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Gas cylinder
Gas cylinder
from Wikipedia

Industrial compressed gas cylinders used for oxy-fuel welding and cutting of steel.

A gas cylinder is a pressure vessel for storage and containment of gases at above atmospheric pressure. Gas storage cylinders may also be called bottles. Inside the cylinder the stored contents may be in a state of compressed gas, vapor over liquid, supercritical fluid, or dissolved in a substrate material, depending on the physical characteristics of the contents. A typical gas cylinder design is elongated, standing upright on a flattened or dished bottom end or foot ring, with the cylinder valve screwed into the internal neck thread at the top for connecting to the filling or receiving apparatus.[1]

Nomenclature

[edit]

Gas cylinders may be grouped by several characteristics, such as construction method, material, pressure group, class of contents, transportability, and re-usability.[2]

The size of a pressurised gas container that may be classed as a gas cylinder is typically 0.5 litres to 150 litres. Smaller containers may be termed gas cartridges, and larger may be termed gas tubes, tanks, or other specific type of pressure vessel. A gas cylinder is used to store gas or liquefied gas at pressures above normal atmospheric pressure.[2] In South Africa, a gas storage cylinder implies a refillable transportable container with a water capacity volume of up to 150 litres. Refillable transportable cylindrical containers from 150 to 3,000 litres water capacity are referred to as tubes.[1]

A pressure receptacle is a general term for cylinders, bundles, tubes and pressure drums for the storage and transportation of compressed or liquefied gases with a water capacity from 0,5 L to 3000 L, and may be refillable or non refillable. Alternative terms include "transportable gas containers" and "transportable pressure containers".[3]

In the United States, "bottled gas" typically refers to liquefied petroleum gas. "Bottled gas" is sometimes used in medical supply, especially for portable high pressure oxygen cylinders. Packaged industrial gases are frequently called "cylinder gas", though "bottled gas" is sometimes used. The term propane tank is also used for cylinders for propane.[citation needed]

The United Kingdom and other parts of Europe more commonly refer to "bottled gas" when discussing any usage, whether industrial, medical, or liquefied petroleum. In contrast, what is called liquefied petroleum gas in the United States is known generically in the United Kingdom as "LPG" and it may be ordered by using one of several trade names, or specifically as butane or propane, depending on the required heat output.[citation needed]

The term cylinder in this context is sometimes confused with tank, the latter being an open-top or vented container that stores liquids under gravity, though the term scuba tank is commonly used to refer to a compressed gas cylinder used for breathing gas supply to an underwater breathing apparatus.

Components

[edit]
  • Cylinder – Either the shell or the complete assembly of shell and all accessories directly attached to the shell, depending on context.
  • Shell – The pressure vessel as a whole, excepting accessories.
    • Shoulder – The end of the shell with a neck or boss into which the valve is fitted.[4]
      • Neck – A coaxial cylindrical extension of the shoulder with a threaded hole into which the cylinder valve or a gas pipe connection is fitted.[5]
      • Boss – A sturdy insert, usually in the centre of the shoulder, into which a valve or gas pipe connection is fitted.[5]
    • Base or foot – The end of the shell opposite the shoulder.[5]
    • Liner – The core on which filament windings are laid. The core may be structural (usually metal), and share the pressure loads, or purely to separate composite wrapping from the cylinder contents, (metal or engineering plastic).[5]
  • Cylinder valve – a shutoff valve directly coupled to the cylinder shell at the neck or boss which is opened to allow gas flow into or out of the cylinder, and closed to prevent such flow. It usually has a threaded inlet/outlet opening to which other equipment can be connected, but in some cases may have an integral pressure regulator on the outlet side, and a separate inlet opening for filling.[4]
  • Foot ring – A permanently attached ring fitted to the base on which the cylinder can stand.[1]
  • Valve guard – A fitting (cap or collar) screwed or clamped to the shoulder, defending the valve from impact during transport, and in some cases, when in use.[1]
  • Permanent markings – Information identifying the cylinder and its specification, stamped into the outside of the shoulder on metal cylinders.[6] On composite cylinders permanent makings can be a printed label encapsulated under the resin or covered by a permanent transparent coating on the shoulder or side wall of the cylinder.[7]

Types

[edit]

Since fibre-composite materials have been used to reinforce pressure vessels, various types of cylinder distinguished by the construction method and materials used have been defined:[8][9]

  • Type 1: Metal only. Mostly seamless forged metal, but for lower working pressure, e.g., liquefied butane, welded steel vessels are also used.[9]
  • Type 2: Metal vessel, hoop wrapped with a fibre composite only around the cylindrical part of the "cylinder". (Geometrically there is a need for twice the tensile strength on the cylindrical region in comparison to the spherical caps of the cylinder.)[9]
  • Type 3: Thin metal liner (that keeps the vessel gas tight, but does not contribute to the strength) fully wrapped with fibre composite material.[9]
  • Type 4: Metal-free liner of plastic, fully wrapped with fibre composite material. The neck of the cylinder which includes the thread for the valve is a metal insert.[9]

Cylinder assemblies

[edit]

Assemblies comprising a group of cylinders mounted together for combined use or transport:

  • Bank – A group of cylinders connected to a gas distribution system for bulk storage, where the individual cylinders may be used together or separately, but are not necessarily supported by a structure which can be used to transport them as a group.
  • Cascade – A bank when used in cascade.
  • Quad or bundle, also occasionally gas pack or gas battery – A bank of high pressure gas storage cylinders, typically mounted upright on a rectangular frame for transport, and manifolded together.[10] A pallet is a similar appearing group of cylinders on a lifting frame with no functional connections. The maximum combined cylinder volume for a bundle is 3000 litres for non-toxic gases and 1000 litres for toxic gases. Gas bundles are specified by ISO 10961:2019 Gas cylinders — Cylinder bundles — Design, manufacture, testing and inspection.[11][12]
  • Rack – A structure to hold cylinders safely upright or horizontal while in use, for transport, or in storage.

Materials

[edit]

All-metal cylinders are the most rugged and usually the most economical option, but are relatively heavy. Steel is generally the most resistant to rough handling and most economical, and is often lighter than aluminium for the same working pressure, capacity, and form factor due to its higher specific strength. The inspection interval of industrial steel cylinders has increased from 5 or 6 years to 10 years. Diving cylinders that are used in water must be inspected more often; intervals tend to range between 1 and 5 years. Steel cylinders may continue to be used indefinitely providing they pass periodic inspection and testing.[13][14] When they were found to have inherent structural problems, certain steel and aluminium alloys were withdrawn from service, or discontinued from new production, while existing cylinders may require different inspection or testing, but remain in service provided they pass these tests.[citation needed]

For very high pressures, composites have a greater mass advantage. Due to the very high tensile strength of carbon fiber reinforced polymer, these vessels can be very light, but are more expensive to manufacture.[15] Filament wound composite cylinders are used in fire fighting breathing apparatus, high altitude climbing, and oxygen first aid equipment because of their low weight, but are rarely used for diving, due to their high positive buoyancy. They are occasionally used when portability for accessing the dive site is critical, such as in cave diving where the water surface is far from the cave entrance.[16][17] Composite cylinders certified to ISO-11119-2 or ISO-11119-3 may only be used for underwater applications if they are manufactured in accordance with the requirements for underwater use and are marked "UW".[18]

Cylinders reinforced with or made from a fibre reinforced material usually must be inspected more frequently than metal cylinders, e.g., every 5 instead of 10 years, and must be inspected more thoroughly than metal cylinders as they are more susceptible to impact damage. They may also have a limited service life.[citation needed] Fibre composite cylinders were originally specified for a limited life span of 15, 20 or 30 years, but this has been extended when they proved to be suitable for longer service.[citation needed]

Design

[edit]

The primary design focus for seamless metal (steel and aluminium) high pressure cylinders is on cylindrical wall thickness. This is calculated using the Lamé-von Mises formula for thick walled cylinders. Where the application may impose significant bending, torsional or local loads, these stresses must also be considered. Cylinder ends are generally approximately hemispherical, and require consideration for openings for internal inspection, filling and access to the contents.[19]a A corrosion allowance may be added to the design thiskness to allow for surface corrosion over the service life where applicable, and the stresses are generally limited so that the test pressure stress is within the fatigue limit for steel cylinders.[13]

The end dome thickness is usually determined by manufacturing process constraints, and for forged and spun ends the thickness tends to be greater than the cylindrical wall, though the pressure stresses in a spherical shell are roughly half those in a cylinder, making the ends much heavier than they need to be to theoretically withstand the pressure load. This extra thickness makes the ends relatively strong and able to support local stress concentrations due to stamp markings and neck threads. In seamless metal cylinders the thicker end wall and relatively small internal volume of the ends make the ends considerably heavier than the cylindrical section for the internal volume contribution, so this type of cylinder tends to be lighter per unit volume when the cylindrical part is longer.

Pressure rating

[edit]

The thickness of the cylinder wall is a function of the material the pressure and the diameter. The thickness of the ends is also affected by the manufacturing process.

  • Working pressure is the pressure that the cylinder is designed to withstand under working conditions at the nominal reference temperature.
  • Test pressure is the pressure the cylinder must withstand periodically when tested for revalidation. Hydrostatic test pressure (TP) is specified by the manufacturing standard. For seamless metal high-pressure cylinders, this is usually 1.5 × working pressure, or in the United States, 1.67 × working pressure.[1]
  • Developed pressure: Cylinder working pressure is specified at a reference temperature, usually 15 °C or 20 °C, and cylinders also have a specified maximum safe working temperature, often 65 °C.[1] The actual pressure in the cylinder will vary with temperature, as described by the gas laws, but this is acceptable in terms of the standards provided that the developed pressure when corrected to the reference temperature does not exceed the specified working pressure stamped on the cylinder. This allows cylinders to be safely and legally filled to a pressure that is higher than the specified working pressure when the filling temperature is greater than the reference temperature, but not more than 65 °C, provided that the filling pressure does not exceed the developed pressure for that temperature, and cylinders filled according to this provision will be at the correct working pressure when cooled to the reference temperature.[1]

Manufacturing processes

[edit]

Type 1 seamless metal cylinders

[edit]

The Type 1 pressure vessel is a seamless cylinder normally made of cold-extruded aluminum or forged steel.[20] The pressure vessel comprises a cylindrical section of even wall thickness, with a thicker base at one end, and domed shoulder with a central neck to attach a cylinder valve or manifold at the other end.

Occasionally other materials may be used. Inconel has been used for non-magnetic and highly corrosion resistant oxygen compatible spherical high-pressure gas containers for the US Navy's Mk-15 and Mk-16 mixed gas rebreathers, and a few other military rebreathers.

