—throwing, contraction, expansion, and others—that combine to produce observable changes, aligning with physics in an eternal space-time framework.

Classical and Late Antiquity

Epicurean and Roman Developments

(341–270 BCE), building briefly on the atomistic foundations of , adapted and expanded the theory to emphasize its ethical implications, founding his school in around 307/6 BCE in a setting that fostered communal philosophical discussion and as pathways to tranquility. He posited that the consists of atoms and void, with atoms possessing inherent qualities like , size, and weight that determine their interactions, thereby explaining all natural phenomena without recourse to divine intervention. Central to his revision was the concept of the clinamen or atomic swerve—a spontaneous, minimal deviation in atomic motion that introduces indeterminacy, enabling atomic collisions and, crucially, preserving human against deterministic necessity. also theorized the as composed of fine, spherical atoms dispersed throughout the body, responsible for sensation and thought, which dissolve at death to eliminate fears of punishment. This atomic framework underpinned his of pleasure (hedonē), where the highest good is the absence of bodily pain and mental disturbance (ataraxia), achieved through rational understanding of atomic processes that dispel superstition and promote simple, natural desires over excess. In the Late , gained prominence as an alternative to the dominant , offering a materialist that rejected teleological in favor of chance-governed atomic interactions, appealing to elites seeking amid political turmoil. The poet Titus Carus (c. 99–55 BCE) played a pivotal role in reviving and disseminating Epicurus's ideas through his epic poem ("On the Nature of Things"), composed in around 55 BCE and addressed to the Roman noble Memmius, making complex accessible via vivid metaphors and Hellenistic poetic traditions. detailed atomic motion, including , to argue for and soul mortality, while systematically explaining natural phenomena—such as as clashes of fiery atomic seeds in clouds and plagues as concentrations of noxious atoms—to demystify fears of gods and fate. His work not only preserved Epicurean doctrine during a period of philosophical competition but also critiqued Roman , positioning atomism as a liberating for ethical living. Roman adoption of extended beyond philosophy into literature, with Lucretius's poem influencing poets like (70–19 BCE), whose echoes atomic themes in descriptions of natural cycles and agricultural harmony, reflecting Epicurean ideals of contemplative retreat. The philosophy spread through informal Epicurean communities, akin to Epicurus's Athenian garden, including villas and circles led by figures like of , who taught in the Bay of Naples and fostered discussions among Roman intellectuals during the late Republic. These networks, emphasizing friendship and atomic-based , provided a counterpoint to Stoic emphasis on duty and fate, embedding atomism in Roman cultural life as a means to personal serenity amid civil strife.

Rejections and Criticisms in Antiquity

Aristotle, in the 4th century BCE, mounted a comprehensive rejection of atomism, primarily targeting the theories of Leucippus and Democritus as outlined in his On Generation and Corruption. He deemed the concept of indivisible atoms illogical because it contradicted the mathematical principle of the infinite divisibility of magnitudes, arguing that atoms could not truly be indivisible without violating observed continuity in nature. Instead, Aristotle advocated for a continuous hylomorphic view of matter, where form and matter are inseparable, and the four elements—earth, water, air, and fire—serve as the fundamental building blocks capable of qualitative alteration and mixture. Plato's critique of atomism appears in his dialogue Timaeus, where he implicitly rejects the materialist atoms of as overly simplistic and geometric in a reductive sense, failing to integrate the ideal forms that underpin reality. Rather than discrete physical particles, constructs the from mathematical indivisibles—triangles composing Platonic solids for the elements—emphasizing a hierarchical structure where sensible bodies derive from eternal, geometric ideals rather than random atomic collisions. This approach prioritizes teleological design by the , dismissing atomism's mechanistic void and motion as incompatible with the ordered participation in forms. The Stoics opposed atomism while embracing corporealism, positing instead a unified permeated by , a tensional, breath-like substance that integrates all matter without discrete particles or void. In contrast to the atomists' reliance on random atomic swerves for qualitative change, Stoic physics viewed —a of and air—as the active ensuring cohesion, growth, and sensation through varying degrees of tension, thereby maintaining a perfect continuum. This rejection preserved and , avoiding the atomists' perceived chaos. In the 2nd century CE, the physician extended medical critiques against atomism, particularly the version of Asclepiades, arguing that discrete particles could not account for the observed continuity and qualitative alterations in biological processes, such as sensation and . He favored the humoral , rooted in Hippocratic and Aristotelian traditions, where the four humors—blood, phlegm, yellow bile, and black bile—interact continuously within a teleological framework to explain , , and bodily unity, rendering atomism's mechanical explanations inadequate for empirical and . By the 1st century CE, atomism had largely declined in antiquity, marginalized by the ascendant Peripatetic and Platonic schools, whose emphasis on continuous matter, forms, and dominated philosophical and scientific discourse. Epicurean atomism persisted in isolated circles but faced systematic suppression through these rival traditions' institutional influence in academies and medical practice.

Medieval Interpretations

Islamic Atomism

Islamic atomism emerged as a significant philosophical and theological framework within medieval Islamic thought, particularly through the rationalist Mu'tazilite school during the 8th to 10th centuries. Mu'tazilite theologians posited that the consists of indivisible atoms known as jawhar (substances), which are inherently devoid of qualities, combined with transient accidents (a'rāḍ) that inhere in them. These atoms form the basis of all created bodies, emphasizing the temporal and contingent nature of the world to uphold the absolute unity (tawḥīd) of and the doctrine of divine . The created world, including divine attributes manifested as accidents, was seen as perpetually renewed by God's will, distinguishing Mu'tazilite atomism from Aristotelian notions of eternal, continuous matter. This atomistic tradition was further developed and radicalized by the Ash'arite school, exemplified in the works of (1058–1111). advanced an occasionalist interpretation, arguing that atoms are discrete and point-like, lacking inherent connections, and are recreated by God in each successive moment to sustain the appearance of continuity. In his (), critiqued for positing continuous matter and necessary causation, which he viewed as undermining divine omnipotence, instead promoting a where all events are direct divine interventions without intermediary causes. This Ash'arite atomism reinforced theological positions by denying natural necessity, ensuring God's absolute control over creation. In contrast, the Peripatetic philosopher Ibn Rushd (, 1126–1198) firmly rejected atomism, defending an Aristotelian framework of eternal, continuous matter against the discrete atoms of Mu'tazilites and Ash'arites. In his Tahāfut al-Tahāfut (The Incoherence of the Incoherence), Ibn Rushd argued that atomism leads to logical absurdities, such as in explaining motion and change, and fails to account for the observed unity and divisibility of bodies. He advocated for a hylomorphic view where matter is infinitely divisible, aligning with Peripatetic cosmology of an eternal world governed by natural laws under . Atomism profoundly influenced by providing a metaphysical foundation that supported doctrines like bodily and divine . By conceiving the body as a temporary aggregation of atoms and accidents, theologians could explain as God's reassembly of these elements without contradicting the annihilation of the original body at . This discrete also bolstered arguments for God's unlimited power, as it eliminated any autonomous causal powers in creation, making all existence dependent on continuous divine volition.