Aluminium

[edit]

Most aluminum cylinders are flat bottomed, allowing them to stand upright on a level surface, but some were manufactured with domed bottoms. Aluminum cylinders are usually manufactured by cold extrusion of aluminum billets in a process which first presses the walls and base, then trims the top edge of the cylinder walls, followed by press forming the shoulder and neck. The final structural process is machining the neck outer surface, boring and cutting the neck threads and O-ring groove. The cylinder is then heat-treated, tested and stamped with the required permanent markings. The extrusion process forms the bottom to match the shape of the die, so a curved or flat bottom can be chosen to fit the requirements of the end user.[21]

Steel

[edit]
Animation showing two stages of deep drawing of a steel plate to a cup, and a similar cup to a diving cylinder blank with domed bottom

Steel cylinders are often used because they are harder and more resistant to external surface impact and abrasion damage, and can tolerate higher temperatures without affecting material properties. They also may have a lower mass than aluminium cylinders with the same gas capacity, due to considerably higher specific strength. Steel cylinders are more susceptible than aluminium to external corrosion, particularly in seawater, and may be galvanized or coated with corrosion barrier paints to resist corrosion damage. It is not difficult to monitor external corrosion, and repair the paint when damaged, and steel cylinders which are well maintained have a long service life, often longer than aluminium cylinders, as they are not susceptible to fatigue damage when filled within their safe working pressure limits and re-validated to the appropriate test pressure.[13]

Steel cylinders are manufactured with domed (convex) and dished (concave) bottoms. The dished profile allows them to stand upright on a horizontal surface, and is the standard shape for industrial cylinders. The cylinders used for emergency gas supply on diving bells are often this shape, and commonly have a water capacity of about 50 litres. Domed bottoms give a larger volume for the same cylinder mass, and are the standard for scuba cylinders up to 18 litres water capacity, though some concave bottomed cylinders have been marketed for scuba. Domed end industrial cylinders may be fitted with a press-fitted foot ring to allow upright standing.[22][23]

Steel alloys used for gas cylinder manufacture are authorised by the manufacturing standard. For example, the US standard DOT 3AA requires the use of open-hearth, basic oxygen, or electric steel of uniform quality. Approved alloys include 4130X, NE-8630, 9115, 9125, Carbon-boron and Intermediate manganese, with specified constituents, including manganese and carbon, and molybdenum, chromium, boron, nickel or zirconium.[24]

Drawn from plate
[edit]

Steel cylinders may be manufactured from steel plate discs stamped from annealed plate or coil, which are lubricated and cold drawn to a cylindrical cup form, by a hydraulic press, this is annealed and drawn again in two or three stages, until the final diameter and wall thickness is reached. They generally have a domed base if intended for the scuba market, so they cannot stand up by themselves. For industrial use a dished base allows the cylinder to stand on the end on a flat surface. After forming the base and side walls, the top of the cylinder is trimmed to length, heated and hot spun to form the shoulder and close the neck. This process thickens the material of the shoulder. The cylinder is heat-treated by quenching and tempering to provide the best strength and toughness. The cylinders are machined to provide the neck thread and o-ring seat (if applicable), then chemically cleaned or shot-blasted inside and out to remove mill scale. After inspection and hydrostatic testing they are stamped with the required permanent markings, followed by external coating with a corrosion barrier paint or hot dip galvanising and final inspection.[25][5]

Spun from seamless tube
[edit]

A related method is to start with seamless steel tube of a suitable diameter and wall thickness, manufactured by a process such as the Mannesmann process, and to close both ends by the hot spinning process. This method is particularly suited to high pressure gas storage tubes, which usually have a threaded neck opening at both ends, so that both ends are processed alike. When a neck opening is only required at one end, the base is spun first and dressed inside for a uniform smooth surface, then the process of closing the shoulder and forming the neck is the same as for the pressed plate method.[5]

Forged from billet
[edit]

An alternative production method is backward extrusion of a heated steel billet, similar to the cold extrusion process for aluminium cylinders, followed by hot drawing and bottom forming to reduce wall thickness, and trimming of the top edge in preparation for shoulder and neck formation by hot spinning. The other processes are much the same for all production methods.[26] [5]

Cylinder neck
[edit]

The neck of the cylinder is the part of the end which is shaped as a narrow concentric cylinder, and internally threaded to fit a cylinder valve. There are several standards for neck threads, which include parallel threads where the seal is by an O-ring gasket, and taper threads which seal along the contact surface by deformation of the contact surfaces, and on thread tape or sealing compound.[4]

Type 2 hoop wrapped metal liner

[edit]

Type 2 is hoop wrapped with fibre reinforced resin over the cylindrical part of the cylinder, where circumferential load is highest. The fibres share the circumferential load with the metal core, and achieve a significant weight saving due to efficient stress distribution and high specific strength and stiffness of the composite. The core is a seamless metal cylinder, manufactured in any of the ways suitable for a type 1 cylinder, but with thinner walls, as they only carry about half the load, mainly the axial load. Hoop winding is at an angle to the length axis of close to 90°, so the fibres carry negligible axial load.[5]

Type 3 fully wrapped thin metal liner

[edit]

Type 3 is wrapped over the entire cylinder except for the neck, and the metal liner is mainly to make the cylinder gas tight, so very little load is carried by the liner. Winding angles are optimised to carry all the loads (axial and circumferential) from the pressurised gas in the cylinder. Only the neck metal is exposed on the outside. This construction can save in the order of 30% of the mass compared with type 2, as the fibre composite has a higher specific strength than the metal of the type 2 liner that it replaces.[5]

Type 4 fully wrapped plastic liner

[edit]

Type 4 is wrapped in the same way as type 3, but the liner is non-metallic. A metal neck boss is fitted to the shoulder of the plastic liner before winding, and this carries the neck threads for the cylinder valve. The outside of the neck of the insert is not covered by the fibre wrapping, and may have axial ridges to engage with a wrench or clamp for torsional support when fitting or removing the cylinder valve. There is a mass reduction compared with type 3 due to the lower density of the plastic liner.[5]

Welded gas cylinders

[edit]

A welded gas cylinder comprises two or more shell components joined by welding. The most commonly used material is steel, but stainless steel, aluminium and other alloys can be used when they are better suited to the application. Steel is strong, resistant to physical damage, easy to weld, relatively low cost, and usually adequate for corrosion resistance, and provides an economical product.

The components of the shell are usually domed ends, and often a rolled cylindrical centre section. The ends are usually domed by cold pressing from a circular blank, and may be drawn in two or more stages to get the final shape, which is generally semi-elliptical in section. The end blank is typically punched from sheet, drawn to the required section, edges trimmed to size and necked for overlap where appropriate, and hole(s) for the neck and other fittings punched. The neck boss is inserted from the concave side and welded in place before shell assembly.[27]

Smaller cylinders are typically assembled from a top and bottom dome, with an equatorial weld seam. Larger cylinders with a longer cylindrical body comprise dished ends circumferentially welded to a rolled central cylindrical section with a single longitudinal welded seam. Welding is typically automated gas metal arc welding.[27]

Typical accessories which are welded to the outside of the cylinder include a foot ring, a valve guard with lifting handles, and a neck boss threaded for the valve. Occasionally other through-shell and external fittings are also welded on.[27]

After welding, the assembly may be heat treated for stress-relief and to improve mechanical characteristics, cleaned by shotblasting, and coated with a protective and decorative coating. Testing and inspection for quality control will take place at various stages of production.[27]

Regulations and testing

[edit]

The transportation of high-pressure cylinders is regulated by many governments throughout the world. Various levels of testing are generally required by the governing authority for the country in which it is to be transported while filled. In the United States, this authority is the United States Department of Transportation (DOT). Similarly in the UK, the European transport regulations (ADR) are implemented by the Department for Transport (DfT). For Canada, this authority is Transport Canada (TC). Cylinders may have additional requirements placed on design and or performance from independent testing agencies such as Underwriters Laboratories (UL). Each manufacturer of high-pressure cylinders is required to have an independent quality agent that will inspect the product for quality and safety.

Within the UK the "competent authority" — the Department for Transport (DfT) — implements the regulations and appointment of authorised cylinder testers is conducted by United Kingdom Accreditation Service (UKAS), who make recommendations to the Vehicle Certification Agency (VCA) for approval of individual bodies.

There are a variety of tests that may be performed on various cylinders. Some of the most common types of tests are hydrostatic test, burst test, ultimate tensile strength, Charpy impact test and pressure cycling.

During the manufacturing process, vital information is usually stamped or permanently marked on the cylinder. This information usually includes the type of cylinder, the working or service pressure, the serial number, date of manufacture, the manufacture's registered code and sometimes the test pressure. Other information may also be stamped, depending on the regulation requirements.

High-pressure cylinders that are used multiple times — as most are — can be hydrostatically or ultrasonically tested and visually examined every few years.[28] In the United States, hydrostatic or ultrasonic testing is required either every five years or every ten years, depending on cylinder and its service.

Valve connections

[edit]
A gas regulator attached to a nitrogen cylinder. From right — cylinder valve, cylinder pressure gauge, pressure control valve (yellow) on regulator (green), outlet pressure gauge, 3-way outlet terminated by needle valves.

Neck thread

[edit]

Cylinder neck thread can be to any one of several standards. Both taper thread sealed with thread tape and parallel thread sealed with an O-ring have been found satisfactory for high pressure service, but each has advantages and disadvantages for specific use cases, and if there are no regulatory requirements, the type may be chosen to suit the application.[4]

A tapered thread provides simple assembly, but requires high torque for establishing a reliable seal, which causes high radial forces in the neck, and has a limited number of times it can be used before it is excessively deformed. This can be extended a bit by always returning the same fitting to the same cylinder, and avoiding over-tightening.[4]

In Australia, Europe and North America, tapered neck threads are generally preferred for inert, flammable, corrosive and toxic gases, but when aluminium cylinders are used for oxygen service to United States Department of Transportation (DOT) or Transport Canada (TC) specifications in North America, the cylinders must have parallel thread. DOT and TC allow UN pressure vessels to have tapered or parallel threaded openings. In the US, 49 CFR Part 171.11 applies, and in Canada, CSA B340-18 and CSA B341-18. In Europe and other parts of the world, tapered thread is preferred for cylinder inlets for oxidising gases.[4]

Scuba cylinders typically have a much shorter interval between internal inspections, so the use of tapered thread is less satisfactory due to the limited number of times a tapered thread valve can be re-used before it wears out,[4] so parallel thread is generally used for this application.[1]

Parallel thread can be tightened sufficiently to form a good seal with the O-ring without lubrication, which is an advantage when the lubricant may react with the O-ring or the contents. Repeated secure installations are possible with different combinations of valve and cylinder provided they have compatible thread and correct O-ring seals. Parallel thread is more likely to give the technician warning of residual internal pressure by leaking or extruding the O-ring before catastrophic failure when the O-ring seal is broken during removal of the valve. The O-ring size must be correct for the combination of cylinder and valve, and the material must be compatible with the contents and any lubricant used.[4]

Valve

[edit]

Gas cylinders usually have an angle stop valve at one end, and the cylinder is usually oriented so the valve is on top. During storage, transportation, and handling when the gas is not in use, a cap may be screwed over the protruding valve to protect it from damage or breaking off in case the cylinder were to fall over. Instead of a cap, cylinders sometimes have a protective collar or neck ring around the valve assembly which has an opening for access to fit a regulator or other fitting to the valve outlet, and access to operate the valve. Installation of valves for high pressure aluminum alloy cylinders is described in the guidelines: CGA V-11, Guideline for the Installation of Valves into High Pressure Aluminum Alloy Cylinders and ISO 13341, Transportable gas cylinders—Fitting of valves to gas cylinders.[4]

Connection

[edit]

The valves on industrial, medical and diving cylinders usually have threads or connection geometries of different handedness, sizes and types that depend on the category of gas, making it more difficult to mistakenly misuse a gas. For example, a hydrogen cylinder valve outlet does not fit an oxygen regulator and supply line, which could result in catastrophe. Some fittings use a right-hand thread, while others use a left-hand thread; left-hand thread fittings are usually identifiable by notches or grooves cut into them, and are usually used for flammable gases.

In the United States, valve connections are sometimes referred to as CGA connections, since the Compressed Gas Association (CGA) publishes guidelines on what connections to use for what gasses. For example, an argon cylinder may have a "CGA 580" connection on the valve. High purity gases sometimes use CGA-DISS ("Diameter Index Safety System") connections.

Common cylinder valve connections
Gas type CGA valve outlet (USA)
Acetylene 510
Air, breathing 346, 347
Air, industrial 590
Argon 580, 718, 680 (3,500 psi), 677 (6,000 psi)
Butane 510
Carbon dioxide 320, 716
Carbon monoxide 350, 724
Chlorine 660, 728
Helium 580, 718, 680 (3,500 psi)
Hydrogen 350, 724, 695 (3,500 psi)
Methane 350
Neon 580, 718
Nitrogen 580, 718, 680 (3,500 psi), 677 (6,000 psi)
Nitrous oxide 326, 712
Oxygen 540, 714
Oxygen mixtures (>23.5%) 296
Propane 510
Xenon 580, 718

Medical gases may use the Pin Index Safety System to prevent incorrect connection of gases to services.

In the European Union, DIN connections are more common than in the United States.