European and Indian Medieval Atomism

In medieval Europe, atomistic ideas persisted marginally within the framework of scholastic philosophy during the 12th to 14th centuries, often reconciled with Aristotelian principles rather than fully embraced as a rival system. Scholastics debated the concept of minima naturalia, posited as the smallest indivisible units of natural substances beyond which a given form could not be preserved, serving as a compromise between continuity and discreteness in explanations of change and mixture. This doctrine addressed Aristotle's rejection of true atoms by allowing for limits to divisibility while maintaining the continuum of matter, influencing discussions in natural philosophy at universities like Paris and Oxford. Medieval Jewish thinkers, influenced by Islamic , also engaged with atomism; for instance, (882–942) adopted a form of atomism to support creation ex nihilo and , though these ideas had limited direct transmission to Latin Christian . While 12th-century Latin translations of Arabic philosophical texts from centers like Toledo, including works by and , enriched scholastic debates on matter, form, and concepts like natural minima, explicit atomism in was more directly revived from sources or developed independently. A notable revival of more explicit atomism occurred through the French philosopher Nicholas of Autrecourt (c. 1299–1364), who drew on ancient atomistic influences to argue against the Aristotelian continuum. Autrecourt proposed that space, time, and motion consist of discrete, indivisible points and instants, with physical changes resulting from the local motion of infinitely small parcels of matter rather than . He rejected prime matter as a fiction and envisioned generation as the aggregation of qualitative atoms (e.g., "white atoms" or "fire atoms"), akin to ancient ideas but adapted with qualitative properties derived from scholastic minima naturalia. His views, presented in works like the Exigit ordo executionis, challenged the and , leading to condemnation by the in 1346 for 66 erroneous propositions; his books were burned, and he was forced to recant publicly at the papal court in . Despite this suppression, Autrecourt's atomism highlighted tensions between nominalist skepticism and orthodox in late medieval thought. In , atomism evolved within Hindu and Buddhist traditions, emphasizing metaphysical realism against idealistic challenges. The Vaiśeṣika school advanced its atomic pluralism, positing eternal, partless atoms (paramāṇu) of four elements (earth, water, air, fire) as the building blocks of the material world, combined into dyads and triads under divine agency to form composites. The 11th-century philosopher Udayana, a key figure in the Navya-Nyāya synthesis with Vaiśeṣika, provided proofs for God's existence by arguing that the precise organization and combination of atoms could not arise from chance but required an intelligent creator, thus integrating with atomistic mechanics. Buddhist atomism, meanwhile, took a momentary and idealistic turn, particularly through (c. 6th–7th century), who refined earlier views into a theory of transient, point-like atoms as fleeting events (dharmas) lacking substantial endurance, existing only as perceptual aggregates to explain the impermanence of experience. These "momentary atoms" inferred from macroscopic phenomena like dust particles interacting emphasized over , denying persistent substances in favor of causal chains. By the later medieval period, however, waned amid the rise of Advaita Vedānta non-dualism, which critiqued pluralistic atomism as illusory in the face of ultimate oneness.

Early Modern Revival

17th-Century Proponents

In the 17th century, atomism experienced a significant revival during the , as thinkers sought mechanistic explanations for natural phenomena grounded in ideas but adapted to contemporary empirical and philosophical contexts. This period saw the emergence of influential proponents who integrated atomic concepts with experimental inquiry and theological considerations, laying groundwork for later corpuscularian theories. Key figures included members of the English Northumberland circle, , , , and Johann Chrysostom Magnenus, each contributing distinct interpretations of atomic matter, motion, and void. The Northumberland circle, centered around Henry Percy, the 9th Earl of Northumberland, in early 17th-century England, represented one of the earliest organized groups to explore atomism through an experimental lens. This intellectual network, which included scholars like Thomas Hariot (1560–1621), emphasized empirical investigations into the particulate nature of matter, drawing on ancient atomist traditions while applying observational methods to phenomena such as optics and magnetism. Hariot, a mathematician and natural philosopher patronized by Northumberland, advanced atomistic views by positing that material bodies consist of discrete minima or atoms arranged in specific configurations, influencing discussions on combinations and void spaces in natural philosophy. Their approach contrasted with purely speculative philosophy by prioritizing hands-on experimentation, fostering a collaborative environment that anticipated the Royal Society's methods. Galileo Galilei (1564–1642) further propelled atomism by invoking corpuscles to explain sensory qualities in his 1623 work . He argued that primary qualities like , , and motion belong to minute particles, while secondary qualities such as arise from the specific configurations and movements of these corpuscles interacting with the senses—for instance, the bitterness of stems from angular, pointed particles that prick the tongue. Similarly, Galileo attributed not to an inherent "hotness" but to the rapid motion and friction of tiny corpuscles, aligning with a mechanistic view where all phenomena reduce to particulate dynamics. This corpuscularian framework, though not strictly atomic due to his acceptance of , bridged ancient atomism with emerging experimental . René Descartes (1596–1650) developed a variant of atomic theory within his mechanistic outlined in Principles of Philosophy (1644), positing the as a plenum filled with indefinitely divisible particles rather than true indivisible atoms. He rejected the void and atomic indivisibility, arguing that matter's essence is extension, allowing infinite division, but described vortical motions of corpuscles—subtle particles of varying sizes and shapes—that explain celestial and terrestrial phenomena, such as planetary orbits within swirling ether-like vortices. These "indefinite particles," categorized into primary (fluid, spherical), secondary (elongated), and tertiary (rigid) types, interact mechanically to produce all effects, integrating atomist-like corpuscles into a comprehensive without eternal atoms or voids. Descartes' framework emphasized God's role in imparting initial motion to these particles, harmonizing mechanism with theology. Pierre Gassendi (1592–1655), a French priest and philosopher, offered a Christianized revival of Epicurean atomism, presenting atoms as solid, indivisible particles created by God and moving eternally in a void. In works like Syntagma philosophiae Epicuri (1649), he reconciled ancient atomism with by attributing atomic origins and motions to divine will, rejecting Epicurean materialism's while retaining core tenets such as atoms possessing size, shape, and weight to explain sensory qualities and natural changes. Gassendi endorsed an containing an infinite supply of atoms, allowing for the possibility of infinite worlds formed by atomic collisions and arrangements, supported by empirical inferences from phenomena like and . His synthesis emphasized probabilistic knowledge derived from senses, positioning atomism as compatible with faith and observation. Johann Chrysostom Magnenus (c. 1590–c. 1679), a physician and professor at the University of Pavia, advocated a modified atomism in his 1646 treatise Democritus Reviviscens, sive de Atomic, reviving Democritean principles of discrete particles in motion within a void to account for diffusion and sensory experiences. Observing the diffusion of incense smoke through a church, Magnenus estimated the number of atoms in a small grain of incense (about the size of a pea) to be around 10^{18}, implying atomic diameters on the order of 10^{-7} cm; he used this to support the existence of minute, indivisible atoms that permeate space and explain phenomena like odors and magnetism without requiring a perfect vacuum. While retaining some Aristotelian plenism by limiting the void's extent, his work integrated atomic motion as the driver of natural processes, bridging medical and philosophical inquiries in the mechanical tradition.