In the UK, the British Standards Institution sets the standards. Included among the standards is the use left-hand threaded valves for flammable gas cylinders (most commonly brass, BS4, valves for non-corrosive cylinder contents or stainless steel, BS15, valves for corrosive contents). Non flammable gas cylinders are fitted with right-hand threaded valves (most commonly brass, BS3, valves for non-corrosive components or stainless steel, BS14, valves for corrosive contents).[29]

Common cylinder valve connections
Gas type BS valve outlet (UK)[29]
Acetylene 2, 4
Air, breathing 3
Air, industrial 3
Argon 3
Butane 4
Carbon dioxide 8
Carbon monoxide 4
Chlorine 6
Helium 3
Hydrogen 4
Methane 4
Neon 3
Nitrogen 3
Nitrous oxide 13
Oxygen 3
Oxygen mixtures (>23.5%) Other guides apply
Propane 4
Xenon 3

Regulator

[edit]

When the gas in the cylinder is to be used at low pressure, the cap is taken off and a pressure-regulating assembly is attached to the stop valve. This attachment typically has a pressure regulator with upstream (inlet) and downstream (outlet) pressure gauges and a further downstream needle valve and outlet connection. For gases that remain gaseous under ambient storage conditions, the upstream pressure gauge can be used to estimate how much gas is left in the cylinder according to pressure. For gases that are liquid under storage, e.g., propane, the outlet pressure is dependent on the vapor pressure of the gas, and does not fall until the cylinder is nearly exhausted, although it will vary according to the temperature of the cylinder contents. The regulator is adjusted to control the downstream pressure, which will limit the maximum flow of gas out of the cylinder at the pressure shown by the downstream gauge. For some purposes, such as shielding gas for arc welding, the regulator will also have a flowmeter on the downstream side.

The regulator outlet connection is attached to whatever needs the gas supply.

Safety and standards

[edit]
It would be safer to have cylinders individually anchored in a cool place, rather than chained in a cluster in the sun, as seen here.

Because the contents are under pressure and are sometimes hazardous materials, handling bottled gases is regulated. Regulations may include chaining bottles to prevent falling and damaging the valve, proper ventilation to prevent injury or death in case of leaks and signage to indicate the potential hazards. If a compressed gas cylinder falls over, causing the valve block to be sheared off, the rapid release of high-pressure gas may cause the cylinder to be violently accelerated, potentially causing property damage, injury, or death. To prevent this, cylinders are normally secured to a fixed object or transport cart with a strap or chain. They can also be stored in a safety cabinet.

In a fire, the pressure in a gas cylinder rises in direct proportion to its temperature. If the internal pressure exceeds the mechanical limitations of the cylinder and there are no means to safely vent the pressurized gas to the atmosphere, the vessel will fail mechanically. If the vessel contents are flammable, this event may result in a "fireball".[30] Oxidisers such as oxygen and fluorine will produce a similar effect by accelerating combustion in the area affected. If the cylinder's contents are liquid, but become a gas at ambient conditions, this is commonly referred to as a boiling liquid expanding vapour explosion (BLEVE).[31]

Medical gas cylinders in the UK and some other countries have a fusible plug of Wood's metal in the valve block between the valve seat and the cylinder.[citation needed] This plug melts at a comparatively low temperature (70 °C) and allows the contents of the cylinder to escape to the surroundings before the cylinder is significantly weakened by the heat, lessening the risk of explosion.[32]

Fusible plugs are also used on some acetylene cylinders.[33]

More common pressure relief devices are a simple burst disc installed in the base of the valve between the cylinder and the valve seat. A burst disc is a small metal gasket engineered to rupture at a pre-determined pressure. Some burst discs are backed with a low-melting-point metal, so that the valve must be exposed to excessive heat before the burst disc can rupture.[citation needed]

The Compressed Gas Association publishes a number of booklets and pamphlets on safe handling and use of bottled gases.

International and national standards

[edit]

There is a wide range of standards relating to the manufacture, use and testing of pressurised gas cylinders and related components. Some examples are listed here.

  • ISO 11439: Gas cylinders — High-pressure cylinders for the on-board storage of natural gas as a fuel for automotive vehicles[34]
  • ISO 15500-5: Road vehicles — Compressed natural gas (CNG) fuel system components — Part 5: Manual cylinder valve[35][36]
  • US DOT CFR Title 49, part 178, Subpart C — Specification for Cylinders[37]
  • US DOT Aluminum Tank Alloy 6351-T6 amendment for SCUBA, SCBA, Oxygen Service — Visual Eddy inspection[38]
  • AS 2896-2011:Medical gas systems—Installation and testing of non-flammable medical gas pipeline systems pipeline systems (Australian Standards).
  • EN 1964-3 – Transportable gas cylinders. Specification for the design and construction of refillable transportable seamless steel gas cylinders of water capacities capacity from 0,5 litre up to 150 litre[39]
  • ISO 9809-1: Gas Cylinders–Refillable Seamless Steel Gas Cylinders–Design, Construction and Testing–Part 1: Quenched and Tempered Steel Cylinders with Tensile Strength less than 1 100 MPa
  • ISO 9809-2: Gas Cylinders–Refillable Seamless Steel Gas Cylinders–Design, Construction and Testing–Part 2: Quenched and Tempered Steel Cylinders with Tensile Strength Greater than or Equal to 1 100 MPa
  • ISO 9809-3: Gas Cylinders–Refillable Seamless Steel Gas Cylinders–Design, Construction and Testing–Part 3: Normalized Steel Cylinders
  • EN ISO 11120 – Gas cylinders. Refillable seamless steel tubes of water capacity between 150 l and 3000 l. Design, construction and testing (ISO 11120:2015)[39]
  • EN 1975 – Transportable gas cylinders. Specification for the design and construction of refillable transportable seamless aluminium and aluminium alloy gas cylinders of capacity from 0,5 litre up to 150 litre[39]
  • EN 84/526/EEC – Aluminium high pressure gas cylinder design[39]
  • EN 12245 – Transportable gas cylinders Fully wrapped composite cylinders[39]
  • ISO 11119-1 Gas cylinders — Design, construction and testing of refillable composite gas cylinders and tubes — Part 1: Hoop wrapped fibre reinforced composite gas cylinders and tubes up to 450 l[39]
  • HOAL — Home Office Aluminium — UK seamless aluminium high pressure cylinder manufacturing standards HOAL1, HOAL2, HOAL3 and HOAL4 (superseded) in HE30/AA6082 or AA6351 alloys.[40]

Transportation

[edit]

Gas cylinders are classified by the UN as dangerous goods for transportation purposes (US: Hazardous materials). Selecting the Proper Shipping Name (well known by the abbreviation PSN) is a way to help ensure that the dangerous goods offered for transport accurately represent the hazards.[41]

IATA Dangerous Goods Regulations (DGR) 55th Edition defines the Proper Shipping Name as "the name to be used to describe a particular article or substance in all shipping documents and notifications and, where appropriate, on packagings".[41]

The International Maritime Dangerous Goods Code (IMDG Code) defines the Proper Shipping Name as "that portion of the entry most accurately describing the goods in the Dangerous Goods List which is shown in upper-case characters (plus any letters which form an integral part of the name)."[41]

Diving gas cylinders:

Hazardous materials
descriptions and
proper shipping names
(PSN)[42][43][44]
Hazard class
or division
Identification
numbers
Label codes Quantity
limitations
Air, compressed 2.2 UN1002 2.2 Passenger aircraft/rail: 75 kg
Cargo aircraft only: 150 kg
Argon, compressed 2.2 UN1006 2.2
Helium, compressed 2.2 UN1046 2.2
Nitrogen, compressed 2.2 UN1066 2.2
Oxygen, compressed 2.2 UN1072 2.2, 5.1
Compressed gas N.O.S. (not otherwise specified)
e.g. normoxic and hypoxic Heliox and Trimix
2.2 UN1956 2.2
Compressed gas, oxidising, N.O.S
e.g. Nitrox
2.2 UN3156 2.2, 5.1

International air

[edit]

International Civil Aviation Organization (ICAO) Technical Instructions for the Safe Transport of Dangerous Goods by Air states that provided that pressure in diving cylinders is less than 200 kilopascals (2 bar; 29 psi), these can be carried as checked in or carry-on baggage. It maybe necessary to empty the cylinder to verify this. Once emptied, the cylinder valve should be closed to prevent moisture entering the cylinder. Security restrictions implemented by individual countries may further limit or forbid the carriage of some items permitted by ICAO, and airlines and security screening agencies have the right to refuse the carriage of certain items.[45]

Europe

[edit]

Since 1996 the carriage of dangerous goods legislation of the UK has been harmonized with that of Europe.[46]

Road transport

The 2009 (amended 2011) UK Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations (CDG Regulations) implement the European Agreement Concerning the International Carriage of Dangerous Goods by Road (ADR). Dangerous goods to be carried internationally in road vehicles must comply with standards for the packaging and labelling of the dangerous goods, and appropriate construction and operating standards for the vehicles and crew.[43][46]

The regulations cover transportation of gas cylinders in a vehicle in a commercial environment. Transportation of pressurised diving gas cylinders with a combined water capacity of less than 1000 litres on a vehicle for personal use is exempt from ADR.[43][46][47]

Transport of gas cylinders in a vehicle, for commercial purposes, must follow basic legal safety requirements and, unless specifically exempted, must comply with ADR. The driver of the vehicle is legally responsible for the safety of the vehicle and any load being carried, and insurance for the vehicle should include cover for the carriage of dangerous goods.[43][46]

Diving gases, including compressed air, oxygen, nitrox, heliox, trimix, helium and argon, are non-toxic, non flammable, and may be oxidizer or asphyxiant, and are rated in Transport category 3.[46] The threshold quantity for these gases is 1000 litres combined water capacity of the cylinders. Pressure must be within the rated working pressure of the cylinder. Empty air cylinders at atmospheric pressure are rated in Transport category 4, and there is no threshold quantity.[43][46]

Commercial loads below the 1000 litres threshold level are exempt from some of the requirements of ADR, but must comply with basic legal and safety requirements, including:[46]

  • Driver training[46]
  • Cylinders should be transported in open vehicles, open containers or trailers, with a gas-tight bulkhead separating driver from load. If cylinders must be carried inside a vehicle it must be well ventilated.[46]
  • Ventilation. Where gas cylinders are carried inside a vehicle, in the same space as people, the windows should be kept open to allow air to circulate.[46]
  • Cylinders must be secured so that they cannot move during transport. They shall not project beyond the sides or ends of the vehicle. It is recommended that cylinders are transported vertically, secured in an appropriate pallet.[46]
  • Cylinder valves must be closed whilst in transit and checked that there are no leaks. Where applicable, protective valve caps and covers should be fitted to cylinders before transporting. Cylinders should not be transported with equipment attached to the valve outlet (regulators, hoses etc.).[46]
  • A fire extinguisher is required on the vehicle.[46]
  • Gas cylinders may only be transported if they are in-date for periodic inspection and test, except they may be transported when out of date for inspection, testing or disposal.[46]
  • Cylinders should be kept cool (at ambient temperatures) and not stowed in places where they will be exposed to sources of excessive heat.[46]
  • Product identification labels attached to cylinders to identify the contents and provide safety advice must not be removed or defaced.[46]
  • It is not necessary to mark and label the vehicle if carrying dangerous goods below the threshold level. The use of hazard labels can assist the emergency services, and they may be displayed, but all hazard labels must be removed when the relevant dangerous goods are not being transported.[46]
  • When the journey is complete the gas cylinders should be immediately unloaded from the vehicle.[46]

All loads above the threshold must comply with the full requirements of ADR.[43][46]

United States

[edit]

Transportation of hazardous materials for commercial purposes[48] in the USA is regulated by Code of Federal Regulations Title 49 - Transportation, (abbreviated 49 CFR).[49] A cylinder containing 200 kPa (29.0 psig/43.8 psia) or greater at 20 °C (68 °F) of non-flammable, nonpoisonous compressed gas, and being transported for commercial purposes is classified as HAZMAT (hazardous materials) in terms of 49 CFR 173.115(b) (1).[50] Cylinders manufactured to DOT standards or special permits (exemptions)issued by the Pipeline and Hazardous Materials Safety Administration and filled to the authorized working pressure are legal for commercial transport in the USA under the provisions and conditions of the regulations.[49][51] Cylinders manufactured outside the USA may be transported under a special permit, and these have been issued for solid metal and composite cylinders with working pressures of up to 300 bar (4400 psi) by several manufacturers.[52]

Commercial transportation of breathing gas cylinders with a combined weight of more than 1000 pounds may only be done by a commercial HAZMAT transportation company. Transport of cylinders with a combined weight of less than 1000 pounds requires a manifest, the cylinders must have been tested and inspected to federal standards, and the contents marked on each cylinder. Transportation must be done in a safe manner, with the cylinders restrained from movement. No special licence is required. DOT regulations require content labels for all cylinders under the regulations, but according to PSI, labelling of breathing air will not be enforced. Oxygen or non-air oxidizing (O2 ≥ 23.5% ) mixtures must be labelled. Private (non-commercial) transport of scuba cylinders is not covered by this regulation.[53]

Empty scuba tanks or scuba tanks pressurized at less than 200 kPa are not restricted as hazardous materials.[54] Scuba cylinders are only allowed in checked baggage or as a carry-on if the cylinder valve is completely disconnected from the cylinder and the cylinder has an open end to allow for a visual inspection inside.[55]

Color coding

[edit]
ISO Cylinder Colour Coding for Different (medical) Gases

Gas cylinders are often color-coded, but the codes are not standard across different jurisdictions, and sometimes are not regulated. Cylinder color can not safely be used for positive product identification; cylinders have labels to identify the gas they contain.

Medical gas cylinder color code Indian standard

[edit]

The Indian Standard for Gas Cylinder Color Code applies to the identification of the contents of gas cylinders intended for medical use. Each cylinder shall be painted externally in the colours corresponding to its gaseous contents.[56]

Permanent markings

[edit]

The shoulder of the cylinder carries stamp markings providing required information about the cylinder.[57]

Universally required markings include:

A variety of other markings may be required by national regulations, or may be optional.[57]

Filling

[edit]

Diving cylinders are filled by attaching a high-pressure gas supply to the cylinder valve, opening the valve and allowing gas to flow into the cylinder until the desired pressure is reached, then closing the valves, venting the connection and disconnecting it. This process involves a risk of the cylinder or the filling equipment failing under pressure, both of which are hazardous to the operator, so procedures to control these risks are generally followed. Rate of filling must be limited to avoid excessive heating, the temperature of cylinder and contents must remain below the maximum working temperature specified by the applicable standard.[1]

Filling by pressure

[edit]

For permanent gases, a cylinder can be filled to the charging pressure, or any lesser pressure that may be appropriate. This generally requires correction to account for temperature changes during filling, and variation from the reference temperature (usually 15 or 20°C).[1]

Charging pressure

[edit]

Charging pressure is the maximum gauge pressure allowed during filling of a pressure vessel when corrected to the reference temperature. The charging pressure is permanently marked on the cylinder.[1]

Filling by mass

[edit]

Filling by mass does not need correction or adjustment for temperature, and is the standard method for filling liquefied gases, as the pressure of a vapour over liquid is determined by the temperature, making it an unreliable indicator of the amount of liquefied gas in the cylinder. The process requires the added mass to be measured accurately, and the scale to be zeroed according to the mass of the empty cylinder.

Pre-filling inspection of the cylinder

[edit]

Common sizes

[edit]

The below are example cylinder sizes and do not constitute an industry standard.[citation needed][clarification needed]

Cyl. size Diameter × height,
including 5.5 inches for valve and cap (inches)
Nominal tare weight,
including 4.5 lb for valve and cap (lb)
Water
capacity
(lb)
Internal volume,
70 °F (21 °C), 1 atm
U.S. DOT specs
(liters) (cu. ft)
2HP 9 by 51 inches (230 mm × 1,300 mm) 187 pounds (85 kg) 95.5 43.3 1.53 3AA3500
K 9.25 by 60 inches (235 mm × 1,524 mm) 135 pounds (61 kg) 110 49.9 1.76 3AA2400
A 9 by 51 inches (230 mm × 1,300 mm) 115 pounds (52 kg) 96 43.8 1.55 3AA2015
B 8.5 by 31 inches (220 mm × 790 mm) 60 pounds (27 kg) 37.9 17.2 0.61 3AA2015
C 6 by 24 inches (150 mm × 610 mm) 27 pounds (12 kg) 15.2 6.88 0.24 3AA2015
D 4 by 18 inches (100 mm × 460 mm) 12 pounds (5.4 kg) 4.9 2.24 0.08 3AA2015
AL 8 by 53 inches (200 mm × 1,350 mm) 52 pounds (24 kg) 64.8 29.5 1.04 3AL2015
BL 7.25 by 39 inches (184 mm × 991 mm) 33 pounds (15 kg) 34.6 15.7 0.55 3AL2216
CL 6.9 by 21 inches (180 mm × 530 mm) 19 pounds (8.6 kg) 13 5.9 0.21 3AL2216
XL 14.5 by 50 inches (370 mm × 1,270 mm) 75 pounds (34 kg) 238 108 3.83 4BA240
SSB 8 by 37 inches (200 mm × 940 mm) 95 pounds (43 kg) 41.6 18.9 0.67 3A1800
10S 4 by 31 inches (100 mm × 790 mm) 21 pounds (9.5 kg) 8.3 3.8 0.13 3A1800
LB 2 by 15 inches (51 mm × 381 mm) 4 pounds (1.8 kg) 1 0.44 0.016 3E1800
XF 12 by 46 inches (300 mm × 1,170 mm) 180 pounds (82 kg) 134.3 60.9 2.15 8AL
XG 15 by 56 inches (380 mm × 1,420 mm) 149 pounds (68 kg) 278 126.3 4.46 4AA480
XM 10 by 49 inches (250 mm × 1,240 mm) 90 pounds (41 kg) 120 54.3 1.92 3A480
XP 10 by 55 inches (250 mm × 1,400 mm) 55 pounds (25 kg) 124 55.7 1.98 4BA300
QT 3 by 14 inches (76 mm × 356 mm) (includes 4.5 inches for valve) 2.5 pounds (1.1 kg) (includes 1.5 lb for valve) 2.0 0.900 0.0318 4B-240ET
LP5 12.25 by 18.25 inches (311 mm × 464 mm) 18.5 pounds (8.4 kg) 47.7 21.68 0.76 4BW240
Medical E 4 by 26 inches (100 mm × 660 mm) (excludes valve and cap) 14 pounds (6.4 kg) (excludes valve and cap) 9.9 4.5 0.16 3AA2015

(US DOT specs define material, making, and maximum pressure in psi. They are comparable to Transport Canada specs, which shows pressure in bars. A 3E-1800 in DOT nomenclature would be a TC 3EM 124 in Canada.[58])

Gas storage tubes

[edit]

For larger volume, high pressure gas storage units, known as tubes, are available. They generally have a larger diameter and length than high pressure cylinders, and usually have a tapped neck at both ends. They may be mounted alone or in groups on trailers, permanent bases, or intermodal transport frames. Due to their length, they are mounted horizontally on mobile structures. In general usage they are often manifolded together and managed as a unit.[59][60]

Gas storage banks

[edit]
Hydrogen storage cylinders in a cascade filling system

Groups of similar size cylinders may be mounted together and connected to a common manifold system to provide larger storage capacity than a single standard cylinder. This is commonly called a cylinder bank or a gas storage bank. The manifold may be arranged to allow simultaneous flow from all the cylinders, or, for a cascade filling system, where gas is tapped off cylinders according to the lowest positive pressure difference between storage and destination cylinder, being a more efficient use of pressurised gas.[61]

Gas storage quads

[edit]
Helium quad for surface-supplied diving gas

A gas cylinder quad, also known as a gas cylinder bundle, is a group of high pressure cylinders mounted on a transport and storage frame. There are commonly 16 cylinders, each of about 50 litres capacity mounted upright in four rows of four, on a square base with a square plan frame with lifting points on top and may have fork-lift slots in the base. The cylinders are usually interconnected by a manifold for use as a unit, but many variations in layout and structure are possible.[10]

See also

[edit]

References

[edit]

Sources

[edit]
  • NOAA Diving Program (U.S.) (28 February 2001). Joiner, James T (ed.). NOAA Diving Manual, Diving for Science and Technology (4th ed.). Silver Spring, Maryland: National Oceanic and Atmospheric Administration, Office of Oceanic and Atmospheric Research, National Undersea Research Program. ISBN 978-0-941332-70-5. CD-ROM prepared and distributed by the National Technical Information Service (NTIS)in partnership with NOAA and Best Publishing Company
[edit]
Revisions and contributorsEdit on WikipediaRead on Wikipedia
from Grokipedia
A gas cylinder (also known as a gas bottle or gas tank) is a designed for the storage and transport of compressed or liquefied gases at pressures above . According to ISO standards, it is typically a transportable pressure receptacle with a water capacity not exceeding 150 liters, though other regulations like US DOT allow larger capacities up to about 450 liters. These cylindrical vessels are engineered to safely contain high-energy gases, preventing leakage or rupture under normal conditions, and are essential in numerous industries due to their portability and reliability. Gas cylinders are constructed from durable materials to endure substantial internal pressures, such as seamless for robustness and , aluminum for resistance, or composite overwrapped designs with fiber reinforcements for enhanced strength-to-weight ratios. Common gases stored include oxygen, , , , and , which are utilized in diverse applications such as medical , industrial and cutting, laboratory experiments, , and fuel storage. In medical settings, for instance, they provide critical support for and respiratory care, while in industrial contexts, they facilitate processes like and chemical manufacturing. Safety standards are rigorously enforced to mitigate risks like explosions or toxic exposures, with organizations such as the Compressed Gas Association (CGA) and the (ISO) establishing guidelines for design, testing, labeling, and handling. Key CGA publications include V-1 for valve connections, S-1.1 for pressure relief devices, and P-1 for safe handling practices, while ISO/TC 58 covers manufacturing and use requirements for pressure receptacles. These standards ensure cylinders are inspected regularly, secured properly during transport and storage, and equipped with compatible fittings to prevent accidents.

Nomenclature and Types

Definition and Uses

A gas cylinder is a designed for the storage and transportation of gases at pressures significantly above atmospheric levels, encompassing compressed gases, liquefied gases, and dissolved gases such as in acetone. The origins of gas cylinders trace back to the late , when high-pressure vessels were invented to facilitate the safe handling and distribution of industrial gases like oxygen for and manufacturing purposes, and later for welding applications. Over time, these cylinders evolved from early metal designs to more robust, standardized containers that support a wide array of modern industrial and scientific needs. Gas cylinders serve diverse primary applications across multiple sectors. In industry, they supply gases essential for processes like , , and chemical manufacturing. Medically, they deliver oxygen for respiratory therapy and other life-support treatments. In scientific settings, cylinders provide pure or mixed gases for experiments, , and analytical . Recreationally, they enable self-contained (SCUBA) for diving by storing breathable gas mixtures. Emerging uses include for vehicles and clean energy systems, addressing demands for sustainable power sources. At their core, gas cylinders rely on fundamental principles of gas behavior, such as the inverse relationship between and described by , which allows a fixed of gas to be compressed into a smaller at higher for efficient storage and portability. This distinguishes them from low-pressure containers, like flexible bags or atmospheric tanks, which cannot safely maintain elevated pressures and are unsuitable for transporting compressed or liquefied gases over distances.

Nomenclature

Gas cylinders are classified using standardized nomenclature, particularly in the United States under (DOT) specifications. Common specs include 3A for seamless cylinders and 3AL for aluminum. Sizes are often denoted by letters, such as "E" for medical oxygen cylinders with ~4.4 liters water capacity or "K" for larger industrial ones with ~50 liters water capacity. Internationally, ISO standards like 9809 specify seamless designs. These terms ensure compatibility and regulatory compliance across applications.