Corpuscularianism and Mechanistic Philosophy

Corpuscularianism, a key development in 17th- and 18th-century , posited that all matter consists of tiny, indivisible particles called corpuscles, varying in shape, size, and motion, whose interactions in could mechanically explain the observable qualities and transformations of substances. This view extended ancient atomism by emphasizing empirical investigation over pure speculation, treating qualities like color, taste, or elasticity as emergent from corpuscular arrangements rather than inherent essences. Robert Boyle (1627–1691), a prominent advocate, integrated the corpuscular hypothesis into chemistry through his experimental work, arguing that chemical reactions resulted from the reconfiguration of corpuscles rather than alchemical transmutations or Aristotelian substantial forms. In works like (1661), Boyle rejected alchemy's reliance on vague principles such as the , instead promoting a mechanistic framework where corpuscles' shapes and motions accounted for phenomena like or . His air pump experiments, detailed in New Experiments Physico-Mechanicall, Touching the Spring of the Air (1660), demonstrated the production of a and the behavior of air as an elastic fluid composed of springy corpuscles, providing empirical support for corpuscularian explanations of pressure and expansion. Building on this tradition, (1711–1765) advanced atomic theory in by applying corpuscular ideas to chemical processes and formulating principles of matter conservation. In his 1756 dissertation, Lomonosov described matter as composed of interacting corpuscles and experimentally verified the law of through sealed-tube reactions showing no net weight change, countering and laying groundwork for . Corpuscularianism linked closely to Newtonian by envisioning atoms moving in a void but allowing for attractive and repulsive forces between them, diverging from the purely contact-based collisions of Democritean atomism. Boyle and later proponents incorporated Newton's gravitational and elastic forces as mechanisms enabling corpuscular cohesion and motion at a distance, thus bridging mechanical philosophy with emerging physics. This integration marked a philosophical shift from metaphysical speculation about indivisibles to proto-scientific inquiry, where hypotheses were tested via instruments and observations, fostering the transition toward modern experimental .

Transition to Scientific Theory

18th- and 19th-Century Foundations

In the late , Lavoisier's formulation of the law of provided a crucial empirical foundation for atomistic conceptions of matter, implying that substances are composed of discrete, indestructible particles that rearrange but neither appear nor disappear during chemical reactions. Lavoisier articulated this in his 1789 Traité Élémentaire de Chimie, where he emphasized precise quantitative measurements in experiments, such as the decomposition and recomposition of into and oxygen, demonstrating mass equivalence before and after reactions. Although Lavoisier himself avoided explicit commitment to atoms, preferring a continuum view of matter, his law aligned with the corpuscularian legacy by suggesting particulate indestructibility as a mechanistic explanation for chemical stability. Building on this groundwork, early proponents like William Higgins advanced proto-atomic ideas that anticipated quantitative chemical theories. In his 1789 book A Comparative View of the Phlogistic and Antiphlogistic Theories, Higgins proposed that chemical combinations occur between indivisible atoms of fixed weights, with elements forming compounds in simple numerical ratios, such as one-to-one or one-to-two. Higgins's model, influenced by Newtonian , envisioned atoms as surrounded by caloric , allowing for explanations of affinity and saturation without relying on outdated phlogiston concepts. These speculations, though not experimentally verified at the time, laid conceptual precursors for later atomic weight determinations by bridging philosophical atomism with emerging chemical . Joseph-Louis Proust further solidified the particulate basis of chemistry through his , established in a series of publications starting in 1794. Proust demonstrated that compounds, such as copper carbonate or iron oxides, always contain their constituent elements in fixed mass ratios regardless of preparation method or source material, as shown in his analyses of oxides where oxygen-to-metal ratios remained constant across samples. This law, fully articulated by 1799 amid debates with Berthollet who favored variable proportions, implied that chemical unions involve discrete units of matter combining in integral proportions, providing empirical support for atomic discreteness over continuous mixture theories. Philosophically, Immanuel Kant's 1786 Metaphysical Foundations of Natural Science accommodated within a critical framework, positing as composed of simple, moving parts endowed with attractive and repulsive to explain impenetrability and cohesion. Kant rejected strict mechanical atomism in favor of a dynamical theory where space-filling properties arise from interactions among ultimately simple substances, allowing in aggregates while preserving elementary particles as foundational. This synthesis reconciled Newtonian mechanics with Leibnizian continuity, enabling atomistic models to fit within empirical without contradicting . Early 19th-century debates on atomic simplicity highlighted tensions in these foundations, particularly through William Prout's 1815 that all elements derive from atoms, with atomic weights as multiples of 's (set at 1). Prout, in an anonymous paper in Annals of Philosophy, analyzed gaseous specific gravities and proposed as the primordial "protyle," suggesting simpler origins for observed elemental diversity and challenging the multiplicity of primitive atoms. This idea sparked controversy, as and others defended distinct atomic species based on experimental combining ratios, yet Prout's influenced pursuits of unified matter theories and refined atomic weight measurements throughout the century.