Components

A gas cylinder consists of several core components that work together to ensure safe containment and controlled dispensing of pressurized gases. The primary elements include the cylinder body, base, collar, , and optional dip tube, each designed to address specific functional and safety requirements. These parts integrate to form a robust vessel capable of withstanding high pressures while minimizing risks during handling and use. The cylinder body, also known as the shell, serves as the main pressure-bearing vessel that holds the compressed or . It is typically cylindrical in shape with rounded ends to distribute stress evenly and is constructed from durable materials such as or aluminum to resist deformation under . The body's internal volume varies by application, but it must comply with standards like those from the (DOT) or ASME for integrity. The base, often referred to as the footring or , provides stability by supporting the in an upright position and protects the bottom end from impact or . It is usually wider than the body and may include ventilation holes to allow drainage, ensuring the remains secure during storage and . In some designs, the base is stamped with details, such as test dates, for . The collar, sometimes called the shroud, encircles the neck area to protect the from accidental impacts and facilitates safe handling by providing grip points or stacking support. It is secured around the cylinder's shoulder and often features openings for access and venting, enhancing usability without compromising the vessel's structural integrity. For cylinders, the collar may also mark the to aid in accurate filling. The is the critical component that controls the flow of gas into and out of the , typically threaded into the body's neck or boss for a secure seal. Common types include handwheel-operated valves, which allow manual rotation for opening and closing, and key-operated (spindle key) valves, which require a specialized tool to prevent unauthorized access. These valves ensure precise regulation and are often equipped with O-rings or seats for leak prevention. An optional dip tube may be integrated into the valve assembly for cylinders containing liquefied gases, extending from the valve outlet to the bottom of the body to enable withdrawal of liquid rather than vapor. This feature is particularly useful for applications requiring liquid-phase delivery and is common in smaller cylinders up to 25 liters in capacity. Safety features are embedded within these components to mitigate risks of over-pressurization or fire exposure. Burst disks, integrated into the or body, rupture at s below 90% of the cylinder's test to vent excess gas safely. Fusible plugs, often backing the burst disks, melt at temperatures around 105°C to release contents during heat events, preventing explosions. Pressure relief devices, such as spring-loaded , are similarly incorporated to activate within specified ranges (e.g., 60°F to 160°F), ensuring compliance with standards like CGA S-1.1. In assembly, the components integrate seamlessly: the base and collar are affixed to the body ends, the valve is threaded into the neck and secured by the collar, and the dip tube—if present—is inserted through the valve prior to final sealing, forming a cohesive unit without internal overlaps. Materials for these parts, such as metals for the body and brass for valves, are selected for compatibility and durability as detailed in materials selection guidelines.

Cylinder Types

Gas cylinders are classified primarily by their construction method, which influences their suitability for various applications, ranging from high-pressure storage of compressed gases to liquefied or specialty gases. The standard classification, often aligned with international standards such as ISO 11439 for lightweight refillable cylinders, includes four main types based on material and wrapping techniques, with additional specialty designs for specific gases. Type 1 cylinders are fully metallic, typically seamless constructions made from or aluminum, providing robust durability for general industrial and medical uses. Type 2 cylinders feature a thick metal liner ( or aluminum) reinforced with hoop-wrapped composite materials, such as , applied only around the cylindrical section for enhanced strength without significant weight increase. Type 3 cylinders consist of a thin metal liner fully wrapped with composite fibers (carbon or ) over the entire surface, including the domes, offering a balance of lightness and pressure resistance. Type 4 cylinders use a non-metallic () liner fully overwrapped with advanced composites like carbon , maximizing portability for demanding applications. Key differences among these types lie in weight, corrosion resistance, and cost, which determine their performance in specific scenarios. Type 1 cylinders are the heaviest but most cost-effective and corrosion-prone in harsh environments, while Types 3 and 4 provide superior due to the protective composite layers, though at higher manufacturing costs—up to several times that of metal types. For instance, composite Types 3 and 4 are preferred in for their lightweight design, reducing diver fatigue compared to traditional Type 1 cylinders. Cylinders also vary by capacity and mobility, from portable handheld units with water capacities of less than 1 liter for personal or use to large stationary or transportable vessels with approximately 450 liters capacity for , equivalent to hundreds to tens of thousands of liters of gas at (STP). Small portable cylinders, often Type 1 or 2, facilitate on-the-go applications like torches, whereas larger ones are typically stationary installations or bundled for safe transport in bulk gas delivery. Specialty cylinders address unique gas properties beyond standard compressed gases. Cryogenic cylinders, designed for liquefied gases like or oxygen, incorporate insulation and double-walled construction to maintain extremely low temperatures. Acetylene-specific cylinders include a porous monolithic mass, such as , saturated with acetone to safely dissolve and stabilize the unstable gas, preventing . Emerging in 2025, smart cylinders integrate embedded sensors and IoT connectivity for real-time monitoring of , temperature, and gas levels, particularly enhancing in applications where is critical.

Materials and Design

Materials Selection

Gas cylinders are primarily constructed from , aluminum, and composite materials, each selected based on requirements for containment, weight, and compatibility with the stored gas. , often carbon or variants like 34CrMo4, provides high tensile strength (up to 950 MPa) essential for high-pressure applications, making it suitable for industrial gases such as or . Aluminum alloys, particularly 6061, offer a favorable strength-to-weight ratio and are commonly used for portable cylinders containing non-corrosive gases. Composite materials, incorporating carbon fiber or over a metal or liner, are employed in Type 3 and Type 4 cylinders for scenarios demanding minimal weight, such as in or medical transport; for CNG vehicle storage, these achieve empty weights of 30-50 kg, significantly lighter than steel equivalents. Key properties influencing include tensile strength, resistance, and conductivity, alongside compatibility with specific gases to prevent or degradation. exhibits excellent tensile strength but is susceptible to in hydrogen-rich environments, where atomic hydrogen diffuses into the lattice, reducing and promoting cracking; this risk is mitigated by limiting tensile strength and using appropriate heat treatments like and tempering. Aluminum provides superior resistance due to its natural layer, ideal for oxidizing gases like medical oxygen, where non-reactivity ensures purity and safety during transport. Composites boast a high strength-to-weight ratio—carbon fiber is approximately 75% lighter than while maintaining comparable or superior strength—and inherent resistance, though they have lower conductivity than metals, which can affect heat dissipation in certain applications. Selection criteria prioritize gas type: for reactive or corrosive gases like , with protective linings is preferred, whereas aluminum suits inert or medical gases to minimize contamination risks. Post-2020 advancements have driven a shift toward recyclable composites, with innovations in carbon reinforced polymer (CFRP) recycling—such as and chemical solvolysis—enabling up to 99% retention of fiber tensile strength and reducing environmental impacts through lower lifecycle emissions. These materials achieve 50-70% weight reductions compared to , enhancing in transport and decreasing the of cylinder logistics. Despite these advances, limitations persist: steel remains the cost-effective choice for heavy-duty industrial use due to its durability under rough conditions, though its weight and vulnerability require ongoing . Aluminum is restricted to non-corrosive gases to avoid , limiting its application in harsh chemical environments. Composites, while lightweight and eco-friendly, incur higher upfront costs and necessitate specialized inspection protocols to ensure long-term integrity.

Design Principles

Gas cylinders are primarily designed in a cylindrical shape to optimize stress distribution under . The cylindrical ensures that hoop stresses, which are the primary tensile stresses acting circumferentially around the vessel, are uniformly distributed along the length, minimizing localized weaknesses compared to other shapes like rectangular or irregular forms. This configuration allows for efficient material use while maintaining structural integrity, as the radial and longitudinal stresses are predictably lower than hoop stresses in thin-walled approximations. The ends of gas cylinders typically feature hemispherical or torispherical (dished) heads to further reduce wall stresses. Hemispherical ends provide the most uniform distribution, approximating the ideal spherical shape where stresses are equal in all directions, thus requiring thinner walls for the same capacity. Torispherical heads, a practical alternative, combine a spherical crown with a toroidal knuckle to transition smoothly to the cylindrical body, balancing stress minimization with manufacturability and cost. Safety factors in gas cylinder design incorporate significant overdesign to account for uncertainties in material properties, variations, and operational loads. Cylinders are typically engineered to withstand burst pressures 1.5 to 4 times the working , with a common minimum safety factor of 3.0 for composite types, ensuring failure only under extreme conditions; for composite CNG cylinders, designs target cycle lives of 15,000–45,000 fills or unlimited service with requalification. Modern designs increasingly employ finite element analysis (FEA) to simulate stress concentrations, validate wall thickness, and optimize geometry, allowing precise prediction of deformation and failure modes under internal . Ergonomics and portability are integral to cylinder design, focusing on user safety and ease of handling in industrial and settings. Integrated handles or shrouds are often incorporated to distribute weight evenly, reducing musculoskeletal strain during lifting and transport; for instance, ergonomic grips on portable cylinders lower the center of for better balance. Weight balance is optimized through material selection and shape refinements, enabling single-person maneuverability for cylinders up to 50 kg without auxiliary equipment. Recent innovations in gas cylinder design emphasize modularity and digital integration for enhanced lifecycle management. Additionally, RFID integration has advanced, with mandatory embedding in certain jurisdictions like India for fuels such as CNG and hydrogen, enabling real-time tracking, inventory control, and safety verification throughout the supply chain.

Pressure Ratings

Gas cylinders are designed to operate safely within specified pressure limits, which are critical for preventing rupture or leakage during storage and transport. The working , also known as service , represents the maximum at which the cylinder is intended to operate under normal conditions; for standard high- cylinders, this typically ranges from 200 to 300 bar (approximately 2900 to 4350 psi); CNG cylinders for vehicles may reach 3600 psi (248 bar) service pressure. The test is the level at which the undergoes hydrostatic testing to verify , generally set at 1.5 times the working , such as 4500 psi (310 bar) for a 3000 psi (207 bar) working or 5400 psi for higher-pressure CNG variants. Burst defines the minimum at which the will fail catastrophically, required to be at least 3 to 4 times the working to incorporate factors against unexpected loads. Cylinders are classified based on their pressure capacities and the state of the contained gas, influencing design and handling requirements. Low-pressure cylinders, typically rated below 200 psi (14 bar) and up to 500 psi (34 bar), are often used for liquefied gases like propane or acetylene, featuring thinner walls and welded construction. High-pressure cylinders exceed 2000 psi (138 bar), commonly reaching 3000 psi (207 bar) or more, and are suited for compressed non-liquefied gases such as oxygen or nitrogen, with seamless or composite construction for enhanced strength. The distinction between compressed and liquefied gases further affects classification: compressed gases remain gaseous under pressure above atmospheric levels, while liquefied compressed gases, which can exist as liquids under pressure at temperatures above -50°C, are categorized into high-pressure liquefied (critical temperature -50°C to +65°C) and low-pressure liquefied (above +65°C), enabling higher storage densities in designs with moderate pressures compared to compressed gases. To ensure structural integrity, cylinder wall thickness is derived from the hoop stress formula for thin-walled vessels, where the circumferential stress σ is given by σ = (P × r) / t, with P as internal pressure, r as inner radius, and t as wall thickness; this equation balances material yield strength against pressure-induced forces to determine minimum t for a given working pressure. Rearranging yields t = (P × r) / σ, guiding designs to maintain stress below the material's allowable limit. Pressure ratings vary by application and environmental factors, with specialized cylinders for in vehicles rated up to 700 bar (10,000 psi) working pressure to maximize storage density in Type IV composite designs as of 2025. To account for temperature increases, cylinders are filled such that the pressure at a reference maximum temperature of 130°F (54°C) does not exceed the service pressure, as per DOT regulations, since gas pressure rises proportionally with absolute temperature per (approximately 1 psi per 5°F increase), and material strength may degrade.

Manufacturing Processes

Seamless Metal Cylinders

Seamless metal cylinders are produced through a series of forming and processes that start with a solid or tube, ensuring a continuous without joints. The primary steps include billet piercing to create a hollow form, followed by or drawing to achieve the desired wall thickness and shape, to enhance mechanical properties, and necking to form the valve-end closure. These methods, governed by international standards, produce cylinders suitable for high-pressure gas storage, with variants for industrial durability and aluminum for lighter applications. For steel seamless cylinders, manufacturing begins with heating a billet of high-strength low-alloy (HSLA) steel, such as 34CrMo4, to 1100–1250°C before piercing and hot to form the initial tube. Subsequent reduces wall thickness while maintaining uniformity, followed by at 860–910°C in water-soluble agents and tempering at 580–660°C to achieve yield strengths of 800–900 MPa and ultimate tensile strengths of 900–1100 MPa, optimizing and resistance. Necking involves hot or forming of the ends to create the cylindrical body with integrated shoulders, ensuring structural integrity for pressures up to 300 bar. As referenced in materials selection, HSLA steels provide the necessary alloying for resistance and strength in these processes. Aluminum seamless cylinders, typically using 6xxx series alloys like 6061-T6, employ as the core process, where a heated is forced through a die to form a seamless tube, followed by spinning or for wall reduction and necking to the dome and neck. Heat involves solution annealing and aging to balance strength and , resulting in cylinders about 40% lighter than equivalents, ideal for and portable uses where resistance and non-magnetic properties are essential. This extrusion-based method allows for complex while adhering to standards that limit tensile strength to 310 MPa for safety. The absence of welds in seamless construction provides high structural integrity, minimizing leak risks and enabling reliable performance as Type 1 cylinders rated up to 300 bar, commonly used for compressed gases in industrial and sectors.

Composite and Wrapped Cylinders

Composite and wrapped gas cylinders represent an advanced class of pressure vessels that enhance strength-to-weight ratios by applying composite materials over a metallic or polymeric liner. These cylinders, classified as Type 2, Type 3, and Type 4, utilize or hoop/full wrap techniques to layer such as carbon or reinforcements around the liner, providing superior performance in high-pressure applications like and . The manufacturing process begins with preparing the liner, followed by precise winding of fiber tows impregnated with , and concludes with curing to form a robust composite shell. Filament winding is the primary method for producing these cylinders, involving the continuous deposition of fiber strands under tension onto a rotating that serves as the liner. In wet winding, fibers are passed through a bath immediately before application, ensuring thorough impregnation and , while dry winding uses pre-impregnated () fibers for cleaner handling and reduced volatile emissions. Hoop wrapping focuses on circumferential to resist radial expansion, whereas full wrapping includes helical patterns for both hoop and axial strength, optimizing the cylinder's response to internal pressures. These techniques are applied to Type 2-4 liners, where the composite overwrap significantly contributes to the vessel's burst pressure and resistance. Type 2 cylinders feature a or aluminum liner hoop-wrapped with composite materials, primarily to bolster axial load-bearing capacity while the liner handles hoop stress. This offers a balance of cost and performance, with the wrap mitigating risks on the metal liner and allowing for pressures up to 300 bar in automotive systems. In contrast, Type 3 cylinders employ a thin-walled metal liner fully wrapped with carbon fiber composites, reducing overall weight by up to 50% compared to all-metal equivalents and enabling service pressures exceeding 700 bar. Type 4 cylinders use non-metallic plastic liners, such as , fully overwrapped with composites for the lightest configurations, ideal for portable applications where weight is critical. curing is essential in these processes, applying heat and pressure to consolidate the and ensure strong interfacial bonds between the liner and overwrap, preventing under cyclic loading. Recent advancements in automated , particularly as of 2025, have introduced robotic systems with real-time tension control and laser-guided fiber placement, achieving winding precision within 0.1 mm tolerances and reducing defects by approximately 20% through minimized fiber misalignment. These innovations have expanded applications in for oxygen systems and for vehicles, where the enhanced durability supports extended service life beyond 15,000 cycles. Such cylinders can achieve pressure ratings that support safe storage at 700 bar or higher, providing critical for emerging clean energy technologies.

Welded and Specialty Cylinders

Welded gas cylinders are produced by forming sheets into cylindrical shapes and joining them via longitudinal seam , a process that creates strong, leak-tight seams suitable for large-volume containers. This method typically employs automated machines using MIG (metal ) or TIG (tungsten ) welding techniques to ensure precision and minimize defects in the joints, particularly for industrial applications requiring high structural . , often selected for its and as outlined in material standards, serves as the primary base for these cylinders to withstand forming and stresses. Low-pressure welded cylinders, commonly used for liquefied petroleum gas (LPG) storage, operate at pressures up to 25 bar and are fabricated by welding carbon steel components to form robust vessels for safe transport and storage of non-reactive gases. These designs prioritize cost-effective production for bulk applications while maintaining compliance with pressure vessel codes. Specialty welded cylinders address unique gas properties through tailored internal features. For acetylene, cylinders incorporate a porous filler material, such as monolithic or fire-resistant masses, saturated with acetone to evenly distribute the gas, prevent void formation, and inhibit decomposition propagation. Cryogenic cylinders, like those for known as , feature double-walled construction with multi-layer vacuum insulation in the annular space to minimize and enable long-term storage of ultra-low-temperature liquids. In 2025, amendments to international gas cylinder rules, such as India's Gas Cylinders (Fourth Amendment) Rules, permit larger water capacities up to 3000 liters for specific gases including compressed natural gas (CNG), hydrogen (CHG), nitrogen, and compressed air, expanding options for high-volume welded storage while adhering to enhanced safety protocols.

Valve Systems

Neck Threads and Valves

The neck of a gas cylinder features threaded interfaces designed to securely attach , ensuring safe containment and controlled release of gases. These threads are standardized to prevent mismatches and leaks, with two primary types: parallel (straight) and tapered. Parallel threads, such as the 3/4"-14 NGO (National Gas Outlet), maintain a constant along their length and rely on an or for sealing, reducing stress on the cylinder during repeated installations. They are particularly recommended for aluminum cylinders to minimize and risks. International standards like ISO 15245-1:2021 specify parallel screw threads, including designations such as M30 x 2, M25 x 2, and M18 x 1.5, with a 60° ISO profile and right-hand orientation for medical and cylinders up to high pressures. Tapered threads, exemplified by the 3/4"-14 NGT (National Gas Taper), narrow gradually to create a self-sealing effect through metal deformation and thread sealant, eliminating the need for additional O-rings. This design is advantageous for applications involving toxic, flammable, or corrosive gases, as it provides robust sealing without relying on elastomeric components that could degrade. However, tapered threads impose higher stresses on the neck and require precise to avoid overtorquing, which can lead to thread damage. Both thread types must match the cylinder's material and pressure rating, with parallel threads often preferred in regions like for oxygen service under DOT/TC regulations. Cylinder valves are critical components that screw into the neck threads to regulate gas flow, typically constructed from for resistance or for high-strength applications. For specialized applications such as compressed natural gas (CNG) cylinders used in vehicles, procurement specifications include designating the valve model or brand and the mounting type, such as neck-mounted or bottom-mounted configurations, to ensure compatibility with installation and operational requirements. Many feature ergonomic handwheels for manual operation, allowing users to open or close the valve securely against . Residual pressure valves (RPVs), a specialized type, incorporate a non-return mechanism to retain a small amount of gas—typically 55-85 —inside the cylinder after use, preventing backflow of contaminants and maintaining internal purity. These valves are essential for , diving, and industrial gases, complying with standards like BS EN ISO 15996, which outlines specifications and type testing for residual functionality. Valve materials and seals are selected to ensure leak-proof performance under demanding conditions, with non-metallic seats like polytetrafluoroethylene (PTFE) providing chemical inertness and low friction for tight shutoff. PTFE seats, often reinforced with steel inserts, operate effectively from -20°F to 400°F and support pressure ratings matching the cylinder, such as up to 4400 PSI for industrial services. This combination minimizes leakage while accommodating repeated cycling without wear. Maintenance of neck threads and valves involves periodic and specialized procedures to preserve integrity. Valve removal requires dedicated tools, such as valving machines or extended sockets, to apply controlled while securing the cylinder against rotation and potential release. For reseating, threads must be cleaned of debris, O-rings or seals inspected for damage, and the valve reinstalled with manufacturer-specified —typically manual force using a fitted —to ensure proper alignment and sealing without over-tightening. These steps, often performed by certified technicians, help extend and comply with safety protocols like those in CSA B339.

Connection Interfaces

Connection interfaces for gas cylinders are standardized mechanisms that ensure secure, compatible linkages between the cylinder valve outlets and downstream equipment, such as hoses, regulators, or filling systems, while prioritizing safety through incompatibility design. These interfaces are critical for preventing gas mix-ups that could lead to hazardous reactions, particularly between incompatible gases like flammables and oxidizers. In the United States, the Compressed Gas Association (CGA) establishes the primary standards for these connections via CGA V-1, which assigns unique outlet configurations to specific gases to avoid cross-connections. For instance, CGA 580 features a standard threaded outlet suitable for non-flammable, non-oxidizing gases like nitrogen, argon, and helium at pressures up to 3,000 psig, utilizing a right-hand thread with a bullet-nose seal. Oxygen cylinders typically employ CGA 540, a right-hand threaded connection designed for oxidizers, while fuel gases like acetylene use CGA 510 with left-hand threads to distinguish them from oxidizer fittings. These threaded types dominate industrial applications, where the nut-and-nipple assembly provides a robust, pressure-rated seal, often up to 3,600 psi. In , the DIN 477 standard governs cylinder valve outlet connections, specifying thread dimensions and configurations tailored to gas types and regional pressures. For example, DIN 477 No. 1 uses a W 21.8 × 1/14" left-hand thread commonly for oxygen, ensuring compatibility within the European market while aligning with safety protocols similar to CGA. Quick-connect interfaces, prevalent in medical settings, facilitate rapid attachment without tools; bayonet-style or DISS (Diameter Index Safety System) connections, such as those for medical oxygen, employ color-coded or keyed mechanisms for one-handed operation and swift emergency use. Safety features integral to these interfaces include deliberate design mismatches to avert erroneous connections, such as the use of left-hand threads exclusively for flammable gases (e.g., or ) versus right-hand threads for oxidizers (e.g., oxygen or ), thereby reducing the risk of mixtures. Gasketed versus metal-to-metal seals further differentiate connections by gas compatibility, with materials selected to resist or ignition. These attach directly to the necks, extending the systems outlined previously. Globally, the ISO 5145 standard harmonizes outlet criteria for gases and mixtures, promoting for high-pressure applications up to 450 bar while incorporating mismatch prevention through unique thread profiles and indexing.

Regulators and Fittings

Regulators attached to gas cylinders serve to reduce the high inlet pressure from the cylinder to a lower, controlled outlet pressure suitable for end-use applications, while also managing flow rates to meet specific demands. Single-stage regulators perform this reduction in one step, offering simplicity and suitability for applications where inlet pressure remains relatively constant, such as in basic welding setups. In contrast, two-stage regulators achieve pressure reduction through two sequential steps—the first stage lowers the pressure to an intermediate level, and the second provides fine adjustment—ensuring more stable outlet pressure despite fluctuations in the cylinder's supply, which is essential for precision tasks like laboratory analysis. The sensing mechanism in regulators typically employs either a diaphragm or a piston design to detect and respond to downstream pressure changes. Diaphragm-based regulators, common in most gas cylinder applications, use a flexible membrane (often stainless steel for high-purity needs) to balance forces from inlet and outlet pressures against a spring, enabling responsive adjustments without external power. Piston designs, found in certain specialty regulators, replace the diaphragm with a sliding piston for direct pressure sensing, providing robustness in high-pressure environments but potentially less sensitivity to minor changes compared to diaphragms. These mechanisms allow regulators to maintain outlet pressures as low as 0.06 psig for delicate processes or up to several hundred psig for industrial uses, while handling flow rates from low volumes in medical delivery (e.g., 0.5–5 liters per minute for oxygen) to higher rates like 200 standard cubic feet per hour (SCFH) in manufacturing. For instance, a typical setup might reduce cylinder inlet pressure of 200 bar (approximately 2900 psig) to 1–10 bar (14.5–145 psig) at the outlet, preventing equipment damage and ensuring safe operation across gases like oxygen, nitrogen, or acetylene. Safe operation of regulators follows established procedures to mitigate risks associated with high-pressure gas release. Before opening the cylinder valve, the pressure-adjusting screw should be backed off by turning it counterclockwise to relieve spring tension and set the delivery pressure to zero. This step prevents sudden high-pressure gas from entering a tensioned regulator, reducing the risks of regulator failure, explosion, or injury. The cylinder valve is then opened slowly. This procedure is also repeated during shutdown: after closing the cylinder valve, the pressure-adjusting screw is backed off to safely depressurize the system by relieving pressure downstream. Fittings complement regulators by facilitating secure connections and distribution of gas from the cylinder to the point of use, including hoses for flexible delivery, adapters for interface compatibility, and manifolds for multi-cylinder systems. Hoses are often constructed from braided (e.g., 304 or 316 grades) with inner linings like PTFE for compatibility with corrosive gases such as or , supporting pressures up to 6000 psig and lengths tailored to applications like cylinder-to-equipment transfer. Adapters and manifolds, typically made from 316 for resistance, enable connections via standards like CGA (Compressed Gas Association) fittings, where the nipple is 316 and the nut 303 stainless steel, rated for 3000 psig in high-purity setups. These components ensure leak-free performance, with manifolds distributing flow from multiple cylinders to maintain continuous supply in industrial or environments, always selected based on gas compatibility to avoid reactions like embrittlement in service. In modern applications as of , electronic regulators enhance precision and monitoring, particularly in and sectors, by integrating digital controls and displays for real-time pressure and flow feedback. For oxygen cylinders, devices like the Matheson Gas Watcher series feature Bluetooth-enabled digital readouts that display cylinder pressure and connect to apps for remote monitoring, improving during therapy. Similarly, systems such as Linde's GRAB 'N GO provide LCD displays showing remaining gas time in hours and minutes, alerting users to low levels in portable setups. For applications, electro-pneumatic regulators like Parker's EPP4 series use closed-loop electronic control with integrated sensors for proportional pressure adjustment (0.05–10 bar outlet), suitable for systems and neutral gas handling, often paired with software interfaces for diagnostics rather than onboard displays. These advancements support emerging and precise delivery, reducing manual adjustments and enhancing reliability.