Dalton's Atomic Theory and Debates

John Dalton (1766–1844), an English chemist and physicist, formulated the first modern atomic theory between 1803 and 1808, building on earlier observations of chemical laws such as the . His ideas were detailed in the first volume of A New System of Chemical Philosophy, published in 1808, where he proposed that all matter consists of indivisible and indestructible atoms that retain their identity in chemical reactions. Dalton's theory posited five key postulates: (1) all matter is composed of tiny, indivisible particles called atoms; (2) atoms of the same element are identical in mass, size, and other properties; (3) atoms of different elements differ in mass and properties; (4) atoms combine in simple whole-number ratios to form compounds; and (5) atoms cannot be created or destroyed in chemical reactions. These postulates provided a mechanistic explanation for chemical combination, emphasizing fixed atomic weights and ratios. Dalton's evidence drew from his chemical analyses of gases, particularly the formation of water from hydrogen and oxygen, where he observed that elements combine in definite proportions by weight, such as approximately 1 part hydrogen to 7 parts oxygen (based on his relative atomic weights of 1 for H and 7 for O, with formula HO). He extended this to other compounds like ammonia, where he inferred a 1:1 atomic ratio (NH) from an experimental weight ratio of approximately 1:5 (H:azote, with azote at 5.4), and carbonic acid (CO₂), with a 1:2 atomic ratio corresponding to a weight ratio of about 1:2.6 (C:O, carbon at 5.4). The law of multiple proportions, a cornerstone of his theory, stated that when two elements form more than one compound, the masses of one element combining with a fixed mass of the other are in ratios of small whole numbers, as seen in the carbon oxides where the oxygen masses are in a 1:2 ratio (7 for CO and 14 for CO₂, relative to fixed carbon). This law unified earlier empirical observations into a coherent atomic framework. Despite its innovations, Dalton's theory sparked significant debates in the early . Swedish chemist , a prominent supporter of atomism, accepted the theory for inorganic compounds but criticized its application to , arguing that organic substances exhibited variable compositions and complex structures that defied simple atomic ratios, leading him to propose "organic atoms" as distinct entities. Berzelius's electrochemical theory further challenged Dalton by emphasizing electrical forces in bonding, which complicated the notion of identical atoms combining solely by mechanical affinity. Another major controversy arose with Amedeo Avogadro's 1811 hypothesis, which stated that equal volumes of gases at the same temperature and pressure contain equal numbers of molecules, resolving discrepancies in of combining gas volumes (e.g., 2 volumes + 1 volume oxygen form 2 volumes ). However, Avogadro's idea of diatomic molecules (e.g., H₂ and O₂) contradicted Dalton's assumption of monatomic elementary gases and was delayed in acceptance for over 50 years due to widespread adherence to Dalton's model and lack of immediate experimental confirmation. Dalton's theory laid the foundation for , enabling chemists to predict and calculate the proportions in chemical reactions based on atomic weights, as demonstrated in early tables of relative masses for elements like oxygen (7), azote (5.4), and carbon (5.4). It also provided precursors to the periodic table through systematic atomic weight determinations, influencing later work like that of on triads of elements with similar properties. These developments shifted chemistry from qualitative description to quantitative science, despite ongoing refinements to address the debates.

Modern and Contemporary Developments

20th-Century Experimental Advances

In 1897, J.J. Thomson conducted experiments on using a , measuring the deflection of the rays by electric and magnetic fields to determine their charge-to-mass ratio, leading to the conclusion that they consisted of negatively charged particles much smaller than atoms, which he named "corpuscles" or electrons. This discovery implied that atoms were composite structures, prompting Thomson to propose the in 1904, where electrons were embedded in a positively charged sphere like plums in a pudding, maintaining overall neutrality. Building on Thomson's work, , along with and , performed the gold foil experiment in 1909–1911, directing a beam of alpha particles at a thin gold foil and observing their patterns via a fluorescent screen. The unexpected observation that a small fraction of alpha particles deflected at large angles—some nearly backscattered—indicated that the positive charge and most of the atom's mass were concentrated in a tiny, dense nucleus, overturning the and establishing the nuclear atom. Rutherford's analysis in 1911 quantified the , showing that the nucleus had a radius less than 10^{-12} cm, far smaller than the atom's overall size of about 10^{-8} cm. In 1913, Niels Bohr refined the nuclear model by incorporating quantization principles, proposing that electrons orbit the nucleus in discrete energy levels or stationary states, preventing classical electromagnetic radiation and explaining the stability of atoms. Bohr's model successfully accounted for the discrete spectral lines of hydrogen, predicting that electron transitions between orbits emit or absorb photons with energies corresponding to the frequency differences, as verified by matching the Balmer series wavelengths. For hydrogen, the model yielded the Rydberg formula with high precision, where the energy levels are given by En=13.6n2E_n = -\frac{13.6}{n^2} eV for principal quantum number nn. Francis 's development of the mass spectrograph in 1919 provided direct experimental confirmation of isotopes, separating ions of into two distinct mass lines at approximately 20 and 22 units, demonstrating that elements could consist of atoms with different masses but similar chemical properties. By accelerating ions through electric and magnetic fields and focusing them based on , measured relative abundances and whole-number mass approximations for over 50 elements, supporting Prout's hypothesis of unity while revealing isotopic variations with resolving power up to 130. The nuclear model was further completed in 1932 when bombarded with alpha particles, producing a neutral that penetrated deeply and ejected protons from paraffin with energies up to 5.7 MeV, which he identified as neutrons—electrically neutral particles with mass nearly equal to the proton. 's experiments ruled out gamma-ray interpretations by measuring conservation in collisions, confirming the neutron's existence as a fundamental nuclear constituent and enabling explanations for defects and stability. This discovery resolved discrepancies in nuclear binding and paved the way for understanding isotopes through proton-neutron compositions.