Filling and Inspection

Filling Methods

Gas cylinders are filled using methods that depend on whether the gas is stored as a compressed gas, liquefied gas, or in a specialized form, with approaches broadly categorized into pressure-based and mass-based techniques. Pressure-based filling is commonly employed for non-liquefied gases, where the gas is compressed to achieve the desired storage pressure within the cylinder. Mass-based filling, on the other hand, is used for liquefied gases to ensure precise control over the amount introduced, preventing overfilling due to risks. These methods utilize specialized equipment and adhere to regulatory limits on cylinder capacities to maintain safety. In pressure-based filling, direct compression involves using mechanical compressors to pressurize the gas directly from a low-pressure source into the cylinder until the target pressure is reached, typically up to 450 bar for gases like oxygen, , or . This method is efficient for high-volume production but requires robust to handle the input. Cascade filling, suitable for high-pressure applications such as scuba or medical oxygen cylinders, employs a of pre-filled storage cylinders at progressively higher pressures to transfer gas sequentially, allowing smaller cylinders to be filled without a single high-capacity . For instance, gas flows from lower-pressure banks to higher ones, equalizing pressures and achieving fills up to the cylinder's rated limit without excessive heating. Mass-based filling is essential for liquefied gases like , where cylinders are weighed before and after filling to determine the exact mass added, ensuring compliance with safety margins. For , cylinders are typically filled to 80% of their capacity by volume to leave space for expansion, calculated as the mass of equivalent to that volume at the gas's liquid . The fill factor is determined by the equation Mass=ρ×V×0.8\text{Mass} = \rho \times V \times 0.8, where ρ\rho is the density of liquid (approximately 0.493 g/cm³ at 25°C), VV is the cylinder's internal capacity in cm³, and 0.8 represents the fill ratio. This weighing method, often combined with fixed liquid level gauges as per NFPA 58 standards, prevents overpressurization during temperature fluctuations. Gas-specific methods address unique chemical properties. For acetylene, which is unstable at high pressures in its pure form, the gas is dissolved in a solvent such as within a porous matrix inside the , typically at pressures up to 15 bar, with the solvent absorbing about 25 times its volume of acetylene to enhance stability. This process involves first filling the with the solvent-saturated matrix, then introducing acetylene gas under controlled pressure. For compressed oxygen gas, filling follows pressure-based methods like direct compression or cascade systems. Cryogenic , where air is purified and cooled to below -183°C via in cryogenic plants to produce , is used for filling specialized insulated (dewars) for liquefied oxygen storage and subsequent . Filling operations rely on equipment like reciprocating compressors for initial pressurization and boost pumps to achieve final high pressures, often up to 300 bar or more for cylinder charging. These air-driven or pneumatic boosters transfer gas efficiently from storage to cylinders, minimizing energy use and buildup. Regulatory limits, such as those in India's Gas Cylinders (Fourth Amendment) Rules, 2025, cap capacities at up to 3,000 liters for gases like , CNG, , and air, with diameter restrictions (e.g., 60 cm for ) to ensure safe filling and transport.

Pre-Filling and Quality Checks

Before filling a gas cylinder, a series of pre-filling quality checks are performed to verify structural integrity, cleanliness, and compliance with safety standards, ensuring the cylinder is safe for use and capable of containing the intended gas without risk of failure or . These inspections are mandated by regulatory bodies and industry associations to prevent incidents such as leaks, ruptures, or impurity issues, particularly for high-pressure applications. The process typically involves external and internal examinations, functionality tests, and documentation reviews, conducted by trained personnel using established criteria. Additional non-visual tests, such as , may be used to detect internal wall thinning or defects. External visual inspections focus on identifying physical damage that could compromise the cylinder's strength. Inspectors check for dents, , and thread damage on the neck, ensuring threads are clean, undamaged, and meet gauge tolerances without cracks or cross-threading. is evaluated for pitting deeper than 1/32 inch (when wall thickness is unknown) or excessive general that reduces wall thickness below allowable limits. Additionally, the hydrostatic testing history is reviewed by examining stamped markings on the or ring to confirm the last test date is within the required interval—typically every 5 or 10 years depending on the type and —and that no evidence of damage, such as charred or bulging, is present. These criteria are outlined in standards like CGA C-6 for , which provide accept/reject guidelines based on defect depth, extent, and specifications to guide fillers in condemning unsafe units. Internal inspections ensure the cylinder interior is suitable for the gas, particularly for purity-sensitive applications. For or high-purity gases, is verified by purging with or evacuation to remove residual contaminants, followed by odor tests for oxygen cylinders to detect hydrocarbons or ; any , grease, , or free detected via ring tests leads to rejection or cleaning. Valve leak tests are conducted using or solution methods to confirm no leaks at connections, with residual valves checked for proper function using specialized tools. These steps prevent that could affect gas quality or cause reactions, as emphasized in guidelines for gas cylinders. Documentation verification is essential to trace the cylinder's and confirm . This includes checking the against manufacturer certificates, verifying expiration or requalification dates align with standards (e.g., no filling if overdue for periodic testing), and ensuring all markings for capacity, pressure ratings, and previous gas service are legible and authentic. Records of these checks must be maintained in batch production logs, including any rejections. For portable cylinders, pre-filling inspections occur before every fill to account for potential handling damage, while periodic examinations align with the British Compressed Gases Association's (BCGA) 2024 guidance, which updates requirements for competency in testing intervals of 5-10 years based on cylinder design and gas type.

Safety and Regulations

Hazard Mitigation

Gas cylinders pose several inherent risks due to their high-pressure contents, including overpressurization, which can lead to catastrophic shell failure from factors such as high temperatures or physical damage. Leaks from cylinders can result in the escape of hazardous gases, potentially causing fires or explosions, particularly with oxygen leaks that enrich atmospheres and accelerate . Additionally, incompatibilities between gases, such as oxygen and hydrocarbons like or grease, can trigger violent reactions, igniting explosively and causing severe fires or blasts. To mitigate these risks, gas cylinders incorporate built-in safety features like pressure relief valves, rupture discs, and fusible plugs, which activate to vent excess pressure and prevent structural failure. Protective caps or valve guards shield the valve assembly from impacts during handling or storage, reducing the likelihood of unintended releases. Storage practices further address incompatibilities by segregating flammable gases from oxidizers, such as keeping cylinders of hydrogen at least 20 feet away from those containing oxygen to minimize explosion hazards. Human factors play a critical role in hazard prevention, with secure chaining or strapping required to anchor cylinders to fixed structures between the waist and shoulder, preventing falls that could damage valves or cause projectiles. Adequate ventilation in storage areas is essential to disperse any leaked gases, ensuring areas are well-ventilated, dry, and protected from ignition sources to avoid accumulation of flammable vapors. Additionally, safe regulator handling is a key practice to mitigate hazards associated with high-pressure gas release and regulator malfunction: before opening the cylinder valve, the pressure-adjusting screw of the regulator must be backed off (turned counterclockwise) to relieve spring tension and set the delivery pressure to zero. This procedure prevents sudden high-pressure gas from entering a tensioned regulator, reducing the risks of regulator failure, explosion, or injury. The same step is used during shutdown to safely depressurize the system. In the 2020s, the integration of , including IoT-enabled sensors for real-time , has enhanced mitigation efforts by providing early alerts; for example, in operations, AI-driven systems analyzing sensor data for gases like can predict potential explosions up to 30 minutes in advance, lowering the risk of gas-related accidents in certain industrial environments.

Testing Protocols

Gas cylinders undergo periodic testing protocols to ensure structural integrity, detect defects, and verify compliance with safety standards, preventing failures under pressure. These protocols include initial qualification tests during and requalification at specified intervals throughout the cylinder's . The primary methods focus on assessing material strength, wall thickness, and overall durability without compromising the cylinder's usability. Hydrostatic testing is the most common method for metallic cylinders, involving the use of a to measure volumetric expansion under . In this procedure, the cylinder is filled with water, sealed, and pressurized to 5/3 times the service pressure (for common such as 3AA), typically using the Ptest=53×PserviceP_{\text{test}} = \frac{5}{3} \times P_{\text{service}}, where permanent expansion is limited to 10% of total expansion to indicate no significant defects. This detects issues like , cracks, or thinning by comparing pre- and post-test water volumes. For composite cylinders, serves as a non-destructive alternative, employing high-frequency sound waves to evaluate wall thickness, detect , and identify internal flaws without pressurization. This method is particularly suited for fiber-reinforced materials, where traditional hydrostatic tests could damage the structure, and involves scanning the cylinder's exterior to map acoustic reflections for material integrity assessment. Visual inspections complement both types, examining for external damage like dents or , while verifies material properties during requalification if repairs are needed. Requalification intervals vary by material and specification: metallic cylinders typically require testing every 5 to 10 years, with aluminum models at 5 years and certain types eligible for 10 years if marked appropriately. Composite cylinders generally follow shorter 5-year intervals due to their sensitivity to environmental factors, though some standards allow extensions based on condition. Post-incident requalification is mandatory after exposure to , severe impact, or to confirm before reuse. In 2025, the Pipeline and Hazardous Materials Safety Administration (PHMSA) issued advisories emphasizing enhanced inspections for imported cylinders, highlighting risks from non-compliant units lacking proper markings and urging visual and pressure verifications to mitigate hazards from fraudulent imports sold . These updates reinforce the need for rigorous testing to address global vulnerabilities.

Global Standards and Updates

Global standards for gas cylinders are primarily established by international organizations to ensure safety, interoperability, and consistent manufacturing practices. The (ISO) plays a central role, with ISO 9809-1 specifying minimum requirements for the design, construction, and testing of refillable seamless steel gas cylinders made from quenched and tempered steel, applicable to water capacities from 0.5 L to 150 L and tensile strengths up to 1100 MPa. The Model Regulations on the Transport of provide a framework for the safe transport of gases in cylinders, harmonizing requirements for design, filling, and handling across member states. In the United States, the (DOT) enforces regulations under 49 CFR Parts 171-178, mandating specifications for cylinder construction, testing, and marking to prevent hazards during use and transport. In the , the Pressure Equipment Directive (PED) 2014/68/EU, including the Transportable Pressure Equipment Directive (TPED) 2010/35/EU, sets essential safety requirements for design, manufacture, and conformity assessment of pressure receptacles like gas cylinders. National standards build on these international frameworks to address regional needs. In the , the Compressed Gas Association (CGA) develops detailed pamphlets and guidelines, such as CGA C-1 for methods of pressure testing and CGA C-6 for cylinder maintenance, providing practical recommendations for inspection and safe handling. In the , (BS EN) adapt European norms, for example, BS EN 12862:2003 specifying design and construction for refillable welded aluminum alloy gas cylinders, ensuring compliance with PED requirements. Recent updates in 2025 have focused on enhancing oversight and adapting to emerging technologies. In the US, the U.S. House of Representatives passed the Compressed Gas Cylinder Safety and Oversight Improvements Act (H.R. 1182), which, if enacted, would limit approvals for foreign manufacturers of cylinders (FMOCs) to one year, extendable to five years upon demonstrated compliance, and authorize annual inspections of foreign facilities to verify production records and sample testing for imported cylinders. In India, the Gas Cylinders (Third Amendment) Rules, 2025, expand permissible water capacities for cylinders used in compressed hydrogen gas (CHG), compressed natural gas (CNG), nitrogen, and compressed air from 1000 L to up to 3000 L, while introducing stricter standards for valves, regulators, and hydrogen storage to align with international safety norms. For applications, ISO 19880-1:2020 establishes minimum , installation, operation, , and requirements for gaseous fuelling stations, including provisions for compatibility and safety in delivery systems. involves standardized markings and ongoing requalification to maintain integrity. UN-certified cylinders bear markings per ISO 13769, including the UN prefix, test pressure, and manufacturing details, indicating compliance with UN Model Regulations for global transport. Periodic requalification is mandated, typically every 5 to 10 years via or hydrostatic testing, as specified in DOT 49 CFR § 180.205 and equivalent international protocols, to detect degradation and ensure continued safe use. These processes align with testing protocols outlined in preceding standards, emphasizing non-destructive methods where applicable.

Transportation and Identification

Transport Regulations

Transport regulations for gas cylinders vary by mode of transportation and jurisdiction, ensuring safe handling of these pressurized hazardous materials to prevent leaks, ruptures, or explosions during transit. International and regional frameworks govern these rules, building on broader global standards for hazardous materials. For air transport, the International Air Transport Association (IATA) Dangerous Goods Regulations impose strict quantity limits, such as a maximum gross weight of 5 kg per cylinder for medical-use gaseous oxygen or air on passenger aircraft, with liquid oxygen systems prohibited entirely. Cargo aircraft allow higher limits depending on the gas classification, but all shipments require advance coordination and compliance with packing instructions to mitigate risks in confined cabin environments. Road and follows the European Agreement concerning the International Carriage of by Road (ADR), which classifies gas cylinders as UN Class 2 hazardous materials and mandates secure loading to avoid movement during transit. In the United States, the Department of Transportation's 49 CFR regulations under the and Hazardous Materials Administration (PHMSA) similarly require cylinders to be transported upright or horizontally in racks, with valves protected by caps or guards to prevent damage from impacts or vibrations. For sea transport, the International Maritime (IMDG) Code outlines requirements for stowing cylinders in well-ventilated holds, segregated from incompatible cargoes, and secured against shifting in rough seas, with portable tanks and multiple-element gas containers subject to specific stability tests. Across all modes, quantity limits apply, such as prohibitions on exceeding 75 kg net weight per package on passenger aircraft for certain non-flammable gases, to limit potential incident scale. Labeling is a critical , featuring UN diamonds that include the four-digit identifying the gas, such as UN 1013 for , alongside class 2.2 placards for non-flammable, non-toxic gases. These labels must be affixed to packages and vehicles, ensuring emergency responders can quickly identify contents and risks. In 2025, the U.S. enhanced oversight for imported gas cylinders during transit through PHMSA's safety advisory on fraudulent or non-compliant imports and legislative actions like H.R. 1182, which amends approval processes for foreign-manufactured cylinders to bolster inspections and traceability. These updates address rising concerns over unsafe imports entering domestic supply chains, mandating stricter verification at ports and borders.

Color Coding Systems

Color coding systems for gas cylinders provide a standardized visual method to identify the contents and associated hazards at a glance, reducing the of errors in handling, storage, and use. These systems typically apply colors to the cylinder shoulder or body bands, serving as a secondary identification aid alongside labels and markings. The primary purpose is to enable quick recognition of gas types, such as distinguishing oxidizing agents from flammables, thereby preventing dangerous mix-ups during operations. For instance, is commonly used for flammable gases across multiple standards to signal risks immediately. In the United States, the Compressed Gas Association (CGA) outlines recommended color coding in its standard CGA C-9, focusing on shoulder colors for both industrial and cylinders, though it is not federally mandated and varies by supplier. Oxygen cylinders feature a green shoulder to indicate their oxidizing properties, while flammable gases like or use red or maroon shoulders, respectively. For applications, cylinders often have a white body with colored shoulders, such as green for oxygen, to align with healthcare protocols and distinguish them from industrial variants. This voluntary system emphasizes that color alone should not be relied upon for identification due to potential inconsistencies. In the , the EN 1089-3 standard harmonizes color coding, mandating white bodies for all medical gas cylinders and using RAL-specified shoulder colors for content identification. Oxygen shoulders are white (RAL 9010), blue (RAL 5010), and grey (RAL 7037), while hazard-based codes apply to non-medical gases: yellow (RAL 1018) for toxic/corrosive, red (RAL 3000) for flammable, light blue (RAL 5012) for oxidizing, and bright green (RAL 6018) for inert gases. Mixtures use banded or quartered shoulders with multiple colors, ensuring compatibility across member states. In , the specifies color coding under IS 4379 for cylinders, applying ground colors to the body and bands to the or for differentiation. Oxygen cylinders have a (no band), a maroon body, and a with signal red and golden yellow bands, while flammables generally incorporate red elements. For medical use, IS 3933 complements this with valve-end colors, such as white for oxygen. These codes are required under the Gas Cylinders Rules, 2016, but enforcement focuses on licensed manufacturers. In countries following GOST standards, such as Ukraine (e.g., GOST 949), cylinders for compressed methane (стиснений метан) are painted red with white lettering "МЕТАН", consistent with the use of red for flammable gases. Variations exist across regions, particularly for medical cylinders; for example, the uses green shoulders on white bodies for oxygen, differing from the all-white shoulder in the under EN 1089-3. In some areas, like parts of , color coding remains non-mandatory or follows local adaptations of international standards. Limitations include paint fading from exposure to weather or chemicals, which can obscure identification over time, necessitating regular inspections and reliance on permanent labels and markings for primary verification. These systems complement textual markings by providing rapid visual cues without replacing them.

Markings and Labeling

Gas cylinders feature permanent stamp markings to ensure , compliance, and safety throughout their lifecycle. These markings include the manufacturer's identification, such as the name or , stamped in a designated format. A unique is also required, providing an alphanumeric identifier for each to facilitate individual tracking. The initial test date is marked in year/month format, indicating when the cylinder underwent its first . Additionally, the test pressure is specified, often prefixed with "PH" followed by the value in bars, while material specifications denote the or compatibility, such as "H" for hydrogen-compatible steel or DOT-3AA for seamless steel cylinders under U.S. standards. These permanent markings are typically stamped on the cylinder's shoulder or base to withstand handling and environmental exposure without fading. 13769:2018 outlines precise placement guidelines, ensuring visibility and durability for volumes between 0.12 liters and 150 liters. , similar requirements under 49 CFR § 178.37 align with ISO 13769 for UN-approved cylinders, emphasizing legibility for inspectors and users. Temporary labels complement permanent markings by providing current operational details. These labels specify the gas name, fill date, and warnings, including symbols and handling instructions per OSHA/GHS standards. They also include the and pictograms for quick identification of contents and risks. Unlike permanent stamps, these labels are updated with each filling and must remain legible to prevent misuse. In 2025, advancements in smart cylinders incorporate RFID tags as temporary or semi-permanent identifiers, enabling automated tracking of fill dates, inspections, and locations via UHF technology compliant with EPC Gen2/ISO 18000-6C. These tags, designed for metal surfaces with IP67 durability, integrate with IoT systems for real-time data, enhancing efficiency in industries like healthcare and . Regulatory updates, such as India's Gas Cylinders Rules Amendment 2025, mandate permanent QR codes, barcodes, or RFID on fuel cylinders (e.g., CNG, LPG) to prohibit refilling without valid identifiers and ensure digital . These markings and labels support critical for recalls and oversight, particularly under post-2025 import regulations. The U.S. Compressed Gas Cylinder and Oversight Improvements Act of 2025 requires annual approval of foreign manufacturers with public listings and inspections, enabling swift identification and recall of non-compliant cylinders imported under the Tariff Act of 1930. Such systems allow authorities to trace serial numbers and RFID data back to origins, mitigating risks from defective imports. Color coding systems provide supplementary visual aids but rely on these markings for definitive identification.

Configurations and Applications

Standard Sizes

Gas cylinders are available in a range of standard sizes tailored to specific applications, with dimensions and capacities determined by factors such as portability, requirements, and intended use. Common capacities span from 0.5 liters for small portable units, used in applications such as PCP air rifles with cylinders typically 10-15 cm in diameter and 25-45 cm in length handling 200-300 bar, paintball (HPA tanks), portable diving, and industrial or rescue scenarios, to 80 liters for larger industrial models, allowing for varying gas volumes while adhering to safety standards like ISO 9809 or DOT specifications. Portable cylinders, often used in welding and fieldwork, typically feature a 20-liter water capacity at 200 bar working pressure, providing around 4 cubic meters of gas such as argon for shielding in MIG or TIG processes. Industrial cylinders are larger, with a prevalent 50-liter water capacity at 300 bar, suitable for high-volume applications like manufacturing and chemical processing, where they can hold substantial amounts of gases like nitrogen or oxygen. For example, a 40-liter cylinder filled with oxygen at 150 bar yields approximately 6 cubic meters of gas, commonly used in medical and industrial oxygen supply. Medical gas cylinders follow designated size codes, ranging from small aluminum units like M6 (approximately 6 cubic feet capacity) for portable to larger K-size cylinders (about 250 cubic feet) for use, ensuring compatibility with regulators and transport needs. Gas capacities are approximate and depend on the service , gas type, and standard conditions (e.g., 70°F, 1 ). In the United States, regional standards under DOT regulations classify high-pressure cylinders by capacity in cubic feet, with common sizes including Q (80 cubic feet), S (150 cubic feet), R (300 cubic feet), and (330 cubic feet), which correspond to metric equivalents of roughly 40-80 liters capacity depending on ratings. These sizes align with international metric standards but are specified in for domestic compliance. Capacities vary by gas and . Recent trends emphasize miniaturization for portable , particularly in 2025 electric vehicles, where swappable capsules or compact cylinders enable on-the-go refueling and integration into systems for extended range without large onboard tanks. For compressed natural gas (CNG) vehicle applications, procurement parameters beyond basic capacity include physical dimensions such as diameters of 350-400 mm and lengths of 1500-2000 mm, empty weights of 30-50 kg for composite cylinders, test pressure at 1.5 times service pressure (e.g., 5400 psi), cycle life of 15,000-45,000 fills or unlimited for qualified designs, gas capacity specified in gasoline gallon equivalents (GGE) or normal cubic meters (Nm³), and mounting types such as neck or bottom configurations, along with certifications like ISO 11439 and ECE R110.
ApplicationExample SizeWater CapacityPressureGas Content Example
Portable ()Standard 20L20 L200 bar4 m³
IndustrialStandard 50L50 L300 barVaries (e.g., 10-15 m³ N₂)
M6 to 0.3-50 L2015-2400 psi6-250 ft³ O₂
Regional Size~49 L equiv.2400 psi330 ft³

Storage Assemblies and Banks

Storage assemblies, also known as manifolded pods or quads, consist of multiple gas cylinders connected together to provide a continuous and scalable supply of gas for demanding applications. A typical quad assembly groups four cylinders, often of standard sizes such as 50-liter capacity, secured in for stability and equipped with manifolds to link the cylinders' valves to a common outlet. These assemblies are widely used in industrial settings and hospitals to ensure reliable gas delivery without frequent cylinder changes. Larger configurations, referred to as cylinder banks, involve dozens or hundreds of cylinders arranged in batteries, connected via extensive piping networks to form a centralized supply . The design incorporates robust or piping, isolation valves for individual cylinders, non-return valves to prevent , and pressure gauges for monitoring. To achieve pressure equalization, the manifold allows gas to draw evenly from all connected cylinders, balancing depletion and maintaining consistent output until the bank is nearly empty; relief valves are integrated to prevent over-pressurization. This setup enables capacity scaling, where banks of uniform cylinders can deliver gas volumes equivalent to 1000 cubic meters or more at , depending on the number of units and fill . Specialized systems like cascade banks enhance efficiency in filling operations at stations, featuring multiple banks pressurized at graduated levels (e.g., low, medium, high) to sequentially fill target cylinders or vehicles without excessive workload. Tube trailers represent an extension of bank designs, utilizing long, manifolded tube arrays for high-volume gas handling in transportable formats. These systems prioritize through features like earthing connections and vibration-resistant components, ensuring operational integrity under load. In applications, storage assemblies and banks serve as critical backups for medical oxygen in hospitals, where automatic changeover manifolds switch seamlessly between primary and reserve banks to provide uninterrupted flow to patient care areas during peak demand or supply disruptions. For emerging fueling stations, cascade banks integrated with modular cylinder systems support rapid refueling, with designs enabling automated swaps of depleted modules to maintain station uptime; by 2025, such innovations are facilitating expanded deployment of for vehicles.

References

  1. https://en.wikiversity.org/wiki/Filling_Scuba_Cylinders/Cascade_filling
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