Quantum and Subatomic Refinements

The advent of in the early fundamentally altered the classical conception of atoms as indivisible, deterministic particles, transforming atomism into a framework where is described by probabilistic wave functions and inherent uncertainties. This shift began with Erwin Schrödinger's formulation of the wave equation in 1926, which posits that electrons in atoms are not point-like orbits but delocalized probability distributions governed by the time-independent : 22m2ψ+Vψ=Eψ-\frac{\hbar^2}{2m} \nabla^2 \psi + V \psi = E \psi Here, ψ\psi represents the wave function, VV the potential, EE the energy eigenvalue, \hbar the reduced Planck's constant, and mm the particle mass. This equation, derived from an analogy between classical mechanics and optics, provided a mathematical basis for atomic spectra and stability, replacing Bohr's quantized orbits with continuous wave solutions that yield discrete energy levels upon boundary conditions. Complementing this, Werner Heisenberg's , articulated in 1927, established that atoms cannot be visualized as classical billiard balls with simultaneously precise position and momentum, as the relation ΔxΔp/2\Delta x \Delta p \geq \hbar/2 imposes a fundamental limit on measurement accuracy due to the non-commuting nature of quantum observables. This principle, rooted in the matrix mechanics formulation, underscored the probabilistic essence of subatomic reality, rendering classical trajectories meaningless and emphasizing observer-dependent outcomes in atomic processes. Building on the nuclear model briefly referenced in prior experimental contexts, the mid-20th century revealed atoms' composite structure through the discovery of quarks as fundamental constituents of protons and neutrons. In 1964, proposed the , positing that hadrons like protons (uud) and neutrons (udd) comprise three s—up (u), down (d), and strange (s)—with fractional charges (e.g., +2/3 for u, -1/3 for d) to explain the SU(3) flavor symmetry and observed particle multiplets. Independently, advanced a similar "ace" model in a report, though Gell-Mann's terminology prevailed. This framework resolved the proliferation of elementary particles by reducing them to quark combinations bound by the strong force. The strong interaction mediating quark binding was formalized in (QCD) during the 1970s, introducing gluons as the force carriers analogous to photons in . Harald Fritzsch, , and Heinrich Leutwyler proposed in 1973 that quarks possess a "color" charge (red, green, blue), with eight massless gluons exchanging color to confine quarks within color-neutral hadrons, ensuring at high energies and confinement at low scales. This non-Abelian gauge theory, with Lagrangian density incorporating gluon self-interactions, explained nuclear stability and data. These developments culminated in the of , integrated in the 1970s, which portrays atoms as composites of leptons (e.g., electrons) and quarks bound by electroweak and strong forces, while remains outside. The electroweak unification, pioneered by Steven Weinberg's 1967 model of massive gauge bosons via , merged electromagnetic and weak interactions into a single SU(2) × U(1) gauge theory, later incorporating quarks and QCD to describe all known atomic constituents except neutrino masses and . and contributed parallel formulations, earning the 1979 for this synthesis. Despite atoms' apparent indivisibility in classical atomism, the model affirms their foundational role as emergent bound states of more fundamental entities. As of 2025, atomism has evolved profoundly yet retains its reductionist core in , where the successfully predicts atomic phenomena from quark-gluon dynamics, though extensions like beyond-Standard-Model searches at the LHC probe deeper layers without overturning the hierarchical structure of matter. This probabilistic, subatomic paradigm continues to underpin advancements in quantum technologies and cosmology, validating atomism's legacy of dissecting reality into irreducible components governed by unified laws.

References

